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By H. Sakurai, M. Kato, F. Tanaka

The Mitsubishi Continuous Copper Smelting/Converting Process employs an electric furnace (CL- furnace) for settling the slag/matte mixture formed in the smelting furnace. The conditions in the CL- furnace change its settling efficiency, resulting in high variability of copper losses in slag. Modifications of the operation and maintenance procedures for the CL-furnace have significantly and sustainably reduced the copper losses in Gresik smelter to below 0.7%. A series of flow patterns evaluation in the CL-furnace demonstrated how the chemical reactions and settling conditions of the CL-furnace has been improved by the new operating procedures. Settling mechanisms for the matte droplets in the CL-furnace is also discussed using image analysis of solidified slag. INTRODUCTION The Mitsubishi Continuous Copper Smelting/Converting Process employs an electric furnace (CL- furnace) for settling the slag/matte mixture formed in the smelting furnace. Since the top-blowing in the S- furnace agitates the molten bath strongly, matte droplets are dispersed over the slag phase when melts flow out of the S-furnace. Thus, the CL-furnace has an important role to settle and recover matte droplets efficiently. Since many papers have ascribed major part of copper losses to matte droplets suspended in slag (Tanaka 2007; Genevski et al., 2008; Starodub et al., 2016), flow patterns of slag in the CL-furnace can affect greatly on the profitability of smelters which have adopted the Mitsubishi process. PROCESS DESCRIPTION Figure 1 illustrates the Mitsubishi process schematically. The Mitsubishi process is the only system for continuous production of blister copper from copper concentrates and consists of 3 furnaces connected by enclosed launders those ensure the minimum emission of fugitives. In a smelting furnace (S-furnace) copper concentrates are fed with flux, oxygen-enriched air to form a mixture of slag and matte which cascades down to a slag-cleaning furnace (CL-furnace). The CL-furnace settle matte droplets in the mixture on the crucible from which matte is siphoned to a converting furnace (C-furnace), while discharging the cleaned slag (CL-slag). The C-furnace converts matte to blister copper by the top-blowing of oxygen- enriched air.

Jan 1, 2019

By K. Thuro, H. Käsling, C. Wieser, G. Nuijten

"The time-dependent behavior of brittle rocks during stress relaxation is of great interest for mining industry, nuclear waste disposal as well as tunneling and underground construction. Several studies have shown that both elastic as well as inelastic deformation occur during stress relaxation (Emery, 1964; Zang & Berckhemer, 1989). While elastic strain occurs already during the drilling process, inelastic deformation is time-dependent and can endure for hours, days or weeks. To investigate the evolution of microcracks during core relaxation, two crystalline core samples were recovered from high in situ stress conditions in Europe’s deepest mine in Pyhäsalmi (Finland). Samples were prepared for testing within one hour after coring such that a large portion of the time-dependent component of relaxation could be recorded over several days using ultrasonic velocity as well as acoustic emission (AE) measurements.Results from AE analysis show an exponential decrease in the number of events over a period of several hours. Repeated sudden increases of acoustic events can be related to the propagation or the interaction of cracks. In the first hours of recording also the signal energies reached the highest values and the increases in signal energy correlate well with increased event rates. On additional drill cores, P-wave velocities were measured parallel and in 45° distances perpendicular to the core axis. After core recovery, stress-induced microcracking caused an exponential decrease in wave velocities similar to AE rates. Lowest compressional wave velocities were measured parallel to the core axis and thus normal to the foliation and in the direction of the maximum in situ stress component. The highest measured velocities occurred parallel to the foliation plane. Within the samples, the anisotropy ratios were up to 1.37 at the beginning of the measurements and increased to values of up to 1.8 after 45 days. The wave velocity anisotropy is in agreement with the in situ stress orientations."

