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By J. B. Gayle

The rate of oxidation of coals with nitric acid has been used by earlier investigators4 5 6/ for determining fusain and for studying petrographic composition. These workers accumulated considerable evidence indicating that, for coals ranging from lignite to low-volatile in rank, the method gives values for fusain that agree satisfactorily with those obtained by optical methods. One group5/even concluded that, when discrepancies are noted between results obtained by chemical and microscopic methods, the results based on the oxidation reaction are probably the more reliable. Unfortunately, after concluding that the method was valid, most of these workers apparently lost interest. As a result, no attempt to exploit or apply the method to problems of utilization has been reported. Recent studies of the influence of inert petrographic constituents on the properties of cokes made from various coals7/ have indicated a need for additional means of characterizing coals and blends used for carbonization.

Jan 1, 1960

By C. C. Stevenson, Thomas Varley

"The art of treating ores by the chloride volatilization process is still in the experimental stage. The process has not been sufficiently developed along chemical and metallurgical lines to state definitely just what place it will occupy in the metallurgical industry. The theory upon which the process operates has received the attention of prominent metallurgists for the past twenty years, and research and experimental work has been conducted by many investigators.Much of the experimental work done has never been published, and it seems that the accumulation of such results if made known would be an important aid to the further development of the process. The object of this paper is, therefore, to bring salient features of the process to the attention of the metallurgical industry, both for the purpose of furnishing information, and receiving from interested parties any comments which the reading of this article may suggest. A bulletin covering the work done at the Intermountain experiment station of the U. S. Bureau of Mines, situated at Salt Lake City, Utah, is in course of preparation.The chloridizing roast is usually accompanied by appreciable losses due, to the volatilization of the metals as chlorides during the roast, these losses often running as high as 30 per cent, depending upon the temperature, the character of the ores and the associated gangue material. It was not until 1891 that Croasdale, (Croasdale, Stuart, Engineering and Mining Journal, Aug. 29 1903) by observing this and stack deposits from the chloridizing roast, recognized the possibility of making volatilization a major instead of a minor feature of the roast. He then made tests on a large number of tires from different, localities, the result of which showed the, general application of the process. The main difficulty, as stated, by Croasdale, was the lack of a suitable means for recovering the fume from the furnace gasesIn 1913, Cottrell (See Mining and Scientific Press, March 29, 1913; alsoTrans. American Institute of Mining Engineering, September 1918. (Additional informa-tion is available from the owners, The Research Corporation of New lark, and Western Precipitation Co., .Los Angeles, Calif.), announced his invention of the electrostatic precipitator, which solved the problem of separating the solids from the furnace gases."

May 1, 1921

By Frank L. Hess

Vanadium, although widely spread in minute quantities through the crust of the earth, is found in few places sufficiently concentrated to be economically mined and prepared for use. Most rocks carry from a trace to a few hundredths of a per cent of vanadium oxide, and coal ash may carry about as much as the rocks, Much of the "coal" quoted in the literature as carrying vanadium has been asphaltite, and in other ccal the vanadium is of late introduction. The ash of the petroleums, though usually present in very small quantity, may carry a large percentage of vanadiun, so that production of vanadium from it has been seriously considered. Naturally the ashes of soze asphaltites similarly carry vanadium.' The great deposit at Minasragra, Peru, to which further reference will be made, is probably an altered asphaltite. Ilmenite and cther iron minerals usually carry vanadium 10 and some has been saved from the minette ores of France. 11 Many veins that carry lead copper and zinc minerals also carry a little vanadium, which, especially if the veins are in a comparatively dry region, such as the southwestern United States, northern Mexico, Northern Rhodesia, Southwest Africa, or Spain, collects in the oxidized parts of the veins as vanadinite,

Apr 1, 1932

By W. W. Agey

As a result of a field examination made during the Bureau of Mines intensive manganese program, three lots of ore were procured from the famous old Paymaster District, 7 miles from Midway Wells, Imperial County, Calif. This district is an old producer and shipped approximately 10,000 tons of 45-percent manganese ore during World War I. A 2-ton lot of ore was taken of a Bureau engineer from the exposure of a small fissure vein in conglomerate on the Turtle Group of claims; 1 mile east of the Pacific Coast Manganese Corp. claims. The vein material consisted of manganese oxides, calcite, and quartz in fairly coarse association.

