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By Shengfan Zhou, XUEWEN WANG, Bianfang Chen, Mingyu Wang

Vanadium was leached from roasted stone coal by NaOH solution, and the effect of leaching temperature, leaching time, addition of NaOH, liquid to solid ratio, the grinding fineness of stone coal, and stirring speed on the vanadium leaching rate was studied. The kinetics analysis for the process is presented by the shrinking core model. The results show that the vanadium leaching ratio of roasted stone coal can be beyond 75% at the 6% NaOH addition, leaching temperature of 95°C, leaching time of 7h, liquid to solid ratio of 1.2mL/g, and grinding fineness of 0.111mm. The leaching process is controlled by interfacial reaction kinetics and the apparent activation energy was 59.36kJ/mol.

Jan 1, 2016

By A. A. Hejja

The effect of composition on electrical conductivity, viscosity and liquidus temperature of the slags was investigated in the temperature range of 1300" to 1450°C. The synthetic slags containing CaO, MgO, SiO,, A1,0, and FeO were similar to those employed in the electric furnace smelting of sulphide Cu-Ni concentrates containing PGM (Platinum Group Metals) from the Merensky Reef of South Africa. FeO and SiO, were found to affect the viscosity and conductivity the most while liquidus temperature depended on MgO content in addition to these. The activation energy for electrical conduction was found to vary from 67 to 159 kJ/mol and that for viscosity from 125 to 209 kJ/mol. Optimization of the slag composition was attempted on the basis of opposite trend of the viscosity-electrical conductivity relationship with slag composition.

Jan 1, 1994

By Priscilla Aki Mori de Hanashiro, Viviane Tavares de Moraes, Denise Crocce Romano Espinosa, Hugo Hashimoto

"The LCDs are used in televisions, calculators, mobile phones, computers (laptops and tablets), video games and other electronic devices. The advancements in technology make obsolete these devices, causing excessive disposal of LCDs and therefore decreasing life span of landfills. In this context, the LCDs from LED LCD TVs arise as an additional source of waste electrical and electronic equipment (WEEE). Thus, it is essential to develop LCDs recycling methods, beginning with the LCD characterization followed by displays processing, aiming the materials separation and using some Ore Treatment Techniques, and finally, the recovery of indium using acid leaching. The analysis methods that will be used in this work are: Fourier Transform Infrared (FT-IR) and Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES).IntroductionLiquid Crystal Display (LCD) technology is applied in modem televisions, calculators, mobile phones, computers and a wide range of electronic devices. It has replaced Cathode Ray Tube (CRT) technology as the most advantageous display product, due to lower electrical power consumption, size and weight reduction, and no radiation emission [ 1]. The constant improving of LCD screen technology reflects on its growing contribution to the amount of waste electrical and electronic equipment (WEEE): an estimated 50 million tons of WEEE are produced every year [2]. Once the most common method of its disposal are landfills, the LCD technology therefore became an environment issue [3].LCD structure is composed by components made by different materials. In order to develop a LCD recycling methodology that gives the right destination to these materials, a previous characterization stage is required. This characterization includes a disassembly process and material identification analysis. One of the LCD components is the screen, which is composed by polymeric and glass layers. The liquid crystal glass was the starting material of this study. It contains indium in the form of indium tin oxide (ITO) film. This ITO film is deposited in the glass by a sputtering process and acts as the electrode material [4,5]. It has in its composition 90% ofln203 and 10% ofSn02 [6]."

Jan 1, 2014

By Bingguo Liu, PENG LIU, Haigang Dong, Jinhui Peng, Libo Zhang

Parameters of technique to decarburize from spent petrochemical catalysts via microwave oxidation roasting were investigated. Decarburization process was performed on a microwave heating system. The results showed that the decarburization percentage of spent petrochemical catalysts was significantly affected by roasting temperature and sample thickness in the range studied. The decarburization percentage was 99.5% in microwave fields under the optimized conditions, roasting temperature 600 °C, roasting time 40 min and sample thickness 2 cm respectively. The residuum after microwave decarburization was characterized by field emission scanning electron microscopy (FE-SEM) which showed that the deposit carbon had been removed effectively.

