Search Documents

By M. F. Lopez, A. J. Mattus, S. B. Magid, D. B. Mobbs

"The use of Caro's acid as a replacement for hydrogen peroxide for the oxidation of vanadium prior to solvent extraction resulted in a 56% reduction in oxidant usage when compared on an equivalent hydrogen peroxide basis. Comparative oxidation tests, using two actual uranium mill raffinates, resulted in premature precipitation of an amorphous ferric vanadate when hydrogen peroxide was used to oxidize one of the raffinates containing a high iron to vanadium ratio. The use of Caro's acid eliminated the precipitation problem, thereby permitting the adjustment of the raffinate pH to a higher, more favourable level prior to solvent extraction.Potentiometric characterization of the raffinates revealed that vanadium is responsible for the inefficiency of hydrogen peroxide compared with Caro's acid, with the oxidation efficiency of iron being the same for both oxidants. A limiting potential between 720 and 740 mV was observed when using hydrogen peroxide, while, when using Care's acid, potentials approaching 1200 mV were achievable.A four-stage, countercurrent extraction performed on the oxidized raffinates did not reveal any operational problems. The extraction efficiency and the extraction coefficient were found to be higher when Caro's acid was used as the oxidant, as opposed to hydrogen peroxide.IntroductionMost vanadium is recovered as a by-product of some other process: leaching of Carnotite uranium ores, oil fly ash, phosphate rock or chromite processing. The major source of vanadium has been from uranium mills incorporating acid leaching of Carnotite ore s at elevated temperatures and pressures. The by-product recovery of vanadium from uranium ores of the Uravan Mineral Belt, located in the Colorado Plateau , is a common occurrence when vanadium recovery is economically viable."

Jan 1, 1983

By David Davidson

Overview- Points To Be Addressed ? Review the building blocks of a successful and vibrant industrial economy ? China?s current position in the global economy ? China?s voracious appetite for raw materials ? Distortion in import/export trends ? Areas of strategic importance for China - Steel and its components - Agriculture self sufficiency - Energy now and for the future ? Do current valuation techniques fairly value ?strategic? assets? China ? The Economical Miracle - Massive shift in population from rural to urban - ?Middle class? growing rapidly, hence strong consumer growth - China is the manufacturing center for the world ? cheap labour and - modern facilities - Infrastructure build out ?US$585b stimulus package and 5 year plan - Rail ? 30,000 kms of new track planned by 2020 - Power ? 50% capacity increase, including 35 nuclear reactors - 100 major new airports - State of the art process and manufacturing facilities - Port capacity ? 100m TEU capacity increase by 2020 Class 1 national highway ? 35,000 km?s by 2020

May 1, 2010

By R. F. Neider, W. R. Bain

"Expanding upon one aspect of a recent paper on ""Fluid Column Roasting at Sherbrooke Metallurgical Co. Ltd.,"" the present paper deals with the operation of the fluid column process to achieve substantial elimination of cadmium and lead during the roasting of pelletized zinc concentrates. Designed to meet the need for additional feed for Matthiessen and Regeler Zinc Company's vertical retort zinc smelter in West Virginia, without recourse to a sintering operation, the plant is capable of simultaneously attaining very low lead and cadmium levels on demand, through operation in the manner described. Fluidizing air admitted via the wind box is supplemented by natural gas admitted via a tuyere bank 15 ins. above the hearth, in quantities adjusted to maintain a reducing atmosphere within the interstices of the bed. In addition, careful attention is paid to bed temperatures, which run from 1,080° to 1,100°C. Under these reducing conditions, 90 per cent of the cadmium and 92 per cent of the lead in the feed are eliminated, the sulphate sulphur content is decreased by 0.5 per cent, sulphide sulphur is held at 0.6 to 0.08 per cent, and the zinc content correspondingly in-creases. The fuel value of the natural gas is recovered as extra steam, which carries a credit. There are some added difficulties with fume accretions, gas conditioning and gas -cleaning, some of which have yet to be overcome."

