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By D. J. Hawk

The mechanical properties of coal are often represented by the orthotropicmaterial model, which consists of nine elastic constants. The material symmetries involved are found in coal primarily because of the natural process by which it was formed. In this thesis the material properties of five U.S. coals, as obtained from cubical testing, are examined, using as a basis for comparison the assumption of the orthotropic material model. An analysis is performed on each set of coal material data in order to examine its conformability to other, less complex material models, these being the transversely isotropic model consisting of five elastic constants and the 'isotropic model consisting of two elastic constants. In addition, the material properties of two American shales are analyzed, based on the assumption that they comply with the transversely isotropic model. An analysis similar to that performed on the coal material is applied to the shale in order to determine the conformity of its material properties to the isotropic model.

Jan 1, 1980

By Daniel E. Sullivan

This Bureau of Mines publication examines the potential impact on minerals of the tariff and nontariff agreements that resulted from the Tokyo Round of the Multilateral Trade Negotiations, which were conducted under the auspices of the General Agreement on Tariffs and Trade. These agreements will affect minerals by reducing tariff levels and by changing rules by which they are traded internationally.

Jan 1, 1981

By L. H. Adami, E. G. King

The heats of formation of four sulfides --MnS ( alabandite ) , FeS ( hexagonal pyrrhotite ) , ZnS ( wurtzite ) , and CdS ( greenockite ) -- were determined by hydrochloric acid solution calorimetry . The heats of formation from the metals and rhombic sulfur at 298.15 ° K are , respectively , -51.01 ± 0.19 , -23.81 ± 0.24 , -45.86 ± 0.20 , and -35.70 ± 0.30 kcal /mole . The corresponding free energies of formation were calculated from the heats of formation and the pertinent entropy values .

Jan 1, 1964

By R. H. Nafziger

Owing to the growth of alloy steel production and its influence on tramp element levels when recycled, foundries have expressed concern regarding the quality of scrap used to prepare iron castings. Reliable and current information was unavailable on the amount of tramp elements contained in iron castings over time. Accordingly, the U.S. Bureau of Mines, in cooperation with the American Foundrymen's Society (AFS), analyzed cast iron samples from participating foundries throughout the United States on a quarterly basis to ascertain possible trends. Each sample was analyzed for 28 elements to determine if changes had occurred as a function of several input variables. This bulletin describes the research and presents analytical results and evaluations over a 5-3/4-year period from January 1981 to September 1986. Results show that iron casting compositions are changing with respect to a few tramp elements such as arsenic, cobalt, chromium, tin, and zinc over the period. Changes in charge compositions probably are responsible. Significant variations between zones also were observed with aluminum, arsenic, cobalt, chromium, copper, and manganese.

Jan 1, 1990

By L. B. Pankratz

Thermodynamic data on the sulfides were reviewed, evaluated, and compiled at the Bureau of Mines Albany Research Center. Values for Cp°, S°, H°298 -(G° - H°298)/T, ?Hf°, ?Gf°, and log Kf are given in tabular form. Cp°, H° - H°298, ?Hf°, and ?Gf° are also expressed algebraically.

Jan 1, 1987

By Horace C. Porter, F. K. OVITZ

The various fuel investigations that were being carried on by the technologic branch of the United States Geological Survey were transferred by law on July 1, 1910, to a new federal bureau, the Bureau of Mines, that was authorized to continue the investigations and make public reports of the results. In consequence of this transfer, the following report is published as a bulletin of the new bureau. The United States Geological Survey had been engaged in analyzing and testing coals, lignites, and other mineral fuel substances under authority given by act of Congress. This work, now centered at the experiment station at Pittsburg, Pa., had its beginning in the operations of the coal-testing plant erected at the Louisiana Purchase Exposition in St. Louis, Mo., in 1904. The results obtained at that plant showed that the work of determining the fuel value of the coals and lignites in the United States with a view to increasing efficiency in their utilization would be incomplete if it did not include systematic physical and chemical researches into the processes of combustion. Hence in its later investigations the Survey carried on such re- searches, concentrating attention on those lines of inquiry which promised results of greatest economic importance. This bulletin is a report on an investigation of the volatile matter in several typical coals-its composition and amount at different tem- peratures of volatilization. As the investigation is still in progress and will doubtless include other coals than those already examined, the bulletin may be considered a preliminary report, stating the prob- lems studied, the methods used, and the results thus far obtained.

