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By K. S. Raja, B. McNall, B. Pesic

"High-level radioactive wastes are stored in large underground storage tanks made of low-carbon steel. The wastes consist of concentrated solutions of sodium nitrate (NaNO3) and sodium hydroxide (NaOH), and the radionuclides 137Cs, 99Tc, and 90Sr. The corroding steel microenvironment may produce localized reducing or oxidizing conditions that affect the solubilities of the species such as Tc(VII) and Tc(IV), which in turn modifies the kinetics of corrosion of the storage tank. To understand the influence of technetate ions on the corrosion of steel, electrochemical polarization studies of A 537 steel samples were carried out in 1 M NaNO3 + 0 .05 M S r(NO3)2 + 0.1 M NaOH with and without addition of HReO4 at different temperatures (24 – 85 °C). The concentration of HReO4 was varied from 0.014 – 0.04 M.INTRODUCTIONAqueous processing of spent nuclear materials generates a large amount of high-level radioactive wastes. The wastes are primarily salt solutions of sodium hydroxide and sodium nitrate which also contain fission products such as 137Cs, 99Tc, and 90Sr. Among the high level radioactive fission products, Tc-99 is of great importance because of its high concentration, long half-life (2.1 x 105 years), high solubility in geologic waters as technetate, and rapid diffusivity through the geologic systems. The solubility of technetate ions varies depending on the oxidizing conditions prevailing in the storage containers. High level radioactive wastes are stored in single shell or double shell tanks made of low carbon steels such as ASTM type A15, A516-70 and A537. Most of the available literature on corrosion of steel in simulated radio active waste environments pertains to nitrate induced stress corrosion cracking (Subramanian & Mickalonis, 2005). The corroding steel microenvironment may produce localized reducing or oxidizing conditions that affect the solubilities of the species such as Tc(VII) and Tc(IV). Corrosion of steel and formation of Fe(II) and Fe(III) will affect adsorption and reduction of Tc species. The radioactive species can irreversibly be sorbed on the steel surface by oxidation of Fe(II) to more stable Fe(III) and fixed as less soluble Tc(IV)/Fe(III). The solubility of Tc species is also affected by other factors such as dissolved oxygen, local pH, temperature etc. How the corrosion behavior of steel will be affected in the presence of Tc species is not clearly understood.Cartledge (Cartledge, 1960) demonstrated that passivation of iron can be achieved in the presence of oxygen along with suitable inhibitor ions/molecules of the general formula XO4 n-, such as pertechnetate (TcO4 -). The pertechnetate ion is univalent. Since it is derived from a strong acid, no buffering action can be expected from this ion. The redox potential of the reaction (1) is 0.738 VSHE (Pourbaix, 1974)."

Jan 1, 2012

By A. Bezama

For over a decade European countries have addressed contaminated sites by developing technologies for managing both polluted soil and groundwater. This development has not only been driven by health and environmental aspects, but also because of economic pressures, as the remediation and redevelopment of derelict areas can be a meaningful alternative to undeveloped areas for the establishment of new industrial, recreational, housing and service locations. In most developing countries, however, the subject of contaminated sites is a new environmental issue that authorities have recently started to deal with. Among these countries, Chile has just started to prepare the country's legal context as well as to foster the formation of research and investigation groups that will deal with the exploration, investigation and management of contaminated sites. That requires a comprehensive technical, scientific and legal support in this stage. Goal of this article is to present the state-of-the-art technologies for site remediation currently applied in industrialized countries, in order to identify the most interesting approaches that can be implemented within the Chilean situation, especially considering the influence of the copper mining industry on the soil and groundwater quality of the environment surrounding their production facilities.

