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By Martin Harper

This paper concludes a five year program on research into the use of a portable X ray fluorescence (XRF) analyzer for analyzing lead in air sampling filters from different industrial environments, including mining, manufacturing and recycling. The results from four of these environments have already been reported. The results from two additional metal processes are presented here. At both of these sites, lead was a minor component of the total airborne metals and interferences from other elements were minimal. Nevertheless, only results from the three sites where lead was the most abundant metal were used in the overall calculation of method accuracy. The XRF analyzer was used to interrogate the filters, which were then subjected to acid digestion and analysis by inductively coupled plasma optical emission spectroscopy (ICP OES). The filter samples were collected using different filter holders or "samplers" where the size (diameter), depth and homogeneity of aerosol deposit varied from sampler to sampler. The aerosol collection efficiencies of the samplers were expected to differ, especially for larger particles. The distribution of particles once having entered the sampler was also expected to differ between samplers. Samplers were paired to allow the between sampler variability to be addressed, and, in some cases, internal sampler wall deposits were evaluated and compared to the filter catch. It was found, rather surprisingly, that analysis of the filter deposits (by ICP OES) of all the samplers gave equivalent results. It was also found that deposits on some of the sampler walls, which in some protocols are considered part of the sample, could be significant in comparison to the filter deposit. If it is concluded that wall deposits should be analyzed, then XRF analysis of the filter can only give a minimum estimate of the concentration. Techniques for the statistical analysis of field data were also developed as part of this program and have been reported elsewhere. The results, based on data from the three workplaces where lead was the major element present in the samples, are summarized here. A limit of detection and a limit of quantitation are provided. Analysis of some samples using a second analyzer with a different X ray source technology indicated reasonable agreement for some metals (but this was not evaluated for lead). Provided it is only necessary to analyze the filters, most personal samplers will provide acceptable results when used with portable XRF analysis for lead around applicable limit values.

Jan 1, 2007

By Samuel W. McNary

In August 1984 the U.S. Bureau of Mines conducted a study of the mineral resource development potential of the Badger Canyon-Antelope Creek area, within the Boulder-Pioneer wilderness study area, about 5 miles northeast of Ketchum, 10. The purpose of this study was to investigate in greater detail an area which was designated by the U.S. Geological Survey (USGS) and the Bureau as having a moderate mineral resource potential for zinc, molybdenum, lead, and silver, and a low potential for copper. One hundred twenty-eight soil samples were taken along a 6,2S0-ft traverse on the ridge separating Badger Canyon and Antelope Creek. 5 Five rock samples were collected from old prospect pits and mineralized outcrops. All samples were analyzed for gold. Silver, copper, lead, zinc, molybdenum, arsenic, antimony, vanadium, and mercury. The metal concentrations in the soil samples along the traverse are irregularly distributed. Samples collected near old prospect pits tend to be high in lead and zinc, undoubtedly a reflection of underlying galena-and sphalerite-bearing quartz veins. All of the copper and mercury values in the soils are less than the detection limit, as are most of the lead, molybdenum, and antimony values. Except for lead and zinc values, the metal concentrations in the rock samples are low. Galena and sphalerite were observed in quartz vein samples collected at the old prospects. The results of the study indicate that the galena-sphalerite-bearing quartz veins and veinlets are too narrow, widely-spaced, and low in metal values to be economic. Low concentrations of metals in the soil and rock samples, combined with the lack of major mining activity in the past, indicate that the area has a low likelihood for economic development.

