Search Documents

By M Pizey, P Lindsay

Coal mining has been occurring on the Stockton Plateau for over 100 years. As a result of both natural conditions and mining activities, surface water on the plateau is known to have low pH and elevated metals concentrations, a condition known as acid rock drainage (ARD). Solid Energy New Zealand Ltd (SENZ), as owners of the current mining operations at Stockton desire to understand the nature and causes of ARD at Stockton to determine whether commercially viable options can be developed to improve the water quality to levels acceptable to the local community and regulators. A series of integrated water quality investigations have been performed towards developing a characterisation of the water quality on the Stockton Plateau and receiving waters. The investigations performed include: design and implementation of a water quality monitoring program to collect a satisfactory base of water quality data from which to develop an understanding of the water quality and its variability, and to collect data regarding the range of flow rates that occur in the principal streams; development of a hydrological model for the Plateau with the ability to predict flow rates at key locations on the plateau and on the Ngakawau River; field investigations of the bio-diversity of the plateau and surrounding areas, to develop a snapshot of the health of aquatic communities and whether streams draining mine workings are æadversely impactedÆ; eco-toxicology; waste dump seepage water quality monitoring at selected basal springs, drilling, investigations and permeability and geochemical testing; data processing of a range of historical data and the newly acquired data for the development of empirical relationships that describe the water chemistry system and its relationship in turn to flow rates in the streams; simulation of the long term water quality record for the measured parameters (pH, acidity and metals concentrations), based on the hydrological model and the empirical relationships developed from the new database; and preliminary development and examination of mitigation options for the ARD issues at the mine. The study has progressed towards design of pilot studies of options for mitigation of the generation of the ARD as well as treatment of the discharges. It is the integrated approach adopted by SENZ from an early time in the investigations, that has enabled fast-tracking of the pilot engineering trials. This paper presents the results of the field investigations and eco-toxicology studies and demonstrates the value of predictive modelling of water quality in the study area, even at a very early stage in the remedial engineering design process.

Jan 1, 2003

The West Fork project is located in Reynolds County, Missouri, in the mineralized zone referred to as the Viburnum Trend. The West Fork orebody has a calculated ore re- serve of 13 600 000 tonne (15 000 000 st) con- taining 5.5 per cent lead, 1.2 per cent zinc, and recoverable values of copper and silver. A total of 64 600 tonne (71 200 st) of lead concentrate and 11 300 tonne (12 500 st) of zinc concentrate will be produced annually. The mill was designed to operate at an average capacity of 3450 tonne/day (3800 st/day), based on a 95 per cent availability factor. The mill will operate 24 hours a day, 5 days a week, with maintenance performed, as needed, on weekends. The mine will operate on an identical schedule; but the underground, pri- mary crushing will operate on a six hour/shift, three shift/day schedule. The 1.07m x 1.22m (42in x 48in) jaw crusher will produce a minus 20cm (8 in) material at an average rate of 191 tonne/h (211 st/h). The jaw crusher has almost twice the throughput capacity required, but the decision to install that size of crusher was based on the need to handle over sized rock in the ore.The coarse crushed ore will discharge into a 180 tonne (200 st) skip pocket, which will allow up to a one hour surge capacity prior to hoisting. Hoisted ore will discharge into a 900 tonne (1000 st) storage bin located adjacent to the headframe. The skip pocket and coarse ore silo comprise the total ore storage capacity. The concept of having no intermediate fine ore storage between the secondary crushing and grinding sections was borrowed from the Brushy Creek Mill of St. Joe Minerals, which operates adjacent to the West Fork property. Integration of the secondary crushing and grinding circuits has worked ' successfully for years at the Brushy Creek Mill. The most obvious advantage to eliminating the intermediate fine ore storage is'capital expen- diture savings. The capital expenditure savings include the cost of silos, feeders, and the cost of additional conveyor length and eleva- tion. Savings in operating costs will also be gained, particularly in reduced maintenance costs. Other factors which influenced the decision to eliminate fine ore storage were the simplicity of the secondary crushing sec- tion and the limited area available for con struction of the facility