Jan 1, 1967

By Mansoor Barati, Xue Yin, Yanhui Sun, Alex McLean, Yindong Yang

The formation and evolution of inclusions in Ti-Stabilized, 17Cr Austenitic Stainless Steel produced by the ingot casting process were investigated through systematic sampling of liquid steel and rolled products. Analysis methods included total oxygen and nitrogen contents, optical microscopy, scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS). The results indicate that the composition of inclusions was strongly dependent on the types of added alloying agents. During the AOD refining process, after the addition of ferrosilicon alloy and electrolytic manganese, followed by aluminum, the composition of inclusions changed from manganese silicate-rich inclusions to Al2O3-rich inclusions. After tapping and titanium wire feeding, pure TiN particles and complex inclusions with Al2O3-MgO-TiOx cores coated with TiN were found to be the dominant inclusions when [%Ti] was 0.307 in the molten steel. These findings were confirmed by thermodynamic calculations which indicated that TiN inclusions could be formed in the liquid phase due to the high contents of [Ti] and [N] in the molten steel. From the start of casting to the rolled bar, there was no obvious change in the composition of inclusions compared to the titanium addition stage. Stringer-shaped TiN inclusions elongated along the rolling direction with lengths varying from 17 to 84µm were observed in the rolled bar, which could detrimentally impact the mechanical properties of the stainless steels.

Jan 1, 2015

By C. Edwards

ABSTRACT The versatility and specificity of rare earth elements (REEs) have led to their use in an everincreasing variety of applications in new technologies; consequently, demand for REEs has increased significantly. However, separating REEs safely and effectively is a complex and expensive process. This paper presents a review of REE mineral processing technologies, providing an update on current capabilities in REE mineral processing and REE extraction from the major commercially valuable REEbearing minerals such as bastnaesite, monazite, and xenotime, as well as the ion-absorption type of REE deposits.

Jan 1, 2013

By Grant D. Nicholas

This paper compares an integrated evaluation approach to decision-making with more traditional sensitivity analysis and Monte Carlo simulation. The primary objective is to highlight the differences in NPV that can arise from using these evaluation methods in a top down and bottom-up approach. Results from three resource scenarios, derived from sampling a "virtual" ore body (reality) on grid spacings of 75m, 50m and 25m, are analyzed and compared.

May 1, 2007

By R. S. Douglas

Introduction The operations of The Granby Consolidated Mining, Smelting and Power Company, L1mited, have always been concerned with the mining of low-grade copper ores. In the fifty years of this Company's existence, nearly 60,000,000 tons of such material has been successfully mined and treated. During these years, many changes in mining practice took place. However, at Copper Mountain, due to the large tonnages of very low grade material, it was realized that something more than changing mining methods would have to take place if these low-grade orebodies were to be mined at a profit and the Company and. its employees enjoy many years of successful operation and employment. Production costs were mounting commensurately with rising taxes and the increasing cost of supplies, labour, freight, and smelting, while the value of the product on the market was not increasing in price to compensate for the higher costs of production. A survey of the mineable ore in 1944 indicated that, of the 12,000,000 tons in the reserves, only 3,500,000 tons was now profitable ore. This reduction in the commercial ore reserves was a serious matter, as it meant that the mine had only two years of life at the profitable shipp1ng rate of 4,800 tons per day. Further, the location in the mine of the orebodies making up the 3,500,000 tons was not suitable for such high production.

Jan 1, 1950

By D. R. Jolley

"The selection of equipment for open-pit mining is an important decision which results in a considerable capital expenditure by the operator. The decision is complicated by the wide product range on the market. Certainly, equipment performance is an important criterion to consider in making the decision. Equally important, however, is the operating inter-relationship among the equipment. A poor balance increases production costs and waiting time as queues form at the bottlenecks. This inter-relationship is dependent on equipment performance, but it is also affected by management decisions (i.e. scheduling techniques).The purpose of this paper is to show how the computer is used to decide which equipment and operating decisions achieve the required production objectives at least cost. Actual mining of the pit is simulated over a period of time using different equipment and scheduling decisions. Production, waiting time and costs are evaluated for each alternative until the operator is satisfied that he has achieved the best result."

