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By J. C. Edwards

Fire experiments were conducted in the Safety Research Coal Mine (SRCM) at the National Institute for Occupational Safety and Health, Pittsburgh Research Laboratory, with coal, diesel-fuel, electrical-cable, conveyor-belt, and metal-cutting fire sources to determine the response of fire sensors to products-of-combustion (POC). Metal oxide semiconductor (MOS) and smoke fire sensors demonstrated an earlier fire detection capability than a CO sensor. This capability was of particular significance for a conveyor-belt fire in which the optical visibility was reduced to 1.52 m with an increase in CO of less than 2 ppm at a distance of 148 m from the fire. Application of a neural-network program to the sensor responses from each type of fire source resulted in correct classifications of coal, diesel-fuel, cable, belt, and metal-cutting combustion with a mean of 96% of the test data correctly classified.

Jan 1, 2000

By T. Estelle Gardner

The Bureau of Mines made enthalpy measurements on sodium bromide and sodium iodide in the temperature range 400° to 1,200° K using an ice calorimeter. Equations representing enthalpy as a function of temperature were derived from the data by the method of least squares. These equations were used to calculate smooth values of heat capacity, enthalpy, and entropy at 50° K intervals from the ice point to 1,200° K. The melting point determined for sodium bromide was 1,020° K; the melting point of sodium iodide was 934° K. The heats of fusion of sodium bromide and sodium iodide were calculated to be 6,270 and 5,680 cal/mole, respectively.

Jan 1, 1967

By H. A. Doerner

The Rare and Precious Metals Station of the U. S. Bureau of Mines has investigated several cases in which widely divergent amounts of molybdenum were reported by a number of custom laboratories to which quartered portions of the same sample had been sent for analysis . On an oxidized lead ore containing considerable vanadium and a little molybdenum , the amount of the latter reported ranged from 3.14 to 0.24 per cent M003 . The high results were due to the fact that vanadium was estimated with , and reported as , molybdenum . When analyzed by the method described in this paper , 0.15 per cent Moog was found, which is a fair agreement with the lowest figure previously reported . In another and more unusual example , a fine- grained rock containing considerable graphite was submitted for analysis . As a white residue could not be obtained by treating this material with acid , several chemists decomposed the ore by a prolonged fusion with soda ash and nitre and leached the melt with hot water in crder to insure the dissolution of any and all the molybdenum present . After precipitating and filtering the silica from the solution , acetic acid , ammonium acetate , and lead acetate were added to precipitate lead molybdate . The solution contained phosphorous derived from the ore , which precipitated as lead phosphate . The latter was mistaken for , and reported as , molybdenum. As two different chemists used essentially the same procedure , their results , although incorrect , checked . Other chemists using different methods found no molybdenum . From these and other instances it is evident that reputable and conscientious assayers may make serious errors in determining molybdenum, and even duplication of results by different chemists does not necessarily insure against error . The elements most likely to cause trouble are vanadium, tungsten, uranium , arsenic , antimony , titanium, tin , phosphorous , and chromium . The precautions necessary to eliminate these and other impurities vary with the type of ore and the method of analysis . Most texts present methods of limited application and omit or fail to emphasize adequately such precautions . No one method can be given that will best fit every case , but the following procedure has been selected as being the simplest reliable method for such occasional determinations of molybdenum in an ore as are encountered in customs work.

Sep 1, 1930

By L. C. IlsLey

A preliminary investigation has recently been made by the U. S. Bureau of Mines to determine whether or not the ordinary mine- type telephone is entirely safe in gaseous atmospheres . Two well known makes of mine- type phones were purchased for this investigation . It is not conceivable that the current necessary for talking over telephones could ignite gas . However , such phones are provided with efficient magnetos , and it was believed that danger might result from the ringing of the magneto . Again , while this type of phone has been designed to have a certain measure of dust and moisture tightness , evidently it has not been designed as an explosion- proof device . either with regard to cover joints and fastenings or strength of castings . Therefore , the problem was simplified . First it was assumed that owing to the construction of the telephones the gas would penetrate into their interior , and the question was to ascertain whether or not the gas would be ignited from the operation of the magneto .

