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By K. G. Lomberg

The density used to covert volume to tons is critical in determining the real in-situ tonnage of Mineral Resources. However, the methods used to determine density and the use of different technical terms are seen to be inconsistent throughout the industry. Probably the best discussion addressing the determination of density was presented by Lipton (2001). This paper does not try to replicate this excellent work, but rather to review current industry practice and present a comparison of the approach to density in public reporting. Some of the technical terms used in reporting and the common methods applied are also discussed.

Sep 1, 2021

By G. R. Addie

The Hydraulic Institute has completed the task of developing a new ANSI/HI standard 12.1-12.6 (2005) for rotodynamic (centrifugal) slurry pumps covering nomenclature, definitions, applications, and operation. The standard provides examples of the different slurry pump types and contains an extensive section on pump and slurry definitions. The effect of slurry on pump performance is covered along with the pumping of froth. Reference is also made to ANSI/HI standard 9.6.7 (2004), which contains a new method for pump performance correction when handling viscous fluids. Classification of slurry services is established and then is used to determine limitations on velocities and total head per pump in order to obtain acceptable wear performance. The new service class, head per stage and other limits are directly related to capital and other cost considerations that will affect solids transport system economics. The writers review the contents of the new standard, highlight the main points, and discuss the reason for the slurry classification, corresponding limits and expected implications, particularly with respect to operating costs of the pumps in solids transport systems.

Jan 1, 2007

The 88th Annual General Meeting of The South African Institute of Mining and Metallurgy was held at Kelvin House, Johannesburg, on Wednesday, 14th August, 1985. Mr J.D. Austin (President) was in the chair and declared the meeting open at 16h00.

Jan 1, 1985

By G. J. C. Young

The new metallurgical plant has a simple, compact layout, being designed for a small team of operators. The reasons for building the new plant are given, and its various sections are briefly described. These include the conveyor plant, milling plant (for run-of-mine milling), thickener plant, agitator plant, filtration, clarification, smelthouse, and central core joining the mill and filtration sections.

Jan 1, 1978

Robert Rampton Porter died on 8th September, 1985, in Salt Lake City, Utah, at the age of 75. Bob Porter was born in Salt Lake City in 1910, and he attended the University of Utah, where he obtained an M.Sc. degree in metallurgy. Galvanizing In conjunction with the National Institute for Materials Research of the CS I R, the South African Hot-Dip Galvanizers' Association has organized the First International Conference on Galvanizing in South Africa. This event will take place at the C SIR Conference Centre in Pretoria from 3rd to 7th November, 1986. Environmental effects of mining A one-day meeting entitled 'The environmental effects of mining and restoration' will be held on 23rd September, 1986, at the University of Manchester Institute of Science and Technology, Manchester, England.

Jan 1, 1986

By B. Besa, S. Nalukui

Globally, the demand for mineral products is ever increasing. Extraction of these mineral resources results in the continuous production of a huge volume of waste material, including tailing dumps. The mass of tailings usually exceeds the actual resource and often contains hazardous contaminants. This study investigated the effects of tailings disposal on soil, water, and air quality in the Nampundwe area. Water, soil, and dust samples were collected from different locations in the surrounding communities. The constituents analysed in the samples included copper, cobalt, iron, sulfate, and silica. According to the results obtained, some seepages occurred from the tailings impoundment to the shallow aquifer in the area. However, the general water quality meets the Zambia Environmental Management Agency (ZEMA) statutory limits. Recorded concentrations of sulfate (1500 mg/l), copper (1.5 mg/l), cobalt (1.0 mg/l), iron (2.0 mg/l), and silica were between 0.003 mg/l and 705 mg/l, which is far below ZEMA’s statutory limit. Silica concentration was also evident in the air. The highest concentration recorded was 260 ppcc (particle per cubic centimeter) recorded in July 2019 from the northern direction of the tailings dam. The concentration was below the statutory limit of 350 ppcc. The topsoil from the northern part of the tailings recorded a silica dust concentration of 39.9 ppcc. Iron was evident in the underground soil with a concentration of 8.01 ppcc, cobalt 0.005 ppcc, copper 0.051 ppcc, while sulfate was recorded as 0.41 ppcc.