Jan 1, 2015

By L. Voisin, G. Damm

"In order to develop a new pyrometallurgical process for eliminating detrimental arsenic and antimony from the impurity-rich matte produced from copper concentrate, and for treating the occasionally generated speiss in nonferrous smelting processes, the phase relations in the Fe-Cu-S-As-Sb system saturated with carbon at 1473 K were investigated. The distribution of elements between the condensed phases at the miscibility gap, where three equilibrated phases of iron-rich alloy, copper-rich alloy, and matte coexist, were also studied. The investigation was carried out by performing a series of laboratory scale experiments in an electrical furnace at 1473 K, followed by a quenching method on the final stage. The samples obtained from the experiments were analyzed by using Inductively Couple Plasma (ICP), Atomic Absorption Spectroscopy (AAS) and Carbon Infrared Spectrometry (CIS) techniques.The results were compared with previous investigations for the Fe-Cu-S-As-C and Fe-Cu-S-Sb-C systems and discussed on the basis of the molar fraction distribution for both arsenic and antimony in the matte phase at five different matte grades. It is expected that by using this phase separation technique it might be feasible both, the cleaning of a complex copper matte and the elimination of arsenic and iron together with an acceptable amount of antimony into the iron-rich alloy phase, which can be discarded as a harmless and smaller deposit."

Jan 1, 2014

By W. P. Nash, T. E. Mccandless

"Abstract - Detrital minerals of upper mantle origin occur in Holocene conglomerates, pediments and antmounds, and in Oligocene conglomerates in the Green River Basin of southwestern Wyoming. The minerals are derived from disaggregated eclogite and peridotite, and are similar to minerals found in mantle- derived igneous rocks such as kimberlite and lamproite, the primary host rocks for diamond. The Green River Basin bisects the lamproite fields of the Leucite Hills (Wyoming) and Kamas (Utah) and overlies the Archean Wyoming craton, which makes the region favorable for diamond occurrence. Lamproite is the favored host for the indicator minerals because unusual high-Fe salitic diopside macrocrysts from the antmounds and from the ~1 Ma old Leucite Hills lamproites to the northeast are compositionally identical. The salitic diopside is uncommon in other igneous rocks and could be a new indicator mineral for use in lamproite exploration. The Green River Basin indicator minerals are eroded from the ~29 Ma old Bishop Conglomerate, whose source area is the Uinta Mountains to the south. No continuous mineral train exists between the Uinta occurrences and those in the Green River Basin. Assessment of the minerals using established and new geochemical criteria indicate that they formed in an oxidizing upper mantle and were transported to the surface by either kimberlite or lamproite. The existence of cogenetic diamond is unlikely based on the mineral chemistry, but selective removal of diamond indicator minerals through weathering and fluvial transport cannot be excluded. Diamonds and mantle garnets are present in the northeastern Uinta Mountains, but they originated as part of the Diamond Hoax of 1872. A representative mineral assemblage from the true igneous host of the indicator minerals is required to fully establish their economic potential. Post-Oligocene erosion and Pleistocene glaciation have hindered efforts to locate a bona fide igneous source for the indicator minerals. Résumé - Des minéraux détritiques provenant du manteau supérieur ont été trouvés dans des conglomérats, des pédiments et des monticules de fourmis de l’Holocéne, et dans des conglomérats de l’Oligocène du Green River Basin, au sud-ouest du Wyoming. Ces minéraux sont issus du démantellement d’éclogites et de péridotites, et sont semblables aux minéraux trouvés dans des roches ignées provenant du manteau, comme les kimberlites et les lamproïtes. Ces dernières sont les roches hôtes du diamant. Le Green River Basin recoupe les champs à lamproïte de Leucite Hills, au Wyoming et de Kamas en Utah, et il surmonte le craton archéen du Wyoming, connu pour la présence de ses diamants. La lamproïte est l’encaissant privilégié pour les minéraux «indicateurs» parce que des macrocristaux exceptionnels de diopsides salitiques riches en Fer, provenant des monticules de fourmis et des lamproïtes de Leucite Hill (~1 Ma), au nord-est, ont des compositions identiques. Le diopside salitique est rare dans les autres roches ignées et peut être un nouvel indicateur dans la recherche de lamproïte. Les minéraux «indicateurs» du Green River Basin proviennent de l’érosion du Conglomérat de Bishop, daté de ~29 Ma, dont la zone source est représentée par les Uinta Mountains, au sud. Aucune continuité des gisements minéraux n’existe entre les affleurements de Uinta et ceux du Green River Basin. La détermination des minéraux, utilisant des critères géochimiques anciens et récents, indique qu’ils se sont formés dans un manteau supérieur oxydant et qu’ils ont été remontés à la surface soit dans des kimberlites, soit dans des lamproïtes. La genèse du diamant n’est que peu liée à la chimie minérale, mais le lessivage d’indicateurs minéraux du diamant par altération météorique et par transport fluviatile ne peut être exclu. Des diamants et des grenats mantelliques sont présents dans le nord-est des Uinta Mountains, mais sont associés avec le Diamant Hoax de 1872. Un assemblage minéral représentati"

