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By R. E. Siemens, Gary L. Hundley

The Bureau of Mines has devised and demonstrated a process for recovering Ni and Co from low-grade domestic laterites . The process consists of four mmaajjoorr steps : ( 1 ) reduction roast , ( 2 ) ammoniacal leach , ( 3 ) solvent extraction , and ( 4 ) electrowinning . Several solid - liquid separation steps are required that affect the economics of the overall process . In this study , two techniques for solid - liquid separation , centrifugation and thickening , were investigated . This report presents the results of ( 1 ) laboratory and pilot plant studies to determine parameters for sizing centrifuges and thickeners and ( 2 ) an economic study of the two techniques , based on the requirements of a commercial - size ( 5,000 - tpd ) laterite processing plant . Sizing and other equipment - related recommendations , based on data from the Bureau's studies , were obtained from commercial manufacturers . The costs of thickening and centrifugation , including all the unit operations affected , were determined by the Bureau's process evaluation group . The total operating costs for separation using the two techniques ( including depreciation on the capital cost of equipment ) were found to be quite close : $ 17.26 per ton of laterite for centrifugation and $ 18.15 per ton of laterite for thickening . For centrifugal separation , the greatest cost was found to be the initial capital cost for the separation equipment ; using thickeners , the greatest cost was for reagent recovery .

Jan 1, 1983

Cutter roof failure, a ground control problem that frequently results in massive roof failure, is common in coal mines of the Northern Appala-chian Coal Basin, causing delays in production and posing a safety hazard to mine personnel. The Bureau of Mines is conducting research on the causes of cutter roof failure to gain a basis from which to predict and prevent its occurrence, and to support such roof when failure occurs or is imminent. Research conducted at the Greenwich Collieries North and South Mines, in central Pennsylvania revealed a correlation between the presence of clastic dikes and formation of cutter roof failure. The research con-sisted of in-mine mapping of geologic and deformational features, rock pressure monitoring, core recovery and evaluation, and in situ stress measurement. It was found that roof failure increased in areas where the occurrence of clastic dikes was most frequent, especially where two or more clastic dikes intersect. Staggering of crosscuts prevented the extension of cutters and deterred the occurrence of large falls extending over several break-throughs. In addition, trusses and cribbing were effective in stabilizing clastic dikes and inhibiting the development of cutter roof failure when employed immediately or shortly after mining.

Jan 1, 1987

By N. S. Dalal, X. Shi

"Electron spin resonance (ESR) measurements on solutions and isolated powders provide direct evidence for the involvement of Cr(V) species in the reduction of Cr(VI) by NAD(P)H. ESR analysis of an isolated Cr(V)NAD( P)H solid yields 6 11 = 1.9831 and 6.i. = 1.9772, indicating that the unpaired electron occupies the d22 orbital of the Cr(V) ion, with square-pyramidal geometry. Addition of hydrogen peroxide (H2 0 2 ) to the N AD(P)HCr( VI) reaction mixtures suppresses the Cr(V) species and generates hydroxyl (""OH) radicals. The ""OH radicals were detected via ESR spin trapping, employing 5,5-dimethyl-1-pyrroline-N-oxide and a-(4-pyridyl-1- oxide)-N-tert-butylnitrone as spin traps. The dependence of Cr(V) and ""OH radical formation on the H20 2 and Cr(VI) concentrations indicates that the Cr(V) species react with H20 2 to generate the ""OH radicals. Similar results were obtained by using various diols (arabinose, cellobiose, FAD, fructose, glyceraldehyde, ribose, and tartaric acid), a-hydroxycarboxylic acids, and glutathione. Investigations with superoxide dismutase showed no significant participation of 02 in the generation of OH radicals. These results thus indicate that the Cr(V) complexes, produced in the reduction of Cr(VI) by cellular reductants, react with H20 2 to generate ""OH radicals, which might be the initiators of the primary events in the Cr(VI) cytotoxicity.In this paper we report an electron spin resonance (ESR)3 spectroscopic detection of Cr(V) species in the reduction of potassium dichromate, henceforth called Cr(VI), by NAD(P)H and other diols. Also reported here is the detection of the hydroxyl (""OH) radical in the reaction between hydrogen peroxide (H2O 2) and a variety of Cr(V) complexes. This work was undertaken because while the reduction of Cr(VI) to lower oxidation states has been suggested as a key step m the mechanism of Cr(VI) toxicity, mutagenicity, and DNA alteration, the details are not yet clear (1-5).Earlier studies on the mechanism of Cr(VI) reduction in cellular systems include those on the reduction of chromate by microsomes (6-8), rat liver DT-diaphorase (9), and aldehyde oxidase (10). All these studies imply that Cr(VI) can be reduced to Cr(Ill) by cellular constituents. Regarding the mechanism of Cr(Vl) carcinogenicity, Jennette postulated that Cr(V) is the ultimate carcinogenic form of chromium compounds (8). This conclusion has led to many further investigations of the formation of Cr(V) in the reduction of Cr(VI) under biologically relevant conditions (11-33). More recently, however, Kawanishi and co-workers (34) have investigated the mechanism of DNA cleavage induced by Cr(VI) in the presence of H20 2 and have argued that it is not Cr(V) itself that is carcinogenic, but it is the reactive oxygenated species (02, 10 2 , ""OH) (produced by the decomposition of the Crv(02) ¾ - ion) that cause the DNA alteration."

