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By A. Mykytiuk, I. E. Puddington, W. D. Macleod, F. W. Meadus

"A laboratory-scale continuous procedure for the up-grading of naturally occurring tin ores, based on the principle of spherical agglomeration, is described. High recoveries are indicated. A proposed second stage suggests useful fractionation steps.IntroductionA LABORATORY-SCALE batch process for the upgrading of a tin ore using the principles of spherical agglomeration has already been described (1). This procedure consisted of milling, for about an hour, a precrushed ore with at least 200 per cent water, 0.2 per cent of a reagent such as tall oil (to render the de-sired ore particles hydrophobic) and about 3 per cent of a viscous petroleum oil. The feed material passed an 8-mesh Tyler sieve, and the percentages of re-agents are based on the dry weight of the feed. Du-ring the grinding, the hydrophobic particles transfer into the oil phase to produce coherent semi-solid bodies while the gangue stays preferentially in the aqueous phase. The concentrate can be separated from the gangue easily by a mechanical operation. Using an ore containing about 0.3 -0.5 per cent tin, grades of from 1.5 to 7.0 per cent were obtained by varying the pH of the system. Recoveries fell from about 80 per cent to as low as 50 per cent as the grade in-creased."

Jan 1, 1966

By A. M. King, J. M. Neilsen

"Roughness at varying scales is an important component of the shear strength of discontinuities. Small scale roughness can be assessed in drillcore and through laboratory testing of drillcore derived samples. Large scale roughness, or waviness, also plays an important part in peak shear strength and a number of methods for its incorporation into defect plane strength models are presented.A number of methods for capturing waviness data from exposed faces are reviewed. A method is presented for deriving waviness from downhole televiewer data, which is shown to be significantly more accurate than structural data derived from core logging. The method is based on work undertaken in the highly anisotropic bedded units of the Hamersley Province, Western Australia where televiewer surveys are routinely undertaken. Values of waviness are derived through a review of variation in dip resolved in the direction of the slope face. This method allows design engineers to incorporate large scale roughness in defect plane shear strengths at the design stage.INTRODUCTIONThere are a number of constitutive models currently being applied by rock mechanics practitioners in calculating defect plane shear strength parameters, such as Patton, Barton – Bandis and Hencher [1, 2, 3]. Most of these shear strength determinations are typically undertaken by determining the base or residual friction angle, and applying corrections for small and large scale surface roughness."

Jan 1, 2015

By P. R. Clark, M. D. Gleghorn

"IntroductionAt TransAlta Utilities Corporation's Highvale Mine, located west of Edmonton, Alberta (Fig. I and 2), dragline stripping has proved to be a practical and economical method of overburden removal and future plans have been based upon the continued use of draglines (Fig. 3) as the major stripping equipment (Williams, 1979, Nikols et al., 1986). However, long range planning has shown that the capacity of draglines alone will be exceeded in the early 1990s as mining progresses into deeper overburden cover (Tapics, 1983). Strip ratios will increase from I.3 bank m!/ t of coal in 1985to 4.5 bank m3 / t in 1995. During this period the depth of overburden will increase substantially and the areas to be mined will be characterized by weak soils including glacially displaced overburden. This increased overburden depth in relatively weak soils will make it impractical to _continue side casting by draglines without prestripping in advance. In 1983, a major investigation was initiated to determine what additional overburden removal equipment was appropriate to the Highvale operations, and recognizing the long delivery times of this major equipment. when it would be required. This paper describes studies and tests which were undertaken in 1983 and 1984 to select prestripping methods and equipment for the future operation of the mine.Previous planning studies have shown that with the current burn schedule and with the economies of progressing from low cover to high cover, as has been practiced in the past, overburden volumes will exceed the capacity of the existing draglines in the early 1990s (Fig. 4). These previous studies had placed reliance on (I tandem dragline operation for future overburden removal requirements up to a depth of 45 m throughout the Highvale Mine. New drilling together with the associated geotechnical studies and some detailed planning on the practicality of using tandem draglines, created concerns about their universal application. Even without considering geotechnical conditions there was a depth limitation to tandem dragJines and substantial prestripping would be required to achieve the ultimate depths."