Mar 1, 2017

By Jongmin Jeong, Jaehong Shin, Joo Hyun Park, Chul-Woo Nam, Kyung-Ho Park

Because sulfur and phosphorus are very harmful in steel products, there are increasing requirements for refining these elements from ferroalloys industries. Hence, in the present study, simultaneous desulfurization (de-S) and reducing dephosphorization (Rde-P) from silicomanganese (SiMn) alloy were investigated using metal-slag equilibration method under highly reducing condition at 1773 K. Experiments were carried out by equilibration between SiMn alloy and MnO-based slag in graphite crucible under p(O2) = 10−18 atm. Slag composition was designed by changing basicity (CaO/SiO2) and MnO content at fixed Al2O3 (=20%) and MgO (=5%) contents. De-S ratio increased with increasing basicity until C/S = 1.5 whereas Rde-P ratio was not significantly affected by slag basicity. This was because thermodynamic driving force of de-S reaction was greater than that of Rde-P reaction under present experimental conditions. The de-S and Rde-P ratios commonly increased with decreasing oxygen partial pressure.

Mar 1, 2017

By S. Abe

An extensive study has been carried out to determine the true cause of floating slimes precipitation which sometimes occurs and badly affects the quality of copper cathodes. Soluhilities of floating slime compounds systematically measured for the ternary system As-Sb-Ri added solely or in combination with conventional copper electrolyte (63°C) and bench scale electrorefining experiments done by varying electrolyte composition, have shown conclusively that the level of Sb(V) ions plays a substantial role in the precipitation mechanism. It was, therefore, speculated that controlling the level of the less soluble S b ( V ) ions below a certain critical level should result in a complete elimination of the undesirable precipitation. This can be easily achieved, for instance, by the addition of a reducing agent such as SO2 gas and the simultaneous employment of a certain type of cheating agent that effectively removes excessive Sb and Bi from the contaminated electrolyte. Long-term pilot testing conducted in line with the above speculation has confirmed the SO2/chelating resin scheme to be industrially very attractive and feasible.

Jan 1, 1987

By Zhanjun Wang, Mei Zhang, Zuotai Zhang, Min Guo

In this study, the viscous flow and crystallization behavior of CaO–SiO2–MgO–Al2O3–FetO–P2O5–TiO2 steelmaking slags have been investigated over a wide range of temperatures. The results indicated that the viscosity of the slags slightly decreased with increasing TiO2 content. The constructed non-isothermal continuous cooling transformation (CCT) diagrams revealed that the addition of TiO2 lowered the crystallization temperatures. This can mainly be ascribed that the addition of TiO2 promotes the formation of [TiO6]-octahedra units, thereby MgFe2O4–Mg2TiO4 solid solution is formed. Moreover, the decreasing viscosity has a significant effect on the diffusion of ion units, such as Ca2+ and [TiO4]-tetrahedra, from bulk melts to crystal-melt interface. The crystallization of CaTiO3 and CaSiTiO5 was therefore accelerated, which can improve the phosphorus content in P-enriched phase.

Mar 1, 2017

By S. N. Monteiro, N. A. Cerqueira, E. B. Zanelato, J. Alexandre, M. T. Marvila, B. C. Mendes, A. R. G. Azevedo, G. C. Xavier

Mortar is a widely used building material and has its application in buildings in extremely vulnerable environments and susceptible to degradation, such as facades. The objective of this work was to evaluate the loss of mechanical resistance to compression and flexure and the loss of mass of the mortars with effluent sludge from paper industry, when exposed to saline environments. The specimens were done with 0, 5, 10 and 15% of incorporation in lime paste and subjected to saline mist equipment that sprays salt solution in cycles simulating natural degradation conditions using literature data. It can be concluded that mortars with a15%incorporation obtained a significant loss of mass and a decrease in their mechanical resistance, which impairs their use in civil construction and influence in other properties of the material, with a level of incorporation of 10% the results within Brazilian standards.