Jan 1, 1986

By Stephen C. Tadolini, Thomas M. Barczak

An underground investigation was designed and implemented by the National Institute for Occupational Safety and Health (NIOSH) to evaluate the effectiveness of pre-driven longwall recovery rooms supported with pumpable concrete roof supports. The pumpable roof supports were instrumented with hydraulic pressure cells to measure support loading. Displacement of the support was also measured to assess the support reaction to ground movements. Movement up to 12.5 m (40 ft) into the roof was measured with sonic probes and multipoint extensometers. Borehole pressure cells were installed in the panel fender and outby pillars to evaluate load transfer. Shield loading was also assessed to determine the impact of the panel fender yielding on face loading. The results show that the yielding of the panel fender produced uncontrollable convergence that caused yielding of the shields and stiff pumpable roof supports when the face was approximately 3.12 m (10 ft) from the recovery room. The shields continued to yield until the face advanced into the recovery room. Convergence in the pre-driven recovery room typically reached 15-20 cm (6-8 inches) once the pumpable supports yielded and shed load through a declining residual load capacity prior to being cut out by the longwall shearer. Roof deformations occurred beyond the 10 m (32 ft) horizon with total deformation ranging from five to 10 cm (2 to 4 inches), indicating that standing support was necessary to help control the span as the longwall face advanced into the pre-driven recovery room. Stability improved as the pumpable supports were cut out, thereby reducing the span between the shields and the outby pillars. In the end, the shields were successfully recovered under stable ground conditions. However, a disconcerting discovery was the load shedding of the outby pillars as the recovery room was mined into. This behavior was not expected with a relatively narrow room that is fully supported with standing support. If this mechanism is indeed occurring, the width of the room and performance of the standing support becomes even more critical. Premature failure of the support can lead to excessive convergence on the shield line that cannot be controlled even with modern shields, resulting in instabilities that can lead to catastrophic results. Understanding the load transfer mechanics associated with the advancement of the longwall face into the pre-driven recovery room and the widening of the room to recover the longwall shields is providing valuable information for the refinement of the NIOSH Ground Reaction Curve for standing and intrinsic roof support system design.

By H. J. Fissan, G. Ananth, K. Rubow, V. Marple

"INTRODUCTION Over the past several years a new type of cascade impactor that utilizes small nozzle diameters (micro-orifice nozzles) has been under development (Kuhlmey et al., 1981; Marple et al., 1981). The small nozzle dimensions allow for particles to be collected as small as 0.024 µm aerodynamic diameter on the last stage of the impactor. To obtain a reasonable flow rate of 30 I min - i through the impactor, a large number of nozzles (up to 2000) are required per stage.Furthermore, by locating the nozzles of multi-nozzle stages in a prescribed manner (described in detail by Marple et al., 1981) and rotating the impaction plates relative to the nozzle plates, uniform deposits can be achieved on the impaction plates. As described by Marple et al. (1981), the advantages of a uniform deposit impactor over the conventional impactor that collects particles only beneath stationary nozzles are: (1) maximum use of the impaction substrate surface, reducing both particle bounce (if substrates are greased) and tare weights of the substrates (if particle mass is measured gravimetrically); (2) deposited particles can be analyzed for elemental composition by X-ray fluorescence (Dzubay and Rieke!, 1978); and (3) the pressure in the impactor can be kept relatively high compared to low pressure impactors that depend on a large slip correction to achieve small particle collection (some types of particles may evaporate at low pressures). The work described in this paper investigates two additional advantages of a uniform deposit impactor. These are: (1) the possibility of collecting two separate deposits at one time on one stage for two types of analysis techniques, and (2) the possibility of utilizing piezoelectric quartz crystal impaction plates more effectively by eliminating the deposit location sensitivity nature of the crystals (Schulze-Frohlich, 1981 ).MICRO-ORIFICE UNIFORM DEPOSIT IMPACTOR (MOUDI)A photograph of an eight-stage MOUDI is shown in Fig. 1. Each stage body of the impactor supports the impaction plate for the stage above and the nozzle plate for the stage below as shown in Fig. 2. By rotating alternate stage bodies, while holding the other stage bodies stationary, the impaction plates (or nozzle plates) will be rotated relative to the nozzle plates (or impaction plates).Rotation of the alternate stage bodies is achieved by gears on these bodies that mesh with gears on an electrically driven drive shaft of a rotating mechanism (Fig. 1 ). The alternate stage bodies are restrained from rotation by pins that rest on the drive shaft."

Mar 1, 1989

By Sarah P. Guerrino

This chapter summarizes data on crude nonfuel mineral production for the United States, its island possessions, and the Commonwealth of Puerto Rico. Included also are the tables that show the principal nonfuel mineral commodities exported from and imported into the United States and that compare world and U.S. mineral production. The detailed data from which these tables were derived are contained in the individual commodity chapters of Volume I and in the State chapters of Volume II of this edition of the Minerals Yearbook. Although crude mineral production may be measured at any of several stages of extraction and processing, the stage of measurement used in this chapter is what is normally termed ?mine output.? It usually refers to minerals or ores in the form in which they are first extracted from the ground, but customarily includes the output from auxiliary processing at or near the mines.