Jan 1, 1996

By D. R. BUDINSKI

Clinton Creek Mine in west-central Yukon produced 0.94 million tonnes of fibre from 15 million tonnes of asbestos ore between 1968 and 1978. The mine closed in 1978. The deposit lies along the margin of a medium sized ultramafic pluton that intrudes schistose and gneissic rocks of the Yukon Metamorphic Complex. Country rocks are metamorphic equivalents of a mixed sedimentary and volcanic assemblage deposited during Precambrian or early Paleozaic time. Movement along the north west-trending Tintina Fault System probably caused the fairly high meromorphic grade that altered the original rocks to schists and gneisses. The ultramafic pluton hosting Clinton Creek Mine is one of several bodies that were emplaced along a deep seated imbricate fault system parallel to the Tintina Trench. Most of rhe intrusions were hydrothermally altered to serpentinite, bur apparently only the one at Clinton Creek contains commercial quantities of asbestos. The Clinton Creek pluton was probably injecred slowly at relatively low temperatures into the crustal rocks as a "mush" that cooled gradually, allowing sufficient time for serpentinization and chrysotile fibre crystallizarion.

Jan 1, 1984

By Mel Torrie

1 Want access to low level vehicle data so 3rd party apps can be applied as desired 2 Hardware Agnostic (COTS plug and play) 3 Common/Open protocols that facilitate integration and the coexistence of a variety of applications on a variety of equipment 4 Minimum computer hardware footprint 5 Technology Independence (including comm. backbone)

May 1, 2013

By Marco Quirion

The Daniel-Johnson dam, formerly named Manicouagan-5 (Manic-5), is located 800 km northeast of Montreal (Quebec) in Canada. This is the largest multiple-arch concrete dam in the world consisting in 13 arches and 14 buttresses. Since its construction in 1969, various type of cracks have appeared on both downstream and upstream faces of almost all the arches of this concrete dam. As a part of the Daniel- Johnson’s dam safety assessment program, Hydro-Québec is currently performing structural analysis of the dam with advanced numerical models to better understand and predict the dam behaviour. Because the buttresses transmit all the arch loads to the rock mass, determination of the properties of the dam foundation should not be neglected in dam global safety analysis and also to insure that reliable input parameters are used in the dam numerical simulations. This paper summarizes the past and the more recent investigations of this foundation used to assess its safety and stability. Moreover, the use of rock mass classification to estimate the deformation modulus, based on empirical equations, gives values in the range of 30 to 40 GPa that are higher than expected values. Using those values in the numerical simulations for dam structural analysis gives an excellent correlation with displacements monitoring of the buttresses.

Jan 1, 2015

By Maria Skyllas-Kazacos

The All-Vanadium Redox Flow Battery that was pioneered and has been developed at the University of New South Wales (UNSW) in Sydney since the mid-1980s is currently regarded as one of the most attractive energy storage systems for large-scale implementation in a wide range of grid-connected and offgrid applications. Several companies are now manufacturing and installing MW-scale VFBs in applications ranging from renewable energy storage, load-levelling, emergency back-up power and power arbitrage. The full-scale uptake of the VRB in commercial energy storage systems however, is heavily dependent on the availability and cost of vanadium used in the VRB electrolyte. Cost is also a function of purity requirements and although there is little scientific evidence on the effect of impurities on the VRB life and performance, VRB developers continue to demand high purity vanadium at considerable cost. This paper will provide a brief overview of the current understanding of electrolyte impurities on VRB performance together with an economic analysis of the impact of vanadium prices on overall VRB capital and levelised costs for a range of applications.

