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By B. R. Mohal, F. F. Aplan, S. Chander

"ABSTRACTThe wetting behavior of coal has been determined in the presence of nonyl and octyl series of nonionic surfactants containing polyethoxy groups of different sizes. The wetting behavior was determined by a modified Walker technique and contact angle measurements. The results show that the wetting rate of coal varies with coal rank, structure of the hydrocarbon chain and number of ethoxy groups in the hydrophilic group of the surfactant. A close relationship has been observed between the wetting rates and the short-time advancing contact angles.INTRODUCTIONNonionic surfactants are used in many applications to improve wettability of solids. They can be used as dispersing agents [ 1 ] or dust suppressants [ 2-5 ] and to control the flotation, flocculation, filtration and flowability of particulates. This study was undertaken to study the effect of a series of nonionic surfactants on the wetting behavior of coal. Two series of surfactants, namely, ethoxylated nonyl and octyl phenols were used. The nonyl phenol series contains a linear hydrocarbon chain containing nine carbon atoms ( CH3( CH2 )8-C6H4,- ( OC2H, ) n, where n is the number of ethoxy groups) . The octyl phenol series contains a branched hydrocarbon chain containing eight carbon atoms ( ( CH3 ) 3CCH2C ( CH3)2-C6H4- ( OC2H4) n ).Initial wetting rates — modified Walker techniqueWalker et al. [ 6 ] developed a sink test to determine the wettability of coal particles. In this technique, coal particles are dropped individually onto the surface of surfactant solutions of different concentrations, and the most dilute concentration in which coal would sink ""instantaneously"" is determined. This technique is a variation of a procedure initially developed by Draves and Clarkson [ 7 to determine the effect of surfactants on wettability of cotton fibers. In this procedure commonly known as the Draves test, the concentration of a surfactant required to give a 'sink time' of 25 s is determined.Other investigators have used slight variations of the Walker method to study the wetting of fine particles [ 8-12 ] , by measuring the time for wetting a given amount of powder. There are differences in the manner in which the time of wetting is measured, however. Some investigators measure the time for the last trace of coal to disappear [ 8,11 ] whereas others determine the time for the vast majority of particles to sink [ 10 ] . Some investigators report a wetting rate [ 11 ] which is a value calculated on the basis of the time for the 'last traces of particles to sink'. The differences in choice of criterion for wetting can result in different values for wetting rates as illustrated in Fig. 1 which is based upon our measurements of the amount of powder wetted as a function of time. The procedure for wetting rate measurements is described in the next section. The technique in which time for disappearance of the 'last traces of particles' is determined gives the smallest value for the wetting rate, while the technique in which the time for wetting of the 'vast majority' of particles is determined will give intermediate rates. The terms 'last traces of particles' and 'vast majority of particles' are usually not defined explicitly and can lead to large differences in wetting rates measured by different investigators. Since our measurements show that the wetting rates for an assembly of powder decreases with time, we have used the initial wetting rates to compare the wetting behavior of coal in solutions of different surfactants."

Mar 1, 1989

By Cleo Griffith Rall, D. B. Taliaferro

The method for determining oil and water saturations described herein has been used successfully for several years in the core laboratories of the Bureau of Mines. The apparatus constructed according to the original specifications has proved very satisfactory; in fact, it has been widely adopted by core laboratories throughout the petroleum industry. The writers have found that the method gives reproducible results, the degree of accuracy depending largely on the attention to details given by the operator. The relative importance of these details of procedure and the design of the apparatus are discussed in this report. In September 1940, the Bureau of Mines published a report describing a method used in its laboratories for the determination of the water content of oil-field cores. The procedure was essentially the same as that adopted by the American Society for Testing Materials for the determination of the water content of petroleum products, although the apparatus and technique were altered slightly to increase the precision of the method and to adapt it to the characteristics of the material to be tested. The report also contained a description of the method used at that time in the Bureau’s core laboratories for measuring the oil content of a core, utilizing the sample on which the water-saturation determination had been made. The procedure involved the transfer of the weighed sample, from which the water had been distilled and measured, to a Soxhlet extractor and the removal of the remaining oil by means of a suitable solvent. Soon after the report was published, the water-determination apparatus described therein was modified so that both the oil and water contents of a core sample could be determined simultaneously. This method, which has been described by Yuster, is now widely used throughout the industry.