Oct 9, 2024

By Y. G. Che, M. Brown, R. L. Gandhi, M. D. Watson

Slurry pipelines have proven to be an economical method of mineral concentrate transport over long distances. Some of these pipelines are internally lined with high-density polyethylene (HDPE) to avoid internal corrosion. HDPE is an inert and extremely smooth material, and it was believed hat scale deposits would not form on it. However, there have been instances of scaling on HDPE lined pipes. Scale problems have also occurred on bare steel pipes. In this paper experience with scale problems in some of these pipelines will be summarized. Alternatives available for control of scale problems will be discussed, and a success story for the control of scale problems in the 300 km long Century zinc and lead slurry pipeline will be presented.

Jan 1, 2007

By B. Geelhoed

A generalization of Gy?s 1979 model for the variance of the fundamental sampling error has been proposed at WCSB2?2005 by Geelhoed. This generalized model can potentially lead to a better correspondence with actual sampling processes. However, a new parameter is required by the new model: ?the parameter for the dependent selection of particles?(Cij). It is important that this new parameter, which is at the basis of the new theory, is well understood in the sampling and blending community. In order to clarify the meaning of Cijand to prevent potential misinterpretation of Cij, we discuss the difference between Cij and an intuitively associated, but different, parameter: ?the parameter for the dependent selection of particle types?(Mij). In this contribution, the theoretical difference between both parameters is clarified. Simulations demonstrate that, numerically, the difference between Cij and Mij can be large. Some additional advantages of the approach which uses Cij are discussed: (i) the approach based on Cijis more general; (ii) in all cases where Mij is known, Cij can be determined as well, while the reverse is not true; (iii) an equation already exists that relates the sample variance to the value of Cij.

Jan 1, 2009

The President: "It gives me great pleasure to call on Professor Howat to present the paper written jointly with P. R. Jochens and C. W. Wolhuter entitled, 'Utilisation of slags for the manufacture of cement.' After the presentation of the paper the President said: "Thank you, Professor Howat, for so ably introducing the paper prepared by yourself, Dr Jochens and Mr Wolhuter. Once again we are deeply indebted to you for bringing to our attention a new development in the metallurgical field, this time a technique for assessing the suitability of slags for the production of slag cement, and thereby providing a means of turning a waste material into a valuable asset. May we hope that this will lead to an end to unsightly slag dumps and, at the same time, to some conservation of our local limestone resources. Discussion within this Institute on the problems of cement manufacture, has of recent years been all too infrequent, and we thank you for bringing this interesting and important subject again to our notice. We are doubly grateful to you and your co-authors. May I now call on Dr Stutterheim, Deputy Director of the Council for Scientific and Industrial Research, to contribute to your paper, and to tell us something about the Conference on the Chemistry of Cement which he attended in Tokyo towards the end of last year." (Applause.) Dr N. Stutterheim, Mr B. F. van der Merwe and Dr F. S. Fulton then contributed to the paper. (These contributions will appear in a later issue of the Journal.) PAPERS OPEN FOR DISCUSSION The President: "Listed on the agenda are papers open for discussion. I would suggest that anyone wishing to contribute to these papars, submit their contributions to the Secretary in writing." CONCLUSION The President: "I would like to thank everybody for their attendance here tonight, and on your behalf I am sure you would like me to thank the authors and the contributors for the most interesting time that we have had this evening. Thank you very much." The meeting closed at 6.00 p.m. NOTICE SYMPOSIUM ON THE RECOVERY OF PYRITE A symposium on the recovery of pyrite will be held on 12th and 13th June, 1969 at Kelvin House, Johannesburg under the auspices of the Institute and the National Institute for Metallurgy. Notices will be sent to members as soon as more details are available as regards the papers and the programme.

By S. M. Graham, G. Mellis

"The determination of the oxidation state(s) of an element present in a solid sample may be required for a number of reasons, including the assessment of the degree of reduction which has taken place during a multi-step production of a metal. In addition, possible flaws in a metal may result from small amounts of oxides included in the solid. The analyte of interest may be present as a major component of a sample of interest, or as a minor impurity - beneficial or requiring removal - in another matrix.Numerous methods have been established for the analysis of species in solution samples - for example, Fe2+ and Fe3+ by titration, Cr6+ by colourimetric means, etc. With appropriate knowledge of the solution being analysed, many of these methods are fairly straightforward, extremely reproducible and accurate. In those instances where the analyte in a solution is known to be in only one form, the analysis is even more straightforward, since it can be achieved instrumentally (by AAS, rCP-OES or rCP-MS, for example).However, the situation with respect to the analysis of solids is not as simple. Various techniques - such as X-ray diffraction - are routinely used by our mineralogists to obtain information about the various minerals present in solid samples, and thus about the oxidation states of the analyte elements present. However, these techniques usually give results that are qualitative, or semi-quantitative at best. They are also usually time-consuming and expensive. One of our colleagues at Mintek, Deshenthree Chetty, has done extensive work in developing a method for the quantification of manganese species in solids using mineralogical methods, and this is no small achievement."