Jan 1, 2014

By E. H. Kranck

Introduction Baffin Island is still too in-accessible to be of interest to the mining industry. However, twenty years ago few people dreamed of mining iron ?ore in Labrador. A journey by air to the most remote places in the Arctic is today no more remarkable than a trip to Europe, and the technical difficulties of mining minerals of high value are not insurmountable. Some ?observations concerning the geology and mineral possibilities of Baffin Island, the largest of the Arctic islands, may therefore interest the members of the Institute, in spite of problematic practical value of the subject. The following short account is mainly based on observations made during the Baird Expedition of the Arctic Institute of North America last summer 1950), and on information available from earlier expeditions. Early Work Baffin Island was one of the first parts of Canada to attract prospectors. Frobisher sent a shipload of rocks, which he believed contained precious metals, from Baffin Island to England. This attempt, however, was a failure and no further serious prospecting work has, so far as I know, been done. During the past few years geological mapping has been carried out by the Geological Survey of Canada (Fortier. Davison, 1949-1950) in the southern parts ?of the island, along the coast of Hudson strait. In 1942, Weeks mapped the coast from Pangnirtung to the head of Cumberland fiord, and Netteling river up to Netteling lake. In the northern parts of the island, only scattered observations have been made ?by Bell, Watkins, Baird, and others.

Jan 1, 1951

By Nadarajah Nanthananthan

Mine backfill has been widely used as a means of ground support. While proper design of backfill is important to ensure ground stability, understanding the failure mechanism and the various influencing factors in a filled block is essential. This paper presents a modified sliding failure model of a confined backfill block. The model considers both the gravity load of the backfill itself and the overlying load from fragmented ore or backfill on the top. A series of new equations were derived and the relationships between factors such as factor of safety, friction angle, cohesion and the exposed stope height were developed. This modified model will be a very useful tool in backfill design, for example, to optimize the design of backfill for a given stope geometry or to determine the maximum backfill height for a particular type of backfill.

May 1, 2007

By Norman M. P. Low

"IntroductionIndustrial applications of mica utilize two commercially important varieties of mica: muscovite and phlogopite. Muscovite mica is a potassium mica with a general chemical formula, H2KA1(Si04)3 h, and is sometimes referred to as a potas hsilicate. Phlogopite is a magnesium mica having a general chemical formula, H2KMgSi(Si04)3, and is distinguished from the muscovite mica by its decomposition in sulphuric acid.Canada is one of the major natural mica producers in the world. A large tonnage of the mica powders is at present mined and processed in the Eastern Townships of Quebec. This Canadian mica is of the phlogopite type. A closely related mineral of the mica family which is widely used in the construction industry is vermiculite. It is a dehydrated magnesium-aluminum-iron silicate characterized by a foliated structure. Expanded vermiculite, which is often referred to as exfoliated mica, is used as many types of thermal and acoustic insulation, as loose fill in buildings, as an aggregate in concrete, as an ingredient in plaster and insulating concrete , and in fire-proofing compositions. Natural phlogopite and muscovite mica powders are used extensively as reinforcing agents in organic polymers. They also have a wide range of applications in commerical products. For example, dry-ground mica powders are used in large tonnage as a surface finish in roofing materials and as a bonding agent in wallboard joint cement. Common products such as paint, rubber, plastics and welding rods contain mica. Recent studies have also shown that mica powders can be added to portland cement in the preparation of concrete products, as they could improve the tensile strength of the concrete products. The potential and possible"

Jan 1, 1982

By S. Pinard, A. Desbiens, R. del Villar, D. Jakelski

"During the fall of 1993, a new Pill-based control strategy was installed in the B grinding circuit at the Kidd Creek Division of Falconbridge Ltd. The control strategy was first evaluated on a grinding circuit dynamic simulator (DYNAFRAG), which permitted the discrimination between more than a dozen possible control alternatives. Once the final choice was made the necessary instruments were purchased and installed. The control strategy was configured on the plant computer and is planned to be commissioned shortly.This paper summarizes the control strategy, the design procedure, the installation and the controller tuning. Some preliminary problems posed by the process prior to implementation are also presented.IntroductionIn 1990 the GRAIIM (french acronym for Research Group on Computer Applications to the Mineral Industry) of Laval University started a research project on Knowledge Based Automatic Control (KBAC). This project is sponsored by a consortium of eight mining companies under the umbrella ofMI1EC (Mining Technology Council of Canada), the Quebec Mining Association (AMQ), CANMET and the Centre de Recherches minerales (CRM). The project also benefits from important grants from the Ministere de l'Education Superieure et de la Science and the NSREC-CRD program.The main objective of this project is the screening of advanced (knowledge-based) methods for data processing (filtering, mass balancing, etc.) and automatic control (model-based control) for their use in the mineral processing operations. The project also aims at transferring these tools to the industrial partners through annual workshops for plant engineers, annual symposia, and through specific in-plant projects where the participation of plant engineers is strongly encouraged.The main objective of this project is the screening of advanced (knowledge-based) methods for data processing (filtering, mass balancing, etc.) and automatic control (model-based control) for their use in the mineral processing operations. The project also aims at transferring these tools to the industrial partners through annual workshops for plant engineers, annual symposia, and through specific in-plant projects where the participation of plant engineers is strongly encouraged."