Jan 1, 1949

By R. Hogg, S. Chander

"The distribution of the wettability of coals of different rank was determined by measurements of contact angles for individual particles. The contact angle was estimated from the equilibrium partitioning of a particle at the water/air interface. Using this technique contact angles were determined for a larger number of particles from a given sample and a frequency distribution of contact angle was obtained. The contact angle distribution was broad for all the coals tested with included an anthracite, a hvA bituminous and a sub-bituminous coal. In comparison, spherical particles of polymethylmethacrylaie gave a much narrower distribution. The distribution for irregular polyethylene particles was somewhat broader than that for the polymethylmethacrylate spheres but broader than that for the polymethylmethacrylate spheres but considerably narrower than that for coal. The broader wetting distribution for coal was attributed to differences in surface chemical properties.INTRODUCTIONA knowledge of the wetting properties of coals is very useful in coal cleaning by flotation and other processes in which separations are based on differential surface properties. The various methods available for measuring wetting characteristics include: contact angle, 1-2 time, time, 3-5 bubble attachment, 6 film flotation,7 displacement pressure, 8-9 penetration rate, 10-11 bubble pick-up, 12 induction time, 13 imbibition time, 14 and calorimetry. 15-16 Of all these methods, however, the measure¬ment of contact angle by the sessile drop and captive bubble techniques have been most widely used. Brady and Gauger"" demonstrated through the use of the contact angle method that the natural hydrophobicity of coal varied greatly from sample to sample. Subsequent experiments showed that this difference correlated well with rank, the larger contact angles generally being associated with the higher rank coals. 18-19 More recent studies by Aplan and co-workers' show that the wettability of various ranks of coals as determined by sessile drop and captive bubble methods is a more complex function of rank. The hydrophobicity of coal usually increases with rank up to about 80% fixed carbon (dmmf) and then decreases."

Mar 1, 1992

By E. J. Gleim

In April 1932, the Bureau of Mines published Information Circular 6595, entitled "Data in Reference to Installation of Cables in Shafts and Boreholes", in which were described methods followed in various sections of the United States when electrical circuits are taken into mines by means of cables suspended in shafts and boreholes. In view of the present tendency to extend high-tension cables along entries and passageways from the bottom of the shaft, borehole, or other point of entrance to coal mines rather than over the surface, it is deemed that the various methods of installing such cables deserve careful consideration, particularly in mines in which gas and coal dust contribute to explosion hazards. This is especially true of localities where there is an inclination to restrict the extension of 2,300- and 4,000-volt circuits into the mines. Probably it is feared that accidental contact with the cables of such circuits may result in more serious shock than with lower voltages; also, it is possible that new circuits are regarded merely as explosion hazards additional to those already existing, regardless of the manner in which the new circuits may be installed. It is the firm belief of some engineers that the circuits can be installed so that they will not be damaged by wrecks or roof falls, thereby eliminating the hazard of explosion from this source while at the same time making the chance of accidental contact remote if not impossible. Moreover, some believe that fire hazards from direct-current systems can be reduced by keeping motor-generator sets close to load centers. Thus, although the alternating-current circuits would be lengthened, the size and extent of direct-current circuits would be kept to a minimum.

Jan 1, 1939

By August J. Kwitowski

The U.S. Bureau of Mines developed and tested a teleoperating system to control a new highwall mining system. A remote operator was provided out-of-sight sensory information and control of coal extraction and haulage equipment. Surface and production testing proved that the teleoperating system supplied the operator with sufficient sensory information to operate the mining system. Details on the teleoperating system provided in this report include (1) sensor selection, (2) a description of the electronic control system, (3) equipment selection and modifications, (4) the positive test results, and (5) recommendations for system improvements.

Jan 1, 2010

By H. R. Wells

The Blackbird district, Lemhi County, Idaho, has long been recognized as a potential source of cobalt and copper. However, the comparatively low grade and small size of the known ore bodies, the small demand for cobalt, and. the lack of adequate roads throughout the region precluded extensive exploration of the early discoveries in the area. Recent advances in alloy metallurgy, accentuated by wartime activities, greatly increased the demand for sources of domestic cobalt. Beginning In 1941, engineers of the Bureau of Mines conducted an examination and exploration program in the Blackbird district. This work was supplemented by an exploration program by engineers of the Howe Sound Mining Co., 730 Fifth Ave., New York 19, N.Y.