Dec 1, 1946

By J. E. Doo1ey

To process and use the heavy ends of petroleum effectively, the development of suitable separation and characterization procedures not currently available was required. A systematic procedure was developed by the Bureau of Mines using such techniques as isothermal and molecular distillation, chemical treatment, silica-alumina gel chromatography, gel permeation chromatography, and spectrometry. Using these techniques, the Bureau achieved a detailed separation and characterization of a 370° to 535° C distillate from Gach Saran, Iran, crude oil. Such a systematic procedure and the semiquantitative data resulting therefrom should be of value in selecting feedstocks and in optimizing petroleum processing operations.

Jan 1, 1973

By T. M. Barczak

This report describes Bureau of Mines research to develop methods to evaluate loading on longwall roof supports to permit better design and more efficient utilization of these structures in compliance with the geological conditions in which they are employed. The resultant vertical and horizontal force acting on the canopy of a shield can be determined, either from a statically determinate solution assuming rigid-body mechanics and elimination of certain unknowns, or from an elastic solu-tion by analysis of the load-displacement relationship of the shield structure. A two-dimensional rigid-body model is presented that determines resultant shield forces by measurement of leg, canopy capsule, and lemniscate link forces. An elastic solution is presented, in the form of an elastic stiffness model with two degrees of freedom, which describes the load-displacement relationship from the stiffness of the shield structure as determined in the Bureau's Mine Roof Simulator (MRS). The ability of both models to determine resultant forces acting on the shield canopy are evaluated from full-scale tests in the MRS. More advanced numerical models are also discussed as part of the Bureau's continuing effort in the evaluation of roof support structures.

Jan 1, 1987

By Jack E. Fraley

Because of their noncombustibility, silicate and magnesium oxycements are desirable for sealing shale in underground coal mines. In this Bureau of Mines investigation, cement samples were cured and tested (nonstandard tests) for submersion to note resistance to dissolution (breaking into parts), which is an important property for a coating. Nonappreciable dissolution during 1 week of submersion was set for passing the test. Over half of the coatings passed the test.

Jan 1, 1977

By B. B. Letson, D. F. Smith, T. E. Gardner, A. R. Taylor

Low- temperature heat capacities of strontium chloride (7° - 300° K) and strontium fluoride ( 11 ° - 300 ° K) were measured with an adiabatic calorimeter . Smooth values of heat capacity , entropy , enthalpy function , and free - energy function were calculated from the heat - capacity data . The smooth values are reported at 10 ° K intervals and at 273.15 ° and 298.15 ° K.

Jan 1, 1963

By W. M. Traver, A. M. Evans

"INTRODUCTION The Bureau of Mines undertook exploration in the Torlingua district, Texas, during June 1943, at a time when the demand for mercury for war industries was considerably more than the anticipated domestic production. In view of the impressive past production of the mines and the favorable geologic conditions in several underdeveloped areas in the district, the investigation was considered of immediate importance.Prior to initiation of the exploratory program, a preliminary examination of the district was made in August 1942 by A. B. Needham, an engineer of the Bureau of Mines. This examination was followed by a comprehensive geological study by the Federal Geological Survey 3/ and further investigation the Bureau of Mines."

