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The phosphatic overburden of Christmas Island is a lateritic soil and consists dominantly of crandallite and millisite. These minerals are polymorphs of general formula, (Na,K)x Ca2-x (Al, Fe)6 (PO4)4 (OH)10-x (2+x) H2O. Iron occurs only in millisite. Both minerals exhibit similar thermal transformations, dehydroxylating near 600¦C and recrystallizing above 800¦C. Dehydroxylation results in crystal structure collapse but retention of crystal morphology. Ggethite, boehmite and apatite are minor constituents of some-of the phosphatic Soils.

Jan 1, 1971

Despite the research interest on non-cyanide gold lixiviants over the past three decades all the non-cyanide gold processes are still at the developmental stages with limited understanding on solution and pulp chemistry in some cases. This is partly associated with:the difficulties in measuring reliable equilibrium data for various gold(I/III) complexes with non-cyanide ligands; the lack of knowledge on mixed-ligand complexes; and different kinetic stabilities of gold(I) complexes with respect to disproportionation. This paper presents reliable equilibrium data for complex formation, dissolution, precipitation, hydrolysis and disproportionation reactions of gold(I/III) compounds with a range of non-cyanide ligands: S2-, HS-, S2O32-, SO32-, SCN-, SC(NH2)2, OH-, NH3, Cl-. Solubility of gold(III) compounds with non-cyanide ligands follows the order: Cl- > NH3 > OH-. In the case of gold metal the solubility order at a given temperature is MgS > Fe(III) or Cu(II) / Cl- > Cu(II)/NH3 > NaOH, but the solubility increases with increasing temperature. Rate of gold oxidation with different non-cyanide lixiviants depends on the oxidant, ligand and temperature and follows the general order of oxidants: Fe(III) or Cu(II) > X2 or OX- > O2 (X = halogen). In the case of metal ion oxidants oxygen is required to reoxidise Cu(I) or Fe(II). Some of the reported data on chloride and thiosulfate leaching of gold are presented to highlight the effect of additives and the copper, silver and sulfur contents of the starting material on the success of non-cyanide leaching processes.

Jan 1, 2004

The efficient and profit-maximising daily and long-term management of the Vera Nancy resource depends on decisions based upon assay data. This paper examines the range of sample sources, the methods of sample collection, assay techniques and Quality Assurance used by the mine. The orebody has a relatively low nugget effect for a gold mine (around 25 per cent) and this greatly assists in reducing sampling error and producing reliable assay data for production decision-making. Reconciliation between mine and back-calculated mill grades generally sees the mine under-calling mill grades by around four per cent.

Jan 1, 2000

By Liu Q, Siefken T. C, Misra V. N

Investigation of the differential flotation characteristics between arsenopyrite and pyrite in a ore concentrate have been carried out on a laboratory Leeds flotation cell. Experimental results indicate that some limited separation between arsenopyrite and pyrite is possible by differential flotation under the conditions of high pH and low pulp redox potential. The best performance in this testwork was achieved by using an oxidizing agent at pH 10.7. Of the oxidizing agents tested, NaOCI gave better oxidizing effect than KMnO4. It has also been observed that the pulp redox potential depends on the pulp pH value. At high pH values a hydroxide layer is formed on the arsenopyrite surface, which has the effect of a depressant on the arsenopyrite.

Jan 1, 1992

By Stokes WPC

The capital requirements to develop a new mining venture are becoming very large; amounts of the order of US$1,000 million are not now unusual among estimates to bring new mining complexes into production. At the same time prevailing political and economic conditions are making it increasingly difficult to determine whether or not a project is likely to be viable. These factors emphasise the need to carry out thorough evaluation studies of all mineral prospects before making major investment. Additionally with the rapidly changing economic climate existing at the present time, it is becoming more and more necessary to carry out reappraisals of existing mines. An important function of both initial evaluations and reappraisals is to provide the operators of the mine with effective mining plans to ensure that the operation will meet its required economic targets. P, p M. tl p b, c v, s c 1 n 1 f r d c e c e u w Modern computers are well equipped to store and manipulate large amounts of data with speed and reliability. Their use in the mining field r is increasing and this trend serves to free f technical staff from much of the time consuming m and error prone hand calculations which were o formerly required in determining reserves and w carrying out all forms of mine planning. r Nevertheless, computers are not a universal

