Search Documents

By Cudmore JF, Rowlands D

Incidents associated with spontaneous combustion of coal have resulted in the loss of many lives and considerable capital and equip- ment. Nevertheless, the factors controlling the propensity of coal to spontaneous combustion are not clearly understood and there is a need for research to study the effects of rank, petrog- raphy, moisture contents, etc. This has been attempted in a study of the propensities of selected Queensland coals to spontaneous combustion. An adiabatic calori- meter was constructed to study the self-heating of a large number of coals. Chemical and petro- graphic analyses of the coals were determined and an attempt was made to relate these propert- ies to the self-heating characteristics of the coal. The results show a strong relationship between rank and self-heating characteristics and that petrographic composition of coal may also be of importance. Some observations on the application of the laboratory results to the practical situation are made as are recommendations for future research.

Jan 1, 1981

Mining software packages are used extensively in industry for resource estimation as well as for mine design and operation. Research undertaken in the W H Bryan Mining Geology Research Unit at the University of Queensland has shown that modifi

Jan 1, 1994

By Lawson F

Narrowly sized samples of synthetic chalcocite (Cu2S) and covellite (CuS) were leached in oxygenated acidic sulphate-chloride solutions. Chalcocite leaches via a two-stage process, the first stage being much more rapid than the second. The apparent activation energies are 42.7 kJ/mol and 68.2 kJ/mol respectively, indicating that both stages are controlled by surface chemical reactions. The leaching of covellite is also chemically rate limited with an apparent activation energy of 77.0 kJ/mol. The shrinking core model is able to be used to describe the leaching processes of both copper sulphides. Over 97% of copper present in chalcocite dissolved in 0.5 M H2SO4i0.5 M NaCl solution under one atmosphere pressure of oxygen at 85¦C in three hours from particles 36 pm in diameter while only 85% of the contained copper in covellite particles 13 pm in diameter dissolved in the same solution under the same pressure at 90¦C in six hours. About 99% of the sulphide sulphur in chalcocite was oxidised to elemental sulphur while only 90% of sulphide sulphur was converted to elemental sulphur during covellite leaching. The mechanism proposed for the two-stage leaching of chalcocite particles is as follows: in the first stage, cuprous ions rapidly diffuse to the external reaction surface where they lose electrons and go into solution as a complex cupric chloride ion CuCl'. The second leaching stage begins when covellite is formed at the external surface. Copper again goes into solution as the CuCl* ion. The mechanism for leaching synthetic covellite is similar to the second leaching stage for chalcocite except that the leaching rate of synthetic covellite is substantially lower than that of the newly formed 'covellite'. Elemental sulphur formed on the particle surface retards the dissolution processes during both chalcocite and covellite leaching. The presence of chloride ions is necessary if essentially all of the copper from chalcocite is to go into solution. When no chloride ions were present, the leaching rate of both newly formed and synthetic covellite was almost zero. The main role of chloride ions in both chalcocite and covellite leaching appears to be to disrupt the passivation film of sulphur on the particle surface.

Jan 1, 1989

By D Feng, G C. Lukey, J S. J, R R. Dagastine

An ongoing challenge in the coal industry is pyrite removal using the flotation method for fine particles. The use of a æseparation in frothÆ (SIF) technique to recover coarse particles of up to a few millimetres in size has presented a potential solution. However the commercial success of SIF is still limited due to the poor understanding of the separation mechanism. The particle floatability in SIF is determined by the constructive or destructive stresses resulting from the forces exerted by the particle on the bubble films. Hence, the surfactant properties and the mineral characteristics (eg hydrophobicity, shape, etc) are the key factors that control the interaction between the particle and froth. In the present work, the interaction forces between different particles (ie crushed glass, pyrite and coal) and a single air bubble are measured in a non-ionic surfactant solution (pentaethylene glycol mono n-dodecyl ether, C12E5) using an atomic force microscope (AFM). Experimental results show that the interaction is primarily dependent on the contact angle (ie the degree of hydrophobicity of the minerals). For crushed glass, the transition from repulsion to attraction was observed as the contact angle increased. As the concentration of C12E5 increased, the adhesion force was suppressed due to wrapping effect. For coal and pyrite with much higher hydrophobicity, long-range attraction was observed. The effect of shape factor was only visible at high surfactant coverage where sign of destabilisation became noticeable on the retracting force curve. These results provide a fundamental understanding of the direct interaction forces of a complex real system between an irregular particle of either crushed glass, pyrite or coal and a single air bubble. Theories developed for interpretation and modelling are thus far based upon the study of ideal systems of glass or polystyrene spheres and an air bubble and were incapable of explaining the interactions in complex real systems. The presented measurements were a first approach to the problem of real mineral-bubble interaction in flotation systems. Thus, the results can only best be interpreted semi-quantitatively.

