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By C. Schmidt, M. Kohnk, C. Siemers, J. Kiese

The application of conventional titanium alloys is limited to 550°C due to their poor oxidation resistance. In addition, severe grain growth is observed in single-phase titanium alloys in long-term runs at elevated temperature leading to a degradation of their mechanical properties. In exhaust applications in automotive or aerospace engineering, products are often manufactured by cold-deformation like deep-drawing or rolling which is normally difficult in oxidation-resistant titanium alloys due to the presence of titanium-silicides. Therefore, in the current study, titanium alloys based on CP Titanium Grade 1S (soft grade) were developed showing (1) improved oxidation resistance due to a concerted addition of silicon, iron and niobium, (2) microstructure stability by the precipitation of hafnium-silicides mainly on the grain boundaries and (3) good cold-deformation properties. The industrial production route was developed so that the new class of Ti-Si-Fe-Nb-Hf-alloys is now ready for application in exhaust systems of planes or cars at minimum 800°C.

Jan 1, 2015

By BRIAN HITCHON

Calcium, magnesium, bromide and iodide extraction from formation waters for use as industrial minerals has occurred in several countries, but not yet in Canada. Potential commercial brine fields exist in th e Upper Devonian Beaverhill Lake Formation of so uthern Alberta, and the Middle Devonian Elk Point Subgroup of north-central Alberta, f rom which calcium, magnesium and bromide are potential products. Iodide contents in fo rmation waters f rom the Upper Cretaceous Belly River Formation and the Lower Cretaceous Viking and Bow Island fo rmations in central and southern Alberta are at the lower range limit of commercial iodide-bearing formation waters elsewhere in the world. Available information is insufficient 10 outline potentially commercial areas in Alberta, but such info rmation can be most easily obtained f rom test borings for shallow natural gas. Lithium is not now produced commercially f rom formation waters but its content should be monitored in view of f uture increased demand for this metal.

Jan 1, 1984

Iron control and iron residue management and disposal are significant issues in all zinc production processes. This paper briefly reviews the most important primary zinc production routes and discusses the challenges posed by iron control in each of them. The technologies and strategies that have proven successful in controlling and managing iron are discussed. SNC-Lavalin's experience in designing and commissioning zinc plants provides a unique perspective from which to review this aspect of zinc production.

Jan 1, 2006

By Michael L. Free, Shukla. Abhijeet

The short-circuiting tendency of a copper electrowinning cell (EW) based on the roughness of cathode deposits was investigated with varying parameters such as Cu concentration, guar concentration, current density, and temperature. A bench scale EW cell was set up to produce copper under conditions similar to industrial Cu EW. In addition, a statistical analysis and finite element analysis were performed to analyze the deposited thickness, surface roughness and maximum feature height. Interaction data for the cathode deposits suggest that current density and Cu concentration together affect the roughness of deposit more than the combined effect of guar and temperature. Model predictions of roughness were similar to experimental values. The predicted time to short-circuiting was similar to the measured time. This study provides an industrial relevant baseline against which new operating parameters can be compared.

Jan 1, 2014

By E. L. Bruce

Red lake is a body of water some thirty miles in length lying about forty miles northwest of the outlet of Lac Seul. It forms one of several large lake expansions on a river which enters the English river from the north, twenty miles below Lac Seul. Before the construction of the National Transcontinental railway a long canoe journey was necessary to reach that part of the English river, and Red lake, two days travel beyond, was one of the furthest outposts of the trading companies in that difficultly accessible triangle of country between Lake Winnipeg, James Bay and the English and Albany rivers. The Hudson's Bay Company post at Red lake is said to be one of the earliest established in the district but there are no records at the post, and as the English and Albany rivers never were used to any great extent as travel routes there is no mention of the place in the diaries of any of the early explorers. Dr. Bell passed through Red lake on his excursion to the Berens river country in 1883, and a brief note mentions that Huronian rocks were seen. To Dr. Dowling, however, belongs the credit for the first thorough description of this basin of sediments and basic volcanics. In 1893 he followed the course of Dr. Bell's trip, of ten years previous, through Red lake to the upper part of the Berens river.