Jan 1, 1970

By D. C. R. Espinosa, P. Aliprandini, J. A. S. Tenório, M. M. Jiménez Correa

"Nickel and cobalt are the main value metals in nickel laterite ore. Cyanex 272 is an extractant used to separate nickel from cobalt present in leach solutions. Previous studies demonstrated the extraction of cobalt, magnesium and manganese at pH 5 using Cyanex 272 as extractant, while nickel remained in aqueous solution. However, it is difficult to separate cobalt from a solution containing magnesium and manganese. One possibility to change the metals’ behavior during the solvent extraction process is to change the mixture of extractants used. In order to study the solvent extraction of cobalt from a solution containing manganese, magnesium and nickel, a mixture of two extractants was investigated. Cyanex 272 (CY) and Versatic 10 (VC) were selected as extractants in the organic phase. The extractant concentrations used were: 20% CY; 15% CY, 5% VC; 10% CY, 10% VC; 5% CY, 15% VC; and 20% VC. In all cases, kerosene was used as a diluent, at 80 vol%. The synthetic leach solution used in this study was prepared according to the composition of a typical nickel laterite leach solution. The pH value of the solution used was 5, and the aqueous/organic ratio used in solvent extraction testwork was 1/1. The study has shown that the composition of the organic extractant mixture did not increase cobalt separation.INTRODUCTION Sulfide and laterite deposits are the main sources of nickel. However, production from nickel sulfide ores has been decreasing over the years, relatively speaking, increasing the focus on the exploitation of laterite nickel ores (McDonald & Whittington, 2008). Laterite ore deposits are found in tropical and subtropical regions. A characteristic of laterite ores is the presence of a complex and heterogeneous mixture of metals (Crundwell, Moats, Ramachandran, Robinson, & Davenport, 2011; Georgiou & Papangelakis, 1998; Gupta, 2003; Kesler & Simon, 2015; Moskalyk & Alfantazi, 2002; Oliveira, 1990). Nickel concentrations in laterite ores are typically 1–2% (Dalvi, Bacon, & Osborne, 2004)."

Jan 1, 2017

By Joseph Hirschi, Behrooz Abbasi, Harrold Gurley, Yoginder P. Chugh

"The research goal was to assess if analytical tool/s can be developed to quantify displacements around a geological fault as longwall face moves toward it and past it. A company was faced with crossing a 2-3 m (6-10 ft.) normal up-thrown fault in the development entries and the face while mining a 375 m (1,200 ft.) wide longwall face. A field monitoring and numerical modeling study was performed to develop data. Field measurements consisted of roof-to-floor convergence and rectangular rosettes in the immediate roof. Numerical modeling consisted of constructing a 3-D structural model using the FLAC3D software with the fault plane incorporated as ubiquitous joint. Based on analyses and field observations data, the coal company was informed of impending movements along the fault plane and likely impacts on the development entries. Additional stiff supports were installed in head gate entries around the stage loader and equipment about 60 m (200 ft.) outby of the longwall face (solid). As the longwall face approached the fault, predicted displacements were documented and manifested by severe loading on the installed supports.BACKGROUND AND STUDY OVERVIEWThis paper summarizes results of a cooperative study aimed at improving longwall mining operations in Illinois. More specifically, the study focused on: 1) In-mine measurements in development entries while mining ahead of and behind a faulted zone, 2) Making observations on stability of pillars and entries while mining through the fault, and 3) Developing simplified analytical structural models using FLAC3D to assess if predictive techniques can be developed to plan mining operations through fault zone. Available data on geometry of the fault with estimates of the cohesion and frictional parameters were used for modeling."

Jan 1, 2015

By J. Kan

In order to determine the recovery functions in an oil sand circuit it is necessary to have more than a minimal determination the mass flows in the network. This over-determination is essential in order to allow for measurements within the flow matrix "to flex" according to an error function. It is then possible to identify the flows and composition at all points with maximum likelihood. These so-called full mappings are not easily obtained. However, in order to obtain an unequivocal determination of all the unit operations recoveries such a balance is needed. When databases are constructed exclusively with coherently balanced sets of data it is possible to obtain a maximally accurate process model by maximizing the probability of correctly identifying the process causality. Indeed, it is doubtful in cases of normal complexity that any sense can be made of data that is not so balanced. Coherent mass energy balancing is a tool developed by mineral processing scientists and engineers. Its rigorous application to oil sands is the subject of this paper. The additional element associated with hydrocarbon requires special considerations. It is shown that at least one currently available mineral processing tool will solve the full-mapping problem for an oil sand operation. Experimental design constraints are discussed in this paper relating to the development of databases for the development of effective process models.