Jan 1, 2005

By Preston JC, Richards DJ

A multicommodity exploration programme was mounted in the 1970s by CRA Exploration Pty. Limited over a major part of the southern Murray Basin in Victoria. Commodities sought were brown and black coal, gold, uranium, diamonds, titanium and zirconium rich heavy minerals, and base metals. An area of 40 000 km2 was held under exploration licences by the Company. Exploration techniques used were literature research, airborne magnetics and gamma ray spectrometry, drilling, and geophysical well logging. Targets were defined in both the Tertiary basin sediments and the underlying Palaeozoic sedimentary and igneous rocks. Although exploration is continuing, large resources of brown coal and low grade titanium rich heavy minerals have already been discovered. Exploration for uranium was abandoned in accordance with statutory requirements. The search for significant resources of the other commodities has not been successful.

Jan 1, 1986

By Leach B. G

A geostatistical study was made of diamond drill hole intersections within 18CC stope block at the C.S.A. Mine, Cobar, N.S.W. The stope block is located in 18CC orebody which is a massive sulphide - multiple vein, Copper-Zinc type, lacking clear definition on gangue mineralogy, base-metal assays and total sulphide considerations. Of the variograms constructed for inter- section width and copper, lead and zinc grades and accumulations, only zinc displayed behaviour amenable to model fitting and kriging procedures. Zinc grades were calcu- lated for sub-blocks comprising the total stope block and comparison with equivalent grades determined by traditional methods showed them to be generally less extreme in the highest and lowest grade sub-blocks. The total-block grades derived by the two methods were almost the same. It is suggested that the failure of copper to show variogram continuity might reflect the difficulty in defining the actual 18CC orebody, a proposition which is supported by the poor continuity in the variogram of horizontal width. In the case of lead the poor continuity may be due to the frequent manner of occurrence of galena as coarse grained patches of limited extent. The results of the study, did not provide a convincing reason to depart from the traditi- onal methods of grade estimation at the C.S.A. Mine.

Jan 1, 1979

By Armstrong M, Kleingeld W. J

Current low prices for many metals mean that deposits have to be mined at high cut-offs (relative to their mean grade), which means that only a small percentage of mining blocks are above cut-off. Worse, at such high cut-offs, the blocks above cut-off are usually not grouped into convenient clumps for mining; they tend to be split into small isolated patches that are difficult to reach and hence expensive to extract. Companies wishing to acquire mineral properties have to be able to work out quickly what percentage of blocks are above cut-off and what can effectively be mined given the mining method envisaged. Moreover they need this information within a relatively short-time. The work presented here relates to typical South African gold mines (ie tabular orebodies) but the long-term objective is to develop tools for quantifying the impact of reserve breakup at high cut-offs for a wide range of underground mines including those that are not tabular. The mining method and the sampling procedure determine whether ore blocks can effectively be located and extracted economically. This project studied the impact of these two factors on the recoverable reserves for Witwatersrand gold mines. In order to be repeatable, the tests were done on numerical models of the deposit obtained by geostatistical simulations. To ensure realism, the orebody model and the mining scenarios were based on a specific mine. The recoverable reserves (ore tonnage above cut-off, the corresponding metal quantity and the average grade) were calculated for a wide range of cut-offs for four mining scenarios, as well as for the base case of free selection: ò Scenario 1: Blocks are taken if their true grade is above cut-off and if they are accessible from a raiseline (no information effect, no marginal blocks). ò Scenario 2: In addition to the accessible pay blocks, adjoining marginal blocks are taken (no information effect, + marginal blocks). ò Scenario 3: Blocks are taken if their estimated grade is above cut-off and if they are accessible from a raiseline. Here the estimator is the average of the face samples (information effect, no marginal blocks): ò Scenario 4: Accessible pay blocks are taken if their estimated grade is above cut-off. Adjoining marginal blocksare also taken (information effect, + marginal blocks). ò Free selection: All blocks whose true grade is above cut-off are taken irrespective of their accessibility. The results can be presented in different ways, for example by plotting ore tonnage above cut-off versus cut-off grade, or metal tonnage above cut-off versus cut-off grade etc. As expected, this shows the hierarchy between the five scenarios from the free selection base case to scenario No 2 (true accumulations, pay +

