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To date, improved thickening of clay mineral dispersions presents major technological and environmental challenge to mining and mineral processing industry worldwide. Flocculant-assisted dewatering processes currently employed during thickening are far from being efficient, requiring further development and process optimisation for dramatic improvement. In this paper, recent studies carried out to modify (i) pulp chemistry, (ii) flocculation performance and (iii) particle interactions to significantly improve the dewatering behaviour of flocculated, model and plant smectite and kaolinite clay dispersions are presented. It is shown that pulp pH-mediated hydrolyzable metal ion hydrolysis and specific adsorption in tandem with high molecular weight flocculant and shear may synergistically act to significantly enhance the dewaterability of both clay mineral pulps. Furthermore, polymeric flocculant structure type is demonstrated to show clear links with floc shear sensitivity, and hence, flocculation performance and pulp dewaterability. The implications and relevance of the findings plant clay mineral waste tailings thickening operations are drawn.

Jan 1, 2006

By Nural Kuyucak, Bohumil Volesky

"Extensive screening revealed a seaweed (alga) biomass type which in its non-living state possesses a very high cobalt sequestering capacity comparable to that of activated carbon and the ion-exchange resin currently used in the cobalt production process. Performance of the new bio-sorbent material was studied by examining its equilibrium metal uptake isotherms generated under different solution conditions such as initial cobalt concentration pH, temperature, and the presence of selected cations and anions. The rate of cobalt uptake was determined, which is a crucial parameter for recovery process design. Almost all cobalt sorbed can also be desorbed with a solution of CaCI2. The bio-sorbent material can be used repeatedly in the sorption-desorption cobalt concentration process. IntroductionIt has been well documented that certain types of microbial biomass, living or non-living, possess a high potential to sequester and accumulate inorganic ions present in aqueous solutions. Metal concentration by microbial biomass from a solution is termed bio-sorption. This phenomenon is quite complex and includes adsorption of metals onto the surface of a microorganism and/or into the cellular structure in combination with ion-exchange, complexation, and/or micro-precipitation. Bio-sorption is generally considered to be a rapid physical/chemical process. The cell wall structure is porous and allows metal ions, as well as large organic nutrient molecules, to pass freely through. Polysaccharides of the cell wall could provide binding amino, carboxyl, phosphate and sulphate groups. In addition to these functional binding groups, polysaccharides often have ion-exchange properties. Sometimes, bivalent cations, such as Ca2+ or Mg2+, help the formation of ionic bond bridges between the negatively charged cell surfaces and positively charged cations in the solution, Proteins in the cell wall could offer functional groups and also offer peptide bonds to bind ions. Interactions between metal and the cell wall components are responsible for the sequestering of metals by way of bio-sorption. Many metals feature a complex solution chemistry and it is not always possible to determine what ionic species are actually present in the solution. The equilibria involved are dependent on pH, concentration, the anions present and other factors. The transport system for the ions are sometimes dependent on both temperature and energy. Biosorbent material could also be regenerated for multiple reuse."

Jan 1, 1988

By F. Rosenblum, P. Spira

"Self-heating of broken sulphide ore or waste rock underground can lead to ignition and cause serious problems in a mine operation. An extensive study has demonstrated that it is caused by oxidation of certain species of pyrrhotite. Self-heating was found to take place in two stages, first progressing from ambient temperature to 1000C with exothermic formation of elemental sulphur in the presence of moisture and oxygen, and proceeding to a second stage in which the sulphur oxidizes to SO2. Ignition may eventually follow. An apparatus was developed to assess the propensity of sulphide rock to self-heating and the potential for hazardous behaviour. The effect of temperature, time, rock size, and surface treatment with chemicals is presented. On the basis of these results, possible approaches for preventing a runaway reaction are suggested for further investigation.IntroductionThe oxidation of sulphide ore, waste rock or tailings backfill, which may cause hazardous conditions underground through heating, oxygen depletion and, in some cases, fire, is well documented (Farnsworth, 1977; Ninteman, 1978; Rosenblum et al., 1982; Reimers, 1987). The self-heating mechanism, nevertheless, has not been satisfactorily explained. The onset of heating from ambient temperature, in particular, has not drawn the attention of researchers. In the course of a previous study (Rosenblum et al., 1982) aimed at finding a method to assess the hazard from using sulphide tailings as backfill, the authors developed an apparatus to measure self-heating rate under controlled, near ambient conditions. This has since provided decisive information in backfill investigations in the Noranda Group.The test methodology devised for tailings failed to predict self-heating in a broken waste rock known to be active. Upon repeated testing, however, a freshly crushed sample began to exhibit appreciable heating and oxygen uptake (Fig. I). After 14 tests, the self-heating rate reached a plateau of about 4O°C/h and then fell progressively to < 5°C/h after 30 tests. It was hypothesized that weathering in the presence of moisture and oxygen during testing had caused the onset of self-heating. Active tailings, on the other hand, are exposed to natural surface oxidation and need not be weathered to show heating. Based on this finding, a new apparatus was developed capable of simultaneously weathering a sample of rock and monitoring its self-heating behaviour."

