Search Documents

By T. OnIin, F. F. ApIan

"A study has been made of the surface properties of coals of differing ranks, in their natural state and as modified by the addition of collectors. The evaluation of their surface properties has been done by captive bubble contact angles, water and methylene iodide sessile drop contact angles, zeta potential, point-of-zero charge (PZC) shift, and flotation. .changes in the hydrophobicity of coal is a function of both the rank of the coal and the collecting reagent.INTRODUCTIONThe chemical and physical properties of a raw coal will determine its response to a given beneficiation process. .For such processes as flotation, filtration, flocculation, dispersion, handling, dust supression and agglomeration, however, it is also necessary to consider the surface properties of the coal and mineral matter constitutents of the raw coal. In the case of a specific particle to be floated, it is also necessary to consider the properties of the coal as modified by the addition of some reagent designed to modify (usually increase) the hydrophobicity of the coal surface. General properties of the coal have been well summarized by Van Krevelen (1) and Elliott (2), while the data for the surface properties of coal are much more scattered in the literature (see, e.g.: Parekh and Aplan (3), Gutierrez-Rodrigues et al. (4), Aplan (5), Arnold and Aplan (6), Hogg and Chander (7) and Rosenbaum and Fuerstenau (8)). While a knowledge of the inherent surface properties of a sample are important, of much greater practical significance are the properties of the particle in the presence of a reagent, such as a collector, designed to enhance the hydrophobicity of the particle. This study will focus on the surface properties of coals of various ranks in the presence of a variety of collectors."

Jan 1, 1989

By E. G. Davis, H. P. LeVan, L. S. Smith

Leaching of a Georgia umber ore when using both ferrous sulfate and pickle liquor was studied in the laboratory . The ferrous sulfate content of the leach solution was the major factor affecting the extraction of manganese from the ore . Time , temperature , and the sulfuric acid content of the leach solutions had relatively little effect on leaching of manganese from the ore ; however , these factors did affect the amount of iron extracted from the umber and/or precipitated from solution . Simulated countercurrent leaching of the ore with pickle liquor containing 130 gpl (grams per liter ) ferrous sulfate ( 48 gpl ferrous iron ) produced a pregnant solution having 16 gpl manganese and 41 gpl iron . Filtration tests of the leach slurries indicated that separating the leach solution and solids by vacuum filtration was impractical , whereas pressure filtration was feasible when the cake thickness was limited to about three- fourths of an inch . Fired pellets of the filter cake yielded a firm , hard product analyzing 56 percent iron and less than 0.1 percent sulfur .

Jan 1, 1964

By T. C. Atchison

This report describes a mobile laboratory designed and constructed by the Bureau of Mines in 1950 to meet the needs of an experimental blasting research program. The laboratory has facilities for making; film recordings of 16 simultaneous transient electrical signals over a broad range of amplitude, frequency, and duration. The signals are recorded with specially designed oscilloscopes and high-speed drum cameras. Each of the 16 channels records on a separate strip of 35-millimeter film by using interchangeable input units, transducers having different sensitivities and output impedances can be accommodated. The laboratory can be used to record both steady-state and transient phenomena originating as electrical voltages or capable of being converted to electrical voltages by appropriate transducers. Thus, the laboratory can, be used in studying various types of vibration problems or high-speed phenomena, such as ground and building vibrations, machinery vibrations, airborne vibrations, electrical-circuit switching phenomena, millisecond timing, and seismic phenomena occurring when rock is broken by explosives.

Jan 1, 1956

By G. M. Kintz, E. H. Denny

Although some engineering colleges recognize the importance of instructing young engineers in industrial safety , the different institutions handle this instruction in various ways . It is believed that a recent industrial safety course , conducted at the Colorado School of Mines through the cooperation of this school and the Bureau of Mines , U. S. Department of Commerce , presents some unusual features that are of interest to other schools and to the mining public .