Jan 1, 1926

By D. E. Deegan, G. Holcroft, T. P. Johnson

"The rising cost of extracting metals from existing traditional deposits, increasingly stringent environmental regulations and a greater awareness of corporate social responsibility issues are all factors in stimulating the examination of mine tailings and small-scale alluvial deposits as a potential source of new raw materials. Furthermore, despite tougher economic times the demand for commodities remains strong, in no small part as a result of the growth of the world’s emerging economies.This combination of social and economic factors looks set to continue in the long term which will encourage greater recovery of materials from previously ignored sources such as mine tailings and ores from alluvial deposits.An expansion in the recovery of useful materials from mining-related activities is likely to require the use of robust and innovative techniques that have a built-in degree of future-proofing; DC plasma technology is one such technology.As a result of its ability to separate the valuable metal and minerals from the waste material while destroying hazardous compounds, Tetronics’ DC arc technology offers an alternative approach to resource recovery from a wide range of mine ores. Harmful cyanide compounds and the vast quantities of water used in conventional hydrometallurgical processing are avoided when plasma processing is adopted. DC arc technology also brings additional benefits, including: the extremely effective destruction of organic materials, the conversion of the inorganic material into a re-useable aggregate and the high tolerance of the process to fine and dusty materials. This paper presents details of Tetronics’ DC arc technology as one of the key pyro-metallurgical solutions available for the recovery of valuable materials from traditional mine ores and tailings, as well as giving specific examples of how the technology has been successfully employed in the recovery of enriched slags, ferroalloys and other metals."

Jan 1, 2016

By Erik Spiller

"Water and cyanide are highly contentious and conflict issues that many gold mining companies encounter worldwide when dealing with local farming communities, industries and cities competing for water as well as non-government and government organizations. Historically, the gold industry has used processes that required minimum amounts of water to treat and recover gold at locations around the world. Examples are dry grinding for refractory gold treatment in the late 1800s and early 1900s and dry blowing in arid/desert regions to recover alluvial gold. In recent times, new dry processing equipment has been developed and include equipment such as air tables and jigs. Researchers have also modified a Knelson concentrator to concentrate gold from dry solids. High pressure grinding rolls (HPGR) with air classifiers are used to treat industrial minerals and pilot trials have shown that the technology can be applied to comminute refractory gold ores ahead of roasting. Dry stacked tailings is being applied on gold mines to reduce overall water consumption This paper will review the available technologies that in combination may be able to substantially reduce the quantity of water used in the processing of gold ores.INTRODUCTION Water makes up most of the world: the planet is 75% water. Some 97.5% is saline water largely in the oceans, so that only 2.5% is fresh water and useful for human needs. The demand for water is driven primarily by population and concomitant economic growth. Overall, some 70% of the water withdrawn from the environment is used in agriculture, 20% by industry, 7% by households and 3% for mining (Brown, 2003: Maupin et al., 2010). Whilst the water needs of the mining industry are minor compared to those of agriculture, an operating mine requires a relatively large quantity of water on a daily basis to carry out operations. Mining activities are often located in remote, arid environments, with limited access to water. There are a multitude of water resources available to the mining industry for its needs. However, much of this water is saline and over the last two decades there has been a continual decline in water quality (i.e. salinity has increased). In today‘s world, there are enormous internal and external pressures to reduce water consumption at a mine, and/or alternatively use water not considered a resource by the local community. Strategies to meet these objectives can be achieved by implementing good water management practices, by recycling process water, reducing water losses by evaporation and seepage (i.e. by increasing and improving dewatering practices) and employing new technologies such as dry stacking and dry processing (Dunne, 2010)."