Jan 1, 1922

By G. Molinda, D. Dolinar

Each year, about 2,000 falls of supported roof occur in the more than 800 underground U.S. coal mines. Therefore to help improve the design of primary support systems, the National Institute for Occupational Safety and Health (NIOSH) conducted a nationwide study of roof falls in over 2,500 km of roadways at 37 coal mines. Information on the roof falls as well as other geotechnical, mining, geologic and roof bolting factors were collected and quantified Then a multi variate statistical analysis was conducted on the data with the roof fall rate being the outcome variable The results were used to derive preliminary design guidelines for predicting the roof bolt length, capacity, and pattern required to effectively reduce the roof fall rate. The equations are fairly limited by a relatively high statistical variance in the data. Also reported is a recent survey of U.S roof bolt manufacturers that shows a significant change in bolt types used over the last ten years.

By E. O. Binyon

The Blue Metal corundum-andalusite deposit, in the Buckskin Mining district, Douglas County, Nev., was explored by the Bureau of Mines in 1945. The results of that work were presented in Report of Investigations 3895, exploration of the Blue Metal Corundum Property, Douglas County, Nev. published in August 1946. That report also describes the property in detail, giving location, ownership, history, geology, and data on beneficiation tests. Further exploration was carried on in April and Way 1947, the results of which are presented in this report. The work consisted of 175 feet of drift and crosscut, bringing the total to 398 feet of underground working, as shown in figures 1 and 2. The 23-foot drift, which was the last work of the initial project, was extended 99 feet northward along the shear zone, and three crosscuts, spaced at approximately equal intervals along the drift, were driven to country rock on the hanging and foot walls of the zone.

Jan 1, 1948

By H. H. Storch

Methane is the chief constituent of natural gas, and large quantities of it are also obtained in coke-oven gas and in the off-gases from cracking higher hydrocarbons. Perhaps the most important potential chemical use of methane is in the production of higher hydro- carbons, both aliphatic and aromatic. The results of a relatively large number of researches have been published in the technical and patent literature on the thermal decomposition of methane, the objective being an industrial process for the production of "antiknock" motor fuel. No industrially feasible process has, however, been developed. An inspection of the literature on this subject indicates that the chief difficulty in the way of accomplishing this object lies in controlling the decomposition so that undesirable products are eliminated. A considerable number of quantitative experiments have been reported, the results of which provide only a vague and confusing picture of the various steps in the thermal decomposition of methane. The reaction mechanism has not been subjected to rigorous fundamental study, and the necessity for such a study is obvious if further progress is to be made. The thermal decomposition is only one of the reactions of methane which are of potential industrial importance and which require further fundamental investigation. The oxidation, hydrolysis, and halogenation of methane are other reactions which must be studied further. In view of the importance of methane as a raw material for various industrially desirable products, it is appropriate that a survey be made of the important facts concerning the physical and chemical properties of methane which will serve as an aid in subsequent experi- mental work. No attempt will be made to present a complete chronological review, but rather a condensed critical description of the important literature will be presented.

Jan 1, 1932

By Tye J. Lasich

This project involved modeling rock masses with varying Rock Mass Rating (RMR) values to determine the degree of instability that develops around an underground opening as a function of RMR. The modeling was performed using Itasca?s UDEC distinct element software, which allows explicit modeling of blocks of rock and how they interact with each other. The analyses included three different orientations of the joint sets, four different joint spacings and three different values of joint strength, which combine for a total of 36 different combinations of model parameters. Two different modes of behavior were observed: local failure of area immediately surrounding the roof and sides of the opening, and deep-seated failure extending a large distance beyond the opening. Quantification of the size of the unstable area that developed provides numerical validation of empirical guidelines used in design of ground support and instrumented monitoring systems.

Jan 1, 2005

By John A. Johnson

"INTRODUCTION The use of wet drilling with adequate ventilation has largely controlled production of dust in drilling rock; however, in some operations, such as shaft sinking and modern tunnel driving, when each of a number of drills is operating in a small cross-sectional area, it is at times difficult to ventilate well enough to keep the dust concentration within desired limits.Some chemical compounds, known as wetting agents, when added to water in small quantities reduce the interfacial tension and make it possible for the solution to wet dust particles more effectively than water alone.This report presents results of tests on the effectiveness of two wetting solutions in reducing the amount of dust produced by wet drilling in basalt.ACKNOWLEDGMENTSThe tests were conducted at the Bureau's Mount Weather Testing Adit, Mount Weathe, Va. The author acknowledges the assistance and cooperation of Wing G. Agnew, superintendent; Marvin M. Reveille, mining-ngineering aide; and the rest of the crew at Mount Weather in conducting the tests. C. W. Owings, mining engineer, Safety Division, assisted in conducting some of the first tests and gave valuable advice and guidance throughout the work and in preparing this report."