Mar 1, 2018

By Xudong Liu, Ganghua Fu, Yufeng Guo, Wei Chen, Yujia Tan, Tao Jiang

Willemite is usually found in high-silicon oxide zinc ore and zinc metallurgical secondary resources but without effective extraction method yet. In this study, zinc was extracted from willemite by sodium salt roasting and ammonia-leaching process based on the idea of zinc phase reconstruction. The effects of Na2CO3 dosage, roasting temperature and roasting time on phase transformation and zinc leaching rate were studied, respectively. The results show that Zn2SiO4 was transformed into ZnO or Na2ZnSiO4 during roasting process. After roasting at 800 °C for 2.5 h at ratio of n(Na2CO3)/n(Zn2SiO4) = 2.5:1, willemite was thoroughly transformed into ZnO. The zinc leaching rate of the roasted sample was 97.62% in NH4Cl–NH3–H2O leaching system, which increased by 91.57% compared with zinc leaching rate of 6.05% when willemite was directly leached in NH4Cl–NH3–H2O system.

Mar 1, 2017

By Raymond E. Healy

Mercurian e1ectrum (Au-Ag-Hg alloy) is the principal Au-bearing phase in the massive sulphide ores at Trout Lake, Manitoba. The average composition of this phase (in wt %) is 49.2 % Ag. 38.7 % Au and 11.0 % Hg, with ranges of 17.34 to 76.47 % Ag, 1.62 to 79.86 % Au and 1.29 to 30.87 % Hg. Compositional variation reflects solid solution in the a-phase of the Ag-Au-Hg system. Backscatter electron imagery reveals systematic zoning and suggests a general crystallization sequence from metamorphic pore fluids of progressively Ag-rich compositions. Investigation of the occurrence of gold in mill products demonstrates that mercurian electrum accounts for over 90 % of the Au in Trout Lake ore. I Invisible" gold in pyrite (x = 0.72 ppm Au) and arsenopyrite (x 30.2 ppm Au) is confirmed by SIMS analyses, and accounts for 7-10 % of the Au in the ore, and 35 % of the Au lost to the tailings. The remaining 65 % of the Au lost to the tailings consists principally of mercurian electrum locked with pyrite. No significant losses of mercurian electrum in the size range amenable to flotation and/or regrinding is indicated.

Jan 1, 1989

By Shihan Zhang, Qingguo Xue, Jingsong Wang, Yaxing Du, Guang Wang

The rotary hearth furnace iron nugget process is in line with China’s energy and resource condition. It has the advantages of short reaction time and high quality iron nugget. The fundamental study on the novel ironmaking process is meaningful. Based on CaO-SiO2-Al2O3-FeO quaternary slag system, the effects of slag basicity and Al2O3 content on the melting of slag were studied. Using the iron concentrate as raw material, the effects of different slag basicity and Al2O3 content on the reduction and melting separation behaviors of carbon composite pellets, such as the starting temperature of melting separation and the morphology of melting separation were studied. Then, the relationship between the properties of slag and melting separation quality was established, which could provide standard for the selection of iron ore for the rotary hearth furnace iron nugget process.

Mar 1, 2018

By Susanne Pignolet-Brandom

Fourteen samples of crushed Duluth Complex rock were characterized by the QEM?SEM automated scanning electron microscope image analysis system to evaluate the application of the system to mining waste rock characterization. The system can reliably distinguish the iron sulfides, the copper-iron sulfides and the nickel-iron sulfides. Calcite was distinguished from all other minerals except fluorite. The volumetric abundances were verified by comparing elemental abundances calculated using the QEM"SEM volumetric percentages and appropriate mineral compositions with elemental abundances determined by standard laboratory procedure. The pH and sulfate concentrations of rinse water from laboratory leach experiments correlated well with the mineralogical data.