Jan 1, 1980

By G W. Scott, H M. Lukey

The Lake Superior Region has been a producer of iron ore for over 150 years. Early mining operations concentrated on direct shipping ores, which are the result of post-depositional upgrading principally by deep weathering. As direct shipping ore reserves became depleted, the focus changed to the production of iron ore pellets from taconite. The post-depositional processes responsible for upgrading taconite are regional metamorphism, contact metamorphism and hydrothermal processes (Clout and Simonson, 2005). While these processes are important in iron ore genesis they can also contribute to liberation problems and in some instances reduced pellet quality (Han, 2004). Low-grade metamorphic mineral assemblages can negatively impact liberation and pellet quality. Low-grade iron formation may contain a suite of carbonate minerals including ankerite, dolomite, kutnohorite, siderite and magnesiosiderite. Variation in the distribution and composition of siderite and magnesiosiderite makes controlling the MgO content of pellets difficult. Carbonate minerals also require calcination in the pellet induration process, which requires additional heat to be added to the system, slowing down the induration process and reducing throughput. Prediction of carbonate mineralogy and carbonate mineral chemistry is an important goal of ore characterisation for pelletising properties. Contact metamorphism causes changes in mineralogy and grain size (Klein, 1973; Gunderson and Schwartz, 1962). Increasing the grain size of magnetite should improve its liberation characteristics. However, plant grinding targets may not allow the coarse-grained, more easily liberating magnetite ores to increase throughput and can actually result in decreased throughput due to recirculation. While magnetite and martite ores are well understood (Lukey, Johnson and Scott, 2007) late open-space filling microplaty haematite ores are not. These ores, while composed of similar minerals, have a unique genesis that results in fine grain size and complex textures that present liberation challenges and often make interpreting laboratory metallurgical test results more difficult.

Jan 1, 2007

By Penttila V

The Paleoproterozoic Hitura Ni-Cu deposit in western Finland is in an ultramafic igneous complex composed of two subvertical plug-shaped bodies embedded in intensely migmatised felsic gneisses. The ultramafic complex is not far from a north-south trending graphitic and sulphidic gneiss zone interpreted to be a primary sulphide-graphite unit in the metasedimentary sequence. The sulphide accumulation exists as a zone parallel to the contact of the northern ultramafic body. The ultramafic rock types, now mainly serpentinites, have primarily been olivine adcumulates in the core grading to olivine orthocumulates and pyroxenites towards the margins. Coarse-grained felsic pegmatite veins injected serpentinite where they now exhibit prominent zoned alteration rims of chlorite, antophyllite and talc. The serpentinite core of the body was primarily an olivine adcumulate derived from a tholeiitic or high-Mg basalt parental magma with about 11 wt % MgO. Metamorphism and alteration have totally changed the igneous mineral compositions and the rock types are serpentinites (from olivine adcumulates), ambhibole-bearing serpentinites and amphibole-chlorite rocks (from pyroxenites). As the result of CO2 alteration talc is an accessory mineral throughout the serpentinite. Like silicates, also sulphide minerals are altered. In the core of the body the low-grade sulphide dissemination still reveals primary igneous interstitial forms. The core sulphides are now mackinawite, pentlandite and valleriite instead of primary igneous pyrrhotite and pentlandite derived from Mss. At the marginal zone the heavy dissemination and net-textured sulphides display pyrrhotite-pentlandite-magnetite intergrowths with magnetite films along cleavage of sulphides, mackinawite in pentlandite and exsolution textures of different low-temperature pyrrhotite phases as the result of alteration processes. Mechanically weak rocks, complicated structures and textures of the ore, magnetite and mackinawite intergrowths in pentlandite and readily-floating MgO silicates cause problems in exploitation of the deposit. Solution to problems come from selective stoping, three-step classification in grinding, froth-washing technique and on-line process control based on ore type determination from process data using an expert System

