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By P. Taskinen, D. Lindberg, H. Viitala

The formation of copper chlorides in flue dust or deposits in heat recovery boiler of copper smelters or waste-fired boilers may lead to formation of corrosive partially molten deposits on walls and heat exchangers of the boilers. These deposits can contain various other metals, such as alkalis, Fe, Zn, Pb together with oxides and sulfates. In the present study, a thermodynamic model for copper-containing binary and ternary metal chloride systems within multicomponent CuCl-CuCl2-FeCl2-FeCl3- PbCl2-ZnCl2 system has been assessed and optimized based on own experimental phase equilibrium data, as well as literature data. The thermodynamic properties of the liquid phase was modelled using the quasichemical quadruplet model and a thermodynamic database was optimized to predict all available experimental data within the experimental error limits. The thermodynamic database allows for more accurate predictions of potential corrosion-related issues in various heat recovery boilers and waste-fired boilers due to formation of copper chlorides. INTRODUCTION In the copper flash smelting, flue dust can cause severe problems in the gas train, used for separating dust from the SO2-rich off gas, by forming corroding accretions on the walls of the heat recovery boiler. Formation of dust build-ups in the boiler need to be cleaned regularly and potential corrosion damage checked, requiring costly and unscheduled shutdowns of the flash smelting process. Compounds of copper and zinc among other elements having high vapour pressures may volatilize during the smelting of the copper concentrate, forming dust when the process gas cools down. Also, particles of solid or liquid iron oxides originating from the ore get transported with process gas to the heat recovery boiler as a result of entrainment in the flue gas (Miettinen, 2008) The dust deposit build-ups on the boiler walls are formed partly by direct impact of particles and partly by vapour condensation on the boiler walls. The initial deposition takes place by the condensation of vapours that contain zinc, lead, arsenic and other metals having high vapour pressures. Also, low melting point eutectic components of alkali salts such as chlorides and sulphates can act as sticky cohesive particles attaching to the boiler walls. The fine particles landing on the surface of the porous dust deposit layer react in the SO2-rich atmosphere of the boiler to sulphates. The process gas within the boiler contains SO2, O2, SO3, H2O and N2 that diffuse into the porous accretions to form a stagnant gas layer within the dust deposit structure. The composition of this gas layer may differ greatly from the composition of the process gas that is flowing on the surface of the accretion layer. Locally HCl and H2SO4 are formed and even a reducing atmosphere may exist within the dust deposit layer, allowing new reactions to take place. The local micro-atmosphere may enable metal sulphates to be reduced to secondary sulphides and even metallic components. Within the accretion layer, components may be formed that would not be stable in the gas atmosphere inside the boiler (Miettinen, 2008). This may be the mechanism by which for instance chlorides of Cu, Fe and Zn are formed within the deposit layer.

Jan 1, 2019

By S. A. Luciani

"In 1957, an asbestos orebody was discovered in the northern sector of the Ungava Peninsula of the Province of Quebec, an area now identified as Asbestos Hill. The deposit is situated on a plateau 1700 feet above sea level and 42 miles inland from Hudson Strait. It is a bleak, iso. lated location of typical arctic environment. Fifteen years were to pass before the first shipment of ungraded fibre was made in 1972. These years we1•e occupied with field surveys and investigations, diamond drilling, engineering design, evaluation of investment and operating costs, and construction. The problems normally associated with mine development were further complicated by location, isolation, and the extreme cold and permanently frozen ground of the arctic regions. Unique to an isolated arctic operation are the organization of support facilities and services, procurement and retention of personnel, construction of access roads and airports, and scheduling of product out and supplies in during the short summer period of sea navigation."

Jan 1, 1976

By James F. Archibald

In historic mining practice, typical thin liner support systems have been considered to comprise non-reinforced or mesh-reinforced shocrete linings. In the early 1990?s, development of alternate forms of liner systems was initiated in Canada which is now undergoing significant international growth in countries which sustain major mining activity. Now internationally designated as thin, spray-on liner systems, a wide spectrum of liner materials, ranging from liquid/liquid to liquid/solid component combinations, has become commercially available. This innovative family of products is characteristically identified as being rapidly deployable, capable of creating ultra-fast setting coverage over rock surfaces, and able to develop tenacious adhesion and pull strength capacities for resisting rock falls and movements. This paper presents a summary of current liner developments and use in principal mining districts world wide. Additionally, a database of material properties for principal product types used in mining and a review of common quality control testing procedures under development are provided. Such information is based upon recent Canadian and international efforts being taken to assess and develop user standards for the implementation of thin, spray-on liners as rock support in mines. This work is intended to continue for a period of years, with the eventual goal being to establish support and installation guidelines for mines based on quantifiable laboratory and field research.