Jan 1, 1910

By J. H. Holden, C. C. Shale, G. R. Strimbeck, W. S. Bowie

Electrical characteristics are presented for air in a 2 - inch pipe - type electrostatic precipitator operating under dynamic conditions at temperatures of 600 ° to 1,500 ° F and pressures of 0 to 80 psig using a negative discharge electrode . Results of this one - geometry study show that current - voltage relationships are a function of air pressure and temperature and indicate that precipitators can be used at any temperature through about 1,350 ° F over the full range of pressure . Corona starting voltage and sparkover voltage vary directly with pressure and inversely with temperature . At temperatures above 1,350 ° F use of precipitators may be limited to operations at pressures somewhat above atmospheric pressure . Theoretical derivations are presented that relate the effect of gas density on corona starting voltage and the effect of ion mobility on corona current . Deviation from the theory is noted at high current levels . Theoretical discussion is presented to explain the apparent electrical limitations for use of precipitators at high temperature , low gas density , and high corona currents , conditions at which calculated ionic velocities are extremely high . Experimental results are interpreted in terms of the theory presented . 1,500 ° F thermal ionization does not appear to be a critical factor .

Jan 1, 1963

By John W. Sweeney

Shales and clays from Illinois were sampled, tested, and evaluated to determine feasibility of producing lightweight aggregate by rotary-kiln methods. Sampling procedures and the 1 ,,,y of the Pennsylvanian shale units are discussed. Chemical, X-ray spectrographic and X-ray petrographic analyses were run on the samples to determine if a correlation existed between chemical mineralogic composition and expansion. Preliminary expansion testing was conducted in a muffle furnace. Rotary-kiln tests were conducted in a 16- inch by 14-foot rotary kiln. The weight of the aggregate ranged from 27 to 59 pounds per cubic foot. Concrete cubes employing the aggregate were tested to determine the qualities of the concrete. Compressive strength of the concrete using the 7-bag of cement cement per cubic yard mix, after autoclave curing for 6 hours, ranged from 2,950 to 6,750 psi. No correlation was found between the chemical, X-ray spectrographic, and X-ray and petrographic analyses and expansion, Sixteen samples made suitable lightweight aggregates in the laboratory rotary kiln. The expansion temperature range of eight of the samples was extremely narrow, and difficulties would probably be encountered in processing these materials commercially.

Jan 1, 1965

By B. W. Gandrud

[The Bureau of Mines is conducting an extensive investigation of coal preparation in the Alabama coal fields in cooperation with the University of Alabama coal-mine operators. In this investigation the drainage characteristics of typical coals from the Warrior and Cahaba fields were studied]

Jan 1, 1941

By Ludwig Schmidt

"IntroductionThe evaporation losses of gasoline in the refinery, can be reduced by proper methods of refinery construction and operation. When gasoline evaporates slowly, as when stored in tanks that are not vapor tight, the most volatile part evaporates first, so that the remaining liquid in not only less in volume, but is also lower in quality. In some,evaporation changes the characteristics of the product so much that it must be reblended to meet trade specifications.Refiners are, therefore, greatly interested in the various appliances and methods used to reduce these losses. In the past this interest has been directed largely to storage tanks, probably because evaporation from tanks is more readily observed than losses during other refinery operations. As tests by the Bureau of Mines on evaporation of gasoline from small storage tanks had indicated that the losses during the various stages of refining might be equal to or greater than those of standing storage, a survey was during the spring and early summer months of 1924 in a large number of refineries in the Mid-Continent field. In order to enable the refiner to select the results of those tests that conform most nearly to the conditions that he has to meet, tests were conducted at various stages of refining, as follows: (1) Randown tanks, (2) (agitators), (3) filling tank cars, (4) storage of refined products, and (3) miscellaneous handling. The results are presented in this paper."