Jan 1, 1995

By H. Utsunomiya, J. Su, K. S. Tamimi, S. Yue, M. Sanjari, L. Kestens, A. S. Kabir, R. Petrov

The recrystallization and texture evolution of AZ31 sheets obtained through two stages was investigated at different stages of post-rolling annealing. The specimens were rolled at the temperature of 100? and at a fast speed of 1000m/min and low speed of 15m/min with a reduction of 30% in one pass. The results show thatAZ31B sheets rolled at 15 m/min and 100 °C has fractured for reductions of more than 30% per pass. However, by increasing the rolling speed to 1000 m/min the rollability was improved significantly and the material can be rolled to reductions of more than 70% per pass. The high speed and heavily deformed materials are fully recrystallized even at 100 °C.

Jan 1, 2015

By A. Makinen

There is an increasing trend between increasing consumption of water and the production of metal concentrate. Along with this trend we see that ore grades are declining and getting more complex to concentrate around the world. This will not only complicate processing but also generate new requirements for the management of water and waste streams on mining sites. The mining industry is a large user of water and its water consumption is growing rapidly. The processing of lower quality ores requires greater volumes of water. For these reasons, the need for efficient use of water and water management at mine sites is becoming more urgent. The perception of water in the mining industry has changed from thinking about it only in terms of "water treatment" to actually seeing it as a valuable resource, a resource that needs proper management. This resource management needs to involve various aspects, such as optimizing water usage of the entire mine or concentrator site, minimizing fresh water usage, minimizing or eliminating waste generated in water treatment and implementing practices for water reuse and water recycling. This paper presents trends and new developments relating to waste and water management in the mining industry.

Jan 1, 2015

By C. Liu

Corrosion behavior of the stir zone in a friction stir weld of dissimilar A12024/AZ31 alloys was investigated in the immersion test in distilled water (pH=6) for different times. Microstructures and the distribution of chemical elements were analyzed by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). Due to the difference in the corrosion potentials between A12024 and AZ31, the AZ31 alloy constituent in the stir zone was susceptible to the corrosion attack in the distilled water. The corrosion attack was found to occur in the narrow region of the AZ31 alloy adjoining the A12024 region, where there was a low ratio of anode-to-cathode surface area. The corrosion attack became more severe in the AZ31 alloy regions with increasing immersion time. The A12024 alloy region in the stir zone of the weld was protected by cathodic reactivity due to sacrificial anode AZ31 alloy.