Jan 1, 1987

By H. Fujihara, K. Uesugi, H. Toda, A. Takeuchi, K. Shimizu

"Hydrogen is trapped at a variety of microstructures, for example grain boundaries, dislocations and particles. It is thought that hydrogen trapped at trapping sites is redistributed to the other sites under loading and then brittle fracture occurs with hydrogen accumulation. In order to understand hydrogen embrittlement behavior, it is necessary to investigate the time evolution behavior of hydrogen accumulation at each trap site. In the present study, changes in hydrogen distribution are observed under stress using Kelvin force microscopy (KFM) that can visualize hydrogen concentration distribution on material surface at high resolution. Spot-like hydrogen enriched regions are observed on the surface of a material. In addition, hydrogen depleted regions are observed around those enriched regions, and the appearance of hydrogen trap due to particles existing near the material surface is revealed. On the other hand, hydrogen trapped at grain boundary can be visualized. From in this result, it was suggested that crystallographic factors influence hydrogen accumulation. The relationship between initiation and propagation of intergranular crack and hydrogen accumulation under stress will be discussed.INTRODUCTIONHydrogen present in a metal sometimes has significant effects on various properties. Hydrogen in a metal is trapped at a variety of microstructure, for example dislocations and grain boundaries. Grain boundaries, dislocations and micro pores are the major trap sites in aluminum alloys. Some researchers considered that hydrogen redistribution and accumulation between these trap sites in a material with loading plays an important role in the brittle fracture behavior. In general, in intergranular fracture and quasi-cleavage fracture, the hydrogen trapped at grain boundaries and dislocations contributes to fracture behavior, respectively. Recently some researchers have shown that the ductile fracture in aluminum alloys is resulted from growth and coalescence of hydrogen micro pores. Analysis using first principles calculation indicates that intergranular fracture occurs when hydrogen concentration reaches 20 atom H/nm2ongrain boundary. From this report, it is considered that hydrogen redistributed during deformation accumulates locally in order to cause hydrogen brittle fracture. In order to understand hydrogen embrittlement, it is necessary to investigate the time evolution behavior of hydrogen accumulation at each trap site. In the present study, we evaluate the relationship between hydrogen accumulation behavior and fracture behavior in Al-Zn-Mg based alloys. In-situ observation was made by combining the tensile test with Kelvin force microscope (KFM) that can visualize the hydrogen concentration distribution on the material surface with high resolution. We also investigate the relationship between hydrogen distribution behavior and crystal orientation."

Jan 1, 2018

By W. R. Dodge

THE growth and development of the assay department of the Hollinger Consolidated Gold Mines, Limited, is a similar story to that of the mine itself. As the mine developed and enlarged, so also increased the demands upon this department, necessitating an increase of capacity for fire assaying and a widening of the scope of work to include chemical analysis, metallurgical tests, research, and screen analysis. The yearly total of determinations, taking an average for the past six years, is approximately 350,000. The major portion of this figure represents fire assaying for gold and silver, being approximately 950 fire assays per day. The assay department occupies the ground floor of the administration building and covers approximately 4,000 square feet of floor space. Ready access is had by motor truck and electric railway for the delivery of samples and the removal of crushed rock and rubbish. The combined weight of all sample rejects amounts to about 5,000 lb. per day, which is sent to the mill bins. There are six departments, each occupying a separate room-grinder room, fluxing room, furnace room, parting room, weighing room, and flux-mixing and storage room.