Jan 1, 1996

By D K, S Freij, A Rossiter, X Han, B Feng

In mining operations, the removal of overburden to expose the ores is achieved by rock blasting using ammonium nitrate based explosives, eg ammonium nitrate-fuel oil mixtures, commonly known as ANFO. However, ammonium nitrate can react with pyritic shales that are often found in many mines, leading to premature detonation or spontaneous explosion. In order to minimise the occurrence of spontaneous explosion, the reactivity of the shale in a mine must be assessed. This will provide a better understanding of blasting risks and thus will improve the safety and the cost efficiency of blasting through the selection of appropriate explosives. In this study, shale samples were collected from different locations in Western AustraliaÆs Mt Whaleback iron ore mine and geochemically characterised. The reactivity of the shale samples towards ammonium nitrate and ANFO was investigated using a combination of large-scale firing range tests and laboratory isothermal reactor tests. Results of the firing range tests show that the reactive ingredients of the shale are the limiting factor for the reactions between shale and ANFO. Based on the firing range test results, further isothermal reactor tests were conducted to investigate the reactivity of shale samples towards ammonium nitrate under controlled conditions. Analysis of the results from the firing range tests and the isothermal reactor tests shows that there are correlations between the reactivity of shale samples and several geochemical characteristics such as sulfate, sulfur, ferrous and zinc content.

Jan 1, 2005

During induration of iron ore pellets produced from magnetite concentrates, there are many reactions occurring simultaneously. While the magnetite is being oxidised to hematite, carbonate fluxes are being calcined, leading to the formation of complex oxides. Calcination of fluxes and the formation of calcium and magnesium ferrites and silicates during the preheat stage can influence the magnetite oxidation process. As the calcination reaction proceeds quicker than oxidation at temperatures experienced during the preheat stage (700 - 1200¦C), the bulk flow of CO2 emanating from within the pellet should disrupt the diffusion of O2 to the magnetite reaction as the gas fluxes are similar in magnitude. This increases the time required for the oxidation of the pellet. Using an infrared rapid heating furnace, experiments were performed on heating individual magnetite green balls in an air atmosphere. These experiments showed that time played an important role in the extent of oxidation and calcination and temperature significantly influenced the initial evolution of high temperature phases such as magnesioferrite, calcium ferrites and calcium silicates. Understanding the kinetics of all these reactions for a particular pellet feed, and their interaction, is important for optimising the design of the induration furnace.

Jan 1, 2005

By K Luthbom, A Lagerkvist

According to the Swedish Environmental Protection Agency, the number of potentially contaminated sites in Sweden is approximately 40 000. The funding for remediation from the Swedish Government alone amounts to $A 60 - 80 M (300 - 400 MSEK) annually for the period 2003 - 2006. Uncertainties will arise when obtaining samples in field, preparing them in laboratories and analysing them. Different procedures give rise to varying errors. Using data for decision-making that does not truly represent the site could be fatal. Misclassification of soil could lead to unnecessary costs or to risks to human health and the environment. The total uncertainty of an environmental sample can be split into analytical uncertainty and sampling uncertainty. The analytical uncertainty is usually known and reported from routine analysis. The size of the sampling uncertainty is less well known. Hence, the question is how big are the sampling uncertainties for contaminated soil and how big is the analytical error compared to the total sampling error? A scrap yard and two landfills within a workshop area were investigated. An excavator dug trial pits and samples were taken with a trowel from the walls of the trial pits. Samples were put into plastic bags and taken off site for preparation and analysis using XRF. Sample preparation included drying and sieving. The samples were homogenised by kneading the sample bags prior to analysis. The sampling and sample handling were performed in an intuitively way without knowledge of sampling theory. However, Pierre GyÆs sampling theory was used for subsequent evaluation of the data from the site investigation. The theory defines seven sampling errors, which can be applied to sampling of soil. Some errors have a variance that can be calculated or at least estimated, while other errors can give some idea whether the bias is positive or negative. The total sampling error varied over three orders of magnitudes from sample to sample. The single largest contributor to the large variation in error was the contaminant level. When comparing the analytical error and the total sampling error the ratio varies more than three orders of magnitude.