Jan 1, 1990

By Kenneth M. Maas

The Bureau of Mines inventoried the land in southwestern Alaska to classify ownership and availability and compared this land with known mineral terranes and mineral deposits. This report discusses and quantifies the potential for favorable location of mining claims for metalliferous (locatable) mineral deposits. Of the nearly 24 million acres that constitute the study area, approximately 3.6 million acres or 17% are available for mineral location, 3.4 million acres or 14% are available with restrictions, and 17 million acres or 71% are unavailable. Mineral terranes are known to underlie about 7.8 million acres or 33% of the study area; 3 million acres or 38% occur on land available for mineral location, 1.3 million acres or 17% occur on land available with restrictions, and 3.5 million acres or 45% occur on unavailable land. The State of Alaska has opened over 91 % of its land in the study area to mineral location; in comparison, the Federal Government allows mineral location on 0.07% of the land under its jurisdiction. There are 117 known mineral deposits or occurrences within the study area, including 77 lode deposits and 40 placer deposits. Of the 41 lode deposits occurring within a mineral terrane, 2 occur on available land.

Jan 1, 1988

By D. W. Bridges

Solvent extraction has become important in recent years as a unit process in extractive metallurgy. The flexibility and simplicity of the technique have attracted widespread attention, and numerous papers describing actual and projected metallurgical applications have been published. However, differences in terminology, procedure, objectives, and standards, as reflected in reports by different operators and investigators, have sometimes made appraisals and comparisons difficult. Consequently, a need appeared for n series of basic reports on the subject. This Bureau of Mines Information Circular is the first of such a series. It deals with the status of solvent extraction in metallurgy, as well as with the rudiments and terminology of the unit operation. In analytical chemistry, extraction of molecular species from aqueous media by immiscible organic solvents has been used for many years to separate and determine chemical elements (61).4 Complex chlorides of iron and other metals are readily soluble in ethers and ketones, as are the nitrates of uranium and thorium. Most metals are extractable as complex salts of some organic reagent, such as dithizone, 8-hydroxyquinoline, or cupferron.

Jan 1, 1962

By Wilbert J. Huff

The work of the Explosives Division, Bureau of Mines, United States Department of the Interior, for the fiscal year ended June 30, 1939, is described in the following pages. This paper is the fourth of a series of annual reports covering the activities of the division since July l, 1936.

Jan 1, 1940

By H. S. Auvil

[The shrinkage of coke after formation is one of the variables that affects the net expansion of the change in both industrial and test ovens. Various test results have been interpreted as indicating that cokes from certain coals shrink to a marked extent and that other cokes show very little shrinkage; out no comprehensive experimental study of the shrinkage of coke after its formation and of the factors influencing this shrinkage has come to the attention of the authors. While investigating the reactivity of cokes made by the BM-AGA method,6/ Reynolds7/ found that granular low-temperature cokes shrink considerably then reheated to higher temperatures. This shrinkage was large enough to influence the behavior of the charge (net expansion or contraction) in a coke oven to a marked extent. Since that time the Bureau of nines has investigated the shrinkage of coke different methods, all of thick had one common objective - the elimination of the effect of other factors, such as swelling in the plastic range, which could either partly or completely mask the shrinkage of the coke. Only parts of these studies have been published8/9/ in abbreviated form in]

Jan 1, 1940

By C. H. Johnson

The Big Jim mine of the United Eastern Mining Co. is at Oatman, Mohave County, Ariz. Oatman is in the foothills on the western side of the Black Mountains, at an elevation of about 3,000 feet. It is on a paved highway about 30 miles west of Kingman, the principal distributing; center for mining supplies in the district, and 25 miles from Topock, en the Colorado River. Both latter towns are stations on the Santa Fe Railroad; Oatman has no roil connection. Mining conditions are typical of western Arizona; water is scarce, no mine timber is available locally, and the winters arc mild and the summers hot. The supply of a killed labor is usually adequate, but in 1933-34 it w not more than sufficient for the restricted operations. Wages have been $4.00 to $4.50 for miners. Electric power was supplied from Kingman and cost about 2.6 cents per kilowatt-hour.