Jan 1, 1989

By K. R. Robilliard

The Peru based tin mining company, Minsur S.A., commissioned Ausmelt Limited to design, supervise construction and commission a tin smelter and refinery for production of refined tin metal. The plant is located 240km south of Lima, near Pisco, Peru and is operated by Funsur S.A., the wholly owned subsidiary of Minsur S.A.. Selection of the Ausmelt Technology followed a series of crucible scale test work and pilot plant trials conducted at Ausmelt's facility in Dandenong, Australia and two feasibility studies undertaken by Ausmelt in 1991 and 1993. Ausrnelt began the plant design in 1994 with the construction phase following in 1995. Commissioning of the plant commenced early in 1996 with a target throughput of 30,000 tonnes per annum of concentrates. In mid 1998 oxygen enrichment of the Ausmelt lance air was introduced to expand the capacity to the throughput of 40,000 tonnes per annum of concentrates. The process route involves the use of an Ausmelt furnace for primary concentrate smelting, followed by a conventional tin pyro-refining circuit to produce high grade tin suitable for sale. Further work continues between Ausmelt and Funsur to investigate the use of an alternative, more economical, fuel source and the installation of a second Ausmelt furnace. The paper reviews the project to date with details of ongoing operations and developments at the Minsur Tin Smelter.

Jan 1, 2000

By Ma Ying

The continuous directional solidification technique of five kinds of special ZA alloys with eutectic, peritectic and eutectoid transfonnation under the condition of continuous casting by heated mold was studied. The mechanism of surface defects appearing in ZA alloy line was discussed and the structure of some defects were analyzed by SEM. The results show that only when the fitting of various technique factors, pressure head, outlet temperature, pulling speed and cooling condition are reasonable under a certain range, can the ZA alloy smooth line be continuously pulled out. Unreasonable techniques will result in hot tear, rough surface, mush outlet, leaking and other defects. The shape and location of solid-liquid zone have an important influence on the formation of the above defects. When the solid-liquid zone is located in the mould outlet or inner mould, the surface of solidification will protrude into the inner mould. If the remaining liquid cannot counteract the solidification contraction, a rough surface will appear. If the solidification surface further into the mould, the ingot in the mould will have a great friction force when pulling and will form a hot tear. When the solid-liquid zone is moved out of mould, the solidification surface will turn into a plane, which easily results in leaking. A vibration or unstable operation will cause an ingot winding during pulling.

Jan 1, 2003

By A. Yudiarto, M. Z. Mubarok

At the present paper, synthesis of magnesia from ferronickel smelting slag is discussed. The first stage was extracting magnesium from the slag by leaching in HCl solution. Magnesium extraction of 97% was obtained from the slag leaching with HCl 8 molar, solid:liquid ratio 1:40 (g/ml) and temperature 80 °C after 24 h. Solution purification was performed by adjusting solution’s pH at 95 °C with addition of MgO powder. At pH range range of 3–4, co-dissolved iron was removed as akagenite (b-FeOOH) precipitate. Dissolved nickel precipitation was detected at pH range of 4–6, while dissolved Mg and Al started to precipitate in the forms of pyroaurite (Mg6Fe2CO3(OH)16∙4H2O) and hydrotalcite (Mg6Al2CO3(OH)16∙4H2O) at pH range of 8–9. High purity of brucite (Mg(OH)2) was obtained by Mg precipitation at pH range of 11–12, under stirring speed of 300 rpm and stirring time of 4 h. Calcination of brucite at temperature of 1000 °C completely converted brucite to periclase (MgO) powder after 240 min.

