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By Eung Ha Cho, Wendi Li

Wet desulfurization of Pittsburgh No. 8 coal and Illinois No. 6 coal were conducted with sodium hypochlorite in the laboratory. Pittsburgh No. 8 coal was leached by hypochlorite at high pHs in one step only. The hypochlorite concentration varied from 0.2 to 0.6 molar; sodium hydroxide concentration, from 0.2 to 0.8 molar; and temperature was at the levels of 80 and 90°C. The desulfurization of Illinois No. 6 coal was conducted in three consecutive steps of pretreatment in concentrated ammonia at room temperature, leaching with hypochlorite at room temperature and hydrolysis in sodium hydroxide solution at 90°C. In the leaching step, hypochlorite concentration varied from 0.2 to 0.8 molar. The desulfurization method of Pittsburgh No. 8 coal was found to reduce mainly pyritic sulfur. More than 70% of pyritic sulfur removal was achieved at the optimum conditions of 0.4 molar hypochlorite, 0.4 molar sodium hydroxide and 90°C. The desulfurization method for Illinois No. 6 coal was capable of reducing significant amounts of organic sulfur. The removal of organic sulfur achieved a 37.8% reduction at the optimum operation of leaching at 0.4 molar hypochlorite and room temperature followed by hydrolysis at 0.3 molar sodium hydroxide and 90°C. The chlorine content in the coal produced by the chlorination during leaching was kept below the threshold value of 0.3% at the optimum conditions of the desulfurization method for each coal.

Jan 1, 2005

By S. W. Stogran

"A brief summary of the environmental testing and analyses required to ensure and maintain compliance of mining properties will be discussed. Programs for new and existing properties and for properties which may be purchased will be outlined and potential solutions to problems will be discussed. In addition to the compliance aspects of operations, due diligence will be discussed.1.0 INTRODUCTIONThe impact of mining projects on the environment is an area of major concern to the public, governmental agencies and mining companies. Due to the ever increasing pressure on the government by special interest groups and the public, governments have implemented legislation to control potential environmental impact of mining, from the exploration phase through to close-out. By not planning for environmental issues during all phases of a mining operation, unavoidable delays and retrofitted environmental programmes will be expensive and cause projects to be delayed, which, ultimately, may cause the abandonment of a mining prospect. Most jurisdictions require at least one full year of background environmental data. Therefore, many thousands of dollars are wasted as construction is interfered with or held up due to data collection. This may be avoided by a thousand dollars worth of sample being collected and analyzed early in the project."

Jan 1, 1992

By Richard Phiri, Mike Milupi, Jackson Kapobe, Anton Lemmer, Charles Mazala

Sustainability of plant operations in a rapidly changing mining environment requires a well-trained workforce to ensure smooth running of operations. To ensure availability of trained labor, Mopani Copper Mines PLC set up a training facility in 2013. The school offers training in Engineering, Mining and Process. The engineering section enrolls grade 12 school leavers for artisan training. Mining section offers comprehensive safety induction program to employees and contractors to meet the Mopani zero tolerance accidents safety policy. The process training section offers advanced training programs for plant operating personnel and university graduates. The program includes needs analysis, theoretical metallurgical modules, practical plant training and e-learning modules. The school also offers assaying and sampling courses. All the above courses are extended to individuals and other mining houses outside Mopani wishing to have their personnel trained. The Mopani sustainable development academy ensures that contractors engaged on the Mopani sites are fully registered, comply with all relevant regulations and have undergone induction program before they can be allowed to work on the mine. INTRODUCTION “Sustainable operation of the mining industry requires a continuous supply of trained human resources” (Kapobe et al., 2018). The publication by the Asian Development Bank (2014) argued that there was a mismatch between the demand for high-level skills and the oversupply of low-level skills. Globally, the mining industry requires continued supply of skilled manpower for its complex operations and long term projects whose sustainability is absolutely necessary. Implementation of newer technologies in plant operations to ensure cost effective and efficient operations requires trained and skilled labor at various levels to handle ever-changing challenges. Dutz (2007:152–156) made three recommendations for Building Worker and Management Skills in India: Strengthen enterprise - based training. The government should help ensure that the benefits of in- service training are widely recognized by enterprises, while simultaneously providing strong financial incentives Improve vocational training - Vocational education and training systems have been unsuccessful in preparing graduates to meet market needs, particularly because of a lack of interaction with industry. Public and private vocational education and training providers should be strengthened to make them more responsive to industry demands. Curricula should be updated to reflect modern technologies. Strengthen business, management education, management of research and commercialization - business and management education should be strengthened through public-private partnerships. Innovative management courses should be introduced. Although these recommendations were made for India, they also apply to Zambia and other low and medium income nations.