Jan 1, 2007

By Michael Moser, Brighty Dutta, David Dreisinger

"Molybdenum is widely used in the industries as an alloying element in the manufacture of steels and super alloys. The widespread use of the element encourages a growing need to develop extraction processes for recovery from both primary and secondary sources. The Solvay Group has developed a solvent extraction reagent named CYANEX®600 for the recovery of molybdenum from acidic solutions originating from both low grade (e.g. copper solvent extraction raffinates, smelter dusts and slags) and high grade (molybdenite) molybdenum sources. CYANEX®600 is a purified form of CYANEX®272 with the active component bis(2,4,4- trimethylpentyl)phosphinic acid. The extraction behavior of CYANEX®600 towards molybdenum in sulphuric acid medium was evaluated. The uptake of molybdenum increased with the increase in concentration of CYANEX®600. The approximate stoichiometry of the extracted complex was: Mo: CYANEX®600 = 1:2. Efficient back-extraction could be achieved with 0.1 M disodium EDTA and 0.1 M (NH4)2CO3, thus providing the option of recyclability of the extractant. The detailed back-extraction studies are currently under progress to find out the possible option for complete transfer of Mo(VI) to the aqueous phase so that high purity Mo salts could be precipitated from the molybdate solutions.INTRODUCTION Molybdenum (Mo) is one of the world’s valuable metals and is highly sought after by researchers due to its versatile mechanical, thermal, chemical properties. Swedish scientist Carl Wilhelm Scheele demonstrated molybdenite to be a mineral sulfide in 1778. Peter Hjelm successfully isolated dark metal powder from the mineral sulphide and named it as ‘Molybdenum’ in 1782 (Gupta, 1992). Molybdenum is a refractory metal of silver gray appearance and is an important alloying element used in the manufacture of steels and super alloys. Molybdenum compounds are widely used in formulation of catalysts (Gupta, 1992). Molybdenum occurs in nature only in chemical combination with other elements. Several molybdenum bearing minerals have been identified, but the only one of commercial significance is molybdenite (MoS2). As molybdenum is a strategic metal for the industrial sector, its widespread use acts as a factor for depletion of the natural resources. Hence, there is growing need to develop extraction procedures for its recovery from both primary and secondary sources. United States, China, Chile, Canada, Peru, and Mexico are listed as the main producers by the U.S. Geological Survey, 2016 (U.S. Geological Survey, Mineral Commodity Summaries, January 2016)."

Jan 1, 2017

By G. Itoh, S. Fukasawa

The Al-Zn-Mg alloys have been known to be susceptible to stress corrosion cracking (SCC), which is based on intergranular cracking arisen from hydrogen embrittlement (HE). The mechanism of HE has not been fully understood yet. In order to elucidate the mechanism of HE, we need to investigate the behavior of hydrogen in the alloys. In this paper, behavior of hydrogen in an Al-5.8%Zn-2.4Mg alloy was investigated by means of hydrogen microprint technique, a method to visualize location of hydrogen emission from specimen surface as silver particles. One side of the tensile test pieces was electrolytically polished and then covered with photographic emulsion. Hydrogen was pre-introduced into the test pieces from opposite side by cathodic electrolytic charging for 30min. Then, the test pieces were stretched with continuing the charging. After that, the specimen was fixed, rinsed, dried and observed with a scanning electron microscope. As a result, silver particles were observed on some grain boundaries.

Jan 1, 2015

By Shuo Zhang, Wenying Liu

"In dump leaching, the efficiency of metal extraction from ores is strongly influenced by the mechanisms of fluid flow. Particle size distribution acts as a fundamental parameter in the determination of fluid flow properties in packed ore beds. In this study, we investigated the particle size distribution in dump leaching by using image analysis technique. The results showed that the particles in the dump varied from smaller than 2 cm to larger than 200 cm in diameter. P80 was calculated to be 200 cm, which was significantly higher than the historical data used by the operation. P25, P50 and P80 were found to increase non-linearly with increasing depth towards the toe of the dump, suggesting the segregation of fine and coarse particles. The image analysis results were verified by applying the rock fragmentation models. The model with the Swebrec function was found to be in better agreement with the image analysis results. Future research will investigate the effect of particle size distribution on the behaviour of fluid flow.INTRODUCTION Fluid flow plays an essential role in the extraction of valuable metals using heap/dump leaching (Amos et al., 2009). The rates of the chemical leaching reactions and microbial activities determine metal concentrations in the leachates and therefore the efficiency of the metal extraction. The reaction rates are influenced by two fundamental processes: transport phenomenon and reaction kinetics (Bouffard & Dixon, 2001). The transport phenomenon refers to the percolation of fluids through channels and pores in a packed ore bed, which carries lixiviants and reaction products to/from ore surfaces by convection and diffusion. The percolation rate of the leaching solution is determined by the hydraulic conductivity of the packed ore bed, which is a function of the permeability and the degree of saturation (Guzman et al., 2008). Permeability, an intrinsic property of a packed ore bed, is strongly influenced by the particle size distribution of the ore grains (Bouffard & Dixon, 2001). Hence, the objective of this study was to investigate the particle size distribution in dump leaching."

