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By R J. Longbottom

In this study the bonding within reduced titanomagnetite-coal compacts was investigated. The aim of the study was to better understand the binding mechanisms in the reduced compacts and, based on this understanding, to improve on their strength.Titanomagnetite ore was combined with sub-bituminous coal to form compacts. The compacts were then reduced by heating in a thermogravimetric furnace (TGA) to temperatures between 1000 - 1300°C under argon. The reaction progress was monitored by measuring the weight loss with time. The reduced compacts were found to have low strength in compression testing. The main form of bonding between the reduced titanomagnetite particles in the compact was by the formation of a slag-like material. Increasing the fi nal reduction temperature was found to have a profound effect on the strength of the compacts by promoting the formation of this slag-like material.Attempts to improve the strength of the compacts were made by changing two variables, the type of coal and the addition of rice husks. The addition of coking coal gave reacted samples that had little strength, while the addition of rice husks may have enhanced the strength of the reduced compacts.

Jul 11, 2011

By R E. McIvor, K M. Bartholomew

Classification system efficiency (CSE) is a simple, powerful metric that provides a comprehensive measure of classification system performance. CSE directly quantifies the amount of coarse solids in the mill, and as a result, also directly quantifies the percentage of mill power being used effectively. In this manner, it is an effective, practical grinding energy efficiency metric.Three independent variables drive CSE: circulating load ratio, sharpness of classification, and classifier bypass. Due to practical downstream constrains on per cent solids, improvements realised by increasing circulating load reach diminishing returns as sharpness of classification and bypass deteriorate in the most commonly used classification device, the hydrocyclone. This combination of effects leads to the use of CSE, and its relationship to operational economics, as an objective circuit optimisation criterion.Its simplicity in measurement makes CSE a useful tool for the plant metallurgist, and it is not subject to a great amount of experimental error. CSE provides the plant operator a fast, simple, and effective means to evaluate the performance of the plant classification system. Improvements in CSE relate directly to circuit throughput and energy efficiency. This paper, through description and plant case studies demonstrates the power and utility of this emerging grinding system optimisation metric.CITATION:Bartholomew, K M and McIvor, R E, 2013. Classification system efficiency - a comprehensive closed-circuit grinding optimisation metric, in Proceedings World Gold 2013 , pp 389-394 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

Professional engineers of today require a wide array of experience and knowledge. It is true that commonly engineering degrees do teach the technical requirements well, but do fall short in the way of teaching other non-technical issues of professionalism to the student. Today calls for an engineer who does not only have a high standard of the technical knowledge required for their degree, but also has a broad range of experience in areas that are becoming increasingly important in engineering. The importance of social responsibility, liability and interpersonal relations is high. Through the face of the changing world, it has become clear that there is a need for a new type of engineer, who has a broad range of expertise, as well as the typical technical abilities required. This paper will outline these non-technical issues and propose ways of combining these ideas into the mainstream engineering degree.

Jan 1, 2004

By R Dunne, S Hart, G Levay

While water represents a major proportion of the mineral pulp processed in flotation circuits, relatively little research effort has been committed to understanding and controlling the influence of water quality on this process. Historically, this probably stems from the perception of water as an inert transport medium. However, the changing attitude towards water as a valuable resource, has given impetus to increasing requirements to use relatively impure make-up water supplies such as treated effluents and a high proportion of internally recycled water. In turn, this has resulted in the need for a more detailed focus on process water quality and its control to minimise adverse effects on sulfide flotation. Along these lines, prior to commissioning of a new concentrator at their Cadia Hill Gold Mine, Newcrest Mining was proactive in examining potential water sources and the influence of water quality on flotation of their copper/gold bearing ore. An extensive water quality survey of all major potential water supplies to the concentrator was undertaken. The flotation performance of the Cadia ore in each of these waters was investigated on a laboratory scale. The results of these studies identified that water quality could indeed have a significant influence on the flotation process. Since operations at the Cadia Hill concentrator began, water quality surveys of both make-up water sources and recycled flotation circuit waters have been carried out on a regular basis. By doing this, a database of water quality has been established which can be compared with plant performance. In parallel with the water quality surveys, a series of laboratory flotation tests have been conducted using a standard ore and waters from various streams to monitor changes in flotation performance as a function of water quality. These tests have indicated that certain water types may have a significant influence on plant performance. More research is required to better understand the impact of water quality on sulfide flotation. This understanding will help operators to minimise adverse effects, while maintaining the best utilisation of available water resources.