Jan 1, 2007

By C. Groccia

As the search for new ore bodies drives mines to be developed at greater depths, the associated high stress environments present challenges for rock support design. Excavations in highly stressed brittle rock are often subject to large volume increases due to rock failure, a phenomenon known as rock mass bulking, which can result in significant wall convergence. Support systems need to be designed to minimize the amount of bulking and to accommodate large wall convergences. In order to design such a support system, empirical guidelines are often used to predict the amount of bulking. However, the empirical guidelines that are currently available are based on a limited number of case studies and consider few input parameters, which may result in an inaccurate bulking assessment. This paper describes methods of collecting quantitative field data at Creighton mine in Canada to better understand rock mass bulking and to further develop the empirical guidelines for bulking assessment for tunnels in highly stressed grounds. Measuring

Aug 1, 2013

By J. W. Reynolds

This paper describes the function of the research and development department of a large mining organization and the benefits which can be derived over the years. Examples are given of work done in rock drilling, ventilation, noise control and the development of backfill stowing machinery.

Jan 1, 1970

Of the many organic impurities present in Bayer liquor, sodium oxalate is known to have one of the most detrimental effects on the Bayer process. Because of its limited solubility, it will co-precipitate with gibbsite during the precipitation stage which results in many operational challenges for the refinery. Despite the importance of this phenomenon, the interaction mechanism between gibbsite and sodium oxalate is not well understood. In this study, the growth of sodium oxalate on three main morphologies (random agglomerates, prims and hexagons) of water-washed and caustic-washed gibbsite was observed under synthetic Bayer conditions using in situ optical microscopy. After a short induction period, oxalate started to nucleate on gibbsite crystals, and grew with a needle-shaped morphology which eventually developed into oxalate bundles. In addition, the results indicated that caustic washing was able to partly decompose gibbsite crystals and thus make the gibbsite surface rougher, which provides more potential sites for oxalate nucleation and growth. The growth rate of oxalate crystals on the basal (001) face of water-washed gibbsite was 1.33 µm/min determined by the time-lapse imaging of in situ optical microscope.

Jan 1, 2014

By L. Paulino, R. A. Camilli, J. Yamamoto, J. C. Araujo

The first paper presented on this work [1], showed how bath ratio was increased from 78% to over 95% using a structured approach to reduce bath chemistry variability. This update will illustrate the steps taken and update the results presented earlier, showing the effects of long power interruptions and several load reductions as well as load increase during the period from 1999 to 2005. Current efficiency was affected by such processes upset; however, bath ratio in range (±0.05) is still higher than 90%, even after an increment of more than 6 kA. This review will explain each of the steps taken to reach stability in this critical smelting parameter.

Jan 1, 2006

By J. E. Gill

Discovered in 1952, the deposits have been explored by diamond drilling on and near a group of islands in lake Nipissing and from under-ground workings. The ore mineral is a uranian pyrochlore. It occurs in breccia zones in association with calcite, apatite, a?cmite, feldsiiars, biotite, magnetite, sulphides, and fluorite in varying amounts. The pyrochlore concentrations occur in a steeply-dipping gneiss series with some crystalline limestone. Trends indicate a ring structure 114 miles in diameter. The main ore zone shows evidence of repeated brecciation and a succession of replacements .giving rise to a complex of rock types. Pegmatite and lamprophyre dykes cut the ore as do calcite-fluorite veins and later faults with small displacements. Columbium and uranium occur al-most exclusively in pyrochlore, but the proportions vary. There is no tantalum and only small amounts of titanium.

Jan 1, 1957

By G. N. Carlson, C. H. Hazelroth, D. R. Dorrance

"Located on the north shore of the St. Lawrence River at Pointe Noire, Quebec are the agglomeration and ship-ping facilities of the Wabush Mines complex. Here, the specular hematite concentrate from the Scully Mine is received for further processing. Modern facilities for handling the ore, either to the 1plant or to stockpile, provide quick and efficient operation of the ore receiving station. Physical preparation of the ore for balling is accomplished with regrind ball mills, filters, bentonite crushing and drying facilities, pumps and related conveying circuits. Rotating table feeders deliver the reground and de-watered ore from storage bins to balling drums, where green ball or green pellet formation is achieved. The green balls are then conveyed to the indurating section. Three Dravo-Lurgi travelling grates, producing a total of 6,000,000 long dry tons of pellets per year, are used in the indurating phase of the operation. These grates, having 38 windboxes and firing at a temperature of 2,500°F, harden the pellets for shipment to various blast furnaces throughout the world."