Jan 1, 1987

By John C. Edwards

Chapman-Jouguet detonation calculations were carried out for pentaerythri-tol tetranitrate (PETN), TNT, and ammonium nitrate-fuel oil (AN-FO) explosives using the compressibility form of an equation of state of hard spheres based upon Percus-Yevick (PY) theory, and a chemical equilibrium detonation code called TIGER. Similar calculations were also carried out with the Becker-Kistiakowsky-Wilson (BKW) equation of state. For PETN, the BKW equation gives somewhat better agreement with experimental values of detonation velocity and pressure. However, in terms of experimental temperatures and concentrations of the minor product species (NO), the predictions of the PY equation are shown to be more satisfactory. Similar comparisons of experimental and theoretical results for TNT and AN-FO indicate that the PY equation has general utility in predicting the detonation properties of condensed explosives at moderate loading densities (Po < 1.3 g/cm3).

Jan 1, 1974

By J. D. Corrick

Research was conducted to develop operating techniques and define some of the limiting parameters for microbially converting hydrous calcium sulfate to hydrogen sulfide. The work was carried out in either glass stoppered flasks or anaerobic fermentors. Using the criteria of pH, temperature, number of bacteria per milliliter of test solution, and hydrogen sulfide produced, it was shown that hydrous calcium sulfate could be microbially converted to hydrogen sulfide at a rate of 7.3 g H2S/1 of fermentor volume per 24 hours. The various parameters defined were pH, temperature, and medium exchange rate. These were shown to be a pH range of 7.2 to 8.8, a temperature range of 30° to 35° C, and a medium exchange rate of 70 percent of the ferment or volume per 24 hours. It was also shown that a daily waste was between 50 and 77 percent as effective as sodium lactate in supporting the production of hydrogen sulfide and that by utilizing a gas to purge the fermentation system, a 1.7-fold increase in hydrogen sulfide was obtained.

Jan 1, 1970

1. In 2003, a total of 258 metal mining operations reported employment to the Mine Safety and Health Administration (MSHA). Metal mines were the smallest mining sector, comprising 1.8% of all mining operations.1 • Gold mines comprised 44.2% (n = 114) of all metal mining operations. Other common types of metal mines were iron ore (n = 29; 11.2%), copper ore (n = 28; 10.9%), and lead and/or zinc ore (n = 21; 8.1%). • Nevada had the largest number of metal mines (n = 48; 18.6%) followed by Alaska (n = 29; 11.2%).

Feb 1, 2005

By P. Bhakta

The U.S. Bureau of Mines developed an alkaline oxidative pretreatment leaching procedure to increase the recovery of gold from arsenopyrite (FeAsS) ores. The best solution compositions for arsenopyrite dissolution were determined using cyclic voltammetry and chronocoulometry. Initial arsenopyrite dissolution occurred at -0.20 V versus standard hydrogen electrode (SHE) in a sodium hydroxide (Na0H) solution. Leaching of a high-grade arsenopyritic ore containing, in percent, 28.2 As, 25.3 Fe, 19.9 total S, and 1.0 Sb and, in troy ounces per short ton, 1.6 Au and 5.5 Ag resulted in >90 pct As extraction at 1000 C, 40 psig O2,4 h, and 2M NaOH solution in a 2-L autoclave. Cyanidation of the leach residues resulted in 90 to 93 pct Au and 60 to 80 pct Ag extractions, compared with only 5 and 15 pct, respectively, without the pretreatment. The procedure was further tested by leaching a low-grade gold ore and a bulk sulfide flotation concentrate prepared from it. Cyanidation of the leach residues resulted in 70 pct Au and 31 pct Ag extraction. The NaOH leachate was partially regenerated by precipitating the arsenate as calcium arsenate [Ca3As04)2] and the sulfate as barium sulfate (BaS04).