May 1, 2002

By Tiziana Apuani

The study refers to an area of about 70 km2, extended in the Italian Central Alps along the the San Giacomo Valley where different civil and mining works are present The regional geological setting is related to the Pennidic Nappe arrangement, characterized by the emplacement of sub-horizontal gneissic bodies resulting from the Mesoalpine isoclinalic folding of crystalline basements, emplaced throw East, and separated by matasedimentary cover units. The investigated geological rocks, belong to the ?Tambò?Unit, overlapped by its meta-sedimentary cover and by the ?Suretta? Unit. The tectonic contact gently dips to the E?NE. The valley, furrowed by the Liro Torrent, follows a N?S striking tectonic lineament, almost parallel to the nappe contact. A number of more then 70 sites, distributed in the studied area, were chosen and detailed structural and geomechanical field surveys were performed to characterize the rock masses, its intact rock and discontinuities. The procedure identifies the number of joint sets, their representative orientation, the set spacing, the type of movement, the amount of dilatation, the degree of alteration, the roughness coefficient, the presence and nature of infill. Rock mass quality indexes, such as the Rock Mass Rating (Bieniawski, 1989) or the Geological Strength Index (Hoek et al. 2002) have been evaluated in each surveyed site. The work is a contribute in assessing how the geometrical and geomechanical properties of the rock masses can be regarded as regionalized variables. The spatial distribution of these properties is a function of the geological and structural phenomena at which the rock masses have been subjected. The presented geostatistical analysis regards the spatial variation of the orientation of the most representative joint set.

May 1, 2009

By Lori Kormos, Jhonny Carrión De la Cruz, Dominic Fragomeni, Elizabeth Whiteman, Jorge Oliveira

"Process diagnosis, flowsheet design and optimisation are most effectively and efficiently achieved through the use of metallurgical testwork combined with more modern quantitative mineralogical techniques. Integration of the mineralogical data in testwork programs provides a resolution that cannot be obtained from assays alone and can direct the flow of work to result in optimized conditions more quickly than would otherwise be possible. At Xstrata Process Support (XPS), QEMSCAN (Quantitative Evaluation of Materials by Scanning Electron Microscope) and EPMA (Electron Probe Micro Analyser) information can be employed to diagnose specific issues in a plant or lab scale test and are routinely combined with other metallurgical data sets to benchmark performance, design and optimise flowsheets. Representative sampling protocols for ore bodies or test products, the use of geometallurgical unit classification and high confidence metallurgical test programs are key components of the strategy. Two case studies from Xstrata Zinc’s Antamina Mine and Concentrator in Perú, and Xstrata Nickel’s Nickel Rim South Mine in Sudbury are described to show how the use of quantitative mineralogy were used to diagnose a plant issue and how the data can be integrated into metallurgical programs to assist mineral processing engineers to design and optimise flowsheets.INTRODUCTIONOver the past decade, there has been a shift away from metallurgical testing that employs only chemical assays to quantify performance; the use of empirical observation in order to optimise a flowsheet; and the extraction of bulk samples for testing or piloting. The integration of geological information into the planning and execution of testwork programs including the use of quantitative mineralogy has improved the overall quality and predictability of metallurgical programs. At the same time, improvements to metallurgical testwork protocols such as rigorous statistical assessment of results, the use of factorially designed experimental strategies (DOE), and replicate flotation with appropriate quality controls, has improved the confidence level in these results.Process diagnosis, which utilizes quantitative mineralogy, can clearly define the root cause of the metallurgical issue. Whether used on its own to diagnose an issue or in combination with other metallurgical testwork, the use of mineralogical data has become the standard in the mining industry."