Jan 1, 1935

By H. E. Powell

A laboratory mineral-dressing investigation was conducted by the Federal Bureau of Mines on four limonitic and four sideritic iron ores from the North Basin of the east Texas iron-ore district. The samples, composited from drill cores, were considered representative of the iron-ore reserves of the area. The objectives of this research were twofold: (1) To devise a mineral-dressing method whereby the yield from currently mined east Texas iron ores might be increased and the grade improved, and (2) to extend such treatment to include the lower grade ferruginous materials that are not amenable to beneficiation by simple washing and, therefore, are not being exploited. Of the mineral-dressing methods used in this investigation, magnetic separation of roasted are was shown to be the most effective. Results show that, by this method, a laboratory recovery of 82 percent of the iron is attainable at a grade surpassing that obtained by current plant practice and that both limonite and siderite are amenable to concentration by the process. The existence of large deposits of iron are in eastern Texas has been recognized for over 100 years. These ores were first exploited during the Civil War and were mined intermittently until about 1911. From that time until 1944 when the Defense Plant Corporation financed the erection of three blast furnaces to use these east Texas ores, production was almost at a standstill.4/

Jan 1, 1960

By W. P. Yana, J. B. Littlefield

"INTRODUCTION AND OBJECT OF EXPERIMENTAn explosion in and rupture of a gas-tight switch box on an electric loader in a mine located near Pittsburgh indicated that the cause was an internally generated inflammable gas-air mixture. This led to the suspicion that moisture condensation or ""other unusual conditions might have caused a spark or are across the surface of the material and that the heat may have created a carbonized path across the synthetic plastic base which would then conduct a large current with the generation of considerable heat and thermal decomposition of the base materials base in the box which exploded gave every indication that this series of events had taken place, and accordingly it was desired to determine what explosive gases such a decomposition of these insulating materials would produce.ACKNOWNLEDGMENTSThe desirability of making this investigation was suggested to the authors by L. O. Ilsley, supervising engineer, electrical section, Bureau of Mines, to whom the occurrence of an explosion in a switch box had been reported. The writers also acknowledge with thanks the assistance of L. B. Berger, chief scientific aide, health laboratory section, Bureau of Mines, in checking the calculations in the tables. DESCRIPTION OF MATERIAL INVESTIGATEDThe ten materials used in the tests, identified by letters A to J inclusive, are described in a succeeding list of materials. All the materials except I had a phenolic odor, especially when freshly cut."

Dec 1, 1932

By A. D. Hahn

This report describes and gives the results of an examination by the Federal Bureau of Mines of ilmenite-bearing placer sand deposits in the 24-mile long valley of Otter Creek, Kiowa and Tillman Counties, Okla. Drilling and sampling was completed in three periods between October 1956 and September 1957. Mineralogic studies and mineral-dressing tests on recovery of ilmenite and other heavy minerals from composited samples of the sands were made in Bureau of Mines laboratories at Rolla, Mo., in 1957 and early 1958. Otter Creek rises in and drains the southwestern extremity of the Wichita Mountains, which are represented locally by knolls and ridges of gabbro and granite surrounded by plains floored with flat-lying Permian red beds. The valley fill consists of a basal sand-clay component, derived from weathering of the igneous rocks, and an overlying silt-clay alluvium. Ilmenite is present in significant quantity and recoverable grain size only in the basal sand-clay.

Jan 1, 1960

By Isaac A. Zlochower, Michael J. Sapko, Ronald S. Conti

The Bureau of Mines has developed a system using a high-speed electropneumatic mechanism for the rapid (grab) sampling of dusts and gases during an explosion. The sampling system consists of an aluminum housing that incorporates two 30-cm3 preevacuated glass vials with rubber septums. Upon actuation, the sampling probe needle is driven through the septum with a pressurized air pulse, filling the tube with gas and dust from the mine explosion. After a predetermined time, the sampling probe needle is retracted by a second high-pressure air pulse to its normal (quiescent) state, allowing the sampling tube to reseal. The onset and the duration of sampling are independently variable and controlled by a time-delay relay package. This technique enables the monitoring of pyrolysis-charring in coal particles and the generation and combustion of the pyrolysis vapors in both large- and small- scale explosions. The following results were obtained from full-scale dust explosion tests at the Bureau of Mines Lake Lynn Laboratory: (1) Gas sampling of the leading edge of the flame front shows the large concentration changes, characteristic of the flame front; (2) gas samples taken entirely in the flame zone consist of pyrolysis and combustion products with very low residual oxygen; and (3) the particles collected in the flame zone show signs of extensive pyrolysis and charring.