Jan 1, 1978

By D Giurco

As part of global systems of mineral production and consumption, the Australian minerals sector is facing sustainability challenges across technological, social, ecological, economic and governance domains, as well as between local, national and global scales. To ensure that the Australian minerals sector progresses towards sustainability, it is imperative to understand the possible ways in which AustraliaÆs mineral resources could support sustainable futures. A significant research gap exists between the complex nature of questions concerning minerals sustainability and the reductionist methods available to deal with them. This paper argues the need for broader, more integrated approaches to questions concerning minerals sustainability, which can address multiple human perspectives, complex and æmessyÆ patterns and processes across multiple organisational, temporal and geographical scales and whole systems of mineral production and consumption. To inform the development of a new approach to minerals sustainability, this work reviews the contemporary understanding of the Australian minerals sustainability problematic, from the perspective of the Australian minerals sector (Minerals Council of Australia), the Australian research sector (Mudd 2007a, 2007b; Mudd and Ward 2008) and a multi-scale international project (MMSD 2002). This review shows the focus of current responses to the minerals sustainability problematic, identifies the need for an integrated approach to questions of minerals sustainability and addresses how different approaches are informed by underlying and unarticulated assumptions about the tolerability of tradeoffs between different societal goals, the treatment of uncertainty and the application of different conceptual geographical, organisational, temporal and life cycle scales to define the minerals sustainability problematic. The Mineral Resources Landscape proposed, offers an expanded conceptualisation of minerals sustainability, to link minerals production and consumption in an integrated assessment across the entire minerals supply chain, connecting social, ecological, technological, economic and governance domains across local, national and global scales. The key leverage points governing change in the Mineral Resources Landscape are identified as: the material source, extraction and production technologies, level of service and value, and consumption patterns. Mapping the key challenges facing the minerals sector, as identified in the review herein, indicates that the boundaries defining traditional conceptualisations of minerals sustainability focus on the material source and technology and ignore two very key drivers of the Mineral Resources Landscape û the æservicesÆ minerals offer to society and the æconsumption trendsÆ which assimilate these services into society. Understanding these overlooked aspects of the Mineral Resources Landscape, along with the conventional areas of focus, is essential for identifying the Australian minerals sector as a provider of sustainable mineral services. This insight prompts a reconsideration of the role of minerals services and consumption trends, together with the role of the material source and technology in shaping change and the emergence of sustainable systems of Australian minerals production and consumption, across multiple scales and domains.

Jan 1, 2009

By Tack K

During its 28-year life the MHD ISP smelter has gone through two phases, each of about a dozen years. The first phase was a learning one; in the second phase the lessons were applied and throughput and production rose strongly. Early experience revealed the robustness and the flexibility of the Imperial Smelting Process. The experience was demonstrated by strong increases in the throughput of mixed lead-zinc concentrates and of secondary (oxide) zinc materials. Purchased material quantities rose from 175 000 tonnes/year to 200 000. The required capacity increase of the IS furnace to smelt the higher throughput was achieved by relatively minor modifications; for instance a change to the internal furnace profile gained an extra two square metres in cross sectional area. The furnace hearth area has remained practically unchanged over its entire history. The paper concludes that there is still more potential to be drawn from the process and MHD intends to sustain raw material input at a new level of 240 000 tonnes/year. However, this rate will have to be achieved under the imposition of more stringent environmental and product quality standards than ever before.