Jan 1, 2010

By Alan D. Akerman

This paper describes the significant advantages and improvements in operational availability, reduced breakdowns, and overall cost reductions that can be achieved through the application of a Reliability Centred Maintenance (RCM) program, including Condition Based Maintenance (CBM) and Equipment Health Monitoring (EHM), in a mine environment. It uses a case study to illustrate the essential elements that constitute the basic requirements to establish such programs. This CBM case study analyzed the Load-Haul- Dump (LHD) vehicle sub-systems and their dominant failure modes, as a precursor to the development of condition indicators. The case study describes a disciplined process to enable condition indicator development and qualification in support of a CBM program. The identified condition indicators vary from readily applicable off-the-shelf monitoring systems and techniques, through to "leading edge" technologies that require further research and development. The paper also explores the developments that have been made in the combination of expert system software associated with modern computer based control systems, and the availability of "intelligent? sensor technology that complement the control system capability.

May 1, 2002

By Kim Le Roux

Cemented paste backfill (CPB) is a relatively new material that is increasingly being used in open stope mining across the world. The advantages offered by this high density tailings backfill include: a lower total cost associated with backfill placement, reduction of excess water underground; and the elimination of the need to process the tailings prior to placement. However, almost all backfill design is based on the performance of laboratory prepared samples since it is difficult to obtain undisturbed samples and conduct in situ testing due to the lack of access to backfilled stopes and the safety concerns in accessible areas. The logistical problems associated with conducting in situ testing and obtaining undisturbed samples of cemented paste backfill (CPB) has lead to the reliance in the mining industry on performance data obtained from laboratory prepared CPB samples. The degree to which these laboratory prepared samples represent the actual in situ condition is not well defined, partly because the influence of the mixing, transport and placement process on the material properties it is not well understood. Therefore, there is a need in the industry to understand how the material properties and hence the performance of the laboratory prepared CPB compares with in situ material. This paper reports the findings of an investigation into the in situ properties of CPB at a gold mine in Northern Ontario. A combination of in situ and laboratory testing, conducted on undisturbed samples, was used to quantify the in situ properties and performance of the CPB. These results were then compared to those of a laboratory based investigation of the same CPB. It is evident from this investigation that the bulk properties of the in situ CPB are different from those of the laboratory prepared CPB. The most significant observed differences are that the in situ CPB has a higher void ratio and a lower degree of saturation than the laboratory prepared material. The implication of these differences on the stability and performance of the CPB will also be explored in this paper. 1

May 1, 2002

By G. Goodall, R. Jabbar, S. Muinonen, A. Cummings

"Glencore’s Sudbury Integrated Nickel Operations in Falconbridge, Ontario, has been in operation since 1930. Many new technologies and practices, now common in the industry, have been implemented at the site and contribute significantly to the industry’s understanding. Since the last update on the Smelter operation published at the NiCo 2005 conference, the Converter Aisle has undergone significant changes in the operation of vessels. The Aisle continues to consist of 4 Peirce-Smith converters, but the Slag-Make Converter, and the Slag Cleaning Vessel have been re-tooled or re-built as Hybrid Vessels (HV), each generating matte for the two Finishing Converters and clean slag for disposal. The complicated scheduling and the overall benefits to the Smelter are reviewed here as part of the on-going tradition of industry support.INTRODUCTION The Glencore Nickel Sudbury Smelter operates a Roast Reduction Smelting (RRS) flow sheet with a specialized Converter Aisle operation that maximizes metal recovery to Bessemer matte. The main process equipment consists of a pair of Fluid Bed Roasters, a submerged-arc Electric Furnace and four Peirce-Smith converting type vessels (Figure 1). In the RRS flow sheet, concentrate is roasted with air to remove sulphur as SO2. Calcine from the Roasters is mixed with petroleum coke upon addition to the six-in-line rectangular Electric Furnace. The coke back reduces the metallic oxides, producing a matte and a discard slag.Gases from the Roasters are sent to a single pass absorption Acid Plant where the SO2 is converted to acid. Under the previous operating targets, approximately 70–75% of the sulphur in the incoming concentrate was fixed as acid with the balance going to the Electric Furnace in calcine for Bessemer matte production. Off-gases from the Electric Furnace and Converters are combined in a balloon flue, treated for particulates in electrostatic precipitators and discharged to the Smelter stack without any SO2 fixation."