Jan 1, 1947

By E. J. Gleim

[of- ac tore affecting the e -success of recent conveyor miningsystems forLt. extraction. 1 GL C ,_tfreedom shoot &apos;_)`u 2--ethe.1 is coal while e en othershot firers re:7 t _e&apos; _U-tin , w J, e coal .Z- 311.ing States conveyors because ;-.;lax .ca requires thatblasting be limited to when c .. men os. _o tend neces¬sary officials 1 s . re out c-z ,r 7t ...y e:e l z<: woes no t a -¬#to 1 C" such restriction on blasting conveyor miningbeen extendedWhere ere t ere. re no _ c: t&apos;_ _c tit-----! . kind cutlasting;,1CL?; C&apos;. _ z)carried anI-7LC. AT continuouslyHowever, unless et._&apos;0:, precations are taken under r&apos;t e , accidents, n is or such, as111 electricity r 1C- from.J--_,._.1t ,° =&apos;1?without usingholes, as well as numerous-o _&apos;1&apos;-1 -= e troublehe record of mineexplosions (some of themSo so _C&apos;_ °:&apos;,v 0f rock- dusting]

Jan 1, 1941

By G. A. Smyres

The Bureau of Mines conducted laboratory studies to determine the feasibility of chlorine-oxygen leaching for treating low-grade zinc sul-fide flotation concentrates. Recovery of zinc sulfides by flotation from complex fine-grained sulfide ores is substantially higher in low-grade bulk sulfide concentrates than in the high-grade cleaned concen-trates required for smelter feed. However, there is no commercial process in the United States for the treatment of low-grade bulk zinc sul-fide concentrates. Leaching experiments using reactors of 500-mL and I-gal capacity were conducted on a bulk concentrate containing 19.3 pct Zn, 35.6 pct Fe, and 39.4 pct S. The effects of pressure, temperature, and percent solids on extraction were investigated. The chlorine-oxygen leaching procedure showed promise for treating the concentrates. Zinc extractions of 95 pct or more were obtained by leaching at 50 pct solids in the temperature range of 1000 to 1200 C. Zinc extractions by leaching with chlorine followed by oxygen at reactor pressures of 50 to 100 psig were independent of pressure.

Jan 1, 1985

By Arno C. Fieldner

Coal for coke production is fundamentally necessary for the manufacture of pig iron , and pig iron must be had for making steel - a vital element in our modern industrial economy . In both World Wars , special effort by Government and industry was required to meet the emergency of greatly increased demands . In the first World War , lack of coke - oven capacity , rather than lack of coking coals , was the principal problem ; but in the second World War both oven capacity and coking -coal mining capacity were pushed to the utmost . Because of inadequate supply , it became necessary to allocate a part of the production of these coals from other fuel use to coke production . This was done by the Solid Fuels Administration . These experiences raised a question , during and after the war, as to the nature and amount of the minable reserves of coking coal suitable for the manufacture of metallurgical coke ; and to what extent the lower -rank and lowergrade coals could be utilized by improving preparation and by appropriately blonding different coals . Obviously , much investigation and research are required to find answers to these questions . Somo work was done by Governmental and industrial agencies during the war , and , fortunately , more has been undertaken since the close of It is the purpose of this paper to review briefly our fuel reserves , with special reference to coking coal , and to discuss the problems of utiliz . ing progressively poorer coking coals as the reserves of high - quality coals approach depletion .

Mar 1, 1950

In 2007, a total of 14,871 mining operations reported employment data to the Mine Safety and Health Administration (MSHA).1 Almost half (48.4%) were sand and gravel mines, followed by stone mines (31.2%), coal mines (13.7%), nonmetal mines (4.9%), and metal mines (1.9%).

Aug 1, 2009

In 2004, a total of 4,401 stone mining operations reported employment to the Mine Safety and Health Administration (MSHA). Stone mines comprised 30.4% of all mining operations.

