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By Liu Wei

In order to make clear the dissolving characteristic of the chrysocolla (CuSiO3?H2O) in the ammonia-ammonium chloride solution, a thermodynamic model of the chrysocolla (CuSiO3?H2O)-ammonia- ammonium chloride-water system is established using the exponential computation method based on both mass balance and charge balance equations. The equation group of the thermodynamic model is solved by the MATLAB Soft on PC. The condition which is favorable for dissolving high concentration of copper in solution is making out. The stable area of chrysocolla (CuSiO3?H2O) and the condition of chrysocolla (CuSiO3?H2O) converting to atacamite (Cu(OH)1.5Cl0.5) is also studied. A group of experiments are designed to validate the veracity of the results of the thermodynamic calculation.

Jan 1, 2010

By Pengfu Tan

One copper Isasmelt furnace has been operated in Xstrata Copper at Mount Isa in Australia since 1992. A thermodynamic model and computer program, CuModel, has been developed to model the distribution behaviors of Cu, Fe, S, O, Ni, Co, Sn, Pb, Zn, As, Sb, Bi, Au and Ag, copper loss in the slag, and heat balance in copper smelting process, matte converting process and copper continuous smelting process. The thermodynamic model has been used to model the key parameters in the control of the copper Isasmelt furnace. The effects of the process parameters on the control of the copper Isasmelt furnace have been predicted and discussed. These process parameters include SiO2/Fe, matte grade, coal, temperature, spec air of feed, oxygen enrichment, and MgO contents in slag.

Jan 1, 2006

By S. N. Lekakh

Phosphorous segregated at grain boundaries during solidification and heat treatment dramatically decreases low temperature toughness of precipitation hardened Fe-Mn-Al-C austenitic steel. A thermodynamic analysis was performed to evaluate the possibility of decreasing P and subsequent segregation by Ca- and Ce-additives in the melt. It was shown that the predicted probability of forming a P containing compounds depends on melt composition and treatment sequence. Experimental heats were performed and several micro- and macro-structural effects of Ca- and Ce-additives were recognized by using an automated inclusion analysis technique.

Jan 1, 2010

By Y. Zhoa

The surface morphology of materials is of fundamental importance to many surface related applications, such as wetting, friction, reflection, drag, and adhesion. Various approaches for micro/nano patterning atop polymer surfaces have been proposed in recent years. However, a cost effective technique is still highly in demand. In this paper, we demonstrate a novel but rather simple and generic approach for surface micro/nano patterning using shape memory polymers (SMPs). Different types of novel patterns are realized and their 3-D surface features are quantitatively analyzed by a PLµ Confocal imaging profiler.

Jan 1, 2010

By S. Y. Tan

The thermal stability of fully silicided NiSi with arsenic doping on silicon was investigated. The aims of the work were to investigate the Ni silicide phase-related issues associated with arsenic dopant and thermal annealing on Ni-FUSI/HfO2/Si and Ni-FUSI/HfSiO/Si gate stacks. It was found that arsenic-incorporation demonstrated some improvement in both morphology and phase stability of nickel silicided films at high processing temperatures regardless underlying gate dielectrics. The correlations of Ni-Si phase transformation and arsenic doapnt with their electrical and physical changes were established by sheet resistance measurements, X-ray diffraction (XRD), atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS) analysis. Furthermore, the modulation of the work function (WF) of Ni fully silicided gates by arsenic impurity is presented, comparing the effects of dopant (As) on the WF and silicide phases (NiSi and NiSi2). It confirmed that the work function of NiSi can be tuned by implanting arsenic dopant, but it ineffective for NiSi2 phase.

Jan 1, 2010

By Zhan Jing

Keywords: thermodynamic, Ni-Co alloy powders, composition, fibrous The mathematics model of Ni(II)-Co(II)-C2O42?-NH3?H2O-H2O of thermodynamic equilibrium system has been developed theoretically according to the law of conservation of mass and the law of simultaneous equilibrium, and the logarithm concentration-pH (log[Me2+]T-pH) diagrams of this system have been made. The effect of ligand and pH value was studied. Two issues in coprecipitation route to synthesize fibrous nickel-cobalt alloy precursor powder, com-position and morphology which are a first priority, are addressed based on thermodynamic analysis and experiments. The results show that suitable pH value range of coprecipitation of nickel ions and cobalt ions in theory can be obtained to maintain fibrous, excellent compositonal homogeneity and stoichiometry in coprecipitation products. Experimental demonstration is also carried out.

Jan 1, 2005

By Elli Nurminen

In this work the thermodynamics of the metallic sulphate decomposition reactions were studied through thermodynamical calculations and thermogravimetric methods. The decomposition temperatures and mechanisms were determined for cupric sulphate, ferric sulphate and also for industrial flue dust from a copper flash smelting process. The aim was to determine the thermodynamic conditions for sulphate decomposition and to estimate whether the reactions are kinetically likely to take place in the flash smelting process heat recovery equipment. The information is essential in CFD-modelling of the reactions taking place in the boiler and for optimising the process.