Nov 1, 1925

By Kenneth L. Kreamalmyer

"The demand for open-hearth iron ore and the existence of suitable smelting facilities in the St. Louis area seemed to warrant investigation of several Missouri iron-ore deposits of the filled-sink type. Preliminary examinations were made in the autumn of 1944 by an engineer3/ of the Bureau of Nines, and in December of the same year funds were allotted for the exploration of these properties by churn drilling. Three properties, the Silver Hollow Bank and the Newbauer and Coleman properties, were drilled. Work was completed May 8, 1945.The Federal Geological Survey and the Missouri Geological Survey and Water Resources assisted in the project by determining the stratigraphy from drill cuttings and by mapping the drilled areas.The properties explored are in the hilly section of east-central Missouri and are connected by all-weather graveled roads with various shipping points of the St. Louis-San Francisco Railway system within 3 to 6 miles of each property.The Silver Hollow Bank, in sec., 8, T, 40 N., R. l W. Franklin County, Missouri, is in the Meramec State Game Reserve. The nearest town and shipping point is Sullivan, Mo„ which is 6 miles distant. The Newbauer property, in sec. 28, T. 41 N., R, 2 W., Franklin County, Missouri, is approximately 3 miles west of Stanton; The Coleman property, in sec. 14, T. 38 N., R. 3 W., Crawford. County, Missouri, is within a short hauling distance of the railway at Elayer, Mb. These are shown on figure 1.The region surrounding the explored areas contains a series of low-lying hills or ridges and narrow winding valleys drained by the Meramec River system. These hills seldom rise more than 200 feet above the valley floors, most of which are approximately 700 feet above sea level. Except for numerous small farms and a few small towns, the entire region is covered by a dense growth of timber and small brush. The St. Louis-San Francisco Railway system, U. S. Highway 66, and numerous all-weather State and county roads traverse the area."

Oct 1, 1945

By S. A. N. Sheya

The U.S. Bureau of Mines performed batch equilibrium contact experiments to examine the ability of activated coconut-shell carbon to adsorb various metal cyanide complexes. Tests were also conducted to determine the effect these cyanide complex impurities might have on the adsorption of gold by the activated carbon. Metal cyanide species included in the investigation were antimony, arsenic, cadmium, calcium, cobalt, gold, iron, mercury, nickel, silver, thallium, and zinc. Tests were made over a pH range of 6.4 to 12.5. The carbon exhibited a preference for gold adsorption over other metals present in solution. In the absence of gold, the metal cyanide complexes were adsorbed; adsorption generally decreased with increasing pH. However, calcium and thallium adsorptions increased with increasing pH, while arsenic and iron were not adsorbed at any pH.

Jan 1, 1989

By G. E. McElroy

"while investigating the presence of heavy strata gases* in certain mines of the East Tintic mining district of Utah, a small, local body of light, very hot gas of high-nitrogen composition was noted in one of the mines. Observations and analyses indicate that this light gas was resulting from very rapid oxidation of finely disseminated pyrite, in lead-silver sulphide ore. The gas was actually mine air which had lost a large proportion of its oxygen content by reaction with the pyrite. This body of gas was hanging in a local high spot about 5 by 5 by 5 feet in size, caused by caving, at the end of a crosscut. Fifty feet from this spot, an air current of 6000 cubic feet per minute was entering the 5 by 7 foot cross-cat from a raise from below.On account of the vapor contained in the gas, the bottom level of the gas could be plainly seen and was practically a horizontal plane, but of slightly wavy appearance, coinciding with the point where an acetylene light was extinguished. This body of gas was visited on three occasions and samples obtained by means of evacaated bulbs and by water displacement. The temperature of the gas was ap¬proximately 175 degrees P. on all three occasions, so that sampling required thick gloves and quick action. Air three feet below the vapor line had a temperature of only 120 degrees F., and a relative humidity of 27 per cent. The stratification of the air and gas mixtures was so sharply defined that the sampler could hold his head a few inches below the vapor level for an appreciable period of time without any noticeable effect other than that due to the high temperature. At one foot below vapor level, it was 135 degrees F., and the relative humidity was 30 per cent. When a candle and an acetylene light were raised into the gas from below, the candle flame was extinguished at a point two inches lower than the acetylene flume, indicating a drop in oxygen content from about 16 per cent to 12 per cent (oxygen content of normal dry air 20.05 per cent) in the distance of two inches."

Sep 1, 1921

By H. P. Greenwald

About mid-December 1936, the safety director of a large coal corporation visited the authors at the Bureau's Experimental coal mine to discuss a rock-dust barrier he had invented primarily for use in trackless entries of coal mines. The rock dust in this device was carried in its original paper containers and means were provided for ripping these open so that the dust might be scattered in the path of an explosion. The inventor termed the device a "bag barrier", and this term has been adopted in the present paper for convenience. At that time the device was in an early stage of development, and the inventor felt that the barrier should be tested to determine whether it had enough promise of being successful to justify further development. The matter was taken under consideration and finally three tests were made during the week of February 15, 1937. It was concluded that while the device did stop an explosion in two of the three tests, it was much loss effective than ordinary rock dusting, and that too few data were obtained to permit direct comparison with tests of other barriers. Apparently, the conditions under which the device could, be successful were somewhat limited, out the limits could not be defined without additional tests.