Jan 1, 1948

By D. A. Reynolds, C. R. Holmes

The Bureau of Mines - American Gas Association ( EM - AGA) carbonization test has been used to determine the carbonizing properties of 66 American coals and a larger number of coal blends . A summary of the results obtained for the first 30 coals , including 6 blends , has been published ,4/ and results for individual coals have been reported as the investigations were completed . A bibliography of all publications pertaining to this work has been issued recently . Many of the coals were carbonized at 800 ° and 900° C. in two sizes of retorts ( 13- and 18 - inch diameters ) ; and , because the quality of coke is affected by changing the size of the retort , this report has been prepared to show the average physical properties of coke from the two sizes . This report also purposes to extend the correlation of the physical properties of coke with the rank of coal made by Fieldner and Davis in their summary of the EM-AGA tests on the first 30 coals .

Jun 1, 1942

By D. Harrington

The record of fatalities from mine explosions in the United States during the past 44 years has been the best in the history of the mining industry, despite the fact that the number of fatalities from this cause during the past fiscal year now is nearly double that of the previous year. During there 4 fiscal years, mine explosions have resulted in an average of 45.5 deaths per year, compared with an average of 153 deaths per year for the preceding 5 years; an average of 542 deaths per year for the 3 years 1907-1909, inclusive, and a yearly average of 265 deaths per year for the 20 years prior to 1929. Other types of mine accidents also have been reduced during this period, but not to the same degree or by as large a percentage as mine explosions. The fact that in this fiscal year ended June 30, 1937, electricity was responsible for 60 percent of the explosions and 85.5 percent of the fatalities resulting therefrom (see tables 3 and 4) is evidence that either mine operators are lax in providing proper electrical equipment or there is laxity in the upkeep and use of electricity in our mines and more particularly in our coal mines. Several large coal-producing States that in the Fast have had numerous disastrous explosions have been free from such disasters for continuous periods of as long as 8 years. The bituminous mines of Pennsylvania, one of the largest coal-producing States, give a good example of what can be done to prevent explosions. 'his State, with its large number of operating mines, many with very definite hazards from gas or dust or both, has had only two major explosions (resulting in 16 fatalities) during the past 7 years; this is a decidedly good record compared with any similar period in the past and when it is considered that during this period about 750,000,000 tons of coal have been produced. Other good records are: Tennessee, without a single fatality from explosions during the past 9 years; Alabama, with 6 fatalities during the past 7 years; Illinois, with no explosions during the past 4 years; and

Jan 1, 1938

By David L. Veith

Caustic scrubbing followed by silica flotation with cationic ether primary amine proved effective in upgrading commercial magnetic concentrates to supergrade products containing 2 percent SiO2, or less. Samples representing 41 million long tons per year of commercial magnetic concentrates from the Lake Superior region were tested by the Bureau of Mines. Bench-scale and pilot plant research indicated an estimated potential of 32 million long tons per year of superconcentrates to be available. Two pilot plant investigations yielded superconcentrates containing 1.1 and 1.9 percent SiO2 that were derived from commercial concentrates containing 7.0 and 4.2 percent SiO2, respectively. Corresponding iron recoveries were 90 and 93 percent at reagent costs of just over 33 cents per long ton of superconcentrates produced. Additional sources evaluated on a bench scale resulted in iron recoveries of 72 to 95 percent in products containing 1.7 to 2.0 percent Si02. Although reagent cost ranged up to 60 cents per long ton of superconcentrate, it is probable that these costs would be reduced in plant applications where benefits are derived from material and reagent recycle.

Jan 1, 1974

By R. P. Maloney

The Bureau of Mines conducted a reconnaissance of the less accessible parts of the Beluga River coalfield in August 1957 to determine, if possible, which areas were most favorable for developing large reserves of coal suitable for open-pit mining. Several outcrops of subbituminous coal were observed within an area about 30 miles long and 3 miles wide; neither the length nor the width of the coal-bearing area was delineated by the examination. Coal beds 30 feet thick or more outcrop at two places, and beds 5 to 20 feet thick or more outcrop fairly abundantly along the Beluga River and its tributaries The coal measures appear to occur in a series of folds. The overburden comprises glacial gravels and poorly cemented sandstones and ranges from 20 to 400 feet in depth. Few partings were seen in any of the coal beds. Samples ranged in calorific value from 6,240 to 8,246 B. t. u. on an as-received basis. Adequate water is available for stripping by hydraulic methods.