Sep 1, 2007

By M. J. Kovalik

The effect of oxidation by air at temperatures ranging from 200° to 390° C on the change of chemical and physical properties of Pittsburgh-bed coal was studied as a function of processing time and temperature. The goal was to prepare a nonagglomerating fuel from a strongly coking coal for use in continuous carbonizing processes and in fixed-bed gasifiers. The oxidized coal was carbonized in a bench-scale apparatus, and the coke strength was evaluated in a Roga tumbler. Strength of the coke was progressively reduced with time of oxidation until the coking power of the coal was apparently destroyed. Time requirements to obtain an essentially nonagglomerating product were inversely related to processing temperature. Gaseous products released from the coal during oxidation reduced the yield of the desired nonagglomerating product, which decreased with time of oxidation at constant temperature and with increase in processing temperature at equal time. Oxidation at a temperature slightly above the lower limit of the plastic temperature range of Pittsburgh-bed coal was most effective because of the short processing time required and moderate processing losses.

Jan 1, 1963

By V. E. Edlund

Laboratory batch flotation tests were conducted on copper converter slags to evaluate the relative merits of recovering copper from slow-cooled versus water-quenched slags. Three slags containing 1.6, 5.0, and 6.6 percent copper were used. More than 90 percent of the copper was recovered in a rougher concentrate leaving a 0.2- to 0.3-percent copper tailings when treating slow-cooled slag. Lower recoveries and higher copper tailings ranging from 0.5 to 0.6 percent copper were obtained from quenched slag. Grindability studies were made on the respective heat-treated slags. Quenched slags proved more difficult to grind than slow-cooled slags. Cost studies showed that quenched slags can be treated at slightly lower cost than slow-cooled slags. However, the cost advantage of processing quenched slags is more than offset by the higher copper recoveries obtained from slow-cooled slags.

Jan 1, 1971

By Richard D. Miller

The helium resources base of the United States was estimated by the U.S. Bureau of Mines (Bureau) to be 894.6 Bcf as of January 1, 1989. These resources are divided into four categories in decreasing degree of assurance of their existence: (1) helium in storage and in proved natural gas reserves, 282.4 Bcf, (2) helium in probable natural gas resources, estimated at 237.7 Bcf, (3) helium in possible natural gas resources, estimated at 263.1 Bcf and (4) helium in speculative natural gas resources, estimated at 111.4 Bef. These helium resources are further divided into depleting and nondepleting, with the helium in storage being in a classification. The depleting resources are those associated with natural gasfields that are, or will be produced for the natural gas they contain. Almost all of the helium in potential (probable, possible and speculative) natural gas resources is included in this classification. These depleting resources are estimated to contain 775 Bcf of the total helium resource base. Helium resources contained in nondepleting natural gas resources, i.e., those in shut-in, abandoned, or otherwise nonproducing natural gas fields, are estimated to total 84 Bcf There is 35 Bcf of helium in storage in the Federal Government-owned Cliffside Gasfield near Amarillo, TX.

Jan 1, 1990

By W. C. Holliman

This report is one of a series of reports on the characteristics of commercial aviation gasolines, It presents compilations of inspection test data on their products furnished by 16 manufacturers of commercial grades of aviation and special date obtained in Bureau of Mines laboratories on 66 samples of these gasolines, Data are presented for 19 samples of grade SO, 17 of grade 91/98, 22 of grade 100/130, and 8 of grade 115/145 aviation fuels. These gasolines are designated July 1948 production, although some of the samples may have been produced a month earlier or later.

Jan 1, 1948

By J. J. Hoeppner

Accurate determination of moisture in coals of various ranks has long been a subject of intensive investigation. Excellent reviews of methods developed over many years are given by Brown (9)4/ and, with experimental comparisons, by Goodman, Gomez, and Parry (11). As pointed out in these and other writings, one of the principal difficulties in assigning absolute merit to one or another procedure is the multiplicity of conditions under which water may exist in coal and the difficulties involved in obtaining sharp separation and distinction between these classes. Gauger (10) states: Water recoverable from coal is obtained from the following sources: (1) Decomposition of organic molecules (sometimes called combined water), (2) surface adsorbed water, (3) capillary condensed water, (4) dissolved water, and (5) water of hydration of inorganic constituents of the coal.