Jan 1, 2003

Inefficient conveyors suffer carryback, leading to the build-up of materials on idlers, and other expensive components. They spill and leak material at loading zones and transfer points, causing accumulations that can damage the belt, wear moving components, and increase both cleanup labor and maintenance expense. They wander or mistrack, spilling material and en- dangering personnel and conveyor components, including the belt itself. And through these inefficiencies, they multiply an operation's hidden costs-the dollars lost because of missed production, of increased downtime, of the expense for the replacement of prematurely worn or damaged equipment. In this paper, the author will examine the importance of belt conveyors to mines and process plants He will trace the state-of-the-art in systems for cleaning belts, and controlling the release of fugitive material from conveyor transfer points, by exploring the roots of the problems, and demonstrating solutions that have been proven to be effective. Included in these systems to improve material handling are transfer point stabilization and sealing systems, dual belt cleaning systems, and belt training idlers.

Jan 1, 1991

By J Jones

A common problem in the mining industry is that company exploration groups operate in relative isolation to the rest of the company; resulting in poor knowledge transfer (Qureshi and Briggs, 2006) and often priority conflicts with mine geology, operations and project departments. In recognition of this problem, Newcrest created a Minerals Division responsible for stewardship and governance of mineral assets across the value chain from reconnaissance to rehabilitation. It was recognised at an early stage that effective collaboration both internally and externally would be required to improve decision making, deliver faster cycle times and improve governance.Collaboration in companies is generally associated with the introduction of new IT functions. However, modern IT-based collaboration systems and practices are relatively simplistic compared to the long-standing practices associated with collaboration and knowledge management in science and engineering disciplines such as geology and mining.The authors of this paper have started a trial of a 12-point plan for effective collaboration, which recognises that significant efficiencies can be gained and barriers to future success removed if more effective collaboration can be achieved between science and engineering divisions in a company along with external professionals and with the collective intelligence (Tapscott and Williams, 2006) of the outside world. To meet growth aspirations some companies, like Newcrest Mining Ltd, are adopting this comprehensive, step change approach by moving from a closed model the isolates mine geologists to an open and collaborative model that uses IT visualisation systems strategically. The paper describes how an open model provides people with the right work environment and the right information at the right time, which will help individuals and workgroups to work more collaboratively day-to-day. The aim is to achieve speed, focus and mitigate risk through an environment where everyone and anyone can contribute effectively (Cisco, 2008).

Aug 22, 2011

By G W. Swana

Elastoplastic parameter is a parameter that describe how much materials behave elastically up to certain stress states and plastically thereafter (Hudson and Harrison, 1997). In the continuum analysis, two main parameters of the elastoplastic parameter are modulus elasticity and Poisson’s ratio. In the slope, elastoplastic parameter holds the main role for stability related to deformation in ductile type of rock. There’s a limitation to determine elastic or plastic deformation at the field for ductile rock type. Field manifestation commonly showed that there was no accumulation zone during and after the sliding failure mechanism, in other hand, at the research area, manifestation of deformation at the toe of slope only indicated by bulging shape. This paper will focus at the sliding failure occurred at Coal mining Pit Y owned by Arutmin Indonesia, which according to failure investigation report similar with the condition described above. This paper also will be based on two hypotheses, first hypothesis is claystone rock mass has not been reached plastic deformation yet and the second hypothesis is there is a chance that elastoplastic parameter of the rock mass has been changed during the deformation/sliding failure process. Research method of this paper are back analysis using probabilistic analysis in Finite Element Method (FEM), which conducted before and after failure. Then, the result of the displacement or deformation of the analysis will be checked with the actual deformation shape. Meanwhile, the change of the elastoplastic parameter will be analysed and interpreted. This paper hopefully able to be developed to study about elastoplastic behaviour of rock mass in actual condition and the influence of another uncertainty factor which determine the slope stability.