Jan 1, 1931

By Simon C. Dominy

"There are two main issues stemming from Vallée’s (2002) comments on Dominy et al. (2001b). First, he raises the importance of quality assurance/quality control (QA/QC) during resource estimation programs, and second, he indicates that the resolution and understanding of continuity (grade and geological) issues are paramount in the classification of resources. In particular, continuity is critical at the boundary between the Inferred and Indicated Mineral Resource categories. The original contribution agrees with the importance of these points, and the principal author offers the following discussion and clarification. Further comment is also provided on the reporting of grade uncertainty through grade ranges.It is worth remembering that vein-gold deposits (e.g., shear-zone, lode-gold, mesothermal types etc.), particularly those containing coarse gold particles (e.g., >100 µm), generally show large variations in grade and an erratic grade distribution. In most cases, diamond drilling is a good measure of geological continuity (depending on drill spacing), but a poor measure of grade and its distribution. High-nugget effect deposits rank among the most difficult deposit types in terms of producing an accurate and precise resource estimate, and clearly represent a distinct deposit type."

Jan 1, 2002

By L. Gawlik

Since the beginning of the 20th century, coal has been the world?s main source of primary energy. In the last few decades, consumption of coal has gradually decreased in some European countries and elsewhere due to the introduction of other energy sources. Regardless, industry continues to use solid fuels for energy production despite of their association with carbon dioxide emissions (about 7 billion Mg). For global development going forward, it is important to estimate what level of energy consumption can be expected as far into the future as the next few decades. To answer this question, specialized global institutions such as the International Energy Agency, the World Energy Council, the World Coal Institute, the U.S. Energy Information Administration, the International Institute for Applied Systems Analysis, as well as oil companies (BP, Shell), conduct periodic forecasts of world energy consumption. The development of such forecasts is very complex because their reliability is influenced by many factors that are difficult to estimate, such as economic development, population growth, climate change, and public awareness. We are all aware that the global demand for electricity will rise significantly in the coming years as a result of anticipated population growth, industrial development, rising living standards, and the general development of civilization. The world?s mineable resources in 2010 were as follows: coal 665.6 million Mg, brown coal 195.4 billion Mg, oil 163 million Mg, and natural gas 185.5 billion m3. The annual global primary energy demand in 2008 was more than 12 billion toe (12,267 Mtoe). In 2006, electricity production in the world amounted to 18,921 TW?h. The structure of the primary energy mix in TW?h (2006) was as follows: coal 41.0%; natural gas 20.1%; nuclear fuel 14.8%; hydro energy 16.0%; liquid fuels 5.8%; and other renewable energy sources 2.3%. The European Union (EU) is one of the largest coal consumers in the world. In 2010, the EU-27 produced 396.1 million Mg of brown coal, and 132.9 million Mg of hard coal; 188 million Mg of coal was imported from outside the EU. The largest hard coal producers in the EU-27 are Poland, Great Britain, Germany, the Czech Republic, and Spain; major brown coal producers are Germany, Greece, Poland, the Czech Republic, and Hungary. For many years, the Polish energy sector has been based on domestic fuel sources ? hard coal and brown coal. The characteristic feature of the Polish balance of primary energy resources is a very high share of coal ? much higher than the world average. Pursuing the decarbonisation of the Polish economy may jeopardize Poland?s energy security, leading to a significant increase in electricity prices, which would hamper the country?s economic development. Price volatility and supply uncertainty are now the dominant features of the international markets for oil and natural gas. The high share of these fuels in meeting energy needs is the reason for unrest in many countries, including those in the EU. Under these circumstances, coal may become the stabilizing element of EU energy security.

Aug 1, 2013

By Matthew Russell, Bobby Randhawa, Leopoldo Mariscal Samaniego, Jose A. Puente, D. Brosig, Paykan Safe