Mar 1, 2017

By Bora Derin, Onuralp Yucel, M. Seref Sonmez, Murat Alkan

"Latest stage in the production of boron carbide by metallothermic methods using magnesium was the leaching process. Boron carbide particles obtained by self-propagating high temperature synthesis contained several impurities such as magnesium oxide and magnesium borates after the metallothermic reactions. Removal of such contaminates by hydrometallurgical methods required to produce high purity boron carbide. Leaching by concentrated hydrochloric acid solutions resulted in the production of pure boron carbide together with high magnesium and boron containing solutions. Removal of such ions from the spent liquor was the necessity to have dischargeable solution. In this study, precipitation of magnesium and boron compounds from relevant chloride containing spent liquors and the production of saleable products was aimed. The effects of chemical reagents, pH of the solution on the precipitation efficiency of magnesium and boron compounds were investigated in the study. Chemical analysis and the characterisationof solid phases by using x-ray diffraction analysis were the latest stage.Introduction A variety of advanced ceramics, inter-metallic, organic and inorganic compounds, oxygen free single crystals, and polymers can be synthesized by using different SHS techniques [1, 2, 3]. In the SHS process, after initiation, reaction becomes self-sustaining and propagates in the reactant mixture. A high amount of heat which is generated during the process accelerates the reaction rate and thus it makes the process highly productive and economically feasible for different production scales. After the SHS process obtained powder mixture needs to reacted with acidic solutions to purify the product. In this case B2O3 was reacted together with C and Mg to synthesis fine B4C powder resulted in the production of MgO as well according to the Eq. 1 and then MgO was removed from the mixture by leaching with the concentrated HCl solution as shown in Eq. 2, respectively [4, 5]."

Jan 1, 2008

By Zhihe Dou, Yan Li, Qiuyue Zhao, Guozhi Lv, Yan Liu, Hongliang Zhao

"Abstract: How to reduce carbon dioxide emissions has become a vexing problem, meanwhile, there exist high energy consumption and low efficiency problems in the existing CO2 capture and storage technologies. For CO2 comprehensive Utilization, this paper researches a new technology of absorbing the CO2 emission with high alkaline calcium or high alkaline wastewater sludge mineralization of calcium and invent a core device for multi-level jet carbonation. The industrial test has been carried out in China Xinyu slag Engineering Co., Ltd. The wastewater flow is 150m3/h in the pilot scale. The prepared calcium carbonate has a whiteness greater than 90%, particle size less than 150nm. The mineralization of aluminum exhaust with waste carbide indicates that the CO2 absorption rate is greater than 99.0%, CO2 concentration in the exhaust gas is lower than 0.08%, the purity of mineralized calcium carbonate is greater than 99.0% and particle size is less than 100 nm.InstructionAccording to the statistic data from IEA (2009), the carbon dioxide discharge from fossil fuel consumption in China has exceeded it in the US by the year of 2007, China, has become the largest emitter of carbon dioxide all over the world. Meanwhile, the economic scale is still on an increasing trend in the next 50-100 years, leading to a continuous increment in carbon dioxide discharge. According to the international energy agency forecasts, the energy-relative CO2 discharge in China will rise to 11,615 million tons, 91.3% higher than it in 2007. In the year of 2012, the CO2 gross discharge has reached 10,000 million tons, obviously higher than the predicted value. It is a tremendous task to reduce the emission. Non-ferrous metals industry is one of the largest emitters of carbon dioxide among the industrial circle, the whole industry might discharge a huge amount of carbon dioxide (over 600 million tons), in which the electrolytic aluminum industry is the largest energy consuming industry and CO2 emitter. At present, the CO2 discharge has focused by the whole world due to the environmental problems it causes; meanwhile, supplement of new carbon source is needed due to the exhausting oil and coal resources, so that various countries in the world are attaching importance of the recycle and purification of CO2. Many countries are studying on the cyclic utilization of carbon dioxide. Gas CO2 is mainly applied in chemical, pharmaceutical raw materials, beverage filling agent, refrigerant, inert medium, solvents, pressure source, the welding protective gas, antioxidant and fire extinguishing agent, etc. Solid CO2 is mainly applied in penicillin production, fish, cream, ice cream and other food storage and transportation at low temperature, etc. nowadays, such methods as absorption method, membrane separation, adsorption, etc. are widely used to recycle CO2, with such problems as high investment cost and technical constraints etc."