Jan 1, 1989

By Donald O. Capstick

A mineral survey of a 13,525-acre portion of the 21,875-acre Owyhee Canyon Wilderness Study Area in northern Nevada was conducted by the U.S. Bureau of Mines in 1984. Two samples from sand and gravel deposits in the study area contained minor placer gold typical of the Owyhee River area. The gold-bearing gravels are too low grade or of insufficient volume to support commercial placer mining operations. The sand and gravel deposits might have minor local construction uses.

Jan 1, 1986

By d&apos, Kathleen J. Amico

THIS SUMMARY appears in Minerals Yearbook volumes I and III, which cover mineral production in the United States, its island possessions, the Canal Zone, and the Commonwealth of Puerto Rico, as well as the principal minerals imported into and exported from the United States. The several commodity and area chapters contain further details on production. A summary table comparing world and U .S. mineral production also is included. Mineral production may be measured at any of several stages of extraction and processing. The stage of measurement used in the chapter is normally what is termed ?mine output." It usually refers to minerals in the form in which they are first extracted from the ground, but customarily includes for some minerals the product of auxiliary processing operations at or near mines.

Jan 1, 1965

By Michael J. Brnich

Since 1991, Pittsburgh Research Center (PRC- formerly part of the Bureau of Mines) researchers have recorded extensive interviews with 30 individuals who are experts in the area of mine emergency response. These individuals, who have an average of 35 years of mining experience and 29 years of mine emergency response experience, related stories and observations from events that they experienced during their combined 850 plus years in mine emergency response. The purpose of this effort was to gather information that could be passed onto both today?s and tomorrow?s mine emergency responders to train and guide them in handling future events.

Jan 1, 1997

By F. Garcia, J. Cervik

The cross-measure borehole technique has been shown by the Bureau of Mines to be an effective method of controlling methane liberated by fracturing the roof strata in longwall gobs where overburden is less than 750 ft (229 m). Boreholes are drilled into roof strata before mining operations affect the roof strata. Longwall mining fractures the roof strata and releases methane from source beds. Surface exhausters or vacuum pumps are used to draw the gas to the surface through an underground pipeline and vertical exhaust hole. The captured methane is thus prevented from entering the mine&apos;s ventilation system. About 71 pct of the methane produced by longwall mining in the Lower Kittanning Coalbed was captured by the cross-measure boreholes. Borehole spacing is an important factor affecting the performance of the technique. Interference tests and measurements of methane flows in return air indicate borehole spacing in the Lower Kittanning Coalbed should be limited to about 200 ft (61 m) except on the first 600 ft (183 m) of the longwall, where spacing should be reduced to about 100 ft (30 m) to capture the large quantities of methane released when the first large roof fall occurs. Comparisons between measured and calculated gas pressure differentials on boreholes indicate borehole length can be reduced from 280 to 140 ft (85 to 43 m), which reduces drilling costs significantly. Additional experimentation is necessary to verify the calculations.

Jan 1, 1985

By James R. FitzSimmons

This report describes an instrument developed by the Bureau of Mines as an improved device for examining roof rock in bolt holes. The unit consists of a commercially available fiberoptic unit adapted for use as a flexible stratascope. Field testing in both metal and coal mines has shown the instrument can be easily transported and used by a single operator. The size and flexibility of the instrument eliminate the need for specially drilled holes.

Jan 1, 1979

By Rose L. Ballard

This chapter summarizes data on crude non fuel mineral production for the United States, its island possessions, and the Commonwealth of Puerto Rico. Included also are the tables that show the principal non fuel mineral commodities exported from and imported into the United States and that compare world and U.S. mineral production, The detailed data from which these tables were derived are contained in the individual commodity chapters of Volume I and in the State chapters of Volume II of this edition of the Minerals Yearbook. Although crude mineral production may be measured at any of several stages of extraction and processing the stage of measurement used in this chapter is what is normally termed "mine output." It usually refers to minerals or ores in the form in which they are first extracted from the ground, but customarily includes the output from auxiliary processing at or near the mines.