Jan 1, 2019

By D. Witchard, G. C. Penny

An important conclusion of the study is that altering the properties of the granulation water is a practical way of improving the sintering performance of blends that contain porous ores, and more work is under way to investigate other additives. Previous studies of iron ore blends containing pisolite ore showed that losses in sintering productivity were a result of deteriorating green-bed permeability. Pisolite ores are extremely porous and absorb a proportion of the water added during granulation. Although increased water addition could be used to counteract losses in productivity, the current study examined methods of inhibiting water absorption by pisolite ore as a means of improving productivity. Additives were used to alter the properties of the granulating water. With no increase in mix moisture contents pilot-scale sintering studies showed that sugar-based additives gave productivities that are higher than those obtained for a comparable ore blend containing haematite rather than the pisolitic ore. Several techniques of adding the sugar to the sinter mix were examined and found to increase productivity to varying degrees. Theoretical considerations, in some cases supported by experimental results, indicate that sugar-based additives not only inhibited water absorption by porous ore particles but also improved the permeability of the sintering bed. The study also suggested that, contrary to some commonly held views, the highly reactive nature of Yandi ore from Western Australia is beneficial for sintering. Porous ores enabled the formation of a strong sinter at fast flame-front speeds-both good strength and a short sintering time are requirements for high-productivity operation

Jun 18, 1905

As part of the Bureau of Mines program to reduce U.S. reliance on foreign suppliers of strategic and critical metals, research was conducted to improve technology for the recovery of critical metals from hardface alloy grinding waste, a form of superalloy scrap. This report describes a hydrometallurgical process that demonstrated on a laboratory scale that 79 pct of the chromium, 97 pct of the cobalt, 99 pct of the manganese, 99 pct of the nickel, and 90 pct of the tungsten could be recovered in chemical form from hardface alloy grinding waste. The process involved deoiling the grinding waste, followed by chloride-based dissolution of the deoiled material. A high-grade calcium tungstate (CaW04) product was recovered from the resultant leach residue by caustic leaching and precipitation. Iron, cobalt, man-ganese, and nickel chlorides were sequentially recovered from the leach liquor by solvent extraction. Amine extractants were used to extract the iron, cobalt, and manganese; decanal oxime was used to extract the nickel. Market-grade cobalt chloride (CoCI2), manganese chloride (MnC12), and nickel chloride (NiCl2) products could be produced directly from the resultant strip liquors. The final raffrnate was a relatively pure chromic chloride (CrCI3) solution that compared favorably with commercial solutions.

Jan 1, 1988

By J. Persson, N. G. Bliss

Electric furnaces used for smelting and those used for scrap melting exhibit different performance profiles in terms of electrical characteristics. However, the underlying principles are the same for either case. The rationalization of these variables is a major concern for furnace operators and designers. This paper presents the results of a two year study of high speed real time data from a number of electric furnaces around the world, covering a very wide range of design philosophy and product manufacture, to provide a better mathematical insight into rationalizing the furnace operation.

Jan 1, 2004

By M. Beth McClenaghan

This paper summarizes diamond exploration techniques used in glaciated terrain, focusing on indicator mineral and geochemical methods applied to glacial sediments. Understanding the ice flow history, depositional history, and stratigraphy of glacial sediments are essential to successful sampling, interpretation and follow-up of indicator mineral and geochemical anomalies related to kimberlites. Kimberlite indicator minerals survive glacial transport over long distances and the relative abundance of each mineral in till is a function of the primary mineralogy of individual kimberlites. Indicator mineral distributions observed at a regional scale define the net effect of glacial dispersal, often along different ice flow directions. Local-scale distributions define individual dispersal trains. The medium sand (0.25 to 0.5 mm) fraction of heavy mineral concentrates prepared from glacial sediment samples is best suited for indicator mineral surveys. The application of till geochemistry to diamond exploration is increasing because it is significantly cheaper than indicator mineral analysis and it can be performed quickly. The <0.063 mm (silt+clay) and 0.5 to 2.0 mm (coarse sand) fractions provide the best geochemical contrast between background and kimberlite-rich till. Kimberlite pathfinder elements that provide good contrast include Ni, Cr, Ba, Co, Sr, Rb, Nb, Mg, Ta, Ca, Fe, K, Ti and REE, the relative importance of which will depend on kimberlite composition as well as that of the surrounding bedrock.