Jan 1, 2017

Current AG and SAG mill circuits have continued the trend to larger, fewer mills. These large mills place a significant additional load on the discharge systems and it has become imperative that the designs of these mill discharge systems are evaluated carefully to ensure maximum efficiency and have the capacity to be able to handle the increased mill discharge volumes. The current generation of multiphysics modeling tools allow a detailed analysis of AG and SAG mill discharge performance. The combination of Discrete Element Method modeling and Computational Fluid Dynamics allows the designer to model in detail all aspects of a mill discharge performance. This includes a detailed description of the build-up of solids and slurry in a mill discharge, the recycle of material back into the mill through the grates, the relative wear rates and the occurrence of overloading at the pinch points. These tools allow intelligent decisions to be made regarding the type of discharge arrangement, pan lifter geometry, and discharge cone design, so as to ensure that the discharge is capable of handling the duties required for a specific installation. This paper details the current state of the art in these modeling tools, and provides an overview of some recent applications.

Jan 1, 2012

By I. Thobadi, C. Pawlik, K. Bisaka, S. Mokoena, M. Erwee

The PyEarth™ process developed at Mintek has been demonstrated successfully at pilot scale. Nine tons of ore containing 2.3 mass % of total rare earth oxides (TREO) from a dormant mineralogically complex iron-rich ore deposit, was subjected to a concentrating smelting step in a 200 kW DC open-arc pilot furnace and the rare earths from the resulting slag were extracted via a hydrometallurgical route. This ore deposit is practically not amenable to extraction by conventional methods. The testwork results proved that the PyEarth™ process was able to optimize the extraction of rare earths while minimizing waste through the removal of iron as a saleable iron alloy. Reduction of iron to the alloy in the smelting step was found flexible, efficient, and controllable, while rare earths were left virtually unreduced in the slag phase. The slag chemistry is selected to optimize both the smelting and leaching performances as well as the alloy composition. Leaching of the resulting slag was found possible and most efficient in hydrochloric acid amongst other lixiviants tested.

Jan 1, 2017

By J. C. Loretto, H. A. Simons

The paper discusses how, in the routine testing of ores, insufficient communication between the laboratory and the design personnel can lead to misunderstanding or misinterpretation of test results and consequent design errors. A number of examples are given together with suggested modified interpretations and the resulting dollar savings indicated by these new interpretations.

Jan 1, 1972

By J. Jung, W. Keller, A. Zucht

"The agitator design for nickel high pressure acid leach autoclaves (HPAL) is critical with regard to the process result, i.e., the recovery rate. Further considerations during the design phase are the avoidance of acid hot spots which reduce the lifetime, due to corrosion of the wetted parts, including components manufactured from titanium. Besides the process knowledge to design HPAL autoclaves, tools such as, Computational Fluid Dynamics (CFD) supplemented by lab testing allow the design of optimized agitation systems. This paper describes the effect that different feed point locations have on instantaneous blending of the reactants. Furthermore, experiments and CFD show where abrasion issues might occur and how to obtain information about the static and dynamic forces acting on internals. We show how simulations can be validated by lab testing to ensure that the CFD models are applied in an appropriate way.INTRODUCTIONAgitated systems in hydrometallurgical processes have to comply with multiple process tasks and in many cases have to withstand extreme operation conditions such as pressure up to 50 bar, elevated temperatures of up to 250°C and exposure to very acidic or alkaline environments and abrasive ores. The process tasks range from instantaneous mixing of reactants, homogeneous suspensions of up to 65% wt. solids with coarse and heavy particles, enhancing the solid-liquid mass transfer for leaching, dispersing large volumes of reactants (gas-liquid, liquid-liquid mass transfer) and moreover to transport generated heat e.g., from exothermic reactions through the vessel walls or internal heat exchangers if required. For economies of scale, agitator systems have reached sizes of 5000 m³ for large open leach tanks with impeller diameters of approx. 6 m, while autoclaves nowadays have exceeded 5.5 meters in diameter with a power demand for a single compartment drive between 300 - 400 kW. In parallel all process industries require a more efficient use of resources, to generate less by-products and higher yields, while ore-bodies tend to be less qualitative and new process routes (e.g. direct leach) are developed. Besides all these facts the mixing solution must be robust and economic. In this paper we want to address our approach in the development and designing of HPAL agitation equipment."