Jan 1, 1943

By Michael J. Sapko, Gregory M. Green, Harry C. Verakis, Kenneth L. Cashdollar

The National Institute for Occupational Safety and Health (NIOSH) and the Mine Safety and Health Administration (MSHA) conducted a joint survey to determine the range of coal particle sizes found in dust samples collected from intake airways of U.S. coal mines. The last comprehensive survey of this type was performed in the 1920’s. The size of the coal dust is relevant to the amount of rock dust required to inert the coal dust, with more rock dust needed to inert finer sizes of coal dust. Dust samples were collected by MSHA inspectors from several mines in each of MSHA’s ten bituminous Coal Mine Health and Safety Districts. Samples were normally collected in several intakes at each mine. The laboratory analysis procedures included acid leaching of the sample to remove the limestone rock dust, sonic sieving to determine the dust size, and low temperature ashing of the sieved fractions to correct for any remaining incombustible matter. The results indicate that particle sizes of mine coal dust in intake airways are finer than those measured in the 1920’s. The significance of these finer coal dust sizes is discussed relevant to the amount of rock dust required to prevent coal dust explosions.

By Bruce K. Cantrell, Stephen W. Stein, David Hassel, Harvey Patashnick

The Mine Safety and Health Administration. Department of Labor, requires coal mine operators to measure compliance with federal re¬spirable dust exposure standards periodically using approved gravi¬metric samplers. However, the gravimetric approach, with its inher¬ent delays, cannot provide dust concentration data quickly enough to allow on-site correction of inadequate dust control strategies or re¬moval of personnel from harmful environments. Furthermore, alleged tampering with dust samples collected to determine compliance with standards prompted the Secretary of Labor to appoint a special Respirable Dust Task Group to study options to improve monitoring and control of respirable coal mine dust. The Mine Safety and Health Administration's Task Group recommended that the U.S. Bureau of Mines develop a fixed-site monitor that would provide continuous information to the mine worker and mine operator regarding dust levels and the status of compliance with the applicable respirable dust standard. In response to the Mine Safety and Health Administration's request, the U.S. Bureau of Mines is investigating several sensor tech¬nologies for continuously monitoring respirable coal mine dust. One of these technologies is the Rupprecht and Patashnick Co. tapered element, oscillating microbalance. The bureau is in the process of investigating the suitability of using this sensor in the high humidity and vibration environment of underground coal mines. Laboratory tests have indicated that, with modification, the sensor can meet the humidity and vibration requirements for underground coal mine use. Currently, the bureau is developing

By J. A. Holmes

As part of its investigation of methods of increasing the efficiency of fuel resources, the Bureau of Mines is continuing the study of the general problems involved in the economic use of fuels in gas pro- ducers that were carried on by the technologic branch of the United States Geological Survey. In the course of this study many inci- dental problems of prime importance have demanded consideration. Among them is the determination, under practically constant con- ditions, of the duration of gas-producer tests necessary to reduce the possible error to a minimum. A discussion of this proper length of test period forms the first part of this bulletin. An attempt to dispel some of the uncertainties that arise in an investigation or to account for some of the minor phenomena often necessitates a systematic and careful study of certain chemical, ther- modynamic, or physical laws, or a combination of these, which in turn may result in information or conclusions of great value. Fur- thermore, seemingly unimportant observations often prove to bear directly upon the design, construction, or manipulation of the machine under test. In attempts to improve the gas producer considerable attention has been given by manufacturers to such questions as fixing or isolating the combustible components of the tar, utilizing the waste heat of the producer for the generation of the steam required by the plant, apply- ing the suction principle to bituminous coal and other tarry fuels, and many allied subjects. Little study, apparently, has been given to the physical-chemical conditions most suitable to the formation of hydro- gen and of carbon monoxide, with a view to regulating the percentages of these gases in generators using fuels other than anthracite coal or charcoal. An attempt was made to introduce such investigations when the operations of the government coal-testing plant began at the Louisi- ana Purchase Exposition in St. Louis in 1904, but owing to adverse conditions these problems were abandoned until the plant was trans- ferred to Norfolk in 1907. The delay in beginning this line of inves- tigations, together with the short testing season at Norfolk, limit the second part of this report to preliminary physical-chemical studies, which, however, were sufficiently significant to warrant careful ex- amination pending more complete researches, which are being carried on at the station located in Pittsburg.