Jan 1, 1993

By I H. Jung, W O. Choe

Gallium (Ga)-containing compounds such as Gallium Arsenide (GaAs) and Gallium Nitride (GaN) are widely used in electronic devices due to their superior electro-optical properties and their usages increase rapidly. For the sustainable supply of Ga to electronic industry, therefore, the recycling of Gallium becomes essential. Pyrometallurgical Ga recycling process involves the complex chemical reactions between slag, matte, liquid metal, gas, refractories, etc. Therefore, the accurate thermodynamic information and phase diagram data for the oxide system containing Ga2O3 is important. In the present study, new phase diagram experiments for binary SiO2-Ga2O3 and ternary CaO-SiO2-Ga2O3 system are carried out using Differential Thermal Analysis (DTA) and quenching experiments followed by Electron Probe Micro-Analyser (EPMA) and X-Ray Diffraction (XRD) phase analysis. Based on new phase diagram data and available literature data, the thermodynamic modelling of the entire CaO-SiO2-Ga2O3 system is performed for the first time.

Jun 19, 2024

By S K. Michelic, N Preisser

For certain applications, steels have to feature a very distinct and well-defined level of cleanness in terms of the number and composition of non-metallic inclusions. Therefore, one crucial aspect of steelmaking is removing and controlling said non-metallic inclusions during the process. Particle removal during ladle refining comprises three stages, namely: 1. Flotation 2. Transport through the steel/slag interface 3. Dissolution of the particle in the slag. Only if all three stages are completed the particle can be considered as fully removed from the steel melt which, in turn, leads to the slag being one of the most influential parameters for inclusion removal and control. Depending on the composition of the particles and the slag, the dissolution can be controlled by different mechanisms. This study focuses on the diffusion-controlled dissolution of solid oxidic particles in slags. For this, a model of particle dissolution has been developed. For modelling diffusion, either the differential equation following Fick’s second law can be solved, or an analytical solution to this equation valid for stationary interfaces can be used. Both approaches allow for calculations of concentration profiles of the dissolving species in surrounding slag. From this, the mass flux can be derived, which finally leads to calculating the boundary layer velocity due to considerations of mass balance. In this work, both methods as well as results of dissolution experiments using High Temperature Confocal Scanning Laser Microscopy are compared. This research aims to provide a framework for diffusion-based dissolution modelling in further expanding the understanding of particle dissolution in secondary metallurgy.

Aug 21, 2024

By Grady B. V O, Cavell K. J, Ault A. R, Newman O. M G, Malcolm J. McPhersqn

Cyclic voltammetry (CV) has been evaluated as a technique for monitoring the quality of an industrial zinc sulphate electrolyte. The basis of the method involves measuring a change in the polarisation of the zinc nucleation reaction at an aluminium surface and relating this to the impurity content and/or the overall quality of the electrolyte. Specifically, the technique aims to be able to indicate and quantify detrimental synergism between impurity elements, something which traditional analytical techniques are incapable of providing. The technique has found some success with regard to monitoring glue additions in a range of metal electrolytes. It has been found that investigations by a number of workers over the past 15 years have produced variable and often misleading results due to the inadvertent use of commercial purity aluminium working electrodes. It has been shown that impurity elements in the working electrode can give rise to a range of responses that are not obtained when pure aluminium is used and that the response is variable due to the lack of surface homogeneity of commercial purity aluminium electrodes. Furthermore, it was demonstrated that previous detection limits reported in the literature were based on the presence of additional peaks in the cathodic scan and not polarisation effects. The results of this study have shown that when a pure aluminium working electrode was used, the method was incapable of detecting any change in polarisation for an electrolyte containing three common impurities (Co, Ni and Ge), at concentrations that would significantly reduce optimum electrolytic performance. A range of methods was tried to sensitise the technique, including raising the temperature and acidity, and adding antimony in order to induce some synergism. In all cases the polarisation response was unchanged. Consequently, apart from the commercialised application for monitoring additions of antimony and levelling agents such as glue, CV has very limited application as an electrolyte screening technique.