The La Caridad copper smelter, located in Nacozari, Mexico, have started a multi-year plan to reduce sulfur dioxide and particulate matter emissions into the environment. In 2014 the smelter completed a voluntary plant-wide SO2 process emissions inventory as part of the smelter’s proactive environmental stewardship policy. In turn, this triggered the development of several environmental projects to alleviate these emissions. A strategy consisting of improved capture efficiency of the sources with greatest impact has been followed to maximize cost-effectiveness. The reduction of secondary emissions from the Teniente Converter, as well as of primary and secondary emissions from the Peirce-Smith Converters have been key areas of priority. Additionally, a new system to capture and recover particulate matter from the Anode Refining Furnaces off-gas is also in the process of being implemented. This paper presents an overview of the work developed behind this effort and the smelter’s vision towards a greener future. INTRODUCTION The La Caridad copper smelter is owned and operated by Metalurgica de Cobre S.A. de C.V. (a subsidiary of Grupo Mexico). Currently, the smelter has a production capacity of 300,000 tonnes of anodic copper per year. The smelter is coupled with a 300,000 t/y electrolytic refinery. Other by-products (such as precious metals and sulfuric acid) are also generated as part of an integrated process. The original smelter started operating in 1986 with one Furukawa concentrate dryer, one Outokumpu Flash Smelting Furnace (FSF), two slag cleaning electric furnaces (SCFs), three Peirce-Smith Converters (PSCs), two Anode Refining Furnaces (ARFs) and one casting wheel. In 1997, a plant expansion project was concluded with the installation of one steam dryer, one Modified Teniente Converter (MTC), one additional ARF, one additional casting wheel, and the electrolytic refinery [1]. Over the years, the smelter management has implemented numerous environmental projects to alleviate SO2 and particulate matter (PM) emissions. The smelter process gas handling system captures the process gases from the FSF, MTC, and the three PSCs. The process gases are cleaned and conditioned and sent to the two acid plants. The first acid plant (with a capacity of 226,000 Nm3/h, wet basis) was commissioned in 1988 to process the FSF and PSC off-gases. A second acid plant (with a capacity of 195,000 Nm3/h, wet basis) was commissioned as part of the smelter expansion project [1]. The PSCs also have a secondary gas handling system with a dedicated baghouse and stack. The Furukawa dryer off-gas reports to a dedicated electrostatic precipitator (ESP) for dedusting before venting via a local stack. Process gas from the two SCFs, along with hygiene ventilation from various sources inside the smelter (including matte and slag tapping hoods from the FSF) report to a baghouse-based gas handling system and vent to atmosphere via a local stack. The original ARFs do not have an off-gas handling system, however, each ARF has a post- combustion chamber which naturally vents the process gases to the atmosphere via a dedicated stack.

Jan 1, 2019

By Michael Loken, April Montera

"The process of blending consistent and predictable feed for the roasters is critical to optimizing product quality and controlling production costs. To assist in this process, Online PGNAA Slurry Analyzers have been installed and evaluated at a Sudbury Ontario smelter. They are used to measure 100% of the full process stream to obtain elemental composition data in real time. This paper explains the application details at Sudbury and the benefits achieved from their Full Stream, Elemental Slurry Analyzers.INTRODUCTIONSudbury Integrated Nickel Operations (Sudbury INO), a Glencore Company consists of two underground nickel/copper mines in Sudbury, Nickel Rim South and, Fraser, along with the Strathcona mill and the Sudbury smelter. The facilities are spread throughout the 60 kilometer-long, oval-shaped geological formation known as the Sudbury Basin (Figure 1). The company has been mining nickel-copper ores in the Sudbury area since 1929. Nickel and copper are the primary focus of operations at Nickel Rim South and Fraser. Other base metals such as cobalt and precious metals are also produced."

Jan 1, 2016

By J. Mullins

Coal was first banked by the Dominion Coal Company, Limited, in 1898, near No. 2 Colliery, the same site as is presently used for that purpose. Though today there are banks at Glace Bay, Sydney, and Sydney Mines, these notes, except when otherwise desirable, will be confined to describing the practice as developed at the No. 2 Banking Station, Glace Bay, as being typical of methods obtaining at all sites. Storing The manner in which the coal was piled is illustrated diagrammatically in the accompanying sketch. A train of coal was brought on the main trestle, which extended the full length of the banking ground at a height of 22 to 39 feet above the natural surface, and dumped into bins which were integral with the trestle work. Chutes from these bins permitted the coal to be fed into 3-ton cars, which were horse drawn laterally on narrow gauge tracks laid about 10 ft. centres, to a maximum distance of 400ft. from the trestle. These cars were end-dump and as the pile extended laterally the narrow gauge tracks were lengthened by shorter or longer filling pieces, so that their ends were always kept at the brow of the bank. Much coal, however, had to be dumped directly on the tracks and hand trimmed to fill the valleys, and level off, between the tracks.