May 1, 2002

During the past decade, the miner-al industries have been faced with an increasing shortage of engineers. The point has now been reached where the shortage may be termed critical. This shortage may be attributed directly to declining enrollment in the mineral science programs offered by the universities on this continent. Although the reasons for declining enrollment are undoubtedly many, two major hypotheses may be postulated. The first is that high-school graduates are either unaware of the mineral industries and the opportunities in them or that they are aware of them but have somehow obtained a false image of their true nature. The second is that they are aware of the true nature of these industries and the opportunities they offer but find them exceedingly unattractive. The problem of dwindling enrollments has, in recent years, been subjected to a concerted attack by the industries and professions concerned. However, their efforts to date have been based essentially on the first hypothesis. Sufficient results are now available to suggest that either the methods of attack are inappropriate

Jan 1, 1965

By C A. Locke, A B. Christie, J Cassidy, J L. Mauk

New and existing gravity and aeromagnetic data are used to determine the structure of the Waihi region and to investigate any relationship between structure, hydrothermal alteration and epithermal mineralisation. The 24 mGal, 10 km diameter, negative Bouguer gravity anomaly which occurs south of Waihi has been modelled as a I.5 km deep asymmetrical basin. This basin, the Waihi Depression, is interpreted to be infilled with low-density volcanic rocks of the Uretara Formation and Whitianga Group, overlying older andesites of the Waipupu Formation. To the north and west, the margins of the depression are defined by the Waihi and Mangakino Faults, which have been modelled with dips of 45 - 60¦ to the south and west respectively. The southern and eastern boundaries of the Waihi Depression are defined by smooth, shallow dipping (15 - 20¦) boundaries. The Waihi Depression is interpreted as a fault-angle depression, resulting from southeast extension in the early Pliocene. The Waihi Fault is modelled as an approximately E-W feature, located to the south of Waihi. Small 2 - 4 mGal positive Bouguer gravity anomalies occur north and west of the margins of the depression, and correlate with known areas of hydrothermal alteration and areas of low magnetic gradient.

Jan 1, 2003

By Junji Shibata

Keywords: Synergistic effect, Solvent extraction, Nickel ion, extractant mixture Waste solution from the Ni non-electric plating process contains 4.0 kg/m3 Ni (II), 0.1 kg/m3 Fe (III), 0.01 kg/m3 Zn (II), 48 kg/m3 SO42-, 98 kg/m3 HPO32- and 31 kg/m3 lactic acid as a typical composition. Solvent extraction, cementation, ion exchange resin and precipitation methods may be used for the treatment of this kind of solution. In this study, solvent extraction of Ni (II) is investigated by using two kinds of extractants in order to clarify the relationship between extraction equilibrium (static synergistic effect) and extraction rate (dynamic synergistic effect) for several extractant mixtures. The static synergistic effect does not take place significantly for the extractant mixtures of acidic extractants and neutral organphosphorous compounds, while a large static synergistic effect is confirmed when the extractant mixtures of acidic extractants and nitrogen-containing compounds are used. Nickel ions can be extracted in the wide pH range of 3.0-8.0 without any pH adjustment by using the several extractant mixtures. At the same time, the extraction rate remarkably increases by using the extractant mixtures of acidic extractants and nitrogen-containing compounds.

Jan 1, 2005

By Hakan Gurgenli

Many coal seams have weak shale immediate roofs that cause ground control problems. Therefore, it is important to know the properties of these shales so that preventive measures can be developed in advance. However, it is sometimes hard to understand this rock type due to its unpredictable behavior. A good example of this situation is found in two shale coal mine roofs located in the Illinois coal basin (Herrin No. 6 seam). Although, these mines are located very close to each other, one of them has many roof falls, whereas the other has no measurable ground control problems. The aim of this paper is to explain why and how one shale roof behaves worse than the other. Laboratory tests, including point load strength index, slake durability index, moisture activity index, weatherability index, water content determination, swelling strain and x-ray diffraction tests were performed to analyze the shale properties. According to these analyses, some useful correlations were found between the engineering properties, moisture-sensitivity indices, and weathering properties. Finally, mine and support design considerations based on the test results were discussed and recommendations to prevent ground control problems were given.