Nov 29, 2022

By D Kay, M Lovitt

Mass Blasts are generally required at the completion of longhole stoping cycles to maximise the recovery of ore from a specific orebody. During the course of mining, the practice is to leave pillars of ore to support the opening left by extracted ore and to mitigate stresses from working areas of the stope. These pillars usually contain ore that has been included in the resource evaluation and is highly valuable to the mining operation. Due to their stressed nature, the removal of pillars by conventional blasting techniques, through small blasts, can result in pillars being reduced beyond their critical size and ultimately failing, rendering the ore unrecoverable. The AurionGold Kanowna Belle Gold Mine operates a Mine to Mill philosophy. This philosopy requires the fine tuning of blasting to provide the best possibe ore feed at the highest grade for mill productivity. This means that ore to the mill must be well fragmented from blasting that provides high extraction rates from draw points, with minimal dilution from overbreak or fall off, and sized to maximise SAG mill throughput. The AT04 Mass Blast contained significant ore reserves which were required to meet gold production targets. KBGB needed the AT04 Mass Blast to perform as well as if not better than conventional stope blasts to maintain mill production. This paper describes the circumstances, planning philosophy, techniques, including the use of Electronic Initiation Systems and Bulk Emulsion Explosives, and results that provided a highly successful outcome.

Jan 1, 2002

By G Bickert

Australia is currently developing and engineering a range of specialised processing options for rare earth (RE) (Lynas, 2011, Alkane, 2005), zirconia (Alkane, 2005), lithium (Galaxy Resources, 2008) and other special minerals and metals required in high-tech applications. The processing of lithium, zirconium and RE minerals is based on complex leaching processes which require extensive liquor clarification, solid liquid separation and solids washing. The filtration properties for those leach liquors, residues and precipitates are not well understood and differ drastically according to the process route applied. Thus, filtration test work is essential for equipment selection, sizing and design. Similar types of slurries are filtered in laterite nickel, TiO2 and other chemical oriented processes, while more experience is available here as those processes are applied widely for a number of decades. The increasing need for dry stacking of tailings requires advanced tailings filtration with properties differing drastically depending on tailings properties. More traditional mineral processes such as flotation commonly apply filtration. All of these and other cases require proper filtration test work particularly evaluation of vacuum versus pressure filtration and the need for cake pressing and/or air blowing for filter presses. Bench scale test work and/or pilot plant operation is common to determine filtration rates, achievable cake moisture and wash efficiencies and sometimes filtrate clarity. While those values are important, there is much more valid information to be obtained by filtration test work.This paper discusses the intricacy of filter selection and sizing based on driving forces (vacuum and pressure air, compression by mechanical means and slurry) and parameters (cake thickness, forces and times) and different processes utilised in common filtration equipment. It will discuss the in’s and out’s of filtration test work design, planning, and in particular data gathering, processing, reporting, evaluation and filter sizing from recent examples of bench and pilot scale filtration test work for above applications together with methods for predicting filtration performance for example where test work is lacking. One focus will be the realistic extrapolation of test work results towards different parameters utilised in full scale equipment and plants. The conclusion of the paper will contain checklist for filtration test work.

Aug 8, 2011

By Ofori-Ansah K

The zeta potential on the surface of activated orit carbon were estimated in lhe presence of selected cations and anions that are normally associated with gold bearing ores in Kalgoorlie area of Western Australia. Additions of such ions to solution of varying pH shifted the isoelectric point of carbon from pH 4.45 to pH 7-8.3, while the anions moved Lhc isoelectric point 10 less than pH 3.2. In the presence of gold cyanide SoluLion additions of spectator ions indicated the isoelecLric poilll to be aL pH less than 3.2; the only exception was for Fe" ion where the isoelecLric point was at pH 5.9. The decrease in zeta potential appeared to be related to the counter-ions present. The decrease may also be related to the adsorption of hydroxyl ion complexes that are likely to be formed when cations are present in the solutions.Gold adsorpLion by activated orit carbon from gold cyanide solution seem to be indicated by the magnitude of zeta potential on the carbon surface. An attempt is made to relate gold adsorption and zeta potential on carbon surface with the pH of the medium.