Jan 1, 1969

By H. P. Dibbs

An account is given of the application of neutron activation analysis to the rapid, non-destructive determination of copper in minerals, using a 14-MeV neutron source. Elements that interfere in the determination of copper by this method are given, together with the errors in the estimation of copper that result from the presence of varying amounts of these elements. The possible use of a compact "sealed-tube" 14-MeV neutron generator for the field assay of copper in minerals is discussed.

Jan 1, 1970

By Adrian E. Scheidegger

"AbstractThe possibilities of deriving pertinent information about fractures in an oil pay from data obtained by core analysis are investigated. It is shown that it is possible to obtain an estimate of the fractured area per unit volume of the pay, and that the size of the fractures can be estimated if their shape is known. A suggestion of a routine procedure for the analysis of fractures is given.1.-IntroductionMany oil fields are producing essentially from cracks or fractures. Where this is the case, it is important to be able to obtain a knowledge of the size and distribution of those fractures in the oil pay. This knowledge has to be derived from the analysis of cores taken from the fields, as it is generally impossible to follow a fracture through the pay by direct means. The necessity of using statistical methods to extrapolate the meagre information obtained from the cores of the wells is therefore indicated.It is known that the fractures are much bigger than the diameter of the cores; thus, if they strike a core, the latter will generally fall into two pieces. The angle of the fracture with the vertical can be measured and, if oriented cores are taken, the exact position of the surface element representing the intersection of the fracture with the drill stem can be determined. Sometimes the edge of a fracture can be seen in a core. The number of •Cores that show such an edge can be noted. Of course, one has to be careful to distinguish between original fractures in the pay and fractures in the core caused by drilling operations. Only the former are relevant."

Jan 1, 1955

By Irvine J. Berscheid

This paper describes a rock drill bit which, although conventional in the processes of manufacture and use on the job, has incorporated into the outer wall or periphery of the insert, where wear is always the greatest, a variable amount of extra metal, distributed in units of height of insert to withstand this excessive wear. Explained are variations of construction, how the extra metal enables the bit to drill more footage, prevent antitaper and the need to gauge grind, increase penetration rate and the length of run per regrind, reduce shank breakage and ma-chine costs, and permit increased production per man-shift, without requiring any change in equipment already on the job. F OR purposes of clarity, reference to bits here means integral rods or multi-winged bits which have their inserts sharpened to a conventional shape. When dull, the insert has worn, on its face, a flat which increases in width as we progress from near the center of the bit toward the outer edge. Very

Jan 1, 1965

By H. J. White

Haynes International, a world leader in the manufacture and production of nickel, and cobalt base alloys has invented and developed a low cost high temperature material, with a unique combination of superior oxidation resistance and weldability/ fabricability. HAYNES® HR-224TM (Ni ? 27.5Fe ? 20Cr ?3.8A1 ? 0.3Si ? 0.3Ti) forms a planar/ continuous/ adherent aluminum oxide film at high temperatures which has been shown to effectively limit chromium poisoning in solid oxide fuel, cell, systems. A 20,000 pound vacuum induction melted (VIM) + electroslag remelted (ESR) heat has been melted and converted into various product forms: sheet, plate, bar, welded tubing, wire, etc. The alloy was designed for service in severely oxidizing environments recuperators, automotive catalytic converters, wire strand annealing furnace tubes, etc. and has been of great interest to solid oxide fuel, cell, manufacturers as a materials of construction in balance of plant (BOP) design. This manuscript presents the physical, properties, mechanica, properties, and oxidation resistance of the alloy compared to other materials being considered for solid oxide fuel, cell, design