Jan 1, 2012

By J. Girard, V. Aubé, M. Barakate, S. Bellec, M. R. Eddahabi, Y. Chaik, M. Deshaies

"The activated carbon used in the carbon-in-leach (CIL) process to absorb gold is subject to breakage. This carbon breakage can be minimized, but it will always be necessary to deal with fine carbon particles, known as carbon fines. These fines contain a significant amount of gold and mining operations generally struggle with the treatment of this product. Since IAMGOLD’s Essakane mine is located in Burkina Faso, shipping carbon fines out of the country was not considered a viable solution due to the logistical burden and legal procedures in place. A benchmarking study demonstrated the complexity of treating carbon fines on site. IAMGOLD partnered with the host government to find an innovative approach to economically recover the gold locked in these fines. This paper describes the new circuits commissioned in July 2016 built to improve carbon fines collection, incinerate the carbon fines and leach the gold in the ashes produced by incineration. These new circuits successfully demonstrate that it is possible to extract more than 94% of the gold content in the carbon fines. This is profitable for the company as it improves the overall mill recovery rate by 1.0% to 1.5% and significantly decreases gold inventory build-up on site.INTRODUCTION The activated carbon used in the carbon-in-leach (CIL) to absorb gold is subject to breakage. This breakage can occur in the CIL tanks, the stripping circuit, the regeneration process or anywhere throughout the pumping and handling processes of carbon through the circuit. Fine carbon particles are invariably created and, because of their small size, present a large specific surface which favors gold absorption (Hilsher et al., 2014). At the very beginning of operations at Essakane, the carbon fines were recovered by means of a thickener and a filter press, but the circuit was undersized and inefficient. Subsequently, a decantation basin was used to settle the fines before the thickener. The settled fines were shovelled from the basin into bags. All these bags were stored in the backyard of the plant. The average tonnage of carbon fines recovered monthly was 23.5 tons with a gold grade at 1938 g/t."

Jan 1, 2017

By S. Kashani-Nejad

The kinetics of the thermal decomposition of samples of Mg2(OH)3Cl.2H2O that were obtained by a novel leaching technique applied to a commercial magnesium electrolysis feed were investigated under ambient atmosphere. Thermogravimetric (TG) Analysis showed that decomposition of Mg2(OH)3Cl.2H2O exhibited a single intermediate stage wherein crystalline water was lost at roughly 108 °C. Conversion of the resulting Mg2(OH)3Cl to MgO, HCl and 1120 occurred at temperatures above 398 °C. Thermal decomposition of anhydrous Mg2(OH)3Cl was seen to be consist of two stages. Both stages exhibit first order kinetics with respect to the weight percent of Mg2(OH)3Cl remaining in the sample. However, the rates of decomposition in the two stages were significantly different. Detailed analysis of the kinetic data suggested that the rate of decomposition of Mg2(OH)3C1 was controlled by the rate of removal of the gases released. The change in decomposition rate during the course of the experiments was explained by HCI being released in stage 1 and followed by release of H2O in stage 2.

Jan 1, 2004

By Katsutoshi Saibara

Network communication note is a cloud system for an earthwork project. It enables backhoe operators and dump truck drivers to monitor their own works in progress currently and performed up to the present, and to have opportunity to reflect on their own bearings in the earthwork operations, and then could increase their situational awareness to the actual work conditions. First, this paper presents problems and purpose. Secondly, the configuration of the network communication note is reported. Thirdly, examples of communications enhanced by the network communication note are shown. Finally, remarks are described.