Jan 1, 2005

By Cripps-Clark CJ

Sulphur partition between metal and slag has been examined on a cast-by-cast basis for BTIP furnaces. Partition values. were calculated from thermodynamic equilibrium data together with oxygen activities computed from the manganese partition. The S-C interaction coefficient, esc , was treated as an adjust- able parameter and the agreement between calculated and measured S partition values optimized. In the case of furnaces operating with low viscosity slags this procedure led to estimates of esc in close agreement with previously measured values. The same analysis applied to daily average data for several Kawasaki Steel furnaces led to the same esti- mates of e c s , indicating a similar approach to equilibrium. Silicon partition between metal and slag has been examined on a time average basis and found to be far removed from thermodynamic equilibrium for most Australian furnaces. A study of Japanese furnaces of comparable size reveals a temperature dependence of Si parti- tion which appears to be close to equilibrium. Australian furnaces approach this behaviour only when operating with low viscosity slags. A preliminary examination of the effects of burdening with TiO 2 on the silicon partition is also reported.

Jan 1, 1980

The Teutonic Bore deposit lies in a major greenstone belt within the Archaean Yilgarn craton of Western Australia. It occurs towards the base of a suite of tholeiitic basalts, some 100 m above a felsic volcanic pile of rhyolitic composition. Sediments comprise a minor, albeit important, percentage of the mine stratigraphy.The deposit consists of a single, steeply dipping lens of massive sulphides totalling 1.4 million tonnes grading 4.16 per cent Cu, 16.4 per cent Zn, 1.22 per cent Pb and 203 g/t Ag. In addition, cross cutting "stringer" mineralisation in the footwall contributes a further 0.75 million tonnes at 2.38 per cent Cu, 1.92 per cent Zn and 52 g/t Ag to the mining reserves. Principal primary sulphides in massive and disseminated mineralisation are sphalerite, pyrite, chalcopyrite and galena, while minor amounts of arsenopyrite and argentiferous tetrahedrite are also present. Weathering has affected the primary mineralogy down to at least 90 m, resulting in a strongly leached oxide profile to about 85 m, overlying a thin, erratic zone of chalcocite supergene enrichment.Lateral metal zoning is marked both in massive sulphide and stringer mineralisation, with Cu/Zn ratios decreasing away from the centre of the orebody. Alteration is well developed in association with footwall stringer mineralisation, changing from a central Fe-Mg carbonate, chlorite and silica alteration zone below the massive sulphides to an outer halo of sericitisation. The spatial distribution of these minerals is patchy. Geochemically, the footwall alteration zone is characterised by central Cao, Na20 and Sr depletion (with less regular enrichment of SiO2 , Fe and MgO), surrounded by a peripheral zone of K20 enrichment.Evidence supports a classic volcanic-exhalative origin, involving submarine discharge on the flanks of a rhyolitic dome and accumulation of the massive sulphides in a local palaeotopographic depression. The sulphides overlie their feeder zone as shown by alteration and stringer mineralisation. Tholeiitic wallrocks are thought to be genetically unrelated to the mineralising solutions, although their presence as a cap over the felsic volcanics may have permitted the build up of a circulating metalliferous brine system prior to sulphide deposition.