Jan 1, 1994

By Robert B. Parsons

"This month, Tax Notes focuses on two features which can potentially ""dress up"" a new issue of common shares to make the shares more attractive to investors. Attaching warrants to a share issue is a relatively common practice, and recent years have seen an imaginative variety of different kinds of warrants, some of which can be subject to somewhat different tax treatment . A less common financing strategy which certainly deserves some consideration involves the possibility of utilizing ""Share Purchase Tax Credits "" in conjunction with a new share issue.IntroductionPrevious subjects covered in Tax Notes have dealt with flow-through shares and other tax angles which can make equity issues more appealing to potential investor s. Two other techniques which can add zest to a new stock issue involve the utilization of warrants and ""share purchase tax credits"" (or SPTCs). This article takes a brief look at the better known subject of warrants and the lesser known matter of SPTCs.Of course, this paper presents only a relatively general summary of the income tax implications of warrants and SPTCs, and is not intended to be a definitive commentary on all of the detailed and complex tax issues that might be relevant in the circumstances."

Jan 1, 1985

By C. Bourgoin

"The limited development and application of new technologies to narrow-vein mining is currently impeding progress in the industry to a point where productivity, working conditions and operating costs have reached a critical stage in many Canadian mines.In an effort to foster the emergence and application of new technologies, Université Laval, together with other organizations, has carried out a R&D project focussed on the need of identifying new development pos5ibilities and of facilitating the transfer of technology in matters related to underground mining methods and machinery.The first phase of the study consisted of an in-depth assessment of current practices and problems in narrow-vein mining. The second phase was a state-of-the-art survey of mining methods and equipment, together with proposed modifications and innovations. The third phase of the project concerns the experimental development as well as the principal application of various proposed technologies.This paper presents an overview of the organizational, technical and strategic considerations which guided the University group and it serves as well to introduce a newly-published brochure, entitled ""Underground Mining Techniques of Vein Deposits"", which summarizes such work to date. More specifically, a perspective of technological developments applicable to narrow-vein mining is presented."

Jan 1, 1994

By Miguel A. Cuba

Resource models are generally constructed using data of different types and/or from different sources. A common issue is the consistency of scale in the information that often leads to a requirement to composite the data prior to model construction. For the purposes of mine planning, development and/or resource assessment, this model may then be upscaled to a relevant selective mining unit. It is well established that the geostatistical parameters for resource model construction is scale dependent. In particular, the volume variance of integrating these various scales has a direct impact on the variogram that should be used in model construction and/or the assessment of volume variance relations as it affects resource estimation. The scaling laws are a set of guidelines that detail how the variogram should change as a result of a change in the volume; these laws are empirically derived and involve some simplifying assumptions, not the least of which is an assumption of shape invariance in the variogram structure. An alternative approach was proposed to directly upscale the variogram via numerical integration, which demonstrates that the assumption of shape invariance is not required and we can directly access the new variogram shape given any volume of interest. This paper compares these two different approaches to variogram upscaling by considering two applications: the first corresponds to a 2D synthetic case and the second looks at a 3D case with data from a porphyry copper deposit. The simulation studies in these cases show that the direct upscaling approach performs better than the scaling laws in fitting the average experimental variogram values at any block size. This is based on a mean absolute error criterion. Moreover, it is also shown that with an increase in the block size, direct variogram upscaling significantly outperforms the scaling laws approach.