Jan 1, 1988

By Robert M. Busche

[Recent developments in the gasification of coal, both by the Bureau of Mines and American industry, have intensified interest in the thermodynamic and kinetic principles necessary for understanding the reaction mechanism and rates and the physical changes that take place. In the course of a Bureau of Mines study of the kinetics of coal gasification at the Synthetic Liquid Fuels Demonstration Plant, Louisiana, Mo., a bibliography of approximately two references was compiled. They are listed n this publication and refer both to American and foreign sources.]

Jan 1, 1952

By Paul Biggs

This Bureau of Mines report contains information on 63 water flood projects in Colorado. Water was injected in 10 formations located in 58 oilfields. Specific field data presented include location, discovery, development, water supply, fluid injection, oil and water production, oil reserves, and oil recoveries by primary and secondary methods. An estimated 3.5 billion barrels of water has been injected to recover approximately 533 million barrels of oil, a ratio of 6.57 to 1. Most of the injection water is from alluvial deposits, although produced water is used in many fields. Injection water treatment is not a major problem. Appraisal of project success or failure in this report is based on technical, rather than economic, information.

Jan 1, 1974

By J. Drew Potts

The U.S. Bureau of Mines identified respirable dust sources and controls on four continuous auger mining sections, two with relatively low dust levels and two with high levels. Factors adversely affecting dust levels included auger equipment design, continuous haulage, and low seam height. Dust controls included ventilation practices and spray systems. Maximizing airflow seemed to reduce dust levels most. Air leakage and shock loss can be reduced by constructing stoppings with brushed-on mortar containing fiberglass and by keeping areas between curtains and ribs free from obstructions and storing equipment not essential for face activities in outby crosscuts. Curtain configuration, setback distance, and installation can also affect dust levels. Use of both blowing and exhausting curtains is the most effective configuration. Setbacks from the face should not exceed 15 ft. Installing brattice curtains at least 5.5 ft from ribs, when entries are 26 ft wide, minimizes velocity head. Installing curtains tightly against the mine roof and floor helps maintain a forward airflow movement in the center of the mine heading; curtain overlap can create a tighter seal. The wet-auger spray system also effectively controls dust, provided the mine is already exercising good ventilation practices.

Jan 1, 1989

By M. M. Tilman

The Bureau of Mines evaluated corrosion resistance of Split Set friction rock stabilizer mine roof bolts to aid in better prediction of useful service life. Electrochemical corrosion testing was conducted utilizing an automated corrosion measurement system. Natural and/or synthetic mine waters from four uranium and two copper mines were the test media for the two types of high-strength, low-alloy (HSLA) steels from which Split Set stabilizers are manufactured, and for galvanized steel. Tests were conducted with waters of minimum and maximum dissolved oxygen content at in-mine water temperatures. Retrieved Split Set stabilizers were also evaluated for property changes. Galvanized steel was found to be far superior to the unprotected steel in general corrosion resistance; limited tests indicate little ten.dency to pitting, contrary to behavior for the uncoated steel. Copper-bearing HSLA steel was slightly more corrosion resistant than non-copper-bearing HSLA steel. Statistical analyses resulted in development of equations relating dissolved oxygen, chloride, sulfate, and magnesium contents of mine waters to corrosion rates of the two HSLA steels (nongalvanized). An equation was developed that relates corrosion rates of galvanized steel to mine water temperature and dissolved oxygen content. Variable conditions in mine environments make corrosion damage difficult to predict and emphasize the need for corrosion prevention and control.

Jan 1, 1984

This section presents highlights of world economic and mineral industry performance in 1982, a year characterized by continued recession, and selected 1983 forecasts of economic indicators of importance to the mineral industry, some of which indicate a modest improvement in the economies of the United States and Western Europe. The U.S. Economy in 1982 In 1982 U.S. gross national product (GNP) in current dollars increased at a rate of 4 percent, but GNP adjusted for inflation (real GNP) declined at a rate of 1.8 percent. Yearend 1982 real GNP was at roughly the same level as in 1980 (table 1). Thus no growth in real terms had taken place in the United States during the 1980-82 period.