Jan 1, 2014

Book review Burkin, A. R. (ed.) . Leaching and reduction in hydrometallurgy. London, Institution of Mining and Metallurgy, 1975. £10. hydroxide pyritearsenopyrite NIM reports Report no. 845 A n electron-microprobe study of the nickel distribution in a serpentinite from Volspruit, Potgietersrus. (22nd Oct., 1969; re-issued Dec. 1975). Report no. 1546 Pilot-plant smelting campaign on iron ores from Tete. (22nd May, 1973; re-issued Jun. 1976). Report no. 1557 Cost estimates for the production of pig iron in the Tete district of Mocambique. (18th Jun., 1973; re-issued Jun. 1976). Report no. 1600 Dilute-acid leaching of slag from Tete ore. (20th Nov., 1973; re-issued Jun. 1976). Report no. 1602 The roasting of Tete slag for the extraction of vanadium. (20th Nov., 1973; re-issued Jun. 1976). Report no. 1635 Magnetic separation tests on Tete slag and ore. (30th Apr., 1974; re-issued Jun. 1976). Report no. 1671 Pyrometallurgical retreatment of a slag for the recovery of vanadium. (11th Oct., 1974; re-issued Jun. 1976). Report no. 1785 Some thermodynamic aspects of systems relevant to the flotation of sphalerite. Report no. 1808 Spectrophotometric determination (with pyrocatechol violet as chromogenic agent) of aluminium in zirconium metal and in the residue from anodesludges. Report no. 1813 The economic potential of some pegmatites from the Kenhardt area in relation to the trace-element content of their border zones. Report no. 1817 The rapid determination by X -ray-fluorescence spectrometry of tungsten in tungsten ores and concentrates. Report no. 1820 The thermodynamics of the formation of chlorocomplexes of iron (III), cobalt (II), iron (II), manganese (II), and copper (II) in erchlorate medium.

Jan 8, 1976

By S. Potgieter-Vermaak

The main mineral components of the so-called heavy sands (or black sand) are the titanium, zirconium and iron-bearing minerals, rutile, zircon and illmenite, accompanied by various minor and trace amounts of silicates or phosphates, often present together with the rare earth elements. The investigated samples originated from Richards Bay Minerals (RBM) in South Africa, which is jointly owned by BHP Billiton and Rio Tinto, the largest titanium slag producer in the world. The present study focused on the characteristics of samples originating from various points in the separation plant. The heavy-mineral fractions and concentrates of a representative suite of samples were investigated using various analytical techniques to establish the differences in morphological and elemental compositions at the different points in the plant. These techniques included: reflected light microscopy, micro-raman spectrometry (MRS), scanning electron microscopy coupled with energy dispersive X-ray analysis (SEM/EDX) and structural and chemical analyser (SCA). All samples comprised a heterogeneous population of zircon and rutile grains with diverse physico-chemical properties, expressed by large differences in colour and trace element chemistry of single grains. The elemental composition proved the presence of the rare earth elements that appeared to coexist with both Ti and Zr minerals. The percentage of grains hosting inclusions, such as anatase, monazite, quartz, spessartine, augite, epidote and actinolite, varied for each sample and could be uniquely characterized by Raman investigations. Keywords: heavy mineral sands, micro-ram an spectrometry, elemental analysis