Sep 1, 1930

By A. U. Miller

Since the organization of the Federal Bureau of Mines, part of the duties of the field men of the Safety Division has been to teach those connected with the minerals industries how to render the proper assistance to an injured worker between the time of the accident and the time when the injured receives medical attention--in other words, "first aid to the injured." For a number of years after the training was introduced, the response of mine officials and workers was very slow. Many times Bureau instructors devoted at least a week to training 5 to 15 or a few more men. However, in recent years since the companies and the Bureau of Mines have had an opportunity to study the results of first aid training, it has been found that in addition to taking care of an injured worker after an accident and thereby greatly reducing the severity rate, the tendency is for the majority of those who take the training to be more careful in their work, or to be more "safety conscious."

Jan 1, 1938

By F. D. DeVaney

The supply of manganese is a subject of much interest. The idea of obtaining it from rhodochrosite-MnC03 is attractive because the carbonate is supposed not to be so contaminated with impurities as the commonly utilized oxides. Large bodies of rhodochrosite-bearing rock have been known for a long while to exist at Butte, Mont. Hence samples were obtained from that place. In the two samples examined quartz was the chief diluting substance. The leaner sample was about one half quartz; some copper, lead, zinc, and iron sulphides were also present. The rhodochrosite amounted to about 40 per cent, so that the sample had a tenor of about 20 per cent manganese. This sample was the subject of the examination reported herein.

Jan 1, 1928

By F. J. Gallagher

Some serious fires have occurred in bituminous-coal mines because of short circuits on direct-current power systems that do not have adequate circuit-breaker protection. The writer's observation of circuit-breaker installations in numerous coal mines leads to the conclusion that many persons am not properly informed as to the true functions, limitations, and operation of circuit breakers. Faulty protection results in fire hazards that endanger lives and property. Proper circuit-breaker protection would greatly minimize or, in many instances, eliminate the hazards; moreover, many operating advantages of proper application of modern circuit breakers would be gained. The purpose of this circular is to show why fire hazards exist in many mines despite the use of circuit breakers and how, the hazards may be overcome. A method is given for determining whether additional circuit-breaker, protection is required for a specific 250/275-volt direct-current distribution system, and, if so, the approximate locations and capacities of the required supplemental breakers.

Jan 1, 1951

By D. L. Nussear, W. E. Wallace, N. Clark, M. Gautaum, G. Hong-Guang

"Results of a research effort directed towards identifying and measuring the genotoxic properties of respirable particulate matter involved in mining exposures, especially those which may synergistically affect genotoxic hazard, are presented. Particulate matter emissions from a direct injection diesel engine have been sampled and assayed to determine the genotoxic potential as a function of engine operating conditions. Diesel exhaust from a caterpillar 3304 diesel engine, representative of the ones found in underground mines, rated 100 hp at 2200 rpm is diluted in a multi-tube mini-dilution tunnel and the particulate matter is collected on 70 mm fluorocarbon coated glass fiber filters as well as on S"" x 10"" hi-volume filters. A six mode steady state duty cycle was used to relate engine operating conditions to the genotoxic potential. Results to-date on diesel exhaust have indicated that use of a primary component of pulmonary surfactant as a medium for collecting and applying respirable particulate material to cells for mutagenicity testing offers a true representation of in-vivo delivery of such respired aerosols to pulmonary cells and the genetic material within. Protocols have been developed to sample and assay the diesel soot and diesel soot/mineral dust complexes which would not compromise the surf ace and physical properties of the particulate material. Evidence has been gathered to show that diesel soot expresses mutagenic potential as dispersions in DPL in the Ames tests as well as sister chromatid exchange activity in the animal lung fibroblast ·derived V79 cell line. The results are comparable to the standard solvent extraction procedure. INTRODUCTIONDiesel engines are primarily associated with transportation; however, they are also very common in the work place. Of particular concern is the use of diesel engines in mining operations. Currently there are 1,950 diesel machines working in underground coal mines throughout the country. These units are used in 151 mines encompassing nine different states (MSHA, 1991). It is believed the use of diesel powered equipment has contributed to higher productivity in these mines. However, the exhaust from diesel engines operated in underground mines has been a subject of concern during the past decade because of its suspected relationship with health aspects. The particulate matter generated by the diesel engine is of particular concern."