Oct 1, 2009

By Kenneth L. Graham

Horizontal directional drilling from existing underground workings will greatly reduce, if not replace, surface exploration drilling. Diminishing ore reserves along with increasing difficulty in acquiring access and permitting of drilling surface holes requires a change in procedure. The length and direction of the required long holes is site specific, but once determined could be quickly mobilized. Data would be available for a much more timely evaluation without any surface disturbance and required reclamation issues. Preplanned directional drilling from underground will also provide an evaluation of already inconsistent uranium deposits located under surface terrain that is inaccessible to surface drilling.

Aug 1, 2010

By C. Groccia

As the search for new ore bodies drives mines to be developed at greater depths, the associated high stress environments present challenges for rock support design. Excavations in highly stressed brittle rock are often subject to large volume increases due to rock failure, a phenomenon known as rock mass bulking, which can result in significant wall convergence. Support systems need to be designed to minimize the amount of bulking and to accommodate large wall convergences. In order to design such a support system, empirical guidelines are often used to predict the amount of bulking. However, the empirical guidelines that are currently available are based on a limited number of case studies and consider few input parameters, which may result in an inaccurate bulking assessment. This paper describes methods of collecting quantitative field data at Creighton mine in Canada to better understand rock mass bulking and to further develop the empirical guidelines for bulking assessment for tunnels in highly stressed grounds. Measuring

Aug 1, 2013

By D. K. Sarkar, Jiawei Xiong

"Self-assembled monolayers (SAM) on the aluminum substrates are used as the adhesion promoter between two aluminum substrates when bonded with the adhesive in adhesive bonding technology. Traditional surface analysis tools are not capable of identifying the presence of SAM on a surface; therefore, EIS has been used to determine their presence on the aluminum substrates. In this study SAMs have been deposited on aluminum using the monomer of (3-Glycidyloxypropyl)trimethoxysilane (GPTS) organosilane. AA6061 aluminum alloys substrates were chemically cleaned with NaOH and HNO3 to remove the native oxides, followed by immersion in silane solutions. In a second method, SAMs were prepared by applying a spin coating of silane solution to the samples. The prepared SAM coated aluminum samples were analysed by EIS in the three electrode corrosion cell using a diluted alkaline solution. The impedance of the SAM coated aluminum is found be higher than the as-received aluminum. It has been also observed that the open circuit potential (OCP) of the SAM coated aluminum is higher than the as-received aluminum. Both elevated values of the impedance and OCP confirm the presence of SAM on aluminum.INTRODUCTIONSelf-assembly (Schreiber, 2000) is defined as the spontaneous formation of complex hierarchical structures from pre-designed building blocks, typically involving multiple energy scales and multiple degrees of freedom. Generally speaking, SAMs are created by the chemisorption of ""head groups"" onto a substrate from either the vapor or liquid phase followed by a slow organization of ""tail groups"" of a molecule. Typically, head groups are connected to a molecular chain in which the terminal end can be functionalized with groups such as –OH, –NH2, –COOH, or –SH to vary the wetting and interfacial properties (Chauhan et al., 2007; Ulman, 1996; Vashist, Lam, Hrapovic, Male, & Luong, 2014). Though there exist several methods to prepare SAM (Chauhan et al., 2007; Chen, Yang, & Zhang, 2014; Cho, Park, Jon, & Choi, 2007; Igor Luzinov, 2000; Reis, de Melo, & Costa, 2006; Song, Zhai, Wang, & Jiang, 2006; Sugimura, Hozumi, Kameyama, & Takai, 2002; Vashist et al., 2014), the two methods vapor phase (Song et al., 2006; Sugimura et al., 2002) and solution(Chen et al., 2014; Igor Luzinov, 2000) are commonly used. Recently, many articles have been published on the fabrication of superhydrophobic surfaces with SAM technology (Cho et al., 2007; Pan, Shen, Shang, & Xing, 2012; Siddaramanna, Saleema, & Sarkar, 2014; Song et al., 2006). Brassard, Sarkar, and Perron (2011) successfully obtained a superhydrophobic film by applying fluoroalkylsilane via self-assembly on monodispersive silica. SAMs are also reported as good candidates for anti-corrosion and adhesion promotion (Chen et al., 2014; Saleema, Sarkar, Paynter, Gallant, & Eskandarian, 2012). However, papers on the characterization of SAM properties are rarely seen. The most commonly used substrate for SAM is silicon and the method implemented is scanning probe microscopy (SPM) such as atomic force microscope (AFM) (Igor Luzinov, 2000; Moores, 2011; Zhang, 2003, 2005). Igor Luzinov (2000) analyzed the epoxysilane SAMs’ surface morphology and microstructure properties using scanning probe microscopy (SPM) and ellipsometry on single-crystal silicon wafers. SAMs have been used to improve the adhesion bonding of aluminum or plastics but no characteristic data have been presented yet (Saleema et al., 2012; Telegdi, 2007; Wang, Xu, Luo, Wang, & Wang, 2009). Recently, Reis et al.(Reis et al., 2006) have studied SAM of alkane diphosphonate (Gardobond X4661) on Al 5052 alloy samples by EIS in a naturally aerated sodium sulfate solution."