Jan 1, 1958

By W. P. Diamond

Coalbeds exhibit a directional permeability, with the maximum permeability oriented parallel to the face cleat. Thus, the most efficient pattern of vertical degasification holes for a coalbed is dependent upon cleat orientation. Surface joints, infrared photolinears, and Ronchi grating photolinears were investigated as potential estimators of subsurface cleat orientation. Cleat orientations were measured in 18 mines, in the Pittsburgh coalbed in southwestern Pennsylvania and northern West Virginia to be used as a standard against which prediction techniques would be evaluated. Two cleat systems with a strong geographic segregation were measured in the study area: N 670 W -N 280 E (950 separation) for the north, and N 76° W -N 17° E (930 separation) for the south. Directional data obtained from the three techniques investigated yielded satisfactory regional predictions of cleat orientation. Analysis of surface joints was the only technique considered sufficiently reliable on a local basis. Prediction of cleat orientation is based on the pairing of the principal directional sets into all reasonable combinations of fundamental systems. The system or systems composed of the most dominant sets nearest to 90° separation are likely to be a reliable prediction of cleat orientation. The most dominant set of the system selected is likely to be the face cleat.

Jan 1, 1976

By A. R. Rule

This report describes preliminary studies by the Bureau of Mines to develop a procedure for extracting the fluorine from low-grade fluorspar ores in which the CaF2 particles are finely locked in the calcite matrix. A combination of flotation beneficiation and pyrohydrolysis is applied to recover and to liberate the fluorine. Flotation of a finely locked high-calcite fluorspar ore containing only 11.7 pct CaF2 recovered over 92 pct of the fluorspar at a grade of 51 to 52 pct CaF2. Pyrohydrolysis of the flotation concentrate liberated nearly 90 pct of the fluorine as aqueous HF. By this procedure over 80 pct of the fluorine contained in the original ore was extracted.

Jan 1, 1974

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Jan 1, 1975

By F. Chen, L. J. Gaydos, L. M. Demers, D. C. Kuhn, S. C. Sun

"In this report, we demonstrate that NF-KB, a ubiquitous transcription factor, plays an essential role in silica-induced inflammatory mediator production in the mouse macrophage cell line RAW 264.7. Compared to the effect of lipopolysaccharide (LPS), silica mediated a stronger activation of NF-KB p50/p50 homodimer at early phase of poststimulation. Furthermore, activation of NF-xB by silica and LPS appears to be mediated by different signal transduction pathways. Both silica and LPS increased mRNA expression in these cells for cyclooxygenase II, inducible nitric oxide synthase, tumor necrosis factor-a and interleukin- I a. This expression was attenuated along with the inhibition of NF-KB activation. It is well documented that exposure of alveolar macrophages to silica can initiate excessive production of inflammatory mediators and cytokines from several early response genes (1-3). At the DNA level, a common structural characteristic of these genes is the presence of one to five NF-lCB binding sequences (KB) in the 5'-flanking region (4-6). In resting cells, NF-KB is retained in the cytoplasm in an inactive form by binding to inhibitory protein known as hcBcx, hcB~. p 105 (precursor of p50) and p 100 (precursor of p52) (7-9). Upon cellular stimulation, these inhibitory proteins are proteolytically degraded or processed by certain proteases, which allows the liberated NF-KB to translocate into the nucleus as an activated form to initiate or regulate early response gene transcription by binding to its consensus element (GGGRNNYYCC)(7).In this report, we demonstrate that silica can efficiently induce NF-lCB activation in RAW 264.7 cells, and that silica displays different characteristic from LPS in the activation of NF-KB, both with respect to NF-KB subtype composition and the signal transduction pathway that leads to the activation of NF-KB. In addition, abrogation of NF-KB activation by inhibiting the protease can dramatically reduce the mRNA expression of cyclooxygenase II, inducible nitric oxide synthase, tumor necrosis factor-ex (TNF-o.) and interleukin-lex (IL-lex). These findings strongly suggest that NF-KB plays an essential role in silica-induced inflammatory mediator production in the monocyte/ macrophage cells."