Jan 1, 2017

By Marcel Vallée

"Abstract - Traditionally, the emphasis in ore and reserve inventory has been to provide fairly simple definitions and presentations for reporting to shareholders and the investing public. The recent introduction of the mineral resource category aims to take into account the "part of the deposit that cannot yet be produced or extracted legally and profitably." Recent proposals still place insufficient emphasis on relating resource/reserve reporting definitions more closely to the needs of mining and exploration operators for the estimation and inventory of these basic material assets.In most schemes, significant ambiguities and shortcomings remain. These concern the potential economic interest of resources, the concept of continuity which is fundamental to the estimation of volumes, mass and grades, the objectives of the production feasibility study and the requirements of the geology, engineering and economic appraisals leading to it, and the "availability" of the permits required to start mine development. Up to now, no industry-wide formal consensus has yet been reached for any of these steps, nor for reconciliation between successive statements.A resource/reserve inventory scheme is presented here that is based on ISO 9000 principles and the Australasian system. Explicit criteria and transition points are proposed to define resource and reserve. Similarly, appropriate criteria are proposed to classify the three mineral resource and two ore reserve categories, based on geological and value continuity and on the objectives of the feasibility study. This scheme offers a way to develop ISO 9001 certification of resource/reserve estimation procedures for mining operations and supply exploration companies with an appropriate inventory system, to allow better information for the shareholders and the investing public.Résumé - L’objectif des inventaires des minerais et des réserves est, depuis le début du siècle, de fournir des définitions simples et d’ordre général visant les actionnaires et le public investisseur. L’introduction d’une catégorie de « ressources minérales » fournira un cadre tenant compte de la "portion d’un gisement qui ne peut encore être extraite ou exploitée légalement et à profit." Cependant, les propositions récentes de systèmes d’inventaires ne comportent pas des définitions des ressources et réserves qui tiennent compte suffisamment des besoins des opérateurs en exploitation et en exploration minière.La plupart des systèmes comportent des ambiguïtés et des carences. Citons la susceptibilité d’exploitation commerciale des ressources, la continuité qui est au centre de l’estimation des volumes, masses et teneurs, les objectifs de l’étude de la faisabilité de la mise en production, le niveau requis des travaux de géologie, d’ingénierie et d’économique qui y mènent, ainsi que la disponibilité des permis dont dépend la mise en production. Il n’y a jusqu’à maintenant aucun consensus dans l’industrie sur ces points, ni sur des procédures de réconciliation entre les estimations successives.Le système d’inventaire des ressources/réserves proposé ici s’appuie sur la structure ISO 9000 et le système australien. Des critères et des points tournants explicites sont établis pour définir les ressources et les réserves. De même, les définitions des trois catégories de ressources et deux catégories de réserves, s’apparent sur la continuité de la géologie et des teneurs et sur les objectifs de l’étude de la faisabilité. Ce projet offre une voie pour développer les critères de la certification ISO 9001 pour les opérations minières, tout en fournissant un système approprié d’inventaire aux compagnies d’exploration, pour mieux informer les actionnaires et les investisseurs potentiels."

Jan 1, 1998

By K. Lillkung, J. Kourunen, M. Latva-Kokko

"Carbon-in-leach (CIL) and carbon-in-pulp (CIP) processes utilize activated carbon to adsorb solubilized gold for recovery. Due to carbon attrition and non-ideal carbon management, however, some of the gold is lost in carbon fines and to the solution. The carbon attrition mechanism inside CIL/CIP reactors is mainly abrasion-related. This is critical to gold loss since gold loading takes place predominantly in the outer shell of the carbon particles. Thus fine carbon dust has a relatively high gold content and such a small particle size that it cannot be captured with safety screens. The attrition rate depends on ore and carbon characteristics, but it is always proportional to the mixing power intensity. This rate can be minimized by continuous suspension level measurement and control of agitation speed. In addition, a novel tank bottom structure can significantly reduce the required mixing power input compared to a flat bottom tank. A major challenge in carbon management is infrequent and inaccurate measurement of carbon concentration in the reactors. In order to reduce soluble gold losses by means of improved carbon management, Outotec has been developing a continuous in-situ measurement for carbon concentration that is tolerant to changes in slurry density.INTRODUCTION Cyanide leaching has been utilized since the late 19th century as a standard technology for hydrometallurgical gold production. Since then, gold and silver recovery rates have increased due to technological development, but very similar recovery methods are still being used. The original recovery method was to use zinc precipitation – similar to the Merrill-Crowe process, which is still common for feed materials with low throughput and high silver content. However, in most cases, activated carbon recovery is preferred due to its improved efficiency. The carbon-in-pulp process (CIP) and its modification, carbon-in-leach (CIL), have a lower residual soluble gold level and are not similarly affected by soluble base metals. The main alternative for the use of carbon is ion exchange resins. The principle of resin processes is similar to the CIL/CIP processes, with a different type of adsorbent material. Carbon processes are usually preferred over resin processes due to the significantly higher cost of resin material and the possibility to use simpler, well-established technology with carbon processes."