Jan 1, 2016

By Louise Corriveau

Exploration strategies have traditionally considered felsic gneiss complexes of the Canadian Shield sterile. This paradigm is challenged with the discovery of extensive granulite-facies Cu-Au, Fe oxides-bearing hydrothermal systems in the 1.4 Ga Bondy and 1.5 Ga La Romaine volcano-plutonic complexes of the Grenville Province. Early identification of magnetite-rich units in association with meta-exhalite and pelite-like units was key to targeting the search for mineralization, protolith information and indicators of pre-metamorphic hydrothermal activity during regional surveys of these frontier terrains. Textural evidences for a volcano-plutonic setting were found. There remained, however, numerous impediments to the recognition that the ubiquitous magnetite-laden units and associated aluminous gneiss were hydrothermal in origin. Many metamorphic reactions form magnetite at the amphibolite to granulite facies transition, and hydrothermally-leached rocks resemble metapelite or migmatitic restite, while carbonate alteration zones may look like marble or calc-silicate rock. Non-typical metamorphic mineral assemblages, modes and colours arise when hydrothermally-derived rock types are metamorphosed. These effective markers served as tools for reliable field identification of hydrothermally-altered rocks. In our case-studies, we traced pre-metamorphic hydrothermally-driven Fe-oxide precipitation in association with sericitization, albitization, pyrophyllite alteration, chloritization, and B enrichment by mapping unusually high contents of (1) magnetite or hematite, (2) biotite, (3) albite, (4) sillimanite, (5) orthopyroxene or phlogopite with cordierite, and (6) tourmaline or kornerupine. The unveiled garnetite, tourmalinite, and aluminous gneiss had assemblages that vary according to metamorphic grade and composition. To assess if high mode of Fe-Mg-Al phases resulted from partial melting (restitic residue) or metamorphism of hydrothermal rocks, we compared leucosome mineral assemblages, shape and amount with that expected of in situ partial melting reactions. In both areas there is no compelling evidence for these units to be restites. In contrast, the presence of lapilli in garnet-cordierite-sillimanite gneiss, though extremely rare, constitutes conclusive evidence for extreme pre-metamorphic high-sulphidation alteration of a volcanic protolith, while Fe-oxides or sillimanite-bearing nodules and veins record a less pervasive alteration. Geochemical research on element mobility and mass balance calculations further testified of an hydrothermal origin for these gneisses. The magnetite-rich units, together with calc-silicate rocks, garnetite, hornblendite, albitite among amphibolite, provided effective guides to sites of fluid discharge and led to the discovery of Cu and Cu-Au showings. With the presence of highsulphidation alteration, these features suggest early Cu-Au VHMS-type alteration halos within a predominantly felsic composite volcano-plutonic arc setting for both case-studies. Evidences for subsequent F-driven orthomagmatic fluid activity are also present.

May 1, 2003

By P. C. Sui

Numerical investigation and parametric simulations of the coupled electrical conduction and mass diffusion in the GDL of a PEMFC are reported. The coupled transport is solved using a 2D, "under-the-rib" computational domain for the cathode GDL. The current density on the GDL/catalyst layer interface, which constitutes one of the boundary conditions for the GDL domain and reflects the activation overpotential in the catalyst layer and the ohmic loss in the membrane, is solved iteratively using a novel numerical algorithm. A parametric study is performed to investigate the effects on current density distribution of various operating conditions such as oxygen concentration and membrane resistance, and of design factors such as GDL geometry, anisotropic transport properties, and deformation under the land area. The results show that the current density distribution under the land area can be dominated by either electron transport or mass transport, depending on the operating regime.

Jan 1, 2005