Jan 1, 1984

By J Cronin

For the last decade, we have read about the great technical innovation that is coming to the mining industry that will increase safety and productivity. There is consensus that it will be a technical innovation that will produce a step change in mining costs and outputs (as opposed to bigger machines or less people); however, this innovation (while freely available) has not taken hold in the industry. While there are a few mines that have embraced technology, the majority of underground mines simply do not have the expertise or technical capability to implement innovation and automation.With unexploited mineral deposits becoming deeper and more remote, and thus more hazardous to mine, telepresence offers the ability to remotely execute production tasks while separating personnel from hazards. As the technologies required to deliver telepresence mature, the potential for there to be no personnel underground during production activities is becoming a reality (the ‘dark factory’). So significant is the capacity of telepresence to mitigate risk, it is proposed that it be included as a separate entry in the hierarchy of hazard mitigation controls.Technical innovation such as the optimised short-term interval control of the production process and the automation of underground mobile fleets offer significant increases in production along with lower operating costs. This paper explores the most critical components for the successful implementation of technology in underground mining; redundant, robust and high-bandwidth communications networks to carry data from distributed networks of smart sensors and to convey teleoperation commands; and high-definition video to provide operators with detailed, real-time data. The days of analogue ‘leaky feeder’ as a base case for communications are over. The human resources required to support the expected wave of innovation are significant and will be difficult to maintain in remote areas as the same skills and expertise are in demand in other industries.The paper highlights barriers to innovation in the mining industry, and a lack of technical and scientific expertise within the industry to be able to identify, implement and manage technologies that can increase safety and productivity. As well, an over-reliance on basic net present value (NPV) financial analysis that is used in the industry punishes investment in technology (capital expenditure; CAPEX) and accepts higher operating expenditure (OPEX) due to the discounting of future savings in operating costs.CITATION:Cronin, J, 2017. Telepresence – the application of remote control and automation technologies for increased safety and productivity, in Proceedings 13th AusIMM Underground Operators’ Conference 2017, pp 213–224 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 16, 2017

By G W. Wilson

Net solar radiation is one of the key factors affecting evaporation from soil covers on waste rock dumps. While net solar radiation is normally taken as a uniform parameter over a site for modelling purposes, there can be significant variation in the radiation actually received on various portions of the dump. These variations are a function of the difference in the cover slope and direction of exposure. A predictive model has been developed to calculate the actual radiation received on the dump surfaces, based on the net radiation data measured at a weather station on a horizontal surface. The model has been designed for application at any mine site in the world, and can be used in conjunction with evaporative flux models to help estimate the effect of three-dimensional variations in the cover surface exposure. The waste rock dump at Equity Silver site (located in British Columbia, Canada) has a barrier-type soil cover system to limit oxygen entry and water infiltration. This cover has been monitored for the past nine years. The new net solar radiation model has been applied to this site and the predicted net radiation was compared to the values of actual net radiation measured on the site. The predicted variations in net radiation over the three-dimensional surface of the waste rock dump have been applied to calculate spatial variations in potential and actual evaporation (or evapotranspiration) from the site. Preliminary analyses indicate actual evaporation from a site at this latitude could vary by a factor of two for exposed versus shaded slopes. The implications of these variations for the site are considered.

Jan 1, 2003

By Y M. Wang, W Z. Liu, L F. Li, X L. Zhang

Based on the blasting crater theory, the equation between k under typical cases and burden line, charge height was obtained by open pit bench blasting analysis model. The model was calculated with mine production blasting. The blastability coefficient k and the best range of blasting burden line were specially emphasised on determination of lateral crater tests.CITATION:Wang, Y M, Liu, W Z, Zhang, X L and Li, L F, 2015. Application of lateral crater test in open pit blasting parameters optimisation, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 463–468 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By J Seccatore, T Marin, M Cardu, G De Tomi, F Galvão, A Rezende, E Melo

Small-scale mining operations are characterised by a large variety of equipment availability and a high level of operational flexibility. Mine planning is usually scarce or absent in small quarries in Brazil, and mine management generally focuses on daily operations. As a result, analysis of the effects of unit operations, such as blasting, over the whole mining process is often neglected. The goal of the following project was to study the effect of production blasting on loading and hauling times, secondary breaking times and primary crushing times at the Experimental Mine of the Research Center for Responsible Mining of the University of São Paulo, Brazil. The operations analysed included blasts that performed:under the average operational standard, defined in this paper as Case 1according to quarry standards, defined in this paper as Case 2.In order to establish the effects of blasting on the downstream process, three key performance indictors were used:The time taken to load the truck, when there is the need for material selection. Due to the fact that we do not have an operational baseline, the increase in time cannot be established, meaning that we must content ourselves with comparing the mean time in each scenario.The average time used for secondary breaking machinery.The time required for the primary crusher to fully process the load of a single truck. The results obtained indicate correlations between the coarseness of the blasted material and these operational times. Solutions are suggested and evaluated for the improvement of the small-scale mining process.CITATION:Marin, T, Melo, E, Seccatore, J, Cardu, M, Galvão, F, Rezende, A, Bettencourt, J and De Tomi, G, 2015. The effect of drilling and blasting performance on fragmentation in a quarry and time for loading, secondary breakage and crushing, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 355–362 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By G Richmond, J R. Glen