May 1, 2004

By H. Bouzahzah

Sulfidic tailings, subjected to atmospheric water and oxygen action, can generate acid mine drainage (AMD); which is the most important environmental problem facing the mining industry. AMD generating potential can be assessed by the static tests which consist of a screening method where the neutralization potential (NP) and the acid-generating potential (AP) of a given rock sample are determined. The AP and NP are determined separately in the different static test existing procedures which can be divided into two distinct classes: chemical and the mineralogical methods. For some chemical method, the AP is calculated on the basis of total sulfide sulfur content in the sample which may overestimate its AP if significant quantities of non-sulfide sulfur species are present (e.g. organic S in coals, some sulfate as gypsum, barite, etc.). However, the mineralogical method evaluates the AP by the sum of the individual sulfides participation on acid generation based on their concentration within the sample and can be more accurate than the chemical method. For AP calculation, the Paktunc (1999a) mineralogical static test takes into consideration all sulfide minerals occurring in the sample. However, it does not take into account the rates of acidity production of these sulfides submitted to weathering conditions. So, the present study focusses on the modification of Paktunc AP calculation by considering the acidity production rates of these minerals. To reach this objective, five base-metal sulfides (pyrite as reference, chalcopyrite, sphalerite, arsenopyrite, galena), diluted within quartz (25?75 wt.%) simulating mill tailings were subjected to a kinetic test to evaluate their AP. The results show that all the studied sulfides minerals generate acidity at different rates, so the Paktunc?s equation for AP calculation has been adapted accordingly.

Aug 1, 2013

By William C. Browning

An economic drilling programme is one which costs the !east in chemicals, equipment, and time. The basis for such a programme with rotary drilling techniques is a drilling fluid in which bentonites do not swell. This is recognized in the growing trend toward gyp and other inhibited mud systems. Therefore, even though the mechanism of thinner action is a subject of applied colloid ,chemistry, the understanding of this mechanism is of economic importance in controlling the flow properties of inhibited muds. In phosphate, or sodium tannate, conditioned muds that are relative-!y free of contaminating-electrolytes, the thinner, or dispersing agent, is adsor.bed, ?creating an electrical double layer about the clay particles. The mutual repulsion of these charged particles effects colloidal stabilization, or deflocculation of the suspended clays, as discussed by Norton and others. In inhibited muds, however, the electrolyte concentration in the filtrate is sufficient to collapse the double layer and flocculation of the mud solids occurs, as evidenced by increased viscosity and gel values. Chemicals to control the flow properties of inhibited muds, therefore, are vital to the successful use of these systems as it is not always economical to adjust flow properties by watering back. Flocculation of suspended particles, as indicated in the work of Vervey, Overbeek, and others, is due primarily to gravity-like, long-range Van der Waals forces. Prevention of flocculation may, therefore, be secured by the interposition of any barrier between the particles, the thickness of which approximates the extension of the Van der Waals at-traction. Organic polyelectrolytes, such as Kembreak, Rayf!o, and Q-Broxin, may act to increase the double layer charge when used in small amounts in fresh-water muds. More important, however, is the fact that in inhibited muds an increase in concentration of the polyelecholyte permits the formation of a condensed film adsorption layer of the polyelectrolyte about the clay particle. When this occurs, the extremely viscous condensed adsorption layer creates a mechanical. barrier that prevents flocculation of clays, even in the presence of inhibiting concentrations of elecholytes. Rheological evaluation of the degree of deflocculation, or colloidal stability, may be made by utilizing the known effects of particle inter-action and volume concentration on the flow properties of suspensions. Rheological evaluation should be supplemented by direct microscopic or ultra-microscopic observation.

Jan 1, 1958

By Viraj Parekh, Kinnor Chattopadhyay, Sina Mostaghel, Xiao Zhang

Electric arc furnace steelmaking is a dominant approach in North America and controlling EAF emissions is a key issue today because of stringent permit limits imposed by various regulatory bodies. In the present study, an attempt has been made to mathematically model EAF emissions, and use the models as a predictive tool for fine tuning the process. CFD modelling has been used to model various fume release scenarios, and optimize the exhaust conditions for maximum capture. Thermodynamic calculations have been used to analyze various chemical reactions which lead to the emissions of hazardous air pollutants with special emphasis on Zinc, Lead and Manganese.