Jan 1, 1995

By Chander S

Properties of surface films on chalcopyrite and pyrite differ due to variations in the mechanism of oxidation of the two minerals. In the case of chalcopyrite the first step in the oxidation is the release of iron as ferric ions, which hydrolyse depending upon conditions prevalent in solution. The iron oxide/hydroxide layer formed by hydrolysis of ferric ions is quite porous and easily detachable from the surface of chalcopyrite. When the surface oxide layer is detached a sulphur-rich layer is exposed making chalcopyrite hydrophobic. The thickness and properties of the sulphur-rich layer determine its flotation response, both in the absence and presence of collectors. In the case of pyrite, on the other hand, iron is released as ferrous ions which require much higher pHs to hydrolyse. These ions remain adsorbed on the surface of pyrite making the surface hydrophilic. When the iron species are complexed with chelating agents such as ethylene diamine tetra acetic acid, pyrite was hydrophobic. Siderite forms in the presence of carbonate ions, which might be present in several flotation systems. Siderite nucleated on isolated sites at the surface. The presence of such a precipitate is likely to influence the interaction of pyrite with various reagents thereby altering its flotation behavior. To determine the mechanism of oxidation, kinetics of oxidation of chalcopyrite and pyrite was studied using several electrochemical techniques, namely, cyclic voltammetry, polarisation and impedance spectroscopy. Floatability of the minerals was investigated by measurement of contact angles on mineral electrodes and by Halimond tube flotation. Impedance spectroscopy was especially useful for estimating various properties of surface film for both the minerals. Properties such as charge transfer resistance, porosity, and capacitances of the surface films on the two minerals are compared under several conditions of oxidation. These properties were found to be a strong function of the rate and the extent of oxidation.

Jan 1, 1993

By M Battersby, F Parra, S Sanchez-Pino

Pneumatic flotation, as developed by Dr Rainer Imhof, has been applied in commercial beneficiation operations since 1987. Over 85 flotation cells have been installed in more than 30 operations, successfully beneficiating a wide range of minerals. Pneumatic flotation is however still considered as a non-conventional flotation process. Due to its highly selective nature in operation it has generally found its market in difficult applications where conventional flotation equipment has struggled. Compa±fa Minera Huasco (CMH) operates an iron ore pellet plant in central Chile. CMH desired to produce a low silica pellet for the export market where the SiO2 grade should not exceed 1.5 per cent. It is common practice in other countries to float quartz from hematite with relative ease. However, the silicates contained in the magnetite ore of CMH are only present as quartz in small quantities and the major undesirable silicates are difficult to float. CMH spent considerable time on developing a reverse flotation process and a reagent suite to try and reduce the silica content to acceptable levels. However, extensive laboratory and pilot plant tests with conventional mechanical tank type cells and with column cells failed to produce the required reduction in impurities. A series of tests with pneumatic flotation cells indicated that this type of flotation technology could achieve the required silica target. A 500 tph Imhoflot pneumatic flotation plant was subsequently constructed and successfully commissioned by CMH, making it one of the largest iron ore flotation plants in the world. This paper details the background and testing that was undertaken by CMH which led them to choose pneumatic flotation as the preferred process and compares the test results with that achieved in the industrial plant.

Jan 1, 2005

By G Baird, M Seto

A low-cost methodology that allows the determination of in situ stresses using oriented core specimens has been investigated. The technique can be used to determine the stresses during the early stages of a project, even in undeveloped areas of a mine. The research aim was to compare the experimental results estimated by the Acoustic Emission and Deformation Rate Analysis methods with those estimated by conventional Hollow Inclusion cell measurements. The studies have been focused on full stress tensor determination from a single oriented rock core. In all cases the rock core specimens recollected the in situ stresses reasonably well compared with the standard overcoring method.

Jan 1, 2000

By Roe P, Lowell A

This paper outlines software development and design work carried out by Mincom Pty Ltd in collaboration with Capricorn Coal Management (CAPCOAL) for computer based design of rehabilitated strip mine landforms at German Creek Mine. Current developments and future application areas for this software are also discussed in relation to other mines in Central Queensland. The development program was initiated in response to statutory requirements placed on mining companies in 1990 to produce a five year Plan of Operations which was to include a contour plan of the final rehabilitated mine landform at the end of the five year planning period. This plan was to be submitted to the Department of Resource Industries (DRI) by 1 December 1990. Due to the limited time given to prepare the plan, a work program was formulated in collaboration with Mincom Pty Ltd to develop suitable software to carry out the design work and provide the required plans and quantities. The software had to include computer based methods to allow design of the proposed landform in line with the rehabilitation strategy adopted by CAPCOAL at the time.