Jan 1, 1931

By C. McLachlan, J. R. Donald

"Positioned at the forefront of the seafloor minerals industry, DeepGreen Resources is on track to becoming a leading producer of base and strategic metals obtained from vast high-grade seafloor polymetallic nodule deposits. DeepGreen believes the seafloor minerals industry is an opportunity for developing a more environmentally and societally attractive way to produce cleaner base and strategic metals. Polymetallic nodules contain nickel, manganese, copper, cobalt and other base and strategic metals. Polymetallic nodules represent an exceptional multi-metal-bearing resource, and no current metallurgical operation or flowsheet exists that can recover the primary metallic values while managing the distinct mineralogy. DeepGreen Resources is developing a new process to maximize the business outcomes consistent with the highest environmental standards, including targeting a near zero waste facility. The present paper discusses the history, context and driving forces of polymetallic nodule project development. An overview of DeepGreen?s Nauru Ocean Resources Inc. (NORI) project is presented along with a literature review of polymetallic nodule processing and the on-shore project development scope and plan at DeepGreen Resources is outlined.INTRODUCTION AND CONTEXT Polymetallic Nodules in the Clarion-Clipperton Zone Containing nickel, cobalt, copper and manganese, polymetallic nodules occur in most oceans of the world. The nodules lie on the seafloor sediment. The largest deposit in terms of nodule abundance and metal concentration occurs in the Clarion-Clipperton Zone (CCZ) on vast abyssal plains at a depth of 4,000 to 6,000 metres. The CCZ is located almost entirely in international waters as presented in Figure 1. It has been estimated that the CCZ contains (International Seabed Authority, 2010): •,>21 billion tonnes of nodules; •,>270 million tonnes of nickel; •,>6 billion tonnes of manganese; •,>234 million tonnes of copper; •,>46 million tonnes of cobalt. There are several active hypotheses for the mechanism of formation of the nodules including precipitation, hydrothermal decomposition of basaltic debris, and involvement of microorganisms. Nodules require a nucleus to start forming, which could be a piece of pumice, a shark tooth, old nodule piece, basalt debris or even microfossils like radiolaria and foraminifera. Nodules form concentrically with layers of iron and manganese hydroxides around a core. Although composed mainly of Mn, Fe, silicates and hydroxides, it is the significant content of Ni, Cu, Co, Zn and Rare Earth Elements (REE) that is generating the economic interest in harvesting these deposits. Nodules vary in size from micro-nodules to about 20 cm, the common size being two to eight centimeters. A typical polymetallic nodule and polished cross-section is presented in Figure 2."

Jan 1, 2017

By R. M. Beauchamp

Base metal processing operations often treat process tailings and acid mine drainage using a high density sludge (HDS) water treatment process. Lime is used in this process, which reacts with existing sulfates to form gypsum. When a recycle stream is incorporated in the process, gypsum levels in recirculating water may build up and cause high levels of gypsum supersaturation. Precipitation of gypsum from the supersaturated process water causes many problems. It is speculated that gypsum may precipitate on sulfide minerals and silica gangues in the flotation circuit, resulting in decreased selectivity and recovery. An understanding of the determinants and nature of precipitation may provide solutions to mitigate the formation of precipitates and improve flotation performance. This study showed that both sphalerite and silica exhibited gypsum- or calcium carbonate-like behavior in the respective supersaturated solutions, indicative of a coating of calcium species on the mineral particle surfaces. The addition of copper sulfate and/or potassium xanthate had little effect on the precipitation of gypsum or calcium carbonate on the mineral particles. Sodium carbonate is encouraging as a method to minimize calcium species interactions on sphalerite/silica surfaces.