Western Metals Mt Gordon Operation is a copper mine and processing plant situated 120 kilometres north of Mt Isa. The unique Mt Gordon copper process utilises a whole of ore acid/ferric pressure leach to produce copper cathode from the Esperanza massive sulfide copper orebody. Esperanza ore contains chalcocite, covellite and minor chalcopyrite hosted in a massive pyrite matrix. These ore stocks will be depleted in late 2003. Recently the process circuit has been upgraded to allow the treatment of lower grade Mammoth ores. These include the installation of a ball mill to complement the existing SAG mill, a single stage rougher flotation circuit and a tailings thickener. The leach bleed neutralisation plant was also upgraded at this time. Commissioning of these new circuits occurred in March 2003 and involved all the challenges of ensuring current production levels were successfully maintained while new process steps were incorporated into the whole circuit. This paper explains the background flow sheet of the patented Mt Gordon process and the reasoning behind the enhancements required for an already successful copper leaching circuit. Included are discussion of the influences of the new ores on individual process components such as comminution, leach chemistry and solid/liquid separation. Longer term ore processing options are also discussed.

Jan 1, 2003

By D J. A Van Zyl, J C. Cunning

Technological advances associated with the expanded application of paste technology in underground mine backfilling are now stimulating an interest in the disposal of process tailings as paste in the surface environment. Concurrent with the development of alternative surface tailings disposal practices is the requirement to fully understand the consolidation behaviour of tailings in paste form, and to relate this understanding to the significant body of data and operating experience from decades of study of the performance of hydraulically placed tailings. One effective method for demonstrating the benefits derived from handling and placement of tailings as paste is to review tailings slurry consolidation theory from the perspective of the changes which take place in the material as it makes its transition from a loose slurry to a dense, stable deposit resulting from managed thin-layer deposition. For a typical process tailings, an example is provided which illustrates the effect which mechanical dewatering has in accelerating the consolidation process and thereby providing a range of benefits from the perspective of surface disposal. Increased rates of filling (rise), expanded use of upstream embankment construction methods and elimination of impounded surface solutions are some quantifiable benefits which can be assembled on a site-specific basis to allow for valid comparisons with more traditional approaches to tailings disposal.

Jan 1, 1998

By M Stephens, T A. Sutra

Currently, there are several open pit mines with production rates of about 200 000 tpd of ore that are reaching the end of their economic lives. In most cases, the remaining orebody extends to depths greater than 300 m below the pit limit, leaving hundreds of millions of tons of reserves that can only be recovered by means of an underground mining method. One such method used for mass production is block caving. This paper presents a ventilation system for a four-zone block cave mine operation developed on a footprint 1000 m wide and 1200 m long. The system is designed for a mine with a nominal production rate of 120 000 tpd of ore using diesel powered units on the production and reduction levels. It discusses the air quantity requirements for the worst case scenario, which is anticipated to occur five years after the mine has reached its full production capacity. Finally, it summarises the results of computer modelling exercises that were carried out to determine an economic ventilation infrastructure that includes shafts, drifts, main fans, and ventilation control devices.

Jan 1, 2005

By A Boucher, M Baudin, P Androszczuk, I Minniakhmetov, A Rigby, P Machado, M Wright, B Van Dijken