Jan 1, 2017

By Chris Twigge-Molecey

"Over the last 50 years there has been a dramatic evolution in the metallurgical engineering field in Canada. In the 60s the field was dominated by large American and UK groups, often selling major process and equipment packages. The local content was limited to wrap around facilities and the civil and structural work. The mining and metallurgical companies had strong internal teams to lead these projects. Over the decades and business down cycles the large foreign contractors disappeared or re-structured and the mining companies largely shed their engineering and project management groups. The resulting gap was filled by a cadre of local specialist engineering companies, some of whom have grown to be world leaders in the field. The paper traces this evolution and examines the underlying causes and consequences."

Jan 1, 2015

By Junto Nishiwaki, Shinji Kumai

"Mechanical and physical properties of the impact welded dissimilar metal joints are controlled by joint interface morphology. An intermediate layer (IML) is often formed at the joint interface and this deteriorates the interface quality in some metal combinations. Numerical and experimental studies were performed in order to examine the formation mechanism of the wavy interface and intermediate layer for explosive welded Al/Cu dissimilar metal joints. The impact welding process consists of (1) high-speed oblique collision of metal plates, (2) metal jet emission and large deformation and temperature increase at collision point and (3) rapid cooling at the joint interface. Euler-Lagrange coupling method, smooth particle hydrodynamic (SPH) method and modified laplacianFoam (LF) method were linked together to simulate a series of processes from (1) to (3), and the final interface morphology including the formation of IML was reproduced. The wavy morphology (wave-height, wavelength) and the position and composition of IML formed at the joint interface of Al/Cu joints were quantitatively in good agreement with those reproduced by numerical analysis. Our simulation results are useful for the control of the interface morphology, reduction of the amount of IML, and improvement of the mechanical properties of the impact welded dissimilar metal joints.INTRODUCTIONImpact welding is a kind of solid state joining method providing extremely high joint strength for both similar-and dissimilar metal combinations. Explosive welding and magnetic pulse welding are representative methods to achieve the impact welding. By a high-speed oblique collision between two metal plates, a metal jet is emitted from the collision point. The metal jet can remove any oxide films and contaminations on the plates and produce an active refreshed surface. Consequently, good metallurgical bonding can be achieved even for dissimilar metals (Crossland, 1982). Solid metals deform like fluids under the high pressure condition at the collision point and characteristic wavy interface is formed. In addition to the wavy interface, an intermediate layer (IML) is often formed at the joint interface in some metal combinations. Elimination or reduction of the amount of IML at the joint interface is desired since the excessive IML formation along the joint interface causes a large reduction in physical and mechanical properties. Formation of IML is considered to result from characteristic thermal history at the joint interface including partial melting due to the local temperature increase and successive rapid cooling behavior at the joint interface. In order to control the IML formation at the joint interface, it is necessary to reveal both heating and cooling processes at the joint interface. However, it is impossible to observe the phenomenon occurring at the joint interface and also difficult to investigate the temperature change at the joint interface directly during the impact welding. Therefore, simulation or numerical analysis is indispensable to overcome this problem. In the present study, the explosive welded Al/Cu joint, which is prone to form IML at the joint interface, was selected for the research. By using a newly developed numerical analysis method, not only the formation process of wavy interface, but also the local temperature increase and successive temperature decrease at the joint interface were reproduced. The formation process of IML was investigated by using both numerical analytic and experimental results."

Jan 1, 2018

By Seong-Ho Ha, Shae K. Kim, Young-Ok Yoon

In the this study, surface segregation of Mg and Ca with Mg addition range from 5 to 10wt% in Al-Mg alloys with Mg+Al2Ca master alloy and its effect on the oxidation resistance were investigated. The addition of Mg+Al2Ca master alloy as the Mg alloying element led to the surface enrichment of Mg and Ca during high temperature oxidation. As a result of the oxidation test by TGA, the oxidation resistance of all the examined alloys was significantly improved with increasing Al2Ca content. The weight change of Al2Ca added Al-5Mg and Al-7.5Mg alloys indicated the complete oxidation resistance during the whole oxidation test time, while a slight weight increase was shown in the case of Al-Mg alloys even with Al2Ca addition. The improvement of the oxidation resistance in Al2Ca added alloys may be attributed to the formation of the protective oxide layer mixed with CaO and MgO on the surface.