Dec 1, 1996

By Earle S. Burnett

This report outlines the experimental procedures for using a Burnett apparatus to obtain compressibility coefficients for multiphase, multicomponent fluid mixtures. The conventional Burnett method is described briefly whereby multiphase compressibility data can be obtained by first determining the compressibility factor, Z, as an isothermal function of pressure alone. Then starting at conditions of temperature and pressure where Z is known, the fluid is cooled at constant volume to some lower temperature at which the resulting pressure is measured, and a corresponding value of Z is obtained from a fundamental relationship between compressibility factors, pressures, and temperatures at constant volume. The isochoric treatment of the fluid, extended to still lower temperatures and along other isochors, eventually results in compressibility determinations for the whole two-phase system thus covered experimentally.

Jan 1, 1963

By Philip C. Good

Unweathered low-grade calcareous phosphate rock of about 20 percent P205 grade was beneficiated by a procedure in which contained carbonates were decomposed by calcination at about 1,000° C. On quenching the hot calcined rock in water, major impurities passed into a slime phase which was mechanically separated from a coarser concentrate fraction. Phosphate rock of two major types was beneficiated in batch-scale studies yielding concentrates containing 31.3 to 38.5 percent P205 at recoveries ranging from 54.8 to 86.0 percent. The samples were from two major deposits in India. Processing information gained was utilized in extending the work to a continuous-flow system, processing phosphate rock at rates up to 157 kilograms per hour. Superphosphate exceeding 16 percent water-soluble P205 was prepared from concentrate derived from continuous-flow processing.

Jan 1, 1976

By F. E. Block, Robert R. Brown, A. W. Henderson

The chlorination of Cr₂ 03 (chromic oxide ) in the presence of carbon with CC14 (carbon tetrachloride ) and COCl2 (phosgene ) chlorinating agents was investigated by employing the radioactive tracer carbon By tagging carbon mixed with Cr₂ 0з , the chlorination reaction was evaluated in terms of the competitive reaction of the elemental carbon and the carbon contained by the chlorinating agent . A unique gas - analysis train was used to separate the chlorination product gases ; CO , CO₂ , and COC12 . The C¹ activity of the gases was determined and used to calculate the reactivity of each source of carbon . Reactivities were determined for the temperature range from 600 ° to 900 ° C. The results of the investigation show that each source of carbon reacts significantly with the Cr2 03 and that the reactivity of each form of carbon depends on the reaction temperature , and each form is independent of the other . Radioisotope and gas - analysis techniques are discussed and a description of the experimental apparatus is given .

Jan 1, 1964

By G. S. Rice, H. P. Greenwald, H. C. Howarth

"Stoppings in coal mines serve, important and. vital functions, such as coursing the ventilating current, sealing off abandoned or dangerous workings, sealing fire areas, and separating mines at boundaries. Stoppings may hold back water, but normally that is not their function; their design is, or should be very different from that of a hydraulic dap which is designed to a definite load, often a very heavy one, from one direction over an indefinitely long period. Hence, a dam usually requires an arched structure to resist hydraulic pressure, and it must be massive to meet vertical stresses due to heavy ground pressure.Stoppings are designed primarily to resist a pressure applied laterally through air or gases. Their strength cannot be stated without specifying the direction of applied load. A stopping may be placed in stress by proof pressure subsequent to erection, through extraction of pillars in the vicinity which may act direct, or by squeezing the ribs or heaving the floor. These forces act more or less parallel to the faces of the stopping and may be very great but measures must be taken suitable to each case, and it is impossible to allow for these in general specifications other than to call for normally good construction. A stopping is principally designed to resist the action of forces at right angles to its face, such as the shocks of blasting, the pressure of gas from instantaneous violent out bursts such as have occurred in certain British Columbia coal mines, sudden compression of the air by great falls of roof in closed spaces, and at time pressures that accompany an explosion of either fire damp or coal dust or both. This paper deals with the tests of pressures of explosions only."

Sep 1, 1930