Jan 1, 1983

By R. R. Sayers

"An important, function of the U.S. Bureau of Mines is to instruct miners in first aid, and as a means of promoting interest in it first-aid contests are held under the auspices of the Bureau, usually in coop; ration with other interested organizations, especially the American Red Cross, the National Safety Council and various operators' and Miners' associations. It was early found that the method of judging first-aid meets is one of the most vital factors in determining the degree of success of the meet.It may be safely stated that there is no method for the judging of first-aid contests that has proved ideal. A method that would give the most uniform judging would necessitate the rating of each team by the same judge or committee of judges and, in order that a judge may rate a team satisfactorily, he should see that team perform several events and average the ratings. Such a procedure is not practicable where there are many terms entered in the contest, as it would prolong the meet indefinitely. To overcome this objection the method has been tried of assigning separate judges to each team but this brings in a new factor the individuality of the various judges, some of whom rate closely, others loosely. The next development was to average the judging by having the judges rate different teams for each event. This would seem to solve the problem out it has been found, after using the method over a wide area for a considerable period of time, that the differences in the judging are too marked to be at all satisfactory. The next development was to appoint a committee of chief judges three to five in number especially trained and experienced, to aid the individual judges in rating the teams. This method has proved satisfactory at small meets but, as committee must review the work of each judge on each event, it has not been deemed feasible for a large meet."

Nov 1, 1920

By J. D. Davis

THE CARBONIZING properties of Chilton-bed coal from Lorado No. 5 mine, HE Logan County, W. Va., were determined by Bureau of Mines-American Gas Association tests at 600°, 700°, 800°, 900°, and 1,000° C. and by expansion tests. Chemical analyses, agglutinating and plasticity tests, and low- and high-temperature assays also were included in the investigation. Blends with low-volatile Pocahontas No. 3 coal were carbonized at. 900° C. The Chilton coal bed lies in the Kanawha, or Upper Pottsville formation of the Pennsylvanian system; the estimated original reserves are nearly 3.2 billion tons. The bed was 39/1 to 57 inches thick in the Lorado No. 5 mine, and the coal was 38 to 57 inches thick. The carbonization sample contained 62.6 percent fixed carbon on the dry, mineral-matter-free, basis, and the heating value on the moist, mineral-matter-free basis was 15,190 B. t. u. per pound; it therefore ranks as high-volatile A bituminous. It contained 1.8 percent moisture, 35.2 percent volatile matter, 57.9 percent fixed carbon, 5.1 percent ash, and 0.7 percent sulfur, as carbonized. The sulfur was largely organic, and the ash softened at 2,630° F. The agglutinating value determined on a silicon carbide-coal mixture of 15:1 was 6.8. In the Gieseler test the coal softened at 327° C., fused at 407° C., attained a maximum fluidity of 5,730 dial divisions per minute at 435° C., and solidified at 487° C. Maximum resistance in the Davis plastometer was 45.5 pound-inches.

Jan 1, 1951

By Martin Hertzberg

In this Bureau of Mines study, an equation is derived for the limit burning velocity for divergent, spherical propagation from an ignition kernel of radius, r: (Su)e = ( ) . For flame propagation into a preexisting, stretching velocity gradient of magnitude dv/dx, the limit velocity is (Su)e = (a dv/dx)1/2. These formulations are shown to be equivalent to the fluid dynamic concepts of Damkoh1er, Kar10-vitz, and Markstein. Existing data for the b10woff limits of flames are shown to give excellent agreement with those concepts provided that proper account is taken of two dilution effects: composition dilution caused by entrainment and velocity gradient dilution caused by flow expansion. Approximate flow-field solutions are also derived for the unburned gas motion above an upward propagating, spherical flame kernel in buoyancy-induced flows. It is shown that;, the upward hemisphere propagates toward a stagnation plane in a counterflow configuration involving the balance between the combustion force, which accelerates the cold gas upward, and the buoyancy force that accelerates the cold gas downward. The position of the stagnation plane above the upward propagating hemisphere is related to the ratio of the buoyant velocity, vb, to the burning velocity, Suo Extinction of the upward propagating wave occurs by flame stretch in that counterflow configuration when n = Vb/Su begins to exceed the expansion ratio, Pu/Pb' and the wave is blown off by its own buoyancy-induced flow field.

Jan 1, 1984