Jan 1, 1993

By G Maude, R Ayres, R N McLean, N A. Reynolds

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The Mabilo copper-gold-magnetite skarn deposit is located in southern Luzon in the Paracale mineral district, where iron has been produced historically from several skarn deposits. Mabilo occurs in the south-west of the district and is distinct and significant because of its high grades of copper and gold compared to historical mines.The Mabilo licence surrounds the Venida prospect, where past small-scale mining has exploited iron, copper and gold mineralisation in oxidised skarn. A ground magnetic survey in 2007 defined a number of strong anomalies under Quaternary volcanic cover south of Venida. The property was acquired by Sierra Mining Ltd in 2011, the magnetic data were remodelled and drilling commenced in September 2012. Diamond drill hole MDH001 targeted the strongest anomaly, which was 500 m south of Venida and under 20 m of volcanic cover. It intersected 94 m with an average grade of 2.2 per cent copper, 1.6 g/t gold and 36.6 per cent iron. Subsequent drilling was targeted by magnetic modelling, incorporating magnetic susceptibility data from drill core, which resulted in a high percentage of successful drill holes.The mineralised skarn preferentially replaces a dipping limestone unit within an Eocene sequence dominated by volcanic siltstone and sandstone, metamorphosed to marble and hornfels in the aureole of a Miocene quartz-diorite intrusion. Skarn occurs discontinuously along the eastern and southern diorite contact, controlled by primary sedimentary facies variation, structural geometry, fault offsets and intrusive contacts.Coarse magnetite skarn with garnet and minor wollastonite and clinopyroxene contains variably abundant chalcopyrite and minor molybdenite. Magnetite skarn occurs in sharp contact with unaltered marble or grades into garnet skarn with minor chalcopyrite. Structurally controlled retrograde skarn alteration is strong to intense and is characterised by bornite, clinozoisite, iron carbonate and chlorite. The retrograde skarn is weakly overprinted by late-stage pyrite veining and brecciation associated with clay-silica alteration with arsenopyrite and tetrahedrite-tennantite.The quartz-diorite stock is interpreted as the source of the prograde skarn-forming and mineralising fluids. Late-stage porphyritic intrusions in the contact zone indicate continuing magmatism during uplift, when telescoping led to a high-level, high-sulfidation overprint. This suggests the potential for deeper porphyry-style mineralisation.CITATION:Reynolds, N A, Ayres, R, McLean, R N and Maude, G, 2015. The Mabilo copper-gold-iron deposit – a new skarn discovery in the Philippines , in Proceedings PACRIM 2015 Congress, pp 431–438 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By G C. Snedden

Tandem row stator arrangements are common in the last stage of multirow, gas turbine compressors. Tandem row stators, or stator and de-swirler vane combinations are used to relieve the loading on the stator but ensure axial flow leaving the compressor. In this paper a standard 40” (1016 mm) ventilation fan in the Air Blow Fan’s range is modified to utilise the plate support struts on the barrel to relieve the aerodynamic loading on the aerofoil stator. Performance maps for both versions of the fan were generated using computational fluid dynamics and are compared across a wide range of rotor setting angles showing a clear advantage of approximately 2 per cent in efficiency for the tandem blade design. In addition, the area of high efficiency that represents the practically usable area of the map extends over a greater area in terms of flow rate and total pressure rise.

Oct 12, 2022

The undeniable fact of life in the next 25 years will be the increasing difficulty of the physical conditions of Australian orebodies facing future miners. We are all familiar with names such as the 3000 orebody at Mt Isa, Hilton, Century, Macarthur River, Cannington, and Ernest Henry. These projects represent a significant. proportion of the planned underground mine development in Australia. Moreover, many of these new orebodies are an order of magnitude more difficult to mine and process than their predecessors. Extraction will be from deeper and potentially more hazardous working environments. Occupational health and safety considerations will place unprecedented demands upon mine operators and technology providers of the future.