Aug 1, 2013

By L Tafaghodi Khajavi, M. Barati

The distribution of phosphorus between solid silicon and iron-silicon melt was determined to investigate the degree of phosphorus removal from silicon by solvent refining with iron-silicon alloys. The distribution coefficient which is the ratio of the mole fraction of phosphorus in solid to that of liquid is as follows: 0.22±0.02 (1310°C), 0.29±0.02 (1260°C) and 0.33±0.02 (1210°C). The removal percentage of phosphorus is: 84.2% (1310°C), 72.5% (1260°C), and 63.7% (1210°C). The average phosphorus content of produced silicon in the proposed solvent refining process would be over two times less than that of the conventional directional solidification. The values of interaction coefficient of phosphorus on iron at different temperatures were obtained as -3460±155 (1310°C), -3595±159 (1260°C) and -3694±119 (1210°C). Self interaction parameter of phosphorus at different temperatures are as follows: 68±4 (1310 ?C), 78±10 (1260 ?C) and 103±19 (1210 ?C). The calculated values for distribution coefficient of phosphorus at infinite dilution are: 0.22±0.00 (1310°C), 0.30±0.00 (1260°C) and 0.34±0.00 (1210 °C).

Jan 1, 2015

By I. Farr, M. R. Mock, J. C. Robison

"HPAL and POX autoclave vapor-space gasses are vented through an autoclave PCV (Pressure Control Valve). The downstream steam-born mist of liquid droplets and solid particles travels in excess of 1000 m/s with megawatts of kinetic power at temperatures up to 160 C. The characteristics of downstream states often result in problems with corrosion, erosion, noise and vibration. Comprehension of those and related characteristics aids in improved pressure control, overpressure control and autoclave level control. We introduce compressible multiphase flow concepts and constructs germane to such flow including choked flow, continuous phase change, shock waves and supersonic flow plumes. Flow modeling based on first principles quantitatively predicts such flows providing a tool for component sizing and a method to estimate effects of water injection on flow. Insight deduced from modeling aids in mitigation of afore mentioned problems of which we share some from-site examples.INTRODUCTION First principles related to fluid thermodynamics and compressible flow have been employed akin to their application in the rocket industry. We will present the results of the application of those principles conceptually and authentically without mathematical rigour while using language of the pertinent disciplines. The autoclave (AC) vapor space over the slurry of a POX (Pressure Oxidation) or HPAL (High-Pressure Acid Leach) system (depicted in Figure 1) is vented via a PCV (pressure control valve) followed by certain ducting, and perhaps a nozzle, before exiting at atmospheric (typically) pressure. As indicated by its name the PCV controls the AC pressure as the flow control component of a pressure control loop."

Jan 1, 2017

By Azadeh Riahi

The main goal of this paper is to investigate the effects of permeability anisotropy in Large Open Pit (LOP) mines for problems that exhibit homogeneous anisotropic characteristics. The most important effect of the groundwater flow in open pit mines is on the stability of the pit slopes. This study will investigate the effects of having increased permeability in both horizontal and vertical directions on three aspects of LOP behavior, location of phreatic surface, pore pressure distribution and stability of slopes. The hydromechanical coupling is simulated using a one-way coupling approach. The Shear Strength Reduction method (SSR) is applied to assess the stability of slopes. The studies performed in this paper suggest that anisotropy in permeability leads to a significantly different regime of pore pressure dissipation depending on two aspects, ratio of anisotropy and the relative magnitude of permeability to simulated time. As a result, variation in safety factors and the location and depth of the failure surface must be expected.