Jan 1, 2006

By Gregory A. Johnson

Operations and Maintenance departments have long had an adversarial relationship. The widespread evolution and adoption of modern management techniques such as Reliability Centered Maintenance (RCM) and Lean Production however has driven interest in working co-operatively to optimize overall plant performance. Mining and minerals operations have long adopted RCM in maintenance, and are now adopting Lean throughout the organization. Modern management initiatives like these explicitly call for co-operation between the two disciplines of maintenance and production and many advances have been made in the realms of people and methodology. One area that has lagged behind in supporting these developments however is information systems. Enterprise Asset Management (EAM) systems in maintenance and newer Manufacturing Execution Systems (MES) in operations have not been truly integrated in the way needed. Complicated plants, different software architectures, continually changing conditions and many variables have lead to systems problems which have contributed to the maintenance/operations divide. Master data synchronization (the ?plant tree?) and integrated reporting of real-time data with transactional data are just two of the issues that are being solved by new approaches in information technology including web services and service orientated architectures. New technologies are coming on-stream to enable the final ?bridging of the gap?.

Feb 1, 2008

The gold salting fraud at Busang on the island of Kalimantan, Indonesia was exposed in early 1997 and resulted from the independent drilling, sampling and assaying of PT Freeport Indonesia which reported assays from the South East Zone with negligible concentrations of gold. Since then, a number of legal actions directed at former Bre-X directors, consulting firms and financial or broking institutions are at various stages and are based on numerous allegations surrounding the supposed existence of obvious and numerous warning signs or æred flagsÆ. These include: the absence of references to visible gold in the drill logs; the alluvial nature of the gold grains; the high gravity recoveries; the invalid comparison with Kelian; the absence of outside scrutiny and the lack of external review/audit and surface depletion of gold. The focus on the red flags has been at the expense of the numerous positive indications or ægreen flagsÆ. These include the morphology and chemistry of the gold grains, the gravity testwork, the amalgamation results, the role of external consultants, the results of a review by one of North AmericaÆs leading minerals auditing groups, the behaviour of the gold at surface and the presence of references to visible gold in the drill logs. The flawed nature of the discussion of the technical facts surrounding Busang has prevented a meaningful and informed discussion about what actually happened and has, therefore, prevented the formulation of meaningful remedies for the future.

Jan 1, 2002

By Rolf Katzenbach

The principle questions related to the design of deep foundations especially in soft soils are the stability and the cost optimised settlement reduction to prevent possible damages and to minimise the deformations of the adjacent infrastructure. The present develop­ments in the design of deep foundations lead to the design approach of the Combined Pile-Raft Foundation (CPRF) which offers a lot of new possibilities, e.g. the utilisation of the CPRF for horizontal loading or the use of the subsoil as a geothermal storage system.

Jan 1, 2006

Kinetic Behaviour of Solid/Solid Separation of Ultrafine Particles in Aqueous Suspension

Sep 13, 2010

By D. Brandt

The Dos Pobres Mine is a copper oxide heap-leach mine located near Safford, Arizona. Mine production is 180,000 tons (163,293 tonnes) per day with a stripping ratio of 2:1. During the startup phase of the mine, the required fragmentation size was easy to achieve as the ore was highly weathered and fractured near the surface. As the mine depth increased, the proper fragmentation size became harder to achieve due to less weathering and different rock types. Because copper recovery increases as crusher product size decreases, achieving the appropriate product size at the crusher is the operating priority. The Engineering Department started a project to improve fragmentation through blasting and thus increase throughput in the crushing system. It soon became clear that input from other departments was going to be required to make this a safe and economical project. Therefore the Crush and Convey and Ore Control departments worked together to evaluate all available data on blast patterns and explosive loads and tracked performance and results. Using image analysis, Drill Energy Index and databases, we have been able to improve fragmentation size and verify the results while controlling costs.

Jan 1, 2011

The Pogo Mine, near Delta Junction, Alaska is a 2500 TPD gold operation employing processes including grinding, gravity, rougher flotation, leach, CIP, and E/W. An OCS(Optimizing Control System) expert control system has been implemented on rougher flotation in early 2008. The OCS system communicates with the Plant DCS(Distributed Control System) through OPC(OLE for Process Control) communication. The initial strategy was to control the flotation cell froth level set points to achieve target froth velocities. This strategy was enhanced by controlling both level and air flow setpoints. The flotation cell air and level are adjusted to reach cell pulling rates (froth velocities). The pulling rate setpoints for each cell are determined based on downstream capacity (concentrate surge tank level). The effect of pH and upstream disturbances is also taken into account in adjusting the air and level setpoints. Feed forward compensation is employed down the flotation row to minimize disturbances.