Mar 1, 1992

By Manuel Gomez

A computerized, interpolative mapping technique based on the moving average method was shown to be adequate to estimate the between-drill-hole values of coal-seam variables. The forecasting of the spatial distribution of coal properties along the seam was of three kinds: (1) Estimation of the variable of interest on a regional basis from widely spaced sample points, (2) prediction of coal properties for product control from closely spaced data, and (3) prediction of coal properties for specified benches, or layers of the coal seam, from closely spaced sample points. Estimates obtained with the computerized, interpolative mapping procedure were useful in the delineation of seam thickness, elevation, and overburden and in the estimation of sulfur and ash concentrations during the early phases of exploration. This grid interpolation technique was found adequate to adjust between-drill-hole values for trends resulting from the combined effect of several variables on a measured response. This information, coupled with statistical and geologic data that can be obtained in the exploration phase of mining, enlarges the information base available for coal-mine development planning, energy forecasts, and environmental control associated with fossil fuel power generation.

Jan 1, 1972

As part of remote sensing research on an abandoned mine lands (AML) site in the Colorado Springs, Colorado area, a geographic information system (GIS) database was generated. This GIS database contains information on the locations and extents of abandoned underground coal mines, the geology of the area, subsidence features and degrees of subsidence risk, topography, drill hole locations, and lineaments (linear features) related to subsurface geologic structures. A GIS database allows the reproducible and accurate comparison and analysis of any data sets which geographically overlap and are within the same coordinate system. The database has been released to the public domain so that government agencies, researchers, educators, and the general public can access this coherent database for the purposes of better understanding the study area and GIS technology. Data files and maps are available in formats that are compatible with the GIS software used in the research project and with most CAD systems so that as many people as possible can make use of the majority of the database. This document serves as the data dictionary for the database by providing descriptions and origins of the data files.

Jan 1, 1992

By Phillip W. Holland

The U.S. Bureau of Mines has developed a mass spectrometer method for determining helium in the parts-per-million to 10% range to an accuracy of ± 1%. The method employs a mass spectrometer, an inlet system utilizing a chromatographic gas-sampling valve, and an activated coconut charcoal trap cooled with liquid nitrogen. Gravimetrically prepared standards of helium in nitrogen were used to demonstrate the linearity of the method over the concentration range of 10 ppm to 10.66% helium.

Jan 1, 2010

By J. B. Gayle

Many investigators have reported studies of size distributions for particulate solids ; usually , these have involved the fitting of size distribution data to a particular mathematical function . Such studies are of unquestioned value and have contributed much worthwhile information regarding the breakage mechanisms for a variety of brittle materials . In connection with a Bureau of Mines study of the size distribution of coke , which has been subjected to the standard American Society for Testing Materials (ASTM) tumbler test , attention was focused on the relation between the 1 -inch tumbler index (usually considered to be indicative of the ability of coke to resist degradation by impact ) and the 1 /4 - inch tumbler index ( indicative of the ability to resist degradation by abrasion ) . Specifically , it was noted that for certain sets of data the correlation coefficients denoting the relation between these indexes were positive ; for other sets of data , these coefficients were negative . Preliminary consideration of this problem indicated that the usual interpretation placed on correlation coefficients was erroneous in this particular instance because the variables being correlated were necessarily related . The work described in this report was undertaken to clarify the interpretation of results of correlation studies for variables of this type .

Jul 1, 1960

By R. E. Coleman

The molecular species occurring at the mineral-reagent interface of the galena-aqueous potassium ethyl xanthate system was studied by developing a technique for using an attenuated reflection method in conjunction with standard infrared spectroscopy procedures. Lead ethyl xanthate was detected from the infrared spectra of all galena surfaces treated in the pH range of 7 to 11. At pH 8.5, lead ethyl xanthate formed as a film chemically bonded to the galena surface. A solvent extraction sampling method was employed with infrared spectroscopy to obtain quantitative data on the lead ethyl xanthate removed from the galena surface. The data showed that between pH 7 and 11 thy quantity of lead ethyl xanthate physically adsorbed decreased as the pH was decreased; in the same pH range, the quantity of free lad ethyl xanthate in the aqueous medium remained constant, and the amount of unreacted xanthate varied.