Jan 1, 1911

This is the final report on Project CR-102 under the auspices of the Department of Environmental Resources, Commonwealth of Pennsylvania .1 The project was activated on January 5, 1970, with financial support from Bituminous Coal Research, Inc., the Pennsylvania Coal Research Board, and the Water Quality Office of the Environmental Protection Agency (WQO-EPA)2 through Grant 14010 EST to the Commonwealth of Pennsylvania Work on the project was conducted according to the procedures outlined in BCR Research Program Proposal RPP-164R, dated April 24, 1969, and a subsequent Revulsion of Scope, dated February 25, 1970. This report covers the entire project period from January 5, 1970, through March 25, 1971.

Jan 1, 1971

Miners, like everyone else, must be able to see well in order to work well. But simply hauling bigger and brighter lights into the mines does not necessarily produce better mine illumination. This chapter tells why. Increasing the power of the light source can create problems of portability, glare, adaptation and contrast. This chapter also discusses some ways to increase illumination by Improving the reflectability of walls, roofs and other exposed surfaces. In Chapter IV you learned that the "brightness" of a room or work area was really a matter of how much light was reflected from the walls, roof, and other surfaces. Therefore, if you want to Improve visibility you should increase the amount of reflected illumination. O HOW DOES ONE DO THAT? One way of Increasing reflected illumination would be to increase the power of the light source.

Jan 1, 1976

By R. N. Roby

"INTRODUCTION A preliminary examination of the Green Monster and Benich copper prospects was made by engineers E. W. Newnan and George N. Bennett, of the Bureau of Mines, on December 13, 1943. In an unpublished report, it was stated that certain geologic features appeared to be similar to those associated with the copper deposits of the nearby Butte district. On these premises, a preliminary diamond-drilling program was recommended to explore 300 to 400 feet below the mineralized outcrops for the possible presence of a sulfide enrichment zone. In accordance with that recommendation, three holes were drilled. This report presents the data provided by that preliminary drilling exploration.ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell D. Moon, chief, conducts preliminary exminations, perform the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocker, chief, analyses samples and performs beneficiation tests.The field work on the Bull Run exploration project was supervised byE. W. Newman engineer in charge of the Helena field office. The chemical analyses and assays included in this report were performed under the direction of A. C. Rice, acting engineer in charge, Bureau of Minos Rare and Precious Metals Experiment Station at Reno, Nev. The diamond-drill cores were logged by geologists of the Federal Geological Survey."

Mar 1, 1947

By VAN. H. MANNING

During the nine years that have elapsed since the Bureau of Mines was established in 1910, the work of the bureau has included many investigations that have proved of high value to the Nation. Eleven mining experiment stations established by act of Congress have greatly increased the bureau's usefulness; being situated in the mining fields, these stations are closely in touch with industrial needs, and the results of their research and educational work are more directly available to those engaged in the mining, metallurgical, and mineral industries. In the United States mining is second in importance to agriculture only. The Federal Government annually appropriates large sums in the interest of agriculture, whereas the appropriations for mining are relatively small. But the nation-wide popularity of Government assistance to agriculture should not overshadow the need of Federal assistance to the mineral industry. With scientific management farms can be made to produce indefinitely without any depletion of the potential resources of the soil, but the mineral wealth of a country is a fixed quantity, and every year's production brings nearer its ulti- mate exhaustion. As the deposits of the richer or more readily available ores, espe- cially those in the West, have been depleted, development of methods for mining and treating the leaner or more inaccessible ores has lagged, so that meeting the increasing demands for certain metals is becoming more and more difficult. In some branches of mining the small inde- pendent operator is greatly handicapped. He has to rely on custom mills and smelters for the profit or loss of his product, and because of relatively inefficient methods of milling or smelting he may receive no return for much of the ore he mines. Even though the small operator thinks he knows of improved methods of obtaining the metals from the ores, he can not afford to install the necessary machinery or to carry on experiments that may or may not prove successful. In view of the increasing need of metals and the impossibility of renewing the ore supplies, efforts should be directed toward developing the most economical and efficient methods in mining and metal- lurgy. The great mining companies carry on independent research work, some of them on a large scale; but as such work is usually undertaken for gainful purposes, these companies do not feel under any obligation to give the results of their investigations to the world. Clearly the solution of the difficulty is to place in the mining districts trained mining and metallurgical engineers who will investigate and solve the problems for the benefit of the whole industry. It is with this purpose in view that experiment stations of the Bureau of Mines have been established to investigate economy, efficiency, and safety in mining, and to make public the results of the investigations. The Federal Government can be of most help in developing the mineral resources of the country when its forces are brought in direct contact with these resources. Mining is as old as civilization, but only within a generation has this country busied itself with any other problem of mining than the amount of mineral products that could be put upon the market. Little concern was felt if much of the metal in an ore was wasted, if the miner lived in unsanitary surround- ings and died of preventable disease, or if accidents occurred fre- quently and from causes that could easily be controlled. Now we realize that the waste of any resource is inexcusable. The mineral wealth of the country can be mined but once. The task before the Nation is to recover as much metal as possible from the ore in the ground, and to do this in the most economical way without waste of human life. This task is of such magnitude as to warrant aid from the Government through experiment stations. In its efforts to make the work of these stations of most benefit to the mineral industry the Bureau of Mines seeks the cooperation of State authorities, of mine operators, of miners' organizations, and of every person interested. These experiment stations also serve an educational purpose. Gen- erally speaking, mining is not a preferred occupation. The miner should have reason to take greater interest in his work; he should feel that the experiments the Government is making affect him vitally by enabling him to increase his production and by making his work safer. The mine operator should realize that the Government stands ready to aid him, and he should know that he can bring his own problems to a Government organization that is trained and equipped to solve them. The surest method of accomplishing these results is to carry the work of the Bureau of Mines into the mining regions through the establishment of experiment stations easily accessible both to the mine operator and to the miner. Many miners in this country do not read English, but they can understand motion pictures of mining methods; they can learn how lives can be saved in case of accident; and they can appreciate the larger results gained by modern methods and equipment. In every