Advanced process and equipment analytics have been around for a while. However, with accessible IT infrastructure and site maturity, it is possible to analyse, monitor, and control processing plants and equipment easily. These various disparate systems provide different reports requiring the involvement of various personnel and attention to different reporting platforms. For efficient harnessing of the systems? capabilities, as well as effective improvement and monitoring of process and equipment, a single point of entry is required. A process and equipment optimization solution was required at a concentrator in South Africa, focussing on the product stream of platinum group metal (PGM) concentrate from the UG2 Reef. The investigation of data to identify strategies for optimization was required to allow visibility into plant operations to guide operators, an easier method to identify process loop problems, identification of imminent equipment failures, and advanced process control to optimize throughput and stability. A collaborative effort between the client and General Electric Intelligent Platforms (GEIP) investigated data-driven solutions to each of the problems. With the focus on process optimization and asset monitoring, as well as equipment monitoring, a combination of approaches was utilized to address the various problem areas that were identified. Each was implemented separately in the control layer of the plant IT infrastructure. The integration was done in a centralized web-based reporting tool that integrated the detailed results from the various solutions. On the process control side, monitoring of control loops was included by calculating performance statistics that were reported daily to identify sub-optimally performing control loops and indicating potential problems. The advanced process control solution for this site includes a surge tank controller, stabilizing flow through the flotation banks, and preventing the surge tank from overflowing or running empty. Equipment monitoring was investigated, for preventative maintenance, by making use of statistical data models to indicate imminent equipment failure. These predicted alarm events included the cause for failure, drilling down, and allowing focus on a specific variable for preventative action. The results included a more stable flow through the mill, with fewer stoppages due to surge tank overflows or running empty. The causes for process drift could be identified and operators could react early. Alarms warning of equipment failure 2½ and 4 months in advance were identified in an offline analysis.

Jan 1, 2012

By J. M. Musadaidzwa

Skorpion Zinc is located 25 km north-west of the small settlement of Rosh Pinah in southern Namibia. Commissioned in early 2003, Skorpion Zinc became the first mine-to-metal operation to commercially apply a purely hydrometallurgical process route to exploit a zinc oxide orebody. The novel technology, known as The Modified ZincexTM Process patented by Tecnicas Reunidas, comprises sulphuric acid atmospheric leaching, zinc solvent extraction (SX) and electrowinning (EW) to produce London metal exchange (LME) Special high grade (SHG) zinc. Forming the core of the process, the SX step has thrived in its role as a barrier to impurities and also in the upgrading of the pregnant liquor solution (PLS), converting it into a loaded electrolyte (LE) sufficiently rich and pure for EW. Against this successful run, a number of challenges have, however, been encountered in SX due the emergence of upset conditions largely emanating from upstream processes. This paper outlines some of the major deviations that have beset the SX process in its first five years of continuous operation. Impurity excursions, temperature depressions, changes in phase continuity, excess aqueous entrainment, the effect of colloidal silica and the accumulation of rare earth elements on the organic phase will be discussed in detail. Keywords: skorpion zinc, solvent extraction, the Modified ZincexTM Process (MZP) DE2HPA, aqueous entrainment (AE), loaded electrolyte (LE), standard liquid validation (SLV) test, organic continuity, aqueous continuity (AC), electrowinning, colloidal silica, phase disengagement time (PDT), rare earth elements (REE).

Jan 1, 2009

By C. L. Workmann Davies

Underground transport and communication in collieries was the theme selected for the 1983 mining school conducted by The South African Institute of Mining and Metallurgy. The response from the industry was so good that three separate schools of one week each were arranged, and a total of 222 delegates attended. Development of Mineral Resources The Institution of Mining and Metallurgy and The Department of Mineral Resources, Government of Thailand, with the cooperation of the Thai Mining Association and Chulalongkorn University, is to hold an international conference entitled 'Role of Government in Mineral Resources Development' in Bangkok from 5th to 8th Decembc -:" 1983. Electronics in Mining A symposium entitled 'Electronics in Mining', organized by The South African Institute of ElectriealEngineers, is to be held in Randburg, South Africa, from 18th to 20th September, 1984.