Jan 1, 1984

By I Doye

Acid mine drainage is a serious environmental problem caused by the oxidation of sulfide minerals responsible for highly acidic, sulfate and metals-rich drainage. Several methods of mine waste management have been developed that reduce liabilities on environment. Layered co-mingling of waste rock with compacted tailings, covers with capillary barriers effect, and co-disposal of waste rock and tailings are these new methods which are used to reduce the formation of acid mine drainage. These methods shield waste rock dumps from oxygen. These techniques could prevent oxidation reaction. In this study, alkaline industrial wastes are used with acid generating tailings to inhibit acid mine drainage. The alkaline wastes selected are cement kiln dust (CKD) and red mud bauxite (RMB). These alkaline materials are used to keep neutral conditions in the fine material layer and to inhibit the metabolic activity of Thiobacillus ferroxidans which catalyses the oxidation of sulfide minerals. A series of timed static leaching tests were performed by reacting samples of mine tailings with two, five and ten per cent alkaline material in order to characterise geochemical balance between liquid and solid phases. Column tests have been set up with oxidised tailings, waste rock, CKD, and RMB. Column tests have been carried out to simulate layered co-mingling, covers, liners, and co-disposal of waste rock and tailings. Column leach tests were conducted in order to investigate the long-term neutralisation potential of alkaline materials and the drainage water quality. Bacteria counting were performed on each sample after testing. The results obtained show that the addition of alkaline materials permit the retention of near neutral conditions in the fine material layer, thus increasing water quality and preventing bacteria development. In fact, the pH results show that the use of five per cent, ten per cent CKD or ten per cent of a mixture of CKD and RMB permit the retention of neutral pH conditions in the reactive layer. At these percent rates, the concentrations of Al, Fe, Cu, Zn, and SO4 in solution are significantly reduced compared to those obtained with the tailings only. In presence of waste rock, the relative position of the fine material layer is important. When the fine material layer overlaying reactive waste rock is composted of reactive tailings with ten per cent CKD and ten per cent (CKD:RMB), a delay was observed before achievement of near neutral pH. The neutral pH conditions remain stable over time. The mixture of CKD and RMB provides a better short-term neutralisation than the use of CKD alone. The use of alkaline materials is beneficial in order to reduce the concentrations of Fe and other metals such as Cu and Zn as well as the number of viable bacteria. The use of ten per cent RMB alone does not involve the neutralisation of reactive tailings. In the cases where the fine-grained layer are below or mixed with the waste rocks, the near neutral pH values are directly reached with ten per cent CKD. However, the pH values decrease rapidly and the number of viable bacteria increases.

Jan 1, 2003

By Baczynski NR, Fagan MJ

A 3050m long section of a 1.65m internal diameter tunnel is presently under construction in the Brisbane area by means of the pipe-jacking method. The soils along the alignment had been deposited in a deltaic/estaurine environment and rapid changes in soil type occur. The tunnel passes beneath several extensive bodies of surface water. Groundwater problems have been experienced with tunnelling through alluvial sands and gravels. Details of the ground conditions, the pipe-jacking method used and tunnelling experience are discussed in this Paper.

Jan 1, 1987

By Turnbull AG

The direct smelting of zinc sulfide con- centrates has been investigated by an extensive series of computer-based thermodynamic equili- brium calculations. The study covers both pure 7.n-S-O-C-N systems and practical concentrate- coal-air-flux systems. It is shown that for a zinc concentrate containing iron and lead sul- tide impurities, a 97% yield of zinc vapour with autogenous operation can be obtained under carefully optimized conditions. The possible integration of this process with existing zinc condensation and recovery processes is Discussed.

Jan 1, 1980

By M Battersby, F Parra, S Sanchez-Pino

Pneumatic flotation, as developed by Dr Rainer Imhof, has been applied in commercial beneficiation operations since 1987. Over 85 flotation cells have been installed in more than 30 operations, successfully beneficiating a wide range of minerals. Pneumatic flotation is however still considered as a non-conventional flotation process. Due to its highly selective nature in operation it has generally found its market in difficult applications where conventional flotation equipment has struggled. Compa±fa Minera Huasco (CMH) operates an iron ore pellet plant in central Chile. CMH desired to produce a low silica pellet for the export market where the SiO2 grade should not exceed 1.5 per cent. It is common practice in other countries to float quartz from hematite with relative ease. However, the silicates contained in the magnetite ore of CMH are only present as quartz in small quantities and the major undesirable silicates are difficult to float. CMH spent considerable time on developing a reverse flotation process and a reagent suite to try and reduce the silica content to acceptable levels. However, extensive laboratory and pilot plant tests with conventional mechanical tank type cells and with column cells failed to produce the required reduction in impurities. A series of tests with pneumatic flotation cells indicated that this type of flotation technology could achieve the required silica target. A 500 tph Imhoflot pneumatic flotation plant was subsequently constructed and successfully commissioned by CMH, making it one of the largest iron ore flotation plants in the world. This paper details the background and testing that was undertaken by CMH which led them to choose pneumatic flotation as the preferred process and compares the test results with that achieved in the industrial plant.