Jan 1, 1919

1. In 2002, a total of 2,065 coal mining operations reported employment to the Mine Safety and Health Administration (MSHA). Coal mines comprised 14.2% of all mining operations. • Bituminous mines comprised 92.5% (n = 1,910) and anthracite mines 7.5% (n = 155) of coal mining operations. • More than 70% of all coal mines were located in three states: Kentucky (28.7%), West Virginia (21.7%), and Pennsylvania (20.1%).

Jan 1, 2004

By L. C. Ilaley

The Buresa. ot Mines at its Pittsburgh Station conducted tests aa earl7 a.a 1911 looking into the satety of miniature electric bulba. The first teata were maie with bulbs euch as were being sold with the partly developed lamps then on the market. 'l'he.sa aarly teats demonstrated the da.nger of using minia.tu:re bulbs in explosive mine atmospheres unless the current that enet gized the glow!ng filament was in aome minner inter.N.ptecl if the glass surrounding the filanant should be broken.

Jun 1, 1922

By C. P. Bowie

During the period of 10 years from January 1, 1908, to January 1, 1918, approximately 12,850,000 barrels of oil and 5,024,506,000 cubic feet of gas were destroyed by fire in the United States, entailing a total estimated property loss of $25,254,200. During this period 503 fires were reported. As is shown in Plates I and II, 310 of these fires were caused by lightning and 193 by all other causes. The losses from the fires caused by lightning were estimated to be $11, 148,000, and from those due to all other causes $14,106,200. Directly and indirectly, the fires resulted in the deaths of nearly 150 persons and were responsible for almost as many more being permanently disabled. For the past three years the Bureau of Mines has been conducting investigations to determine the nature and the specific causes of these fires, with a view to suggesting means whereby they may be suc- cessfully combatted and, in some places, perhaps eliminated entirely. As the subject of oil and gas fires is necessarily broad, no attempt is made in this bulletin to treat it exhaustively; rather the bulletin aims to point out what has been done by operators in the past, and to describe various fire-prevention methods and fire-fighting appa- ratus which are being used or adopted by many of the larger oil companies. These methods and apparatus, it is believed, if uni- versally employed by operators, will largely decrease the present enormous annual losses. In the discussion of oil-well fires, the methods used in extinguishing several of the larger and more perplexing ones are described. As the right procedure for extinguishing any oil-well fire must be de- termined largely by local conditions, it is not probable that all of the methods used at some one fire, as described, will be applicable to a future fire. However, the operator, from these descriptions, may at least gain suggestions that will greatly assist him in fighting similar fires.

Jan 1, 1919

By Ron Merkel, A. Mayton

Operators of underground mobile equipment, particularly shuttle cars, are often exposed to significant levels of whole-body vibration (WBV) and shock. The human factors group at the NIOSH-Pittsburg Research Center has investigated the use of viscoelastic foam to reduce shock for the equipment operator and improve seats on mine shuttle cars.