Jan 1, 2010

By W. G. Q. Johnston, J. S. Fox

"A semi-continuous belt of Aphebian magnesian extrusive and related sub volcanic rocks has been delineated by the authors over a distance of 150 kilometres in the central La Ronge lithostructural domain in Saskatchewan. They range in composition from peridotite to basalt and attain true thicknesses of up to 800 metres. For the most part, they are confined to a basal position in the La Ronge/Wasekwan metavolcanic sequence, and appear to have been extruded onto sialic crust. However, at Lynn Lake, Manitoba, in the eastern continuation of the domain, similar rocks seem to be found only at a relatively high stratigraphic level.Although metamorphism seems to have obliterated any quench textures that may have existed in these rocks, ultramafic pyroclastics, pillows and amygdules as well as intercalated, fine-grained clastic sediment attest to the volcanic nature of these rocks. Bulk chemical analyses indicate that these rocks are heterogeneous, with komatiites, tholeiitic picrites and even rocks with some of the characteristics of boninite all being present. The close temporal and spatial relationship of ""boninites"" and komatiites in the belt may suggest a high degree of Aphebian mantle inhomogeneity in the domain.Nickel-copper mineralization has been found in differentiated tholeiitic stocks within the La Range domain (e.g., at Lynn Lake), but none has yet been found in the ultramafic volcanics. However, the tholeiitic picrites do host one economic gold deposit - the Agassiz Mine at Lynn Lake .Because of the depleted nature of their mantle source, the ""boninites"" of the domain are not considered to be likely hosts for mantle-derived nickel sulphide mineralization. However, the opposite is true of the komatiites, and this points to the need for whole-rock geochemistry in setting priorities for nickel exploration in the belt. In contrast, all of the magnesian rocks of the domain probably have the same gold potential. Inasmuch as the geophysical response to gold mineralization in the domain is likely to be unpredictable, lake-sediment geochemistry, followed by base-of-till and/or alteration oriented lithogeochemistry, should be emphasized during gold exploration."

Jan 1, 1981

By A. Zaidi

"The mining and metallurgy industry is highly energy intensive and one of the largest energy users in Canada. Energy costs are also a major component of total production costs in this industry as described in the 1990 Report of The Canadian Industry Program for Energy Conservation (CIPEC). For some plants, energy costs are reported to be up to 30% of total production costs. Therefore, a reduction in energy costs provides an opportunity to improve industry profitability. The specific energy intensity and production costs can be reduced by using modem energy efficient natural gas technologies. In addition, these technologies often improve product quality and increase productivity. Natural gas not only offers economic benefits, but is also environmentally benign as compared to other major energy sources. Emissions of NO"", CO2 particulates and SO2 are lower with natural gas than other fossil fuels.This paper provides a brief overview of some state-of-the-art gas technologies for the mining and metallurgy industry including cogeneration, oxy-air-fuel burners, ceramic immersion tube heaters, direct gas contact process, low NOx burners, and energy efficient liquid heating systems.CogenerationCogeneration is defined as the simultaneous production of electricity or mechanical power and useful process heat from a single fuel source. One of the primary considerations in selecting a cogeneration system is the relative quantities of electrical and thermal energy which are to be produced. Two types of systems are discussed below."

Jan 1, 1993

By W. T. Gotheridge

The principal sources of coal-dust underground are, of course, coal, and the working of coal. Coal-dust is most dangerous when it is in the finest state of division. This class of dust is found mostly on the roads, being blown or shaken off the loaded trams in transit, or carried in suspension by air currents. The air current passing from the working faces may also carry dust in suspension into the return airway, and the air current from the surface may carry dust from the shakerscreens into the intake airways. The mosl dangerous dust we have to contend with is, (a) that which is most finely divided, and (b) that which contains the most volatile matter, including the inflammable occluded gases, and also oxygen absorbed from the air. According to experiments, coal-dust in a fine and dry state would intensify an explosion, in air free from fire-damp carrying in excess of 3 ozs. of fine dust or 6 ozs. of coarse dust per cubic yard. The volatile matter in the dust must be between 12 and 31 per cent. in the ash-free coal, the latter percentage giving the highest flame velocity. It is vary difficult to propagate flame where coal-dust contains a large percentage of stone-dust, (say 50 per cent.). Shale-dust or other incombustible dust containing no volatile hydro-carbons or carbonaceous matter will prevent the extension of an explosion if mixed with coal-dust in proportion of say 70 per cent., and if the dust is finely divided and dry.