Jan 1, 2015

By M. Rylatt, E. Legault-Seguin, C. Mohns

"With energy costs increasing and ore grades diminishing, the role of preconcentration in hard-rock mining operations has gained greater interest. Dense medium separation is a process that can be conducted at particle sizes from 250 to 0.50 mm with high separation efficiency, depending on liberation characteristics of the valuable minerals. Pilot-plant case studies conducted at the SGS Lakefield site are presented, including mineral systems such as spodumene, sulfide-bearing gold ores, and complex sulfide ores. These case studies demonstrate that, for amenable ores, mass rejection of 20–60% is possible while maintaining recoveries of greater than 90%.RÉSUMÉ Au vu de la hausse des coûts liés à l’énergie et du déclin de la teneur des minerais, le rôle de la préconcentration dans les exploitations minières en roche dure présente un intérêt croissant. La séparation (ou concentration) en milieu dense est un processus pouvant être mené sur des calibres de grains de 250 à 0.50 mm avec un rendement élevé de séparation, en fonction des caractéristiques de libération des constituants des minéraux métallifères. Sont présentées dans cet article des études de cas menées dans des usines pilotes du site de Lakefield de SGS, lesquelles incluent des systèmes de minéraux tels que le spodumène, les minerais aurifères sulfurés et les minerais sulfurés complexes. Ces études de cas montrent que pour les minerais présentant les caractéristiques de libération appropriées, il est possible d’atteindre un rejet en masse de 20 à 60 %, tout en maintenant des récupérations supérieures à 90 %.INTRODUCTIONPreconcentration is the process of rejecting gangue minerals while ensuring recovery of valuable minerals prior to more intensive, downstream processing. Preconcentration has been practiced in the industry for many years, and is gaining greater interest as the industry copes with processing lower grade, more difficult ores, which typically require finer grind sizes and incur higher energy costs.The benefits of preconcentration are:• lower mining costs, which allows for nonselective mining;• lower process capital and operating costs (e.g., resulting from reduced grinding, flotation, and fines disposal stages);• increased ore reserves, which provides the potential to treat lower grade ore;• increased mine production without expansion of the existing plant or concentrator;• reduced overall tailings impoundment by converting the reject into a byproduct (e.g., underground backfill or aggregate);• improved efficiency of downstream processes (e.g., silica removal in electric arc furnace feed, removal of softer sliming minerals prior to grinding);• potential application to brownfield operations and greenfield projects; and• a “green” process option, which reduces processing energy consumption;– reduces mill feed;– increases stage metal recovery (higher grade feed);– increases mill metal output per tonne processed;– reduces surface plant, tailings dump, and tailings pond requirements because the plant has a small footprint and can be installed underground; and– can be applied to retreatment of old tailings dumps to recover metal values and reduce environmental impacts (e.g., dissolved metal runoff, acid drainage)."

Jan 1, 2017

By W. Curlook, L. M. Pidgeon

THE PURPOSE of this investigation was to study part of the ternary system Co-Fe-S. Jensen ( 1) established the solubility limits of sulphur in pyrrhotite. The compound with 61.7 per cent Fe, corresponding to a formula Fe12S13, was found to melt congruently at l,192°C. Hulsmann and Weibke(2) determined the Co-S phase diagram from O to 35.2 per cent S. The solubility limits of sulphur in the com-pound Co(l-x)S were not determined. The initial object of the present in-vestigation was to determine the composition at which the compound Coci-xiS melted congruently. Once this was ascertained, it was decided to investigate the ternary system Co-Fe-S from the region of 100 per cent Co(1-x) S to the region of 100 per cent Fe12S13.

Jan 1, 1953

By B. Rivard, D. Francis

A layered Archean magma chamber is exposed at the base of the Yasinski segment of the La Grande greenstone belt. This intrusive complex lies beneath a sequence of mafic volcanics and is underlain by granitoid basement which is crosscut by a swarm of gabbroic dykes. The gabbros of both this complex and the dyke swarm of gabbroic dykes. The gabbros of both this complex and the dyke swarm define a pronounced Fe-enrichment trend. The volcanic patterns of the La Grande and Eas tmain greens tone belts, however, define a series of iron depletion trends which originate in the iron enrichment trend of the gabbroic intrusives. These patterns suggest that the gabbros produced in the intrusive complex may serve as parental liquids for some of the lava suites of the James Bay greens tone belts.