IGO Ltd’s (IGO’s) Nova Operation (Nova), which is 160 km east-north-east of the town of Norseman in Western Australia (WA), mines and processes nickel-copper-cobalt (Ni-Cu-Co) sulfide ore from the magmatic Nova-Bollinger Deposit (Nova-Bollinger), which is hosted by the Mesoproterozoic age high-grade metamorphic rocks of the Albany Fraser Orogen. Over its 56-month life-of-mine (LOM) operations to 31 December 2020, Nova has processed 5.63 Mt of ore grading 2.04 per cent Ni, 0.86 per cent Cu and 0.07 per cent Co from its underground mine. At the end of 2020, both the Nova-Bollinger JORC Code reportable Mineral Resource estimate (MRE) and Ore Reserve estimate (ORE) were >90 per cent classified in the highest JORC Code confidence categories of Measured Mineral Resource and Proved Ore Reserve respectively. The high JORC Code classification confidences assigned to the Nova-Bollinger MRE and ORE results from the 386 km of surface and underground diamond drill testing of the deposit to a nominal 12.5 by 12.5 m pierce point spacing in mineralisation. The close spaced high-quality drilling and bulk mining method employed at Nova has effectively removed the need for any grade control modelling outside of the MRE process. Importantly, having only the one fully drilled out deposit being mined and only the one process plant, Nova’s reconciliation process is in the fortunate situation of not being confounded by issues such as external ore sources and constant updates as new grade control information becomes available. IGO’s Nova reconciliation processes are focused on reconciliation ratios that quantify operational period differences between the MRE and ORE head grade and tonnage forecasts and the process plant head actuals. These metrics have been used to identify key reconciliation issues and have initiated several studies into the causes for specific reconciliation results, which are discussed in the paper. In late 2020, a period of sustained poor reconciliation results led to the recognition that increasing the understanding of risk between the MRE and ORE should be investigated. To assist with modelling stope level risk within the mine plan and subsequent reconciliation, an attempt was made to develop a formula to quantify ‘stope risk’ from MRE metrics such as sample spacing, kriging efficiency and so on

Mar 22, 2022

By L Bertoss, D Carvalho

In the last decade, the use of advanced implicit modelling software/algorithms in mineral resource workflows has become a best practice in the mining industry. In most cases, these workflows can easily replicate the level of detail of explicitly modelled geometries, even for very complex deposits. These techniques are flexible and can produce fast results since software is responsible for generating 3D surfaces and solids based on geological and interpretation data. Nevertheless, depending on how unique and complex some deposits are, intense manual editing and input are required to honour the geological context and produce the desired outcome. The current geological modelling workflow at George Fisher Mine (GFM) is based on the semi-automatic built-in tool that generates stratigraphic sequences (stacked lithology layers) based on logging and mapping data. This tool (stratigraphic sequence from Leapfrog Geo™) works for the majority of areas in the mine but fails to capture observed mineralisation pinch-outs in operational areas and at extrapolated boundaries of the deposit. These pinch-outs have the potential to negatively impact grade forecasts if not resolved manually. Using built-in software tools only, the alternative for a more accurate model is to generate each individual layer and adding tens of thousands of manual interpretation points to honour pinch-outs (based on the amount of existing drilling in the mine and number of layers). This approach would require an estimated minimum of two to four years of a full-time employee (FTE) to be exhaustively completed. This study presents an automated approach to generate pinch-out points using a set of Python scripts that only take a few minutes to run. The newly generated points are then combined into the commercial software workflow as interpretation points, honouring observed pinch-outs. The remarkable time difference between approaches removes chance of manual errors and allows mine geologists to spend valuable time in validation and testing of scenarios, ensuring they are more representative of the deposit’s geology.

May 24, 2023

By L Klemettinen, A Jokilaakso, D Attah-Kyei, P Taskinen, M Tiljander, D Sukhomlinov, D Lindberg

In this study, the use of carbon neutral biochars as reducing agents in the pyrometallurgical treatment of nickel slag was investigated at 1400°C in order to recover valuable elements such as copper and nickel from the slag. A large amount of slag is generated during the nickel matte smelting. Nickel slag contains valuable elements such as copper, nickel and cobalt, which can be recovered. Disposal of this slag results in loss of resources and may cause pollution of the environment. It is important to retrieve these metals for environmental and economic reasons. In this study, the slag was reacted with non-fossil reducing agents (biochar) which were produced from hydrolysis lignin and black pellet biomass pyrolyzed at 600 and 1200°C and with metallurgical coke for comparison. The reduction experiments were done at 1400°C for 15, 30 and 60 mins under inert gas atmosphere. The samples were quickly quenched and analysed with Electron Probe X-ray Microanalysis (EPMA). The results showed that the use of biochar resulted in faster reaction kinetics in the reduction process compared to coke. The fast reaction kinetics is attributed to the relatively high content of volatiles in this biochar, leading to gas formation and thus mixing of the sample material. Moreover, thermodynamic modelling was also performed using FactSage™ to simulate equilibria with different amounts of biochar. The metal to slag distribution coefficient calculated from the results of thermodynamic modelling were consistent with experimental results. In addition, thermodynamic calculations confirmed that nickel is reduced rapidly and it deports to the metal alloy phase. As the reduction progresses or extra reductant is available for reactions, more iron is deported to the metal phase. The calculations also revealed that Zn vaporises into the gas phase.

Jun 19, 2024