Jan 1, 1994

By N Power, R Hassell, E Jones

Wiluna Mining Corporation are progressively re-entering the old Wiluna underground mining complex. The existing underground was abandoned in 2013 by previous owners and left to flood with water levels reaching above the East Pit portal and Happy Jack Pit portal and up to 300 m below surface in the Bulletin underground. Re-entering the mine commenced in 2017 with dewatering of the Bulletin decline. The underground development had been previously supported with friction bolts, with weld mesh in places. Until mid-2021 rehabilitation requirements were based on an external visual inspection of the installed ground support scheme. However, several incidents involving falls of ground due to corroded bolts have occurred during this time, showing that this approach was inadequate. The challenge the operation faced was should the entire decline be rehabilitated, the implication being not only a large rehabilitation cost but also the impact of severe delays to the mining schedule. The question was asked can the operation better understand the level of corrosion damage and potentially optimise rehabilitation requirements. A proposal to use a systematic approach to assess corrosion by environmental condition mapping, visual external corrosion assessment, and internal corrosion assessment via borehole camera inspections was provided and accepted by Wiluna Mining Corporation. The objective of this work was to produce a three-dimensional map showing the degree of corrosion on the reinforcement systems in the capital infrastructure, this would then be used to risk assess and prioritise rehabilitation requirements. This paper summarises the approach, methodology and results that provided the Wiluna mine planning team with information to enable planning of resources and budget to justify priorities of rehabilitation.

Nov 29, 2022

By B P. Wrench, M J. Gowan, P J. Chapman

Embankment dams constructed mainly of sand or non-plastic fine soils are susceptible to liquefaction, particularly in high-rainfall, high-seismicity environments where there is sufficient water to saturate the materials and sufficient energy from an earthquake to cause liquefaction. This paper shows the process adopted to review the stability of an existing cross-valley, centreline-raised cyclone tailings sand embankment dam.The study showed that two-dimensional stability analyses did not sufficiently capture the potential for instability, overestimating the depth of the critical failure surface. Instead, three-dimensional modelling was required to provide a reasonable representation. Post-liquefaction stability analyses carried out using the three-dimensional model indicated an adequate factor of safety (FoS). The FoS under seismic conditions was still considered to be a concern based on pseudostatic analyses (but noting the limitations of the analysis method).Earthquake-induced settlements were estimated using an empirical approach based on case history records (Swaisgood, 2003). The post-earthquake event settlement was estimated to be in the order of 600 mm, which is considered to be acceptable for the embankment, taking account of the proposed long-term freeboard of more than 8 m under operating conditions and 2 m under the probable maximum flood condition.CITATION:Chapman, P J, Wrench, B P and Gowan, M J, 2015. Review of static and seismic stability of a cross-valley sand tailings embankment in a high-rainfall, high-seismicity setting, in Proceedings Tailings and Mine Waste Management for the 21st Century , pp 163–172 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015

By M-E Boucher

While the haematite concentrates produced in Eastern Canada and the magnetite concentrates that Australia will soon be producing are different feed materials, the pellets they produce have similar physical and metallurgical properties. This paper will examine the similarities and differences in the evolution of pellet microstructure for pellets produced from magnetite and haematite. The molten slag phase generated at high temperatures has a lower melting point when in contact with magnetite compared with haematite due to the higher divalent iron content. The presence of some slag is beneficial for bonding but too much can inhibit oxidation of magnetite, although slag generation at lower temperatures reduces energy usage. In pellets produced from haematite, magnetite is generated artificially from the combustion of the carbon particles added to the pellet feed as a source of energy. Maintaining the optimum production level and mineralogy of such æsecondaryÆ magnetite, allowing for its subsequent reoxidation, is important for the quality of haematite pellets. In both magnetite and haematite pellets, balancing the slag formation and oxidation (re-oxidation for haematite pellets) of the magnetite (secondary magnetite for haematite pellets) is necessary.