Jan 1, 1956

By C. Harry Benedict

This paper, describing the leaching practice at the Calumet and Hecla mills, Lake Linden, Mich., is one of a series on milling methods and costs being published by the United States Bureau of Mines. GENERAL DESCRIPTION The reclamation plant is located along the shores of Torch Lake at a slightly lower level than the concentrator itself. The entire location of the original concentrator, in connection with the present reclamation plant, has been ideal, lore particularly as the leaching and flotation departments are common to both units. After 15 years of operation and with the reclamation sands just a little more than half exhausted it would appear that the remaining life of the deposit could be worked by the present plan, without decided changes or renewals of plant or equipment.

Jan 1, 1930

By Herbert H. Einstein

The thrust of research reported in Part I was to collect in-situ data from exploration programs and the published literature, and to empirically establish distributional patterns for these variables. Since discontinui¬ties in a rock mass govern to a large extent its engineering properties and thus the performance of any slope in the mass, work has been devoted to determining the appropriate distributional forms for attitude spacing and length of discontinuities and to distributional properties of resis¬tance and deformability parameters. The conclusion from these analyses is that trace lengths are logNormally distributed and that joint spacing is Exponentially distributed, regardless of orientation of the sampling line, and regardless of whether each joint set is considered separately or not. Joint orientation (attitude) data representing 22 individual joint sets from eight sites (a total or approximately 20,000 joints), do nor strongly support any of the commonly used distributions as broadly applicable in practice. The autocorrelation )f geometric joint properties is also examined. However, no significant spatial correlation could be found even after extensive data manipulation. The investigation of resistance and deformability parameters starts with a review of mechanisms and models that are used to represent them. Review and statistical evaluation of approxi¬mately 2,000 discontinuity shear tests has shown that good statistical estimates for use in reliability analyses can be obtained for friction angles.

Jan 1, 1979

By Danqing Xu, A. W. Khair

"This paper presents a laboratory simulation of regrinding and resulting dust generation. An Automated Rotary Coal Cutting Simulator (ARCCS) was modified to conduct regrinding experiment. In order to estimate the effects of coal properties and operating parameters on regrinding and dust generation, an orthogonal fractional factorial experimental design was implemented in regrinding experiment. Marple personal cascade impactors, Series 290, were used to measure dust concentration during experiment. Three types of coal seams, namely, Waynesburg, Pittsburgh, and Lower Kittanning, were used to represent different coal properties. Experimental results and complete parametric analysis were presented.In a rotary cutting system, all the broken coal and part of the remaining coal from previous cutting cycles must be transported through part or entire circumference of the cutting drum. This transportation of already recovered coal through the cutting zone of rotary head makes it a rotary grinder. Some of the coal particles will be subjected to secondary fragmentation or regrinding in the process. The potential effect on dust generation by regrinding is significant because the cutting head utilizes kinetic energy to comminute recov¬ered coal material. The moving bits and bit blocks on the cutting head impact coal particles and transfer some of their kinetic energy to the particles. After obtaining kinetic energy, coal particles are free to impact one another and they also impact the coal seam or cutting head. During impact, high impact force and high internal stress concentration are created in the particles. Kinetic energy is transformed into strain energy. When stored strain energy exceeds allowable strain energy, the particles will break. A great amount of respirable dust will be generated due to impact failure. In reality, regrinding occurs at the same time as primary cutting. The particles to be ground are the result of primary cutting. Both primary cutting and regrinding produce dust. Therefore, it is impossible to separate regrinding from primary cutting. In order to study respirable dust generation by regrinding and analyze the influencing parameters, a laboratory approach was adopted. In this approach, it is possible to study the regrinding separating from primary cutting."

Mar 1, 1992