Jan 1, 2005

The process of evaluating orebodies at the feasibility study stage is extremely important. In recent times many groups have indicated that they would like ore reserve estimation to be numeric and objective. Whilst sampling, geological, mining and mathematical principles may be used to analyse the data, all ore reserve methods require the use of experience factors and as such are value j ddgment statements.

Jan 1, 1990

By Trois P

A fully instrumented and bench-mounted diamond drilling machine, purpose designed and built, has been used for investigating the effect of aqueous solutions of various chemical compounds when used as drilling fluids. The rocks investigated were andesite, basalt and granite, the chemical compounds were alkylamines, with various hydrocarbon chain lengths, aluminium chloride and dioxane. Rotation speed seems to be one of the major factors affecting the emergence of mechanochemical effects as the results obtained with aluminium chloride clearly indicate. Penetration rate is either unaf- fected or enhanced by the presence of certain compounds, such as aluminium chloride. On the other hand, penetration rate diminishes when the drilling fluid contains dioxane and exhibits an apparently unpredictable behaviour with alkylamine solutions, although it appears that an increase in hydrocarbon chain length usually equates to an increase in penetration 1. Full Professor, Mining and Mineral Dressing Department University of Cagliari - Italy 2. Associate Professor, Mining and Mineral Ikea- sing Department University of Cagliari û Italy rate. Rock texture seems to have a pronounced effect on test repeatability. With hexadecy- lamine acetate solutions in concentrations ranging from 10-5 to 5 .10-4 molò dm 3 and 41.88 radòs-1 rotation speed, 46 % increments in penetration rate of andesite were observed, with respect to water, whereas penetration rate decreased in basalt by as much as 60¦%o when a dioxane solution was used as drilling fluid. An interpretation of the observed effects is proposed in the light of current knowledge of solid state physics and physical Chemistry.

Jan 1, 1992

INDEX OF CONTENTS.1. Historical.2. Manufacture.3. Heat Treatment.4. Fatigue, Failures.5. Consideration of the Establishment o£ a Central Testing or Proving Station.HISTORICAL.Since the introduction of improved high air pressure drilling machines in the early part of the century, efforts have been made to develop the quality of the rock drill bit, in order to take advantage of the greater increase of power output per unit weight of the machines (1). This resulted in the change from solid to hollow steel in the second decade of the present century (2).As the greatest sufferers from the dread disease of silicosis (3), it seemed appropriate that the South African gold mines should be the first to use hollow drill steel. Since then solid drills have become practically obsolete for mining purposes.Water is used with hollow steel drills not only to keep the cutting end cool, but also to assist in preventing the formation of undue dust during drilling. It is of interest to note, however, that water fed through hollow steel or sprayed into the air is only partially effective in removing fine dust particles a few microns in diameter, which particles are said to be the most potent in producing silicosis (3a).So far as the composition of "straight" carbon steel drills is concerned, a commission appointed by the Johannesburg mines carried out a very exhaustive series of tests on drill steels.These drills were manufactured from steel made by all the standard methods, including Swedish, Bessemer, crucible, openhearth, and, to a limited extent, electric furnace steel. It should be remembered that the commissioners' report was issued in 1913, when hollow drill steel had not yet been introduced. Only solid steel drills were then in use.

Jan 1, 1947

By Lyman GJ

Systems for the routine on-line determination of ash content of process streams in coal preparation plants and handling systems have been in use in Australia for over four years. More recently, monitors for on-line moisture measurement have been developed to complement the ash measurement function. The technology for these systems is reviewed briefly. The development of reliable ash and moisture monitors has made the implementation of automatic systems of coal quality control practical. The emerging philosophies of automatic control in Australian preparation plants are examined with particular emphasis on systems involving dense medium circuit regulation. Related developments in flotation control and coal sorting are noted to complete this overview.

Jan 1, 1987