Jan 1, 1983

COUNCIL The following served on Council during the year under review: Office bearers: Messrs V. C. Robinson (President), Prof D. D. Howat and Dr J. P. Hugo (Vice-Presidents), J. K. E. Douglas (Immediate Past President) and D. G. Maxwell (Honorary Treasurer). Ordinary Members of Council: Dr M. G. Atmore, Dr J. M. Bereza, H. P. Carlisle, W. W. Malan, C. E. Mavrocordatos, Prof R. P. Plewman, Dr R. E. Robinson, Dr M. D. G. Salamon, P. W. J. van Rensburg, L. W. P. van den Bosch, P. A. von Wielligh. Branch Chairmen: J. Meintjes, J. M. Meyer (Acting), J. N. Saunders (Retired). Past Presidents serving on Council: R. J. Adamson, M. Barcza, H. Britten, R. C. J. Goode, P. Lambooy, Prof J. de V. Lambrechts, Dr J. T. Mclntyre, J. F. Reid, H. Simon. Ten Council meetings were held during the year with an average attendance of eighteen and the standing committees held forty-six meetings. FINANCE The annual accounts, which are attached to this report, show an excess of income over expenditure of R5 051 compared with an excess of expenditure over income last year of R4 608. This major reversal of fortunes is due in the first instance, of course, to the increased subscriptions. There were, however, other important contributors, particularly sales of the Proceedings of the Symposium on Open Pit Mining and profits on the operation of symposia and colloquia. It would appear from a study of the accounts that there has been a substantial drop in expenditure on secretarial fees. In actual fact, however, our total expenditure on secretarial fees was higher. A portion of this expenditure was charged against the administration of the Symposium on Open Pit Mining and, in addition, the charge against the Journal accounts for secretarial fees was increased. It will be recalled that in last year's annual report it was mentioned that subsequent to the new arrangement for publication of the Journal, the expected improvement in the finances of the Journal had been slow in materialising. After a total period of 18 months there was still no sign of improvement and it was accordingly decided to end the arrangement. As a result, the drain on the finances of the Institute was considerably lessened in the second half of the year. During the course of the year Council became concerned about the rapid depletion of our accumulated funds and gave careful and detailed attention to all aspects of the Institute's financial affairs. Particular attention was given to: 1. The fact that the Institute does not have a solid financial backing and must appeal for funds every time any special event such as a symposium is held. 2. The responsibilities of the Institute to the profession and the community, with particular reference to the desirability of establishing Institute bursaries and participating in other educational activities. 3. The rapidly rising cost of living. 4. The immediate financial position of the Institute. 5. The rapidly increasing cost of publishing the Journal due to the increasing number of papers available. In the meantime the immediate financial position of the Institute has improved but as this is due largely to non-recurring or irregular items of revenue, it should not be given undue weight. After careful consideration it was decided that an appeal should be made to industry for financial assistance, which would be used to cover the cost of symposia and other unusual expenditure and also, if possible, to build up the capital resources of the Institute so that there is a solid foundation for the future. Before appealing to industry, Council wished to be quite certain that there could be no criticism of the Institute for not having done our best in a personal capacity. Furthermore, Council examined many comparative statistics, including those circulated to members, which showed that, while expenditure per member has risen at an average annual rate of 7,5% over the last fifteen years, subscription revenue per member has risen at only 3,4% per annum. It was with this background that your Council decided to raise the subscriptions. Initial approaches have been made to the big mining groups and there has been a very generous response, although the details of how financial assistance will be provided have not yet been worked out. It seems likely that some form of affiliated company membership will be the most suitable method of achieving this. When these details have been fixed, it is the intention to extend the appeal to all corners of the mining industry as well as manufacturing and metallurgical industries. It is believed that these measures will ensure that the finances of the Institute are placed on a firm foundation on which the expanding activities can be planned. The MacArthur Forrest Memorial Fund shows an excess of income over expenditure of R73 and the total fund was, therefore, increased by this amount to R4 411. The balance sheet shows that the market value of quoted shares and debentures increased during the year fron R6 540 to R9 160. The market value is now almost exactly the same as the book value. Accumulated funds now amount to R23 010 compared with R17 959 a year ago.

By D. Limpitlaw

Industrial mining in Zambia started in the 1930s when the world class copper deposits near the border with Katanga were developed. The discovery of these deposits began at the turn of the century when the first claims in the Copperbelt were pegged at Chambishi, north of what became the town of Kitwe1. World War I and the difficulties of raising sufficient capital for such large scale undertakings delayed the exploitation of these deposits. Following this hesitant start, a large copper mining complex was built, resulting in the development of five major towns, all highly dependent on the mining and beneficiation of copper and cobalt. Copper became so important to the country that, on independence, the only non-mining town to make it onto a list of the top six was the capital, Lusaka. From commissioning of the mines to the end of the colonial period in 1964, copper production increased to just over 640 000 t annually2 (see Figure 1). After the establishment of the new Zambian state, production continued to increase, supported by a benign legislative environment and strong international copper prices. The government of Kenneth Kaunda was intent on improving the conditions of the rural poor and reducing unemployment in urban areas. To this end, the government embarked on an ambitious project of refocusing Zambia's economy away from the colonial role of commodity supply to one of decentralized mass employment. The Copperbelt industrial complex was key to the success of this approach, and in 1969 the Zambian State acquired a 51 per cent stake in Zambia's two main copper producing companies: Roan Selection Trust and Rhodesian Anglo American Corporation. The former became Roan Consolidated Mines Ltd (RCM) and the latter became Nchanga Consolidated Copper Mines Ltd (NCCM). In the year they were nationalized, the mines produced at least 720 000 t of copper? and employed approximately 48,000 workers (see Figure 2)2-4. The subsequent economic policies of the Zambian Government depended heavily on the state's ability to monopolize the proceeds of copper mining.