Jan 1, 1986

By J. J. Cummins

The Bureau of Mines heated at 150° to 350° C for 0.5 to 360. days Green River oil shale that had been previously extracted by benzene to provide information on in situ processing conditions, to determine the effect of low-temperature heating on the unconverted kerogen, and to determine the composition of benzene-soluble thermal products. The methods used in determining the composition of the soluble thermal products consisted of fractionation of the soluble material, elemental analysis of the soluble products, fractionation of the polar resins by ion-exchange chromatography, gas chromatographic analysis of [n]-alkanes3 and mass spectral analysis of the branched plus cyclic alkanes and aromatic oils. The methods used to determine the effect of low-temperature heating on the unconverted kerogen remaining in the oil shale heated residues consisted of carbon-hydrogen analysis, volatile material determination, carbon residue determination, and oxidation rate determination. In general, it was concluded that significant increases in the degradation of kerogen to oil occurred between the temperature range of 250° to 350° C; that the composition of the soluble products depends upon the temperature at which they are formed; and that the [n]-alkanes are pyrolytically degraded from the kerogen structure. In particular, the 250° C heating temperature is beneficial to the formation of branched plus cyclic alkanes. Also, the heated and unconverted oil shale kerogen and the soluble thermal products become more aromatic as the temperature increases from 150° to 350° C.

Jan 1, 1974

By J. H. Perry, D. W. Houseknecth, C. A. Kertis, A. T. Iannacchione

Major problems facing the development of coal and gas resources of the Hartshorne Coalbeds include the complex distribution of minable and unminable coal, high methane content and bed pressure, faulting, variations in degree of dip, presence of natural gas fields in associated sandstones, and legal problems, caused by local geologic characteris- tics, in identifying gas origin. This Bureau of Mines study provides pertinent geologic information for long-range planning of subsurface coal and gas production from the Hartshorne Coalbeds. Pittsburg, Coal, Hughes, and Atoka Counties, OK, have approximately 1 billion metric tons (1.1 billion short tons) of Hartshorne coal in place. The methane resource of Hartshorne Coalbeds is estimated at 9.2 billion m3 (325 billion ft3) and varies with overburden and rank, These estimates were compiled from gas well density logs, coal-core data, out- crop measurements, abandoned mine maps, and the literature. The Hartshorne Coalbeds represent a valuable coal and gas resource which at present is contributing nothing to coal and gas production. This report discusses potential problems and serves as a reference for future exploration and development work. Recognition of these potential geologically related problems prior to development of this basin will reduce hazards and allow for an economic recovery of these resources.

Jan 1, 1983

By R. V. Ramani, R. Stefanko, G. W. Luxbacher

MINE VENTLATION NETWORK ANALYSIS

Jan 1, 1977

By D. H. Chambers

The Bureau of Mines developed a process for producing high-purity zinc and tin by electrorefining from liquid amalgams. Commercial grade metals were dissolved in mercury to produce saturated amalgams at room temperature. Amalgams were also prepared by electrolytic transfer from soluble anodes of the metals to a mercury cathode. Amalgams formed by both methods were used as anodes in electrorefining cells to produce high-purity cathodes. Metal impurities, excluding mercury, were at levels of less than 5 ppm in zinc and 9 ppm in tin. Mercury content was about 2 to 10 ppm in zinc products, and this was effectively removed by heating the cathodes in a vacuum. Mercury was excluded from tin cathodes by pumping the tin electrolyte through tin turnings and controlling the cell temperature.

Jan 1, 1969

By Laurance L. Oden

The Bureau of Mines studied three processes for preparing NaAl(OH)2C03) the intermediate compound which is calcined to produce alkalized alumina: (1) Mixing of Na2 C03 and of A12 (S04)3 solutions, (2) digestion of aluminum hydroxide in solutions of Na2C03 and NaHC03 at 90° C, and (3) addition of CO2 at 25° C to caustic solutions of aluminum to precipitate aluminum hydroxide followed by digestion at 90° C. The first process had the highest raw material consumption and washing requirements, and successful application of process 2 depended upon the availability of active aluminum hydroxide. Process 3 was the most effective, considering both process technology and raw material requirements. Procedures were also investigated for washing, filtering, drying, and calcining precipitates. Analytical methods included X-ray diffraction, atomic absorption spectroscopy, differential thermal analysis, and thermogravimetric analysis.

Jan 1, 1969