Jan 1, 2007

By T Higuchi, K Fukada, K Takehara, Y Iwami, S Fujiwara

Following the Paris Agreement adopted in 2015 and the SDGs, reduction of CO2 emissions has been taken up as an issue worldwide, and the steel industry, which has a particularly large emission, is required to significantly reduce it. Most of the CO2 generated in the steel industry is generated from the ironmaking process, due to the use of coke and its raw material coal in the ironmaking process. JFE Steel Corporation has been considering the use of hydrocarbon-based gaseous fuels and liquid fuels as a partial alternative to coke breeze used in the sintering process since 2006, immediately after the Kyoto Protocol came into effect in 2005. In a laboratory study, a pot test was used to investigate the effect of the type of fuel, its amount and its injection method on the heat pattern in sinter bed. As a result, the authors developed a technology, in which a predetermined amount of gas fuel or liquid fuel was injected from the surface of sintering bed to extend the holding time of 1200°C or higher at which liquid phase sintering occurs in the layer, to improve the sinter strength while reducing the amount of coke breeze. The authors succeeded in putting this technology to practical use using hydrocarbon-based gas fuel in 2009 and achieved a maximum annual reduction of 60 000 tons of CO2 per sintering machine. In this report, the authors introduce the results of laboratory studies on the use of various energy sources, the practical application of the technology for injecting hydrocarbon-based gaseous fuel into the sintering machine, and the operational results.

Nov 8, 2021

By S S. Kanchibotla, E J. Sellers, L Julian, A Musunuri

Fume events in coalmines are typically associated with wet conditions, soft ground and deep holes. An ACARP research project used laboratory and field testing combined with literature reviews, numerical models and field investigations to characterise the influence of these conditions on the propensity for fume. This paper highlights the results for soft ground and wet conditions and proposes a proactive fume mitigation methodology. A simple numerical model is used to show how fume arises in soft rock that yields more under the loading of high-pressure, water-resistant explosive blends than for ANFO. The blends cool more rapidly after detonation into the lower temperature zone favourable for NO2 production. Low-pressure, high detonation temperature explosives are loaded or charged into soft ground. Water resistance must be considered because soft, faulted and fractured ground can lead to fume from degradation by water flow and non-ideal detonation of product in cracks.A suite of tests were developed to quantify ANFO and emulsion blend performance over time that can be carried out in a mobile laboratory on-site. Index tests such as viscosity measurement and water resistance in beakers are proposed to quantify long-term product performance because small components, such as surfactant, prill impurities and prill fines, contribute to inconsistent product performance. Water ingress experiments and detonation tests aligned with field investigations identified and characterised the role of groundwater in damaging ANFO and causing fume.Fume risk management is achieved using a proposed proactive fume mitigation methodology to characterise influences such as seasonal rain variation, groundwater flow hydrogeology, rock mass strength and structure well ahead of blast design. The design of blasts and selection of explosive products to consider expected conditions will reduce fume, improve efficiency in the mine and offer cost advantages.CITATION:Julian, L, Musunuri, A, Sellers, E J and Kanchibotla, S S, 2015. Mitigation of post-blast fume in soft ground and wet conditions, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 511–518 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By OÆNeil G. R

The gold adsorption capacity of ash-char and ion exchange resin Zerolit F.F. (I.P.) was evaluated by obtaining Freundlich isotherms in the presence of selected variables. It was found that the presence of Na , 2+, Ca 2+ cations and SO4 , CN , S Z, 0 2- Zn anions prompted adsorption of gold onto the char and reduced gold adsorption capacity of the resin. Temperature, particle size of adsorbent and pH of solution were found to influence the gold adsorption capacity of char and the resin. The most efficient desorbent for gold adsorbed on the ash char was S2 ions. Optimum sulphide concentrations were found in the region of 1% Na2S. Investigation into the concentration of gold from actual carbon contaminated gold residue dumps in Kalgoorlie area onto ion ex- change resin showed limited success in one case and not so in another. Maximum gold adsorption by the resin appeared when cyanidation and sulphidization treatments were carried out simultaneously in the presence of the resin.