Jan 1, 1924

By Toivo Toivanen

The paper begins with a brief history of the nickel industry in Finland, and then deals with the introduction of the flash smelting process. The main part of the paper is devoted to nickel refining, which is studied under four main headings -grinding, leaching, electrolyte precipitation, and nickel electrowinning. Flowsheets are illustrated, and the equipment used is described. Analyses of the material in the various stages, from concentrate to high-grade nickel matte, are also presented. N ICKEL made its appearance in the Finnish mining industry forty years ago, when a nickel deposit was discovered at Petsamo in Lapland. Mond Nickel Co. received the concession for this deposit from the Finnish Government, and the Petsamon Nikkeli Company constructed a mine and a nickel smelter (1), the completion of which was prevented by the 1939 Winter War. The mine and smelter were, however, completed soon afterwards in spite of World War II,

Jan 1, 1964

By A. Roy MacLean

This paper outlines the changes in modern-day coal mining that have been brought about by the increased cost of labour and the use of new and highly efficient equipment. In the latter category are mentioned the ramp-plate, the Bretby cable carrier, armoured face conveyors and the shearer-loader. Greater productivity and increased safety are emphasized.

Jan 1, 1969

By Dan Nower

Machinery Health Monitoring of Shovels MINExpo 2012: Caterpillar announced the largest Electric Rope Shovel, capable of 120 short tons The next day, JoyGlobal (P&H Mining) ?one-upped? CAT, introduced a shovel capable of 135 short tons Large Concern: breakdown (unplanned outages) of one machine will be more disruptive to production

May 1, 2013

By Marc Boyer

Modern civilization, modern industry, and modern standards of living, bring into, sharp relief the present-day essentiality of metals .and minerals, and the wide and diversified use which is made of them. Any attempt, therefore, to appraise the international situation today must take into consideration the metal and mineral resources of the world. If, as some believe, the world is divided into two distinct ideologies of political belief, one unalterably opposed to the other, so that armed conflict is unavoidable, then the question of national strength in mineral resources becomes of paramount importance. If, however, it is possible to avoid war by raising the standard of living in the underdeveloped ?areas of the world, thus ensuring all peoples everywhere against the dread spectres of starvation and disease, then the development of the world's mineral resources assumes even greater importance. Today it is difficult to realize that, prior to the industrial revolution in Great Britain, only a few of the metals and minerals now in common use entered into the everyday life of the people. !iron and steel, copper, lead, tin, and zinc, usually in .their unalloyed forms, along with the more common industrial minerals, were those most widely used, and then only in limited amount. With the advance of technology in metallurgy and in fabricating skills, the list of commercial metals and minerals has expanded until today they number more than eighty.

Jan 1, 1951

By J. A. Reid

THE views and observations expressed herein on this old but constantly recurring question are our own, no effort having been made to align them with standard texts. Therefore, while they may find general acceptance amongst fellow engineers, they must stand as personal opinions and as such are open to debate and discussion. In order properly to consider the subject, it should first be 'set in proper perspective. Why are Prospects Examined? Prospects are examined to determine whether they may contain economic concentrations of metals or minerals, the legitimate mining business being run, pretty largely, to make money. Next to food and clothing, modern civilization is based on metals, with which are included in this discussion minerals, oils, and fuels. A constant and increasing demand for the common metals requires the location of replacements for depleted orebodies, while the use and appreciation of new metals brings increasing demand for them. Aluminium is a good example of a metal which has, within recent years, made great progress. Today, we are becoming increasingly aware of magnesium, chromium, tungsten, thallium, and other lesser known, metals.

Jan 1, 1945