Jan 1, 2014

By M. Hamamoto, S. Tanaka, K. Noda

"Tamano Smelter or Hibi Kyodo Smelting Co. Ltd. is operating with the Tamano Type Flash Smelting Furnace method which is a flash smelting furnace without slag cleaning furnace but which can discharge a slag equivalent to that from the slag cleaning furnace and with the development or coke combustion technology which is the basis of this world's only one type flash smelting furnace process, the smelter exhibits a low operation cost under high productivity operation. Utilizing this experience and improving it we have developed and put to practice an operation guide system using a general purpose computer in order to further establish s stable operation. In this paper these improvements are described. Background of System DevelopmentWith the recent rapid progress of general purpose computers and improvements in their performance an environment for the use or computer in process simulation at low cost and simple operation has been established. If an accurate operation simulation can be done with the Tamano Type Flash Smelting Furnace the merits would be very great and thus we started development of the system. The official name of this system is Computer guide system for Coke Combustion in the T-FSF and taking the initial letters we call it CCCT. We aim to achieve operation with stable mane grade, temperature and slag loss in the furnace by maintaining the most suitable combustion conditions of concentrate and coke in the flash furnace with the assistance of CCCT to the flash smelting furnace operators.Through several production expansion projects clone in the past by oxygen enrichment the copper concentrate treatment quantity and matte grade have increased step by step as shown in Figure I. Following this increase the difference between the operation calculation results al the initial stage of coke combustion and the actual behavior of furnace (matte grade. temperature in the furnace. etc.) gradually became bigger. Further operation procedures taken by different operators against the same phenomenon were sometimes different depending on each individual, which from time to time caused the operation to become unstable. Prior to the development of the system we checked out thoroughly the weak points of operation calculation procedures which were in practice until that time. The results were analyzed and study was carried out to establish a most suitahle operation calculation procedure and finally we reached this system"

Jan 1, 2000

By Olga Slavkina

A new technology of bacterial leaching by means of the Thiobacillus ferrooxidance bacteria is proposed. The equations of reactions that describe of the first and the second stage of bacterial leaching of sulfide raw materials containing non-ferrous metals are given. The theory is analyzed and the technology of processing of some complicated substandard concentrate containing copper and zinc is proposed. The main technological operations including a two-stage bacterial leaching and stages of copper and zinc recovery in the form of marketable product are described. The results of the experimental validation of the main technological parameters of the first stage are given. The main possibilities of a more complete zinc and copper recovery at the second stage of bacterial leaching are discussed in comparison with single-stage leaching process.

Jan 1, 2003

By Shengli Wu, Yuandong Pei, Zhixing Zhao, Shuhai Ou, Jiangshan Shi, Huaiying Ma, Jun Xiong

Spraying technology on sintering surface bed after ignition has become a hot research topic, with the purpose of achieving energy-saving, emission reduction and improvement of sintering indexes. In this paper spraying steam technology was researched from theory, experiment and practice. First of all, from the thermody- namic and kinetic analysis, the mechanism of sintering surface spraying steam was analyzed and its advantageous effect was con firmed. Based on this, sintering pot test and commercial trial were carried out respectively. The results shown that spraying steam is bene ficial for increasing coke combustion ef ficiency with improving CO 2/(CO+CO2) in the exhaust gas from 80% to about 85% level, through decreasing CO content of flue gas by more than 1000 –2000 ppm. There was a suitable spraying amount to improve the quality of the sinter, and the spraying position of the steam cannot be excessively front and rear. Due to the low steam pressure (1 kg) and temperature (about 100 °C) compared with industrial steam (3 kg and 130 °C, respectively), the sinter quality such as yield index was affected by spraying steam in sintering pot test to a certain extent, and proper spraying amount (0.008 m 3, 50 kg sinter) in sinter pot test is far smaller than application amount in commercial trial (2t/h). It is thought that suitable spraying steam parameters has a comprehensive effect of energy saving and quality improvement.

Mar 1, 2018