Jan 1, 2017

By G. Simard, M. J. Gagnon, A. Charette, G. Péloquin

"In the Bayer process, flocculants are introduced in the feed well to enhance the aggregation of red mud particles. To gain a better understanding of the flocculation process taking place in the feed well, shearinduced flocculation was achieved using concentric rotating cylinders (Couette system). Our previous work has shown the effect of the shear rate on the aggregate’s settling rate and on residual turbidity of the Bayer liquor. In this study, the data demonstrated that the aggregates at selected shear levels appear as a population with a widespread size distribution. By using an imagery apparatus, it was possible to measure the size, the shape, and the sedimentation velocity of the larger red mud aggregates. Marked differences were noticed in the characteristics of the aggregate populations obtained under various shear conditions. IntroductionIn the Bayer process, red mud particles are separated from the liquor in primary clarifiers and washing circuits under the action of synthetic polymers. The agitation in the feed pipe and in the feed well affects the flocculation since the aggregates are formed by the interaction between the red mud particles and the polymers. A minimum shear rate is needed to initiate the aggregation process of fine particles (Warren, 1975).Different systems have been used to study the effects of shear on the flocculation process (Tampo and Watanabe, 1979; Klimpel and Hogg, 1986; Scott et al., 1996; Biggs and Lant, 2000). The Couette flow system has been used in some studies on shear-flocculation (Oles, 1992; Farrow and Swift, 1996a, 1996b). The importance of the physical properties of the aggregates in determining the efficiency of the solid-liquid separation process within a given gravity thickener has been demonstrated (Farrow and Warren, 1989a)"

Jan 1, 2002

By Å. Kruukka, H. F. Broicher

The iron ores of the Kiruna mine in Sweden are of exceptional quality except for the phosphorus content in certain zones of the orebody. The prevention of mixing ores high in phosphorus with those low in phosphorus has always been of significant economic importance. The ongoing introduction of tele-mining and automatic haulage by LHDs requires new means in the field of quality control underground, as the experienced miner as well as the underground laboratory assistant no longer are involved in the process. As of 1998, LKAB has been testing prototypes of LIF (laser-induced fluorescence) analyzers for non-contact and real-time measurement of the phosphorus content of ore being transported by LHDs from the stopes to the respective ore pass assigned to a certain ore quality. The principles of the analysis of laser-induced fluorescence, the different test phases and results are described and conclusions made. With bulk sorting of ore underground, the mining engineer supports the efforts of the metallurgist in the processing plant.

Jan 1, 2002

By H. A. Dakin

"An introduction to the metallurgical requirements of the Flin Flon concentrator reveals the magnitude of ore blending which is required in its operation of three flotation circuits. The resulting variability in flotation heads which has in-creased the separations complexity justified the development of an on-line analysis system.This paper provides a summary of the development and operation of that system. Particular attention is devoted to the problems encountered and where possible their solutions; as the requirements of accurate information and minimum downtime of the sampling system and x-ray analyzer are considered essential. The addition of a recess central computer has provided information in a more easily understood form and as well has allowed the start of automatic reagent control.An indication of the on-line analysis system's value to the concentrators' operation is provided by an examination of the plant in metallurgical data and reagent costs in previous years.The metallurgical plants of Hudson Bay Mining and Smelting lie adjacent to the city of Flin Flon on the Manitoba-Saskatchewan boundary. Plant operations commenced in 1930 treating copper-zinc ore from the local mine. In recent years ore bodies near Flin Flon and in the Snow Lake area, about seventy-five miles east, have been brought into production.By the beginning of 1973 the number of producing mines had increased to nine; with all the ore being handled by the Flin Flon concentrator. Figure l, showing mine ore assays during 1973 indicates the variation in metal content possible."

Jan 1, 1974

By Virginia T. McLemore

The Gallinas Mountains are in northern Lincoln County and southern Torrance County, New Mexico, USA where a series of alkaline igneous bodies, including porphyritic latite, trachyte/syenite, andesite, and rhyolite laccoliths, flows, dikes, and plugs, have intruded Permian sedimentary rocks belonging to the Permian Abo, Yeso, and Glorieta Formations. A small amount of bastnaesite, a REE mineral, was recovered during processing for fluorite from the Gallinas Mountains. Four types of deposits are found in the Gallinas Mountains: epithermal REE-F veins, Cu-REE-F veins, REE-F breccia pipes and iron skarn deposits; all are associated with Tertiary alkaline to alkalic-calcic igneous rocks. Alteration includes brecciation, silicification, chloritization, and fenitization. District zonation is defined by Cu-REE-F (±Pb, Zn, Ag) veins that form center of the district, surrounded by REE-F veins. Carbonatites are inferred at depth by the presence of fenitization, carbonatization of the breccias, presence of REE and similarity of the intrusive rocks and mineralization to areas with known carbonatites.