Jan 1, 1966

By J. B. Stephenson

The Bureau of Mines, under an interagency agreement with the Department of Energy (DOE), investigated the feasibility of hardfacing the critical surfaces of valves and similar devices by chemical vapor deposition. The purpose of this research was to increase the wear resistance of these components for use in the abrasive and erosive environment of coal gasification units. Tungsten and molybdenum coatings were produced on nickel-plated carbon steels and stain-less steels by hydrogen reduction of the metal hexafluoride at 325° to 600° C. Titanium nitride coatings were produced on low-carbon steels by the reaction of titanium tetrachloride, hydrogen, and nitrogen at 1,000° C. Titanium carbonitride coatings were produced on low-carbon steels by the reaction of nitrogen, hydrogen, and methane at 900° C. Tungsten, molybdenum and titanium nitride coatings were formed on 6-, 10-, and l2-inch (0.15-, 0.25-, and 0.30-meter) ball valve seats for evaluation in the low-Btu coal gasification pilot plant at the Morgantown Energy Research Center, Morgantown, W. Va.

Jan 1, 1979

By M. S. Seehra, V. S. Babu, L. Farinash

"The diesel particulate matter (DPM), a constituent of the diesel engine exhausts, is known to be a potential carcinogen. 1- 3 Consequently, suitable methods to control/eliminate DPM have ·been under investigation in recent years. The DPM can be controlled by using fibrous ceramic traps. However, clogging of traps by DPM requires the impractical periodic trap replacement. Following the recent work by Garner and Dent,4,5 we are investigating the in situ use of microwaves to regenerate the ceramic traps, thereby eliminating the trap replacement step in this process. The use of microwaves instead of conventional heating for trap regeneration has the advantage of selective heating of the DPM instead of the trap, if the trap absorbs insignificant microwave power relative to the DPM. Also, the oxidation characteristics of the DPM are needed to understand fully this regeneration process.The rate of energy absorption P per unit volume of a sample is given byP = wE"" |Eo|2 • (1 )where w is the angular frequency, |E0|2 is the intensity of the microwave radiation, and E” is the imaginary part of the dielectric constant (E = E’ + iE”) . Thus measurements of E11 for DPM and ceramic trap material are needed to determine their capacities for microwave absorption. In this paper, we report these measurements carried out at · a frequency of 8.7 GHz. Following microwave absorption, the DPM is expected to oxidize. The oxidation characteristics of the DPM have been investigated using Fourier transform infrared (FTIR) spectroscopy of the evolved gases CO2 and CO and using thermogravimetric analysis (TGA). Finally, some information on the structure of carbon in DPM has emerged from the analysis of its x-ray diffraction spectra. Results of these experiments are reported in the following pages."

Dec 1, 1996

By V. R. Spironello

The Bureau of Mines is conducting studies of the slags related to ferrous technology to evaluate acceptable substitutes for the auxiliary flux, mineral fluorspar, in foundry operations. This work is directed toward the Bureau's goal of minimizing the Nation's dependence on scarce and critical minerals Comparative basic practice cupola (18-inch-ID) trials were made to evaluate a waste material called "used potlining," which contains significant levels of fluorine, sodium, and aluminum in various compounds. Used potlining is recovered from alumina reduction cells after its useful life, and was supplied by the Aluminum Co. of America (Alcoa) to the Bureau for evaluation. The material in the lump and pelletized form (with limestone) provided extremely fluid slags based on visual observation during cupola operation. No adverse effects were found on cupola performance, metal and slag chemistry, the environment, or mechanical properties of the castings produced. Fluorine recovery in the slag was equal to, or higher than, that of fluorspar; fluorine losses to the scrubber water and solids were lower. The acidity of the scrubber Hater was somewhat neutralized. No difference was observed in furnace-refractory attack, as determined by the level of magnesia in the slag and visual inspection. The recovery of sodium in the slag, presumably as the oxide, significantly increased slag fluidity, suggesting that less than equivalent fluorine may be required. There was no contamination of the gray iron by the aluminum from the used potlining. Used potlining was completely satisfactory as a substitute for fluorspar in cupola ironmelting.