Jan 1, 2015

By Haibin Ma, Jie Song, Qingyou Han, Xiaoming Wang, Wei Vian

In the grain refinement of aluminum, Al3Ti and TiB2 particles are introduced to reduce the casting grain size down to 200 micrometer level, which makes cold working possible. The particles are brought in by the addition of Al-Ti-B type master alloys. It is generally believed that TiB2 particles are stable and nucleate a-Al grains in solidification in the presence of extra titanium than the stoichiometry of TiB2 from the dissolution of Al3Ti particle in the master alloys. Titanium in solution either form Al3Ti layers on the surface of TiB2 particles or as solute to promote the nucleation and to restrict the growth of a-Al grains. However, a consensus on a grain refinement mechanism is still to be reached due to the lack of direct observation. This paper presents finding on the TiB2/Al3Ti interfaces in an aluminum matrix. It demonstrates a strong epitaxial growth of Al3Ti on the surface of TiB2 particles, a sign of the formation of an Al3Ti layer on the surface of TiB2 particles in grain refinement practice. The Al3Ti layer has a crystal coherency with a-Al and hence offers a substrate for heterogeneous nucleation of a-Al grains.

Jan 1, 2015

By G. Granata, C. Tokoro, M. Matsuoka, K. Horiuchi

"Given the high demand of copper and the lack of new high-grade deposits, low grade copper ores containing copper oxides and refractory sulfides need to be processed as well. However, in order to recover copper from refractory copper ores, the leaching performances should be improved. In this study, we investigated the effect of the mechanical activation in the leaching of copper from covellite. The influence of a mechanical treatment by planetary ball milling on leaching rate in sulfuric leaching media was evaluated by using X-ray diffraction (XRD), mineral liberation analysis (MLA) and X-ray absorption fine structure (XAFS). Results showed a significant increase in copper leaching from around 50%up to 100% along with an improvement of the leaching kinetics when using planetary ball milling. XRD spectra showed the disappearance of the covellite peak from (101) face, thus suggesting the amorphization of covellite associated with the use of planetary ball milling. XAFS results showed that the coordination number of Cu changed from 6 to 3, thereby confirming the effectiveness of the mechanochemical effect.INTRODUCTIONDuring the last decades, while the copper grade in copper ores has been decreasing, the concentration of impurities such as arsenic tends to increase, thus requiring for the processing of low grade copper ores. For a suitable processing of copper minerals, hydrometallurgical processes are preferable due to the lower costs, the lower environmental impact and the easier implementation (Watling, 2006). However, for an economical recovery of copper, the leaching performances must be improved.Among the recent advancements in leaching technologies, the mechanochemical activation allows for an improvement of the leaching performances by means of high-intensity grinding(Mohammadabad et al., 2016). In the first place, the improvement is the result of the dramatic decrease of particle size, which results in an increase of the mineral surface area and the consequent enhancement of leaching kinetics. Furthermore, the intense mechanical stress due to the high-intensity grinding could induce the rupture of the crystal structure producing a decrease of crystallinity. Such changes of the mineralogical structure, also known as mechanochemical effect, can lead to more leachable mineral, thereby resulting in a greater dissolution of copper. Last but not least, whereas the mineral surface might undergo passivation during leaching, the high-intensity grinding can continuously refresh the surface of the mineral, thus exposing portions of unleached bulk mineral."

Jan 1, 2017

By John Lund

INTRODUCTION GOLD-BEARING placers of Alaska and the Yukon Territories are buried under a layer of permanently frozen alluvial overburden, or &apos;muck&apos;, which varies in depth from twenty to one hundred feet. The placers, and the decomposed bedrock layers upon which they are deposited, are also permanently frozen. During the summer, surface muck which is exposed to the sun will thaw, but only to a depth of a few feet. To reach a valuable deposit, the frozen overburden must be either penetrated with shafts, or stripped from the deposit entirely. In either case, before the placer can be mined, it must be thawed. At modern dredging operations, the frozen muck is stripped from the placer by powerful jets of water from hydraulic giants. The placer, and several feet of decomposed bed-rock, are then thawed by forcing water through narrow pipes which have been driven into the deposit. Other methods of thawing frozen placers were used extensively during the early years of the Klondike &apos;gold rush&apos;, but experimentation later proved that creek water at its natural summer temperature was a more effective and economical thawing medium than any other which had been used. EVOLUTION OF COLD WATER THAWING Early prospectors of the far north reached placers by digging shafts through the frozen muck. They then thawed the placer sand and gravel by building wood fires at the bottom of the shafts.