May 1, 2011

By K. Dinh

The Ground Penetrating Radar (GPR) has been studied for a long time as a non-destructive evaluation (NDE) technology for inspection of concrete structures. Currently, the most widely used technique for interpreting GPR data of concrete bridge decks is the one that based on the amplitudes measured at various interfaces such as asphalt-concrete, top rebar, or slab bottom. The assumption behind this technique is that a sound concrete deck should have the same reflection amplitude at these interfaces while any low number would indicate some sign of deterioration. Unfortunately, this assumption is not completely valid in most cases. As a consequence, the reported test results usually do not reflect real condition of concrete bridge decks in question. The main goal of this paper is therefore twofold: (1) to discuss the limitations of the amplitude analysis method, and (2) to propose a new model that interprets GPR data of concrete bridge decks. The model methodology is based on the comparison of GPR A-scans between two inspections, using the so-called correlation analysis. The results, indicated by the correlation coefficients, are then employed to develop a contour map that estimates different levels of deterioration. The model is then implemented to a case study in order to illustrate its methodology.

Aug 1, 2013

By L. Connolly, F. R. De Luca

"Rubber liners at Denison Mines Limited are used in 10 1/2x 24' low discharg0 pebble mills. These were originally 10 1/2 x 13 Dominion overflow type ball mills. Experience here shows that the wear of rubber and ni-hard lifters is approximately the same in the feed end half of the mill, while the wear of rubber lifters is much greater in the discharge half. The wear of rubber plates is considerably less than white iron in the feed end half of the Mill and slightly more in the discharge end half of the Mill. Rubber components are lighter to handle but their installation is time consuming. This leads to the conclusion that a combination of ni-hard lifters a~~ rubber plates is the most economical compromise in Denison's case, for the Mill. Rubber discharge grates are superior to steel grates, while steel feed end liners are superior to rubber.The Use of Rubber Mill Liners at Denison Mines LimitedGrinding is done in two identic0al circuits each consist-ing of one 10 1/2 x 14' Dominion overflow rod mill, two Dorr Oliver quadraplex rake type classifiers, two 10 1/2 x 24' Dominion low discharge grate pebble mills and ancillary pumps and conveyors for pebbles. There is one centrally located distributor box that receives the discharge of the 4 pebble mills and splits it out to the classifiers."

Jan 1, 1974

By Paul Staples, Chris Morley

"The development of the Cerro Verde, Amplats Mogalakwena and Boddington projects over the last few years has helped to establish the use of high pressure grinding rolls (HPGR) in comminution circuit designs in large-scale hard-rock applications. The increasing acceptance of this innovative and sometimes controversial technology has had the natural effect of prompting many other new projects to examine HPGR as an alternative to the established, usually SAG-based, comminution circuit design approach.At the current stage of development of the technology, HPGR-based circuit capital costs are generally higher than for the equivalent SAG-based circuit, so that HPGR must offer sufficient operating cost benefits to offset the additional capital costs over an acceptable pay-back period. It is usually necessary to undertake comprehensive project-specific trade-off studies to quantify this effect.This paper describes the processes involved in the execution of a typical SAG-HPGR trade-off study, from the preliminary assessment of ore characteristics and project criteria, through testwork, circuit modelling, equipment selection and cost estimates, to a project-economics comparative assessment of the options. The trade-off study determines both the technical feasibility of the respective technologies and their commercial viability in the given project setting.The paper concludes with a cautionary note to the effect that, while HPGR has many potential benefits, it is not a panacea, and that, for some ore types and project conditions, the more established conventional technologies are often more appropriate."

Jan 1, 2010

By M. E. Coleman, G. Money

Pneumatic Conveying and Process Injection Technologies have been implemented in the metals markets for the last 40 years and have considerably improved the productivity and the performance of many processes. There have been many steps forward in handling technology and this paper seeks to consider those now offered by Clyde Materials Handling who as an established customer-driven solutions provider has turned its attention to supporting the Metals Market. Clyde seeks to utilise its knowledge, expertise and technologies to transform the production processes of its customers, who operate in the ferrous and non-ferrous metals industries.