Jan 1, 2006

By Leonardo F. Trivino

Despite the significant economical and safety implications of poor blasting practice in mining and quarrying operations, the default practice in many large operations, including both design and control, is considerably below standard when compared to other engineering disciplines. Blast dynamics includes a number of complex phenomena, such as the generation, propagation and interaction of stress waves, the expansion of high pressure, high temperature gases from the explosive components, and their combined effects upon the rock mass, including fracturing, fragmentation and displacement. In order to tackle this non-trivial problem, a combined finite and discrete element software (Y-code) capable of accounting for the dynamic behaviour of stress waves, simulating fracturing processes and modeling the expansion of gases is under development. The constitutive models used in this particular software are fundamentally simple, however, non-linearity and chaotic behaviour result as natural consequences of the interaction of relatively simple processes and mechanisms, such as propagation of stress waves in the immediate vicinity of the exploding borehole, and the creation and propagation of fractures. Advances on its development and comparisons with experimental data show realistic propagation of stress waves and fracture networks.

May 1, 2013

By J. K. Gowans

The Research and Design group of the Project Development Division (PDD) of Placer Dome Inc. includes metallurgical, electrical, civil and mechanical engineers. They provide metallurgical research and conceptual flowsheet development, feasibility concepts for the processing and ancillary facilities, and manage the detailed design of the facilities once approval has been given to a mining project. This paper describes how this group works, within the Project Development Division, to help develop feasibility studies with the Evaluations Group, manage detailed design, and provide support for the Construction Group. The paper briefly reviews the history and growth of the group and describes how it is evolving. The role of outside engineering firms and how they are incorporated into the division’s objectives are also discussed. The paper highlights the differences between Placer Dome’s Project Development Division and other mining groups, and why this approach fits the way Placer Dome does business.

Jan 1, 1998

By L. W. Krahenbil

The programmable Logic Controller (PLC), at its present stage of evolution, is now considered as a mature control system. The PLC combines the solid-state reliability of hardwired logic and computer control systems with the simplicity of a relay ladder logic. Relay symbolic programming through a function-oriented keyboard provides a means which plant personnel can easily become accustomed to work with. In a large coal facility, it is shown that the control engineer can provide improved control flexibility with the advanced capabilities of the PLC.

Jan 1, 1979

By T. R. Madhavan

The development of contact angles on highly polished ?uraninite surfaces, using sodium oleate and dodecyl ammonium acetate as collectors, has been studied at different collector and hydrogen ion concentrations. It was found that sodium oleate in acidic media (up to a neutral: PH) and dodecyl ammonium acetate in neutral and alkaline media give good contact angles. It appears that the combined forms of these collectors, viz., oleic acid and free amine, are more important in effecting contact. W ITH the emergence of uranium as a strategic metal in the last fifteen years, considerable effort has been directed toward the commercial recovery of uranium from its ores. This has resulted in the development of a uranium technology. It is only in recent years, However, that fundamental data regarding the floatability and surface properties of uraninite and ?pitchblende have been elucidated by different methods. Contact-angle measurement is one of the important tools for tl1e evaluation of the conditions of floatability