Jan 1, 1951

By Joo Hyun Park, Hyun-Sik Park

"Gold is one of the most valuable and precious metals. But, the extraction efficiency of gold from natural resources is very low and labor-intensive due to very low concentration of gold, i.e.,1–5 ppm, which means that gold extraction processes produce extensive amounts of tailings. The gold content in printed circuit boards (PCB) from waste mobile phones is about 100 to 400 ppm, which is enormously greater than the concentration found in natural ores. Consequently, processes for recycling waste PCB and gold mine tailings become of increasing importance to maintain a sustainable society. As processing these waste materials by pyrometallurgical methods has become more economically attractive, understanding the thermodynamic behavior of gold in smelting slags under oxidizing and reducing conditions has become increasingly important. Therefore, in this study, the effects of slag chemistry, oxygen potential and temperature on gold solubility in smelting slags are discussed. From the results presented, the predominant species of gold is strongly dependent on the basicity of slag. Furthermore, more basic slags showed higher solubility of gold at a given oxygen partial pressure, and more oxidizing atmospheres enhanced the dissolution of gold to the molten slag phase. As a consequence, careful control of the slag composition during pyro-processing of gold-containing waste materials is required to maximize gold recovery. INTRODUCTIONGold has good physicochemical properties. Thus, it plays an increasingly important role in industrial applications. For example, over 300 tons of gold are used annually in electronic components (Hageluken &Corti, 2010).However, 75% of all gold ever produced has been extracted since 1910 and gold reserves in the world are becoming rapidly depleted (Louis & Pluchery, 2012).The cost of gold production and its price in the market have increased rapidly during last 20 years as shown in Figure 1, and interest in the recycling of gold-containing materials has naturally increased.The wastes from electronic equipment (e-wastes) contain large amounts of precious metals compared to their own respective ores, and therefore such wastes may be considered as a secondary source of valuable metals. For instance, the concentration of gold in natural ore is commonly 0.5–15 g/ton-ore (0.5–15 ppm), while its concentration in electronic circuit boards is over 10 times higher, typically being about 150 ppm in expansion cards and over 10,000 ppm in central processing units(Barbieri et al., 2010).Also, gold mine tailings are discharged after the flotation process as slurry form then stored near the operating plants (approx. 100 ton per day in one Korean gold mine). Gold mine tailings contain gold at about 1–2 g/ton. This is the reason why Au-containing materials such as e-wastes and mining wastes are highly important sources of gold (Yamasue et al., 2009)."

Jan 1, 2017

By Hämäläinen M., O. Hyvärinen, E. Jääskeläinen

HydroCopperTM is a new hydrometallurgical process for the treatment of copper sulphide concentrates, which has been developed by Outokumpu. The process includes chloride leaching of copper concentrate, solution purification and precipitation of copper(I) oxide, an intermediate product, which is reduced and cast into copper products. The reduction can be carried out by pyrometallurgical methods or hydrometallurgically in an autoclave. This paper discusses the thermodynamic and kinetic aspects of the hydrogen reduction of copper(I) oxide in an autoclave. The results of the laboratory tests are presented and discussed. Finally, the autoclave method is compared with other options.

Jan 1, 2004

By Si Qin

Unknown goafs and roadways of abandoned coalmines can be a great water inrush hazard for coalmine workers. Consequently, advance detection of such hazards is of great importance. By detonating seismic charges in underground coal seams, we can collect seismic data using a surface survey line, which is located across the ground projection of the underground shot point. This experiment was conducted in a coalmine in Shaanxi Province, China. After surface elevation compensation and travel time adjustments, we accurately determined the position of the goaf boundary along the survey line based on the wave velocity anomaly on the seismic record. Then we used a scattered wave imaging technique to enhance the energy of the scattered waves that are generated when the coal seam roof slide wave (refracted wave when the incident angle bigger than the critical angle) hits the roadway, thus confirming location of a geological discontinuity (roadway). This experiment shows that the coalmine ground seismic method, employing an underground explosive charge and a surface seismic array, has the ability to detect an abandoned roadway and goaf in advance of coal mining, thus can improve worker safety.

Aug 1, 2013