Jan 1, 2008

By K. Delbeke

Within the framework of the EU Existing Substance (93/793/EEC) and REACH regulations EC/1907/2006), the copper industry initiated in 2000 a comprehensive Voluntary Risk Assessment of copper and several copper compounds. The Italian Government's Istituto Superiore di Sanità, reviewed the process and reports on behalf of the European Commission. Copper exposure levels to man and the environment from production of copper anodes and cathodes, copper powders and copper chemicals as well as fabrication and use of semi-fabrication products and down stream user products were collected across Europe. Environmental and human health effects data were obtained from literature as well as novel research programs and used to deduct safe threshold

Jan 1, 2007

By J. Patterson

"Acid Mine Drainage (A.M.D.) formed from oxidation of disposed pyritic wastes presents a potential pollution hazard for Equity Silver Mines Limited and the mining industry in general. Failure to collect and treat these acidic effluents can eventually affect the quality of receiving streams and endanger aquatic life forms. Treatment and discharge of A.M.D. to the receiving environment must comply with stringent anti-pollution laws.Wastes mined at Equity Silver Mines Ltd. are predominantly acid generating and must be handled according to a materials management plan to minimize impact on the environment. Effluent collection and treatment facilities have been constructed to address the short term environmental concerns with reclamation and research programs being developed to address and monitor abatement measures for control over the long term.The purpose of this paper will be to offer a brief overview of these measures. Key topics for discussion will be: kinetics of Acid Mine Drainage, acid generating potential, water treatment and sludge handling, special wastes, waste dump construction, waste rock amendments, bacteriocide research, simulations, and reclamation measures. Programs designed to evaluate impact on the receiving environment, although they form an extensive part of the program, will not be discussed in this paper.INTRODUCTIONEquity Silver Mines Limited is located in the Central Interior of British Columbia, within the Omineca Division, 35 kilometers southeast of Houston Mining and approximately 575 kilometers by air north-northeast ofVancouver (Figure 1).The deposit consists of three economic mineralized zones: The Southern Tail, Main and Waterline Zones. Mining of the Southern Tail commenced in April, 1980 and was completed in the first quarter of 1984. Main Zone production was initiated during the last quarter of 1983 and the Waterline Zone remains undeveloped to-date. Remaining reserves are in the order of four years contingent on favourable metal prices. The three deposits (Figure 2) occur within a window of interbedded volcanic and minor sedimentary rocks. The older volcanic sequence is bounded on the west by a small granite-like stock and on the east by a gabbro-monzonite complex. All are overlain by a series of younger lava flows."

Jan 1, 1988

By E. W. Thorton

"This paper is intended to show that grinding media can effect flotation results, and in some instances the results are vastly different. I do not suggest that autogenous grinding is beneficial in the separation of all complex base metal ores, in fact I know of a case where autogenous grinding would be disastrous to any selective flotation. I do however contend that prospective flow sheets and reagent balances of any complex base metal ores should be tried with both types of grinding. I feel fortunate that the paper to be presented later in this meeting by Rene Klymouski will, I think, compliment and perhaps explain some of the results of my research.This paper will be in four parts. The first part deals with a literature survey on the subject. Surprisingly enough, very little information has been printed on the subject. The second part deals with results obtained in bench scale tests on an ore from Chester Mines Limited. It was in these tests that we realized that steel grinding was giving us serious problems. So bench scale tests are shown giving results with a stainless steel grind, a mild steel grind and a grind in a ceramic mill with ceramic billets.The third part of the paper deals with results obtained in the Mines Branch Pilot Plant, when again we ground the ore with three different types of grinding media. Incidentally, this has been the only pilot plant test made at the Mines Branch in which flotation products were made on both steel grinding and autogenous grinding on the same ore. The fourth part deals with two other New Brunswick ores and is intended to show that changing the grinding media effects ores other than that of Chester Mines Limited."

Jan 1, 1973

By W. van der Merwe

ABSTRACT With the gold industry processing more complex ores, the online measurement and control of cyanide addition to the gold leaching circuit has become more critical. This paper compares the two commonly employed ‘free’ cyanide online analysis methods (amperometric and potentiometric endpoint silver nitrate titration) with the rhodanine endpoint silver nitrate titration and ion selective electrode methods common at site laboratories. Measurement differences between these methods are presented and discussed for cyanide solutions containing copper and zinc with varying cyanide to metal ion ratios. The resulting cyanide available to leach gold is also compared using these measurement techniques.

Jan 1, 2013