Jan 1, 1964

By J. Groppo, W. Zhang, R. Honaker

"The flotation of monazite is depressed when using hydroxamic acid as a collector in the presence of calcium ions which may exist due to the dissolution of minerals such as calcite. Minor dosages of sodium hexametaphosphate (SHMP) were found to effectively depress calcite, whereas the flotation of monazite was not impaired in single mineral flotation tests. However, in a mixed mineral flotation system, monazite flotation was depressed significantly. The mechanism of hydroxamate adsorption on monazite and calcite, the depression mechanism of calcite on monazite, as well as the depression mechanism of SHMP on calcite and monazite were studied using micro-flotation, electro-kinetic, and adsorption tests. Findings indicate that the adsorption of hydroxamate on monazite was due to chemisorption while adsorption on calcite was a result of physical interaction. SHMP significantly increased the negative charges of calcite surfaces which depressed the adsorption of the hydroxamate anions on the calcite surfaces due to an elevated electrostatic repulsion force. When calcium-rich minerals such as calcite are mixed with monazite, the calcium ions dissolved from the mineral surfaces specifically adsorb onto the phosphate oxygen sites on the monazite mineral surfaces thereby causing depressing effects. The addition of SHMP to suppress collector adsorption on the calcite surfaces interacts with the calcium species that were specifically adsorbed onto the monazite surface, which prevents hydroxamic acid adsorption onto the rare earth oxygen sites due steric hindrance and results in the flotation depression of monazite. INTRODUCTIONAs one of the commercial rare earth ores, monazite has been widely exploited to produce additives for catalysts, batteries, alloys, etc. Because of the complexity and the fine nature of some monazite ores, methods such as gravity, magnetic, and electrostatic separation to treat beach sand monazite fail to produce satisfactory concentrates, suggesting the use of floatation is warranted (Cheng, Holtham, & Tran, 1993). The primary associated minerals of monazite ores include ilmenite, quartz, zircon, rutile, sillimanite (Dixit & Biswas, 1969; Pavez a& Peres, 1994, 1993). Using sodium oleate as collector for monazite has been reported in many studies (Cheng et al., 1993; Dixit & Biswas, 1969; Pavez & Peres, 1994, 1993). Several investigations have reported maximum floatability of monazite occurring at pH values between 8 and 9 (Cheng et al., 1993; Dixit & Biswas, 1969). A study conducted by Pavez and Peres (1994) compared the use of hydroxamate and sodium oleate for the treatment of a monazite ore and found that hydroxamate significantly improved the grade of rougher concentrate."

Jan 1, 2016

By Yihan Liu, Jintao Zhang, Chen Xiao, Xiaomeng Zhao, Guanglei Song

To estimate the performance of the inert anode materials based on NiFe2O4 spinel ceramic during it used for aluminum electrolysis, we investigated the wetting process of cryolite molten salt which is in composition of industrial aluminum electrolysis with carbon anode and NiFe2O4 based cermet materials, by means of determination the interface wetting angle between the molten cryolite electrolyte and the solid anodes interface. The results show that the wetting angle between the electrolyte and carbon anode is larger than 90 angulation, this means that they basically can not wetting; however the nickel ferrate spinel ceramics behaves much better. In regard to the NiFe2O4 matrix materials, their initial wetting angles is 76.9. The initial wetting angles for 1.0wt%MnO2, 2.5wt%TiO2 and 0.5wt%V2O5-doped samples are respectively 56.86°, 52.98° and 51.93°. However, after 50s later, all the wetting angles came down below 15°.

Jan 1, 2015

The recovery of fine hydrophilic gangue in flotation is related to the recovery of water. Water is carried by bubbles as a film and wake into the froth. The amount carried (entrained) depends on bubble size, gas rate and the subject of this paper, frother type. To isolate the effect of frother type from that of bubble size and gas rate, gas holdup is used as the correlating variable. Measurements were made using a bubble column (no solids) operated continuously with the overflow recycled. Continuous operation meant some foam depth was required to ensure only entrained water is recovered. Using an automatically controlled 7cm foam depth the overflow rate of water is used as a measure of 'water carrying rate'. It is shown that the common frothers can be grouped into four families based on the water carrying rate-gas holdup relationship.

Jan 1, 2006

By F. H. Hueston, R. S. Barclay

"Depending on the application, zirconia, fused magnesia and graphite have been found to be the most suitable crucible materials for melting uranium metal and its alloys. Although graphite has been found to be satisfactory for uranium and uranium alloy castings with cross sections of 4 square inches or greater, ceramic-type molds are superior for small sections and those shaped castings which prohibit the economic use of machined graphite molds. Heating cycles, addition mechanisms and furnace conditions for melting are discussed."

Jan 1, 1967