Jan 1, 1981

By J. N. Geyer

In coal mining it is essential to maintain the roof over working places and roadways in the safest condition possible. To this end every effort should be made to win the coal with the least injury to the immediate roof strata, as broken strata certainly present a greater hazard than a sound roof. The chief causes of injury to the roof in mining are inherent in the method of development and recovery and the blasting practices followed. The first, which may produce severe stresses in the roof, weakening it over comparatively large areas has been discussed in previous papers3 and will not be treated here. The second cause is local in effect, but with the same general method of blasting being employed throughout a mine having uniform roof conditions, similar effects on the roof may be expected. In the Bureau's investigation of accidents caused by falls of roof and coal it has been necessary to make a careful study of blasting practices and their effect on the immediate roof. The purpose of this paper is to show the effect of the observed methods of blasting on different types of roof and to point out methods that have been proved to be least harmful to the roof strata. The data used in preparing this paper have been compiled from reports made by Bureau engineers engaged in the study of falls of roof and coal, and embrace mines opened in the Pittsburgh coal in Ohio and Pennsylvania and the Pittsburgh and Sewickley coals in West Virginia.

Jan 1, 1933

By Robert H. Merrill

Measurement of the deformation of a borehole in rock subjected to a change in applied stress can be used to calculate the magnitude and direction of the applied stress, provided a satisfactory deformation-applied stress relationship exists , In this investigation by the Bureau of Mines the deformation of a bore- hole in a rock model subjected to a known applied stress was compared with the theoretical deformation of a hole in an elastic, isotropic plate and was found to be in good agreement. Hence, this relationship can be used to calculate the applied stress on a borehole from borehole deformation measurements.

Jan 1, 1961

By Frank D. Lamb, D. A. Woodard

"INTRODUCTION The iron-ore deposits near Cranberry, N. C., were worked as early as 1820, and records show that to date at least 1,500,000 tons of ore has been mined.. The early operators depended on selective mining and hand cobbing to yield a product containing 40 to 50 percent iron. Later, a magnetic concentrator was erected by the Cranberry Furnace Co. and was operated periodically until 1930. The magnetic cobbing method employed yielded satisfactory concentrates, but the plant was shut down because costs were too high. 4/Early in 1944, in connection with the sponge-iron program of the Bureau of Mines, North Carolina and Tennessee were surveyed for the purpose of finding a readily available source of high-grade iron ore for use in the experimental production of sponge iron at Salisbury, N. C., and samples from various sources were tested in the laboratory. The Cranberry ore proved to be best with respect to grade of magnetite concentrates produced, and it was decided that a pilot mill should be built on the Cranberry mine property and that the concentrate made there should be shipped to Salisbury for direct-reduction tests in a commercial brick kiln."

Dec 1, 1946

By Paul W. Jeran

Subsidence over a series of longwall panels undermining sloping terrain in southwestern Pennsylvania was monitored to verify the Bureau of Mines subsidence prediction model for the northern Appalachian coal region. Comparison of the field data to model output shows close agreement. Vertical movements over each panel ceased with the mining of the adjacent panel. Horizontal movements were significantly affected by topographic slope. The distribution of horizontal strains over each panel were similar, with a zone of compression occurring over the center of each panel. The zones of compression were flanked by zones of tension toward the rib. The magnitude of the tensions were affected by the slope. The strains developed at the completion of each panel were not significantly altered by the mining of subsequent panels.

Jan 1, 1988