Jan 1, 2006

By Oliver Zach

To know as much as possible about the condition of the refractory material (lining thickness, slag layer, build ups, ...) in an high temperature furnace is very important due to the safety and economic impacts. The new CONSCAN system offers the possibility to measure the inner surface of an furnace, and based on this results to calculate the thickness of the refractory lining, slag layer, build ups,.... The CONSCAN System provides this results as figures and graphics. This system is also working under hot conditions so it is not necessary to cool down the furnace. Based on these results the process control and the refractory lining concept could be optimized for maximum campaign life of the furnace.

Jan 1, 2006

By Jilai Xue

Fe-Ni alloys can be used as raw material in making stainless steel. Laterite nickel ore is one of mineral resources for producing nickel alloys. In this work, the laterite ore after dehydration at 800 °C and the anthracite as reducing agent were mixed for pre-reduction at 900 °C, and then reduced to form Fe-Ni alloys at 1550-1620 °C through carbon-thermal reduction process. A high Ni-content alloy component in the metallurgical mixture can be formed through pre-reduction. Better separation of the resulting metals from the slag is found with lower Ni-content alloys produced or higher temperatures during reduction. An effective processing of Fe-Ni alloys needs further understanding of the process fundamentals and optimizing of the process parameters.

Jan 1, 2010

By Daudi R. Waryoba

Keywords: Wire Drawing, OFHC Copper, Recrystallization, Orientation imaging Microscopy (OIM), Texture inhomogeneity Textural inhomogeneities have been investigated in oxygen free high conducting (OFHC) copper wire drawn at room temperature to a true strain of 2.31, and isothermally annealed at 250°C and 750°C for annealing times ranging from 10 s to 1 hr. Local orientations were mapped by means of orientation imaging microscopy (OIM). The microtexture of the drawn wires showed a strong <111> + weak <100> duplex fiber texture at the inner core, whereas the mid and surface regions had a comparatively weak texture. Annealing at 250°C resulted into a recrystallization which originated from the mid section, proceed towards the surface regions and ends in the inner core. Recrystallization resulted into a strong<100>+weak<111> duplex fiber texture. A similar textural inhomogeneity was observed during short annealing at 750°C. However, prolonged annealing gave rise to abnormal grain-growth that proceed from the inner core to the outer surfaces with a dominant <111> fiber component at the inner region and mixed components of <111>, <100>, and <112> at the outer surfaces.

Jan 1, 2005

By Jian Yang

The mechanism of resulfurization in the desulfurization process with magnesium vapor produced in situ by aluminothermic reduction of magnesium oxide was clarified in the present work. The influences of various operating parameters on the resulfurization were studied and the methods that could prevent resulfurization were proposed. There are two kinds of mechanisms of resulfurization in the desulfurization process with magnesium. One is decomposition of the desulfurization product of MgS under the inert atmosphere. The other is oxidation of MgS under the oxidative atmosphere. Under the present experimental conditions, lowering operating temperature and oxygen partial pressure in the atmosphere could effectively prevent the resulfurization. Adding CaO onto the melt surface was an effective method for preventing the resulfurization due to transformation of the desulfurization product of MgS into the more stable compound of CaS. Since addition of the activated charcoal powders greatly decreased the transfer rate of oxygen in the atmosphere to the melt surface, it also reduced the resulfurization remarkably.

Jan 1, 2006

By R. Shimpo

Equilibrium calculations by a computer may sometimes fail in giving solutions when the system includes a large number of components and more than three phases, and especially when no definite information about stable phases is given. An improved method of calculation is presented in which the number of phases need not to be initially fixed, phases can appear or disappear in the course of&apos; calculation and a new method is combined with the Newton-Raphson method to obtain solutions easily. The improved method is applied to the copper smelting operation and all the successive stages of the operation are successfully simulated.

Jan 1, 1983

By Wenming Wang

Recycling of retired cadmium telluride (CdTe) photovoltaic (PV) modules has attracted attention due to new European environmental regulations. Recycling tellurium from CdTe PV modules is becoming more important because of the low availability of this metal. We investigated several treatment paths for reclaiming tellurium from solutions obtained from leaching fragments of CdTe PV modules. Our experiments showed that conventional soda ash neutralization/hydrolysis methods recovered only 50~60% of tellurium. However, by appropriately combining neutralization and sulfide precipitation, almost all the tellurium present in the leaching solution was precipitated and recovered; the concentration of tellurium in the processed solution was reduced from 900-1000 mg/L to less than 1 mg/L, yielding a tellurium recovery greater than 99%. This method can be incorporated in the scheme of recycling spent CdTe PV modules and manufacturing wastes. It may be also an alternative to the current operations for removing tellurium from copper anode slime leaching solutions.