Jun 1, 2012

By Afshin Sadri, Wai Lai Ying, Brycklin Wilson, Zoe Coull

"Although there have been great steps forward to integrate corrosion engineering into operations, there is still an underlying tendency for maintenance tasks to be performed in a reactive manner. This is especially true when strategies focus on lagging indicators such as visual inspections, RCA (root-cause analysis), and FMECA (failure mode, effects and criticality analysis). This trend to “reactive maintenance” can be avoided by utilizing more inspection and monitoring methods to identify leading indicators of failures. Prevention is generally less costly than repairs; moreover, when paired with appropriate monitoring techniques, intervention of corrosion protection can be more effectively timed and based on more accurate data. Hatch asset reliability studies show nearly 80% of defects are introduced through operations and maintenance. Therefore, proactive corrosion management can provide the necessary feedback to optimize operations and maintenance strategies preventing costly corrosion losses. Understanding corrosion risks gives a clear picture of the benefits of a proactive approach to asset performance. Monitoring techniques (Non-Destructive Testing, field testing, sampling, etc.) by nature are a more effective means of improving maintenance efforts and preventing corrosion losses than other methods (RCA, FMECA). This paper will outline the importance of proactive corrosion management and demonstrate its benefits through industry examples.INTRODUCTION Over the past few decades, with the growth of technology and awareness of sustainable development many studies have shown the benefits of a proactive approach to maintenance strategies. However, in practice there is still an underlying tendency for maintenance tasks to be performed in a “reactive manner”. This is especially true when strategies focus on lagging indicators such as visual inspections, RCA (root-cause analysis), and FMECA (failure mode, effects and criticality analysis). This trend to “reactive maintenance” can be avoided by utilizing more inspection and monitoring methods to identify defects and leading indicators to failures."

Jan 1, 2017

By F. H. Edmunds

Introduction This paper, it is hoped, will serve as an introduction to further work upon the origin of the soils and to a more complete interpretation of the geology of Saskatchewan from a study of the soils of the Province. The great difficulty that is encountered in mapping the structure of the prairie regions of the west must be evident to all who have made the attempt. The rarity of good exposures, due to the extensive coverings of glacial drift, is the greatest obstacle, making it difficult to determine the exact stratigraphical position of such exposures as may be found. In many cases palæontological evidence is lacking, or, if available, our present knowledge of the stratigraphy is insufficient to justify division of the formations into horizons; and until many of these formations have been subjected to petrographic investigation, little can be done in using lithological differences as an aid to the correlation of the usually sparse outcrops met with in the Province. Topography may be of the utmost value as an indication of geological structure when considered in conjunction with other evidence. It does not necessarily follow that, because an area in Saskatchewan has resemblances in surface configuration to an area of oil-producing land in Texas, there is sufficient justification for sinking money in wells without further investigation. Such - investigation should include the study of available soil maps.

Jan 1, 1929

By C. H. Hopper, D. R. Derry, H. S. McGowan

"The property of Matachewan Consolidated Mines is in the Matachewan area on the west side of Montreal river. It lies in the western extension of the Kirkland Lake sedimentary belt. The first discovery of gold on the property was made by S. Otisse, in 1916. The property was taken over by Ventures, Limited, in 1933 and production commenced in late 1934. To date (December 31st, 1947) it has amounted to 2,308,800 tons, from which gold and silver to the value of $9,567,600 has been recovered. The mill is currently treating 650 tons of ore a day.GENERAL GEOLOGYThe deposits lie close to the south contact of a belt of sediments striking in a general east-west direction. The sediments, presumed to be of Timiskaming age, consist of light buff arkose and greywacke, containing small pebbles. The Keewatin volcanic rocks to the south are andesites or basalts with cuff and agglomerate bands developed especially near the contact with the sediments. The lavas and sediments are overlain by relatively flat-lying sediments of the Cobalt series to the south and west of the mine, but these later sediments are not involved in the mineralization under discussion. The Keewatin lavas and Timiskaming sediments are intruded by dykes and lenses of red syenite porphyry that have approximately the same strike and dip as the invaded rocks. Later diabase dykes, apparently post-ore, run in a north-south direction and cut all rocks except the Cobalt series.OREBODIESThe gold-bearing mineralization forms bodies of two different types: (1) Within the volcanic rocks irregular orebodies with limited vertical extent. These consist of a series of flat-dipping quartz stringers and adjacent lavas and /or cuffs fractured, bleached, and mineralized with pyrite and gold. They are higher grade than the second type (average about 0.16 oz. gold a ton) and formed the main source of ore for the first 5 years of production. They are described in more detail than can be given here in an article by C. H. Hopper (4). More recent work on deeper levels has failed so far to find orebodies of comparable grade, though low-grade mineralization of a similar type does occur on the projected rake of the main group of the 'basalt type' of orebodies."

Jan 1, 1954