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By Y L. Ma, M Chen, W Bruckard

With the extensive exploitation and gradual depletion of high-grade copper reserves, the mining industry is paying more and more attention to the hydrometallurgical extraction of copper from lowgrade and arsenic bearing copper ores. Hydrometallurgical processing, such as heap leaching, column leaching and bioleaching, provide a viable alternative to the traditional pyrometallurgy due to its harmony with the environment, moderate capital investment, and low operating costs. However, the slow leaching kinetics of enargite (Cu3AsS4) and chalcopyrite (CuFeS2) remain problematic for commercial leaching practice. The formation mechanism and the nature of the passivating layers during leaching is still a matter of debate in hydrometallurgical research. In this study, the dissolution mechanism of enargite and chalcopyrite in sulfuric acid solution was investigated using a range of electrochemical and spectroscopic analysis methods. Electrochemical oxidation of enargite demonstrated an obvious passivation region from 500 to 750 mV (Ag/AgCl). The formed passivation film was found a n-type semiconductor behaviour, which is different from the original enargite with a p-type behaviour. The results of X-ray photoelectron spectroscopy (XPS) suggested that a nonstoichiometric film Cu(3−x)As(1−y)S4 (x>>y) accumulated on the electrode surface, which accounted for the obvious decrease in current density in the passive potential region. For chalcopyrite, three important potentials of 550, 680 and 730 mV which are related to the formation and dissolution of passivation film were observed based on the cyclic voltammetry (CV) and potentiodynamic polarisation. Raman and X-ray absorption near edge structure (XANES) spectra studies of the chalcopyrite electrodes after being treated under these three potentials indicated a metal-deficient sulfide of Cu1−xFe1−yS2 (y>>x) might be responsible for the passivation phenomenon. Hence, it is concluded that the passivation of enargite and chalcopyrite are similar which are caused by metaldeficient sulfide surfaces although the compositions of the metal-deficient sulfide are different.

Aug 24, 2022

Mount Isa Mines Limited has been mining silver-lead-zinc ore at Isa Mine for 60 years. Mining methods have evolved continuously, and current production rates of 4.7 Mt/yr are obtained from a combination of sublevel open stopping, cut and fill, and benching methods. In the near future, orebodies mineable by open stoping will be gradually depleted, and the relatively new benching method will be further refmed to replace cut and fill methods wherever possible.

Jan 1, 1993

Mining projects frequently fail to meet their financial objectives. A significant area of poor performance lies in the areas of resource estimation, reserve definitions, selective mining and metal accounting. The processes leading to the exploi

Jan 1, 1998

Iron and steelmaking slags have been utilised for a century. All dumps are now exhausted. Because of constraints in establishing new stock yards, all slags have to be utilised immediately. At present, this is being achieved. Only in a situation where there is an increase in pig iron and crude steel production, together with the impact of new residual materials competing from other industries can marketing problems be anticipated.

Jan 1, 1979

The main objectives of this paper are to identify the main sources of coal dust and to investigate measures for minimisation of dust generated at these sources at the Bukit Asam open cut mine, on the island of Sumatera, Indonesia which uses a

Jan 1, 1994

A simple and rapid method for delennining gold and silver in carbon samples is described. The method involves dissolution of carbon ash in a strong oxidising medium of aqua regia and hydrofluoric acid. Gold and silver are determined in the resultant solution using atomic absorption speetrometry (AAS). The method is efficient and reproducible. Gold results are comparable to the standard fire assay results, with agreement of results within ± 5 per cent. The co-efficients of variation for gold and silver are 0.37 and 0.39 per cent respectively for six replicate analyses. The analysis of gold and silver in a batch of ten carbon samples can be completed in approximately four hours.

Jan 1, 1992

By Craw D

The Southern Alps in the South Island of New Zealand are currently rising rapidly as a consequence of continental collision along the Pacific-Australian plate boundary. Rapid uplift has resulted in a major thermal anomaly in the shallow crust beneath the alps. Alpine topography and associated intense precipitation, coupled with the thermal anomaly are responsible for vigorous combined topographic/convective circulation of water through the shallow crust.

Jan 1, 1995

By Minglin W, Zhixing L

The laws of detonation wave velocity variation in propagation process along the charge under channel influence are investigated widely in this paper. The result is obtained by blasting experiments. Bore hole is simulated by plastic tube or steel pipe (with outer diameter 45 nun, inner diameter 40 or 41 mm). Blasting experiment is carried out with a cylindrical charge of 32 mm diameter. The author analyses the characteristics of energy distribution along the charge under above-mentioned conditions. Reasonable initiating position and initiating direction are also analysed. A double-direction initiating method which consists of several initiating charges is put forward. The blasting effect of this initiating method when used in underground mining is stated out.

Jan 1, 1990

At Renison Limited, on the West Coast of Tasmania, modern trackless decline mining is practised to exploit the various tin bearing sulphide deposits. With footwall accesses, one of three adaptations of horizontal mechanised cut and fill, 1. unsupported, 2. pillar supported,and 3. unsupported - resuing is used to stope each defined ore block. The stoping method is basically determined by the dip and true thickness of the ore with emphasis on high ore recovery. Extreme flexibility is possible by the selective mining of stope lifts, the consumption of development waste as fill and the utilisation of the same mobile equipment in all phases of production. This has resulted in high productivity and low cost per tonne of ore.