Jan 1, 1991

By Dennis B

The Hilton Mine, 20 km north of Mount Isa was discovered in 1947. The underground mine has been a significant producer from 1989. The long development history is the result of complex orebody geometry, difficult metallurgy, dewatering problems and competition for development funds from the then expanding Isa Mine at Mount Isa. At present it produces 1.4 million tonnes annually. Its 21 million tonnes of reserves are necessary to supplement Isa Mine production.Hilton Mine is located in the Urquhart Shale formation of the Mount Isa Group, within the Mid Proterozoic Mount Isa Inlier. The seven developed orebodies have suffered strong structural deformation. Each orebody has a unique mixture of mineralogy and texture which effects ore value and metallurgical performance. These characteristics have proven useful for correlation purposes.The faulting and folding have caused difficulties with orebody interpretation, geomechanical complexities and has influenced the choice of mining methods: Initial cut and fill and open scope designs have given way to bench mining methods in response to better understanding of the eedloav and economic constraints.

Jan 1, 1993

Magnetic separation using particle rotation in a continuously rotating magnetic field offers very low to insignificant non-magnetic particle entrapment, and precise magnetic fractions. The precision of rotating magnetic field separations makes the method ideal for dry laboratory magnetic analysis work, where conventional laboratory magnetic separators can give misleading or uncertain data. The very low entrapment characteristics make the method ideal for entrapment-critical separations within the diamond exploration industry or in gold recovery. A single wet rotating magnetic field (RMF) unit is able to achieve a cleaner separation (at similar or better recovery rates) than a three-stage separation using conventional wet drum separators. The RMF separator is able to work effectively at particle sizes below 50 ¦m, and RMF separation could, at least in theory, be used down to single domain particle sizes. Rotating magnetic field (RMF) separation is carried out by magnetically spinning the particles at frequencies up to 300 Hz. The particle rotation itself may be used to roll the particles out of the separator. At angular velocities of 100 Hz, magnetic flocs are unable to form, and any entrapped particles are energetically expelled. In an RMF separator, the outer drum can be stationary while the inner magnet rotor rotates, allowing, for example, the injection of cleaning water underneath the separating magnetics to help remove small suspended non-magnetic particles.

Jan 1, 2000

By Prosser AP

The large body of knowledge about the relation between chemical process efficiency and mineralogical features is of only limited use. The profession ought to try to improve the methods of using information as well as adding to the knowledge. One attempt isòdescribed. Correlations between process efficiency factors and the mineralogical features of low- grade concentrates have been developed from both a theoretical analysis and experimental measurements. The ultimate recovery of a reactive phase in an inert matrix can be calcu- lated from simple measurements of the particle size, porosity and pore size of the concentrate, and the grain size of the reactive mineral., The rate of recovery, up to 98% recovery, can be calculated from simple measurements of particle size, porosity, proportion of reactive mineral and tortuosity. Some details are given. The correlations are of potential use in process selection and preliminary design. Satisfactory predictions have been made for near-ideal systems. Improvements in the measurement of pore size and tests on more realistic materials are required. The ultimate benefit of the correlations will be determined by the magnitude and frequency of the effects of mineralogical features other than those specified above.

Jan 1, 1975

By Dyson NF

Nickel sulphide precipitated from waste liquors at the Yabulu plant of Queensland Nickel Pty Ltd was pressure leached under various conditions. Leaching at 130¦C and 700 kPa of air dissolved 95 per cent of the nickel as the sulphate in less than 2 h. Leaching at 130¦C and 350 kPa of oxygen dis- solved 95 per cent of the nickel in less than 1 h. Dissolution was faster with oxygen than with the equivalent pressure of air. Crystallization of hydrated nickel sul- phate from the resulting clarified leachate is readily achieved. Because the sulphide pre- cipitate also contains minor amounts of iron, copper and cobalt, the crystallization product contains these metals in excess of the amounts required for electrolytic-grade nickel sul- phate. This grade of product could only be produced if the contaminants were removed prior to crystallization. Alternatively, the "crude" nickel sulphate could find a market as a feed for the electrolytic production of Ni-Fe coatings.

Jan 1, 1984

The theory of declining optimimum cut-off grades is more than 25 years old, but for a number of reasons it is still not widely used in industry. A lack of faith in the veracity of estimated grades is not in itself a reason to abandon any attempt to optimise cut-off grades. The use of declining cut-off grades has been thought to cause high-grading, but in fact this is only true if an artificially high discount rate is used in the calculations. Perfect application of an optimum cut-off grade should ensure that only ore generating more than a minimum net return is mined, and that as much as possible of the ore capable of generating that return is mined. Therefore differing mining costs in different parts of some underground mines necessitate local modifications to cut-off grade. Optimisation of cut-off grade is of necessity an iterative process. Integration of that process into a feasibility study need not be excessively time-consuming. A number of approximations can be made to speed the optimisation (any attempt to achieve a high level of accuracy is probably doomed to failure by a lack of precise cost and price projections). A procedure is outlined for optimising cut-off grade during planning of a typical underground mine.