Jan 1, 2006

By Pengfu Tan

A thermodynamic model has been developed to model the desilverising process of lead by the addition of zinc during lead refining, whereby silver-zinc solid solutions are formed, and floats out of the dissolved zinc/silver in the lead bath. The solubility of silver-zinc solid solutions in lead decreases with falling temperature. A number of variations and modifications of the desilverising process are modeled, and applied to a wide range of silver contents in lead bullions in the industry.

Jan 1, 2005

By Torben Edens

Norddeutsche Affinerie?s (NA?s) primary smelter continually increased production in the past decade. The smelter?s concentrate capacity was expanded from 500,000 in 1993 to 1,000,000 t/a dry concentrate in 2000 and the goal of the present upgrade is 1,150,000 t/a. These goals were reached without erecting new equipment in the anode area, but instead by refitting the existing plant. The life-span extension of the casting moulds was absolutely necessary to increase the casting performance from 260,000 to 450,000 t anodes per year on a single casting wheel. Different mould manufacturing processes and alloys were tested in order to find the optimal mould. In the past the moulds were cast directly, now the anode mould is milled into NA copper cakes. Accompanying measures taken were the shortening of maintenance and repair times as well as improvements in the refining furnace equipment.

Jan 1, 2005

By Yuanbo Zhang

Zinc leach residues produced by hydrometallurgical zinc plants contain many valuable elements (zinc, iron, lead, gallium, indium silver, etc), while they have not been utilized effectively hitherto. In this paper, a new process of flotation-reduction roasting-magnetic separation to recover these valuable elements from zinc leach residues is developed on a basis of mineralogy investigations of them. The results show that silver concentrate with grade of 4321.6 g/t and recovery of 80.69% have been obtained, using 1750 g/t Na2S as conditioner, 750 g/t ammonium dibutyl dithiophosphate and SN-9 (assistant collector) as combined collector and 100 g/t terpenic oil as frother, if zinc leach residues with 523 g/t silver are floated at pH = 5.0. When the flotation tailings are subjected to reduction roasting at 1100? for 2 h, the volatilizations of zinc, lead and indium are over 96%. After roasted products are treated by wet-grinding and magnetic separation, the grade of gallium and gallium in the concentrates achieved respectively reaches 1805 g/t and 1536g/t, and the recovery of them is high to 94.67% and 93.20%, respectively.

Jan 1, 2006

By Pengfu Tan

A thermodynamic model has been developed to predict the distribution behaviors of Cu, Fe, S, O, Pb, Zn, As, and heat balance in a lead blast furnace. The modeling results have been validated by the plant data of a lead smelter in Asia. The model can be used to predict for any set of controllable process parameters such as feed composition, smelting temperature, degree of oxygen enrichment and volume of oxygen-enriched air. The effects of the blast air, industrial oxygen, and coke charge on the distributions of Cu, Fe, S, O, Pb, Zn, As, and heat balance, and on the lead loss in slag have been presented and discussed.

Jan 1, 2005

By Xuan Li

Aluminum slag is generated when aluminum metals are recycled through a smelting process in the presence of salt. There are small amounts of aluminum metals trapped in the aluminum slag. This research aims at evaluating the use of aluminum slag as an expansion agent for the production of lightweight concrete by taking advantage of the residual aluminum metals in the slag. The research identified key elements of producing lightweight concrete products through utilizing various mixture components including sodium hydroxide (NaOH), lime (CaO), cement, and gypsum. The volumetric expansion rate was investigated and the density and strength of the products were determined. The results show that aluminum slag can be utilized for the production of lightweight concrete products.

Jan 1, 2010

By Huang Kai

By adding the solid oxalate acid powder into the solution of nickel chloride or its ammonia coordinated solution, the uniform compound particles were prepared and the precipitated particles were transferred to the mono-dispersed NiO particles by calcination. In this study, the various experimental conditions were investigated, the characteristics of the corresponding obtained particles were analyzed, and the formation mechanism of the particles was elucidated. It was found that the solid oxalate acid provided the solid-solution interface for the precipitation and induced the nucleation and growth of the product particles.

Jan 1, 2005

By Natalya. N. Ankusheva

The problems of ore-bearing palaevolcanic structures in folded belts are actual because of their high productivity in nonferrous, ferrous and noble metals ores. Now relationships of location and conditions of formation for sulfide-massive and gold-bearing deposits are investigated very well in Urals. But carboniferous sulfide-barite mineralization, for example the barite veins in Arcaimsky palaevolcano are?nt studied enough now [3-5]. The purpose of this research is the studying of mineralogy and thermobarogeochemistry of barite from the hydrothermal veins. It will allow to determine the conditions of its formation and to compare it to the similar mineralization of others ore types.

Jan 1, 2006