Jan 1, 2009

Introduction The Homestake Mining Co. has always been big on gold. After 108 years in the business, the company and its principal product are almost synonymous. The relationship continues. On Sept. 28, 1985, Homestake held formal dedication ceremonies for its newest gold mine - McLaughlin. The McLaughlin open-pit operation is located in northern California, some 113 km (70 miles) northeast of San Francisco. It lies near the boundaries of three counties - Napa, Yolo, and Lake - and a portion of its facilities are located in each. McLaughlin was originally the site of the Manhattan mercury mine that produced nearly 80,000 flasks of the quicksilver from the 1860s to 1978. At the September dedication, Homestake renamed the mine in honor of the late Donald H. McLaughlin. McLaughlin was with Homestake for nearly 60 years. He rose from exploration geologist to his ultimate positions of chief executive officer, director, chairman of the board of directors, chairman emeritus, and chairman of the executive committee. The discovery of the McLaughlin deposit occurred in 1978, the last year of operation for the Manhattan mine. Homestake geologists used a newly developed model and found surface gold at the mine site. That same year, Homestake signed an agreement with the property owner and began a two-and-a-half year exploration program. An initial discovery announcement of 31.1 t (1 million oz) of gold was made in 1980. In 1981, this was revised to 93.3 t (3 million oz), or 18 Mt (20 million st) of ore grading 5.2 g/t (0.152 oz per st). Expected mine life is 20 years. Construction began in September 1983, following the issuance of stage one permits. Start-up of operations took place in early 1985 and the first gold-silver dore bar was poured on March 4. Since then, more than 540 kt (600,000 st) of ore has been milled, producing about 1.6 t (50,000 oz) of gold. Of special interest at McLaughlin is the use of three autoclaves for gold extraction. According to Homestake, this is a first. The autoclaves are designed for a 90% gold recovery rate. Early results have proven yields at this rate and higher. Geology The McLaughlin deposit is about 1.5 km (5000 ft) long. It occurs as a wedge-shape, narrowing to a verti-

Jan 1, 1986

By Dale Preece, Stephen Chung

Blasting induced rock fragmentation is an art that has been developed and refined for hundred’s of years through blasting and recording the results. Good blasting fragmentation practices were thus developed through experience. However, this method requires a history that is typically developed in a mine over a number of years and sometimes at considerable expense. Quantification of fragmentation as a function of rock-mass characteristics and blast design is attractive. Developments towards this end have included semi-empirical methods as well as computer codes that explicitly treat shock wave transmission and the subsequent rock breakage. This paper will present predictions of fragmentation resulting from rock blasting using the computer code AUTODYN and a new state-of-the-art material model for brittle rock and concrete.

Jan 1, 2003

By Marc C. Bétournay

Under the requirement to define the economic advantages of using hydrogen fuelcell vehicles, a broadscoped project was initiated to quantify the costs associated with operating fuelcell vehicles and diesel vehicles. While ventilation savings are clearly an advantage for the former, a complete and detailed analysis of this and other operational and capital cost elements was undertaken in order to provide the mining industry with factual information in considering the changeover from one technology to another. This article outlines the results of the investigations to date defining the costs/benefits associated with: capital purchases, operations (electrical/diesel, mine air heating fuel, ventilation, openings, surface and underground infrastructure, maintenance, labour, etc.), delivery of energy, regulatory obligations, and mine production. Considerations are given to the type and size of a mining operation, the depth, and location in North America. Significant ventilation power, equipment and infrastructure savings are possible with the application of fuelcells for shallower mine applications. At depth, where heat is an issue, there is a reduction in benefit. Specific qualifiers such as minimum air velocities, dust dilution, shaft and heating system velocity limits must be considered on an individual mine basis. While the capital cost for fuelcell mining equipment is currently higher than diesel versions, the high cost of fuelcells is anticipated to be reduced significantly in the near future with the intensification of manufacturing. In either case the operational savings would probably be sufficient to balance the supplementary capitalization costs. A comprehensive cost-benefit report will be issued in the near future.

May 1, 2003