Jan 1, 1991

By Mutton B. K

Hilton Mine is being developed as an integrated component of the Mount Isa operation, to achieve continuity of silver/lead/zinc production well into the next century. The mine has a chequered history from its discovery in 1947 through several periods of intense development activity, each of which has been curtailed due to the further development of the Isa Mine operation. This era has now passed; to sustain increased production rates at Mount Isa, there is a requirement for Hilton ore in 1989. The decision was made in 1983 to accelerate the programme of Hilton development by installing skip hoisting facilities in the main service shaft (P49), to facilitate the development of the mine to pre-production status. The Hilton development plan provides for the mining of selected orebodies, a broadening of the underground exploration drilling programme, and the establishment of significant mine infrastructure. Several technical challenges have been identified as important. The Hilton orebodies, although occurring in the same rock type as Isa Mine, are more faulted, jointed and intersected by intrusive dykes. The ore is more variable in terms of ore continuity, boundaries, grade and metal distribution and the mineralogy more complex. As a consequence the development of this project consists of a co-ordinated programme of mine exploration and development, rock mechanics investigations and metallurgical research and development work. Production will commence in 1986 at a rate of 1000 t/day using mechanized cut and fill techniques. It is planned to introduce sublevel open stoping and by 1996/97 the production rate will be 2.5 million t/yr.

Jan 1, 1986

There is no other effective way for study ing firedamp and coaldust explosions than to produce controlled explosions in a pre-monitor- ed environment - either mine openings kept for the purpose, or special surface galleries. Such explosion testing facilities have been employed historically at Buxton in U.K., with lesser known installations at Bruceton, U.S.A., Tremonia, West Germany, Katowice-Mikolow, Poland and elsewhere. Both firedamp and coal dust explosions are studied. Normally coal dust explosions are initiated by somewhat standardised methane air mixtures, by explosives, or purely by coal dust. Various structures and suppression installations are installed in roadways and galleries prior to explosion to simulate destruction and suppression, and the results of such tests form the basis of suppression installations, especially stone dust barriers and water barriers. Other data collected from these experiments include rev- ersals of explosion waves, pressures and temperatures and duration of explosion waves, analyses of aftergases etc. Other uses of explosion testing galleries include testing of explosives, electrical equipment and frictional . sparking.

Jan 1, 1981

It is a privilege for me to participate in this vitally important discussion of The Role of Governments in the Management of Resources. The distinction of my fellow participants is evidence that this event is a matter of extreme importance and attracts international attention. In the management of natural resources, government and private enterprise share awesome responsibilities for the economic well-being of nations. Mining and its relation to the prosperity of nations is almost as old as recorded history. Copper was being mined and extractive metal- lurgy practised at Timna in Israel's southern desert as far back as 4000 B.C., and the rich mines of Laurium not only saved the Greeks from Persian domination 2500 years ago, but also provided Athens with a monopoly of silver in the Mediterranean world. This bolstered the economic power of Athens and led to the golden age of Greek commerce and culture.

Jan 1, 1978

By Motyka J, Adamczyk AF, Witczak S

A case study of migration of a paper factory fluid wastes, on the distance of 5 km from an underground disposal site to an ore mine is presented. The ore mine in question, situated in SW Poland is pumping 3.5 m3/s (ca 300 000 m3/day) of groundwater, producing a cone of depression about 150 m deep and several kilometers wide. The migration of wastes (pollutant) occurs within the carbonate karstic aquifer of Triassic age. The aquifer is about 100m thick and is characterized by the coefficient of hydraulic conductivity equal to 8 m/day on the average. The results of systematic measurements carried out for 13 years enabled to estimate the mean breakthrough curve of the pollutant. On this basis and taking into account the coefficient of hydraulic conductivity as well as the mean hydraulic gradient between the disposal site and the ore mine, the migration parameters of the polluting material, i.e. the real flow velocity, the effective porosity and the longitudinal disper- sivity have been calculated. As the measurements considered a long migration distance of the pollutant, the obtained hydrodynamic dispersion constant (dispersivity), in the authors opinion, is reliable enough to be applied for regional groundwater calculations, regardless of the "scale effect".

Jan 1, 1988