Jan 1, 1977

Conditional simulation is a branch of geo- statistics which allows the simulation of a mineral deposit so that predictions can be made about the variability of some particular parameter of the deposit. A summary of the general principles, advantages and limitations of conditional simulation is presented together with an example based on coal seam thickness.

Jan 1, 1981

This paper outlines the thermodynamic and mass balance principles which affect the distribution of cobalt between matte and slag during the pyrometallurgical treatment of nickel-copper sulphides and considers the implications with regard to maximising the recovery of cobalt from the smelting and converting circuit.

Jan 1, 1994

By Crawford J

The paper asks the question 'Why Limit the HYDROTRANSPORT of material to the confines of your washplant'.A brief historical review of widely accepted slurry transport operation establishes that we are not talking about new technology - simply applying proven experience to an innovative continuous system.The paper reviews a simple potential application and compares capital and operating costs with conventional trucking.No attempt has been made to develop a complete mine plan and the comparison has been limited to material transport costs.

Jan 1, 1992

By Corbett GJ

Epithermal gold-silver deposits occur in young volcanic terrains where post-mineral cover commonly impedes the search for mineralisation. At the Togi Project in Honshu, Japan, a complex mineralised system is largely covered by post mineral volcaniclastics. A combination of high resolution electrical resistivity surveying and detailed airphoto interpretation has, with close geological control, enabled synthesis of structural and alteration characteristics of the Togi geothermal system, in turn permitting ranking of the prospects for drill testing.

Jan 1, 1990

By Jifan X, Yongyu W, Liangjing L

Shallow interception of groundwater is a special dewa- tering form in the specific geological and hydrogeological conditions. It has an economic and technical effect. The roof of the Fankou Lead-zinc deposit is the Hutianqun aquifer made up of the limestone of the upper Carboniferous system. - A "water-bearing basin" is surrounded by the aquifuge and the aquitard below ¦0 m level at the Shiling Hill section in the Hutianqun aquifer. Based on the natural conditions, an interception gallery is excavated at -40 m level out of "the water- bearing basin", the other gallery excavated at ¦0 m level in the poor water-bearing zone of the Jinxing Hill. During 20 years of experience, the better interception effects have been gained.

Jan 1, 1988

A test model is presented for the simulation of dewatering by gas injection of a porous aquifer above longwall workings. A finite difference model used in the oil industry was modified to match the underground mining conditions. The model is suitable to cope with the problem of dewatering reservoirs of low transmissivity. After comparing more versions, it has been concluded, that the investigated dewatering method can be proposed under special hydrogeological conditions only.

Jan 1, 1988

Geomorphology is one of the most basic elements in geographic enviroments. Geomorphological mapping is significant in the spatial distribution of representing land form and understanding various features of geomorphology. Geomorphological mapping began very early in China, as the map, showing conekarst(karst pinnacles) of Juiyishan, Hunan province, it was drawn in 168B.C., which was excavated from Han tomb. Mawangdui, Changsha. Its original idea of map-making is rather similar to that of modern map and could undoutedly be the oldest map of tropical karst discovered in the world.Before liberation, landform mapping was done piecemeally and only a small number of maps were prepared by a few editor as insets.

Jan 1, 1990

Rock bolting provides a supplement or alternative to conventional timber and steel supports. The tensile strength of the bolts lies within a range established by manufacturing quality control. Rock bolt testing determines the ability of the rock, anchor and individual bolt as an assembly to accept load. The.test is performed to the yield strength of the bolt or anchor and deflection is observed. The anchorage index, inches deflection per 1000 lb load increment, is a measure of anchorage quality. This allows comparison with anchorages under ideal conditions. It also permits comparative assessment of roof bolt anchors in a particular environment.

Jan 1, 1971

By Evans RH, Todd G

Statistical thinking and statistical process ppq;ro4 are essential adjuncts of total quality management aqd too continuous improvement of operating efficiency arid, p*Nc; a4 W,

Jan 1, 1991

A new plant for grinding limestone was built at the Risdon Works of the Electrolytic Zinc Company of Australasia Limited to meet increasing process demands expected to reach 150 tonne/day of ground limestone. Plant specifications included open- circuit wet grinding, a single ball mill, a feed sizing of minus 6 Tyler mesh, a product sizing of 100 per cent minus 200 and 95 per cent minus 325 Tyler mesh and for the plant to be unmanned during normal running. Main features of plant and equipment are described; grinding performances given, as well as operating experience since commission- ing of the plant in March, 1976.

Jan 1, 1977

By Dorricott M. G

Rock bolt installation is generally carried out in two steps. First the hole is drilled and the drill steel is extracted, then the bolt is inserted into the hole and tightened or grouted. With single pass bolting (SPB), however, these two steps can be carried out at the same time. This kind of bolting system has at least three advantages, (1) the time used for the bolt installation could be reduced, (2) the condition of safety for the operators could be improved, and (3) the degree of automation of the rock bolting practice could be increased. The study presented in this paper is concerned with the development of the SPB system. The current state of the system is discussed, and further improvement of the technique is explored.

Jan 1, 1992