Jan 1, 1984

By G. F. Round

In order to obtain values of angle of shearing resistance and initial resistance for McMurray oil sand for use in general design calculations, the shear strength of this oil sand was measured in a controlled strain type tester, modified so that the rate of deformation could be varied between 0.01725 and 0.1869 inches per minute. Effect of temperature was investigated by adapting the equipment to operate at both 71 ° and 185 °F. The data are reported in terms of angle of shearing resistance and initial resistance for varying rates of deformation, composition and temperature. While the main sets of results reported here were obtained at a bulk density range of 108.7- 109.5 lb. / cu. ft., some results were obtained at a bulk density range of 101-102 lb. / cu. ft. Analysis of varance tables have been drawn up from the results obtained from least squares correlations and significance tests applied. It was concluded that oil content and temperature were significant variables for the degree of shear strength developed by the oil sand; increase of oil content and decrease of temperature each cause an increase in shear strength. The bulk density range 108.7 to 109.5 lb./cu. ft. gave angles of shearing resistance from 30° to 40° and initial resistance values of 0.37 p.s.i. to 0.85 p.s.i. For the bulk density range 101 to 102 lb. / cu. ft., lower values of shear strength were obtained, indicating that compaction density was also of importance

Jan 1, 1960

By Walter Nelson

Considerable thought and discussion had been devoted toward provision for increased milling capacity at the Allenby concentrator of The Granby Consolidated Mining, Smelting and Power Company operations as early as 1940. During the war, plans for the installation of an additional grindi.ng unit were formulated but were not carried out. It took considerable time after the war to prepare the mine again for its highest rate of production since, with the scarcity of men, development work had been sacrificed in favour of maximum ore shipments. In order to prepare for the expected competitive market in copper, the matter of increasing the capacity of the concentrator was again given serious attention. As ore became available in the mine and the output of the mill was increased, limitations for a satisfactory recovery were observed, due to the overloaded condition of the classifier units at the higher tonnages. From a metallurgical standpoint, the ore from the Copper Mountain mine had always been difficult to treat on account of the finely disseminated character of much of the mineralization and the difficulty of grinding to the desired fineness. This trouble has become aggravated with time as an increasing amount of wall-rock has diluted the ore and lower grade orebodies have been mined. It therefore has been, and is, the practice at the concentrator to maintain the maximum amount of reduction in size of material fed to the flotation units as is possible for the daily tonnage to be milled. This means that all the grinding units are operated for the maximum possible time, and that the classifiers are regulated to return as much feed ?as possible to the mills. The number of tons to be milled for ?the day is determined by the concentrator superintendent after ascertaining the availability of ore from the mine, the condition of the concentrator ore bins, and the need for repairs in the rolls plant. In order to maintain the tonnage des1red, hourly estimates are made of the rate of grinding by weighing the amount of ore contained on one foot of each of the belts conveying the feed to the various ball-mills, and adjustments are made accordingly.

Jan 1, 1950

By J. A. Finch

Individual mineral cyclone performance curves were determined for the four major minerals at two lead-zinc concentrators. Sizing was by screen and cyclosizer down to approximately 10 um, with lead , zinc and iron as saying of each size fraction. The performance curves were similar in shape and located according to the mineral specific gravity, Pm. The curves displayed a discontinuity at the fine end and a magnitude of short-circuiting of fines to the underflow which increased with Pm. Mass fraction of water to the underflow was only a guide to this short-circuiting. Sharpness of separation seemed in dependent of Pm. An inflection in the over-all performance curve was shown to be a consequence of the individual component mineral performance. A general relationship was observed showing that the flow regime of classification changed from laminar/ intermediate to turbulent with increasing cyclone feed size. Individual mineral size reduction for the four major minerals at one of the concentrators was also determined. Size reduction of the silica was greater than that of the galena, in contradiction to their accepted relative grind-ability. The observation did correlate with silica being much coarser than the galena in the feed to the ball mill. It is suggested that the silica acted as a buffer to the galena.

Jan 1, 1977