Jan 1, 2011

"Chairman: Professor J. de V. Lambrechts Rapporteur: Mr R. HempPapers:Computer-aided design of a flash smelting installation by M. A. T. Cocquerel, R. T. Gates and L. A. GreenPlanning of mine ventilation by E. U. Reuther and A. DohrnenCoal mine ventilation systems in the U.S.A. by R. Stefanko and R. V. Ramani Heat flow models in ventilation planning by A. J. Dickson and A. M. StarfieldThe first of the papers in the session dealt with a flash smelter installation, while the remaining three papers dealt with mine ventilation. In view of this the Chairman proposed that the paper on flash smelting be introduced and discussed first, after which the remaining three papers would be introduced followed by discussion on all three.Dr Cocquerel, who presented the first paper, used some typical flow diagrams to illustrate the process and stated that the program considered only steady-state operations and did not take into account the dynamical changes. Subjective judgment was necessary for the preparation of input data and some degree of user appreciation was required.Dr Cocquerel said that no work bad yet been done on an optimization program, but that this was being considered. Such a program would require a large amount of physical and chemical data which were not yet available. The variables to be optimized were the energy and material consumptions and the loss of metal in the slag.The Chairman opened the discussion by asking Dr Cocquerel if he could give a brief description of the flash smelting process for the benefit of those not familiar with the subject. Dr Coquerel replied that in the Outokumpu process con¬centrates were injected directly into the furnace, and that the process was somewhat analogous to flash distillation or evaporation processes, but was perhaps closer to the burning of pulverized fuel.The process had two distinct advantages. First, the heat evolved in the smelting reaction was used to heat the furnace, which resulted in less fuel consumption, and, second, the effluent gases were cheaper to treat than the effluent gases from other pyrometallurgical processes. This was important particularly in view of the current interest in pollution problems.Mr P. Marais thought that the authors had done themselves an injustice by not including details of the very complex processes taking place in the furnace."

Jan 1, 2014

By S. M. Spottiswoode

A simple method for the application of excess shear stress (ESS) analysis to the mining of planar reefs is examined. The potential for seismicity associated with mining is expressed as the calculated increase in ESS on a regular grid of points 50 m above the reef, and is compared with observed seismicity around a deep-level, relatively geologicaly-undisturbed gold mine. Thirty regions were studied, involving over 2000 seismic events with magnitudes greater than 1,5 on the Richter scale and associated with almost 2 million square metres of stoping. The total seismicity, measured either as the number of seismic events or as the total radiated energy, corelated more closely with changes in ESS than with ERR. The incidence of rockbursts also favoured the ESS model. Corelation coeficients of around 0,8 for seismicity and ESS indicated that the assumptions inherent in the method used are collectively reasonable. The total seismicity in each region was found not to be strongly controlled by the presence of dykes and faults, although numerous individual seismic events were located close to such features.

Jan 1, 1988

By J. A. Venter, M. K. G. Vermaak, J. G. Bruwer

Electrostatic separation is employed in the concentration of zircon and rutile. The zircon concentrate undergoes an acid treatment to remove impurities from the surface of both the zircon and rutile. The purpose of the acid treatment is to increase the difference in the resistivities of the two minerals, thus ensuring the best possible electrostatic separation efficiencies. Previous test work suggested that these impurities are not removed, but only modified; the surface modification seemed more prevalent in the case of the rutile. The resistivity of the rutile changes with pH and thus the electrostatic separation of the rutile is influenced. X-ray photoelectron spectroscopy (XPS) indicates that there is an increase in the OH and adsorbed H2O concentrations on the rutile surface. XPS also showed significant differential charging on the rutile surface, which indicates that the species on the rutile surface have different resistivities. The zircon particles from the conducting and non-conducting streams have similar resistivities and no major differences in their surface species. Zircon losses during the final electrostatic separation appear not to be due to surface effects, but due to shielding of particles during the separation.

Jan 1, 2007