Jan 1, 1979

An integrated computer system (the Short Term Mine Management System) has recently been developed by B.H.P. Steel Long Products Division in Whyalla, South Australia for use in their open pit iron ore mines.The system incorporates blast design, comprehensive blasthole data handling, grade coilrol, stockpile scheduling and management and reconciliation within a single, user friendly computer package. The blast design system allows the blasting engineer to design the layout of holes for a production blast using geological information projected from the bench above to aid in appropriate blasthole positioniog in particular rock types. The grade control system allows mining blocks to be designed and evaluated from blasthole information using interactive graphics processes. The handling, storage and reporting of blasthole survey, assay and geological logging data forms an integral part of this system. Stockpiles can be constructed from a number of mining blocks to reach a specified target grade using the stockpile management system. Although not yet integrated, the reconciliation system will reconcile stockpiles back to mining blocks and to the geological model.

Jan 1, 1990

By Kapoor M. L

Emf measurements on SE galvanic cell: SS; Ni-NiO I solid electrolyte/ZrO2 + CaO I [Pb + Bi]liq alloy; (PbO); SS were made in the temperature range 913-1034 K to determine the thermodynamic properties of oxygen dissolution in liquid lead. Bismuth alloys with bismuth in the dilute concentration range of 0 to 3.08 mass per cent and oxygen in the alloy varied by equilibrating the metallic system with a suitable (PbO) slag. Wagner's interaction parameter approach was used to calculate the ternary interaction parameter, eBiO at temperatures of 913, 953 and 993 and 1034 K and to observe the temperature dependence eBiO = 19 200/T - 17.454. Quasichemical fonnulation was employed to yield lnf BiO and reveal the effect of bismuth on oxygen in lead. The results obtained are discussed on the basis of theoretical models and the value of Wagner's energy parameter 'h' estimated to predict the results in a Pb-Bi-O system.

Jan 1, 1995

By Gardavsky V, Gabell AR, Green AA

The I,)hyllosilicate mineral chlorite is a common constituent of altered rocks associated with volcanogenic massive sulphide deposits, and literature studies indicate that, in general, this mineral is progressively enriched in magnesium relative to iron as an orebody is approached. Studies have shown that there is a direct correlation between the Mg/Mg + Fe ratio of chlorite and its absorption spectra in the 2.7 to 3.0 um range. However, this region, which contains the fundamental 0-H stretch absorption features, is affected by intense atmospheric absorption, and therefore cannot be used for remote sensing. At shorter wavelengths (0.4 - 2.5um), there are windows where the atmosphere is sufficiently transparent and vibrational absorption bands still occur, although they are clue to overtones and combinations, and accord- ingly are much weaker than the fundamental features. Shifts to longer wavelengths with increasing iron content can still be observed in this region of the spectrum and, with better spectral resolution and sensitivity, it may be possible to monitor subtle variations in chlorite chemist by remote sensing techniques.

Jan 1, 1987

The source and origins of the hydrothermal fluid of orogenic, or quartz-vein lode-gold deposits remain uncertain and disputed: Resolution would likely have a significant affect on exploration strategy. The gold-carrying fluid is interpreted to be a low-salinity mixed aqueous-carbonic fluid of near ambient pH and redox state, that may be derived either magmatically through crystallisation of granites at depth in the crust or through metamorphic reactions in a range of rock types. Classic isotope and geochemical tracers of fluid source have not differentiated these possibilities and have produced conflicting conclusions. Mass balance calculations show that fluid composition will be modified by wallrock reaction between source and deposit, and tracers should not be expected to give clear indications of fluid source. Fluid oxidation state can also be modified along flow paths. Tracers should be interpreted with care and with view to possible modification. Modelling of full flow paths and examination of the hydrothermal histories of proposed source rocks may be alternative approaches to determining fluid source.

Jan 1, 2002