Jan 1, 1938

By Joseph Blake Smith

Coal resource data from published sources and company files were used by the Bureau of Mines to determine the location and extent of strippable coal reserves in Wyoming. Total strippable reserves of 23 billion tons were estimated in seven major coal areas. Seven large strip mining operations were active in 1969, and their production totaled 45 million tons of coal. Cutoffs used to define strippable reserves were (1) minimum coalbed thicknesses of 5 feet; (2) overburden-to-coal ratios of less than 10 cubic yards of over- burden per ton of coal; and (3) total overburden thicknesses of less than 120 feet, except where reserves occur in multiple beds or a single thick bed. Tertiary rocks along margins of the Powder River basin contain most of the strippable coal reserves in Wyoming. The Wyodak beds, ranging in combined thickness from 30 to 1.30 feet, crop out on the east flank of the basin and contain an estimated 19 billion tons of strippable subbituminous C-rank coals under less than 200 feet of overburden. Partings between these beds total less than 60 feet. The 100- to 200-foot-thick. Healy bed on the western flank of the basin and the 35-foot-thick School and 20-foot-thick Badger beds on the south also contain large strippable reserves. Elsewhere in Wyoming, strippable reserves. Elsewhere in Wyoming, strippable deposits are subbituminous coal of Late Cretaceous and Tertiary ages, mostly in the Hanna and Great Divide basins in the south-central portion of the State and in the Kemmerer-Hamms Fork region in the southwestern corner.

Jan 1, 1972

By Karl E. Starch

This Bureau of Mines report is a background study of severance taxes on mineral production. The rates, bases, and other features of State severance tax legislation as of March 1978 are presented, as are the amounts of State severance tax collections for fiscal year 1977, Some statistical comparisons between severance tax collections, total State tax collections, and total value of mineral production in the States involved are presented to portray the relative importance of severance taxes both in State tax revenue systems and in mineral industry revenues. A general discussion of the purposes and principles of taxation, the unique nature of a mining enterprise, the various types of taxes imposed on mineral production, and the character and rationale of the severance tax and its impacts on mining firms sets the severance tax in perspective. A bibliography of materials on the severance tax is included.

Jan 1, 1979

By P. F. Sands

This U.S. Bureau of Mines report reviews the state of the art in blind pneumatic stowing of backfill in voids in abandoned coal mines. It contains a short history of the development of pneumatic equipment in mining and four recent case histories of blind pneumatic stowing. Limitations of pneumatic stowing in terms of equipment wear, costs, backfill material, and methodology are discussed, and some new procedures and designs are reviewed. A bibliography covering pneumatics in mining is included also. This report provides background for the preparation of a Bureau test program in which the variables affecting the efficiency of pneumatic backfilling will be studied using a full-scale surface test facility.

Jan 1, 1990

By James D. Brown

The Bureau of Mines has written a computer program in FORTRAN to facilitate the calculation of concentrations from X-ray intensities in electron probe microanalysis. Philibert's absorption and Castaing's secondary fluorescence corrections are used; no atomic number correction is included. Background and dead time corrections are applied to the data before calculating the relative intensities. Data from any type of electron probe microanalyzer can be used with the program.

Jan 1, 1965

By Gerald W. Elger

To determine the feasibility of removing nonferrous metal impurities from automobile scrap by thermal treatment in a rotary kiln, the Bureau of Mines conducted four series of tests with synthetic scrap mixtures heated at various temperatures under oxidizing and reducing conditions. The treated scrap mixtures were melted in an electric-arc furnace and cast into small ingots for impurity evaluation. Analyses showed that the ingots were essentially free of residual metal impurities except for copper. Test data indicated that in an oxidizing atmosphere the percentage of copper removed increased with treatment temperature. Percent of copper removed in a reducing atmosphere was found not to be temperature dependent. A significant finding was that copper was embrittled under some of the operating conditions and was mechanically removed by fragmentation.

Jan 1, 1968

By Floyd R. Anderson

Noise control of existing pneumatic drills is difficult and runs into cost, performance and weight penalties. A need exists for a start-from-scratch approach for quiet pneumatic rock drills. The designs based on Leavell Principles which has been successfully used in demonstrating a quiet and vibration free paving breaker, is the concept chosen here. This report shows the feasibility of a quiet stoper for drilling roof bolt holes in coal mines. The work is directly applicable to pneumatic percussive rock drills. The report shows an oscillator based on patented Leavell concepts which results in a vibration free tool and noiseless exhaust. Dynamics of the oscilator is analyzed. Independant rotation of drill rod is provided by an air motor (screw expander) and flushing of cuttings is accomplished by an air ejector in a compact lower housing. The feasibility of no exhaust noise, low drill machine noise, and vibration free casing is discussed.

Jan 1, 1977