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By M. R. Henzinger, W. Schubert

"The quality of the backfill applied at a shield driven tunnel is of significant importance failure of the lining. The used material also affects the interplay between support and excavation behaviour.In this research the state of the actual bedding situation is investigated by an analytical approach, laboratory tests and numerical simulations. The numerical simulation using continuum methods have shown shortcomings. These shortcomings regarding the instability of large strain simulations restrict the possibility to reproduce the relocation of the backfilling material. The performed scaled model tests have shown that the regripping process of a double shielded tunnel boring machine affects the soil failure within the gap. With the analytical results the influence of the wall friction can be predicted. Therefore the angle of the failure surface can be determined. The results have shown that the wall friction significantly increases the failure angle. INTRODUCTIONFor tunnel boring machines (TBM) with single (SM) or double (DSM) shield, precast liningsegments are used as rock support. These segmental linings are installed within the protection of the TBM shield. In order to reduce the friction while advancing, the shield diameter is smaller than the diameter of the cutter head and therefore also smaller than the excavation boundary. The difference depends on the expected radial convergences. Since the lining segments are mounted within the shield the steering gap between the shield and the excavation boundary increases and is hereinafter called annular gap.In the process of tunneling in hard rock, the annular gap is usually filled with fine grained and closely graded gravel, termed as pea gravel. The backfilling process starts as soon as possible after the shield tail passes the lining. Due to the operational procedure within the working area of a TBM, a fully backfilled annular gap might not be established after every ring closure. This leads to an unfavorable distribution of the pea gravel leaving the segmental lining partially without bedding. Segmental linings can develop sufficient resistance only when properly bedded."

Jan 1, 2015

By O. Laitinen, M. Rudolph, J. A. Sirviö, H. Liimatainen, R. Hartmann, University of Oulu

The increasing complexity of the ores composition worldwide calls for suitable collectors with specific properties, such as selectivity, wettability, and in regard to current regulations, environmental sustainability. Therefore, collectors have to satisfy many features to improve the efficiency of flotation processes. Cellulose nanocrystals gain more and more interest due to the versatile synthesis routes which enable the integration of specific functional groups and components with different degrees of hydrophobicity within the molecular structure. Consequently, cellulose nanocrystals can be employed in flotation processes as depressant or collector molecules, respectively. Nonetheless, the usage of cellulose nanocrystals is still limited due to a lack of the characterization of nanocrystal-mineral interactions and the change of the surface wetting properties of minerals after adsorption phenomena between nanocrystals and minerals. In these studies, butyl-amine cellulose nanocrystal (BAC) and quartz are used as model system to investigate physicochemical properties of both, BAC and quartz, and examine the applicability of BAC in flotation processes. Therefore, the surface charge distribution and electrophoretic mobility of BAC and quartz are investigated and compared to understand the effect of electrostatic interactions between BACs, and BAC and quartz. Based on this, the adsorption of BAC on quartz is examined. Finally, microflotation experiments test the efficiency of BAC to be used in flotation processes. The flotation response is correlated to the specific surface charge of BAC revealing the dominant effect of surface charges on effective particle-bubble adhesions.

Jan 1, 2016

By I. C. Brown, J. F. Henderson

"IntroductionThe Yellowknife greenstone belt lies along the west side of Yellowknife bay on the north shore of Great Slave lake, some 600 miles north of Edmonton, Alberta. The producing gold mines along the belt include the Con-Rycon and Negus which came into production in 1938 and 1939, and the Giant Yellowknife, which followed in 1948. In addition to these, the Akaitcho and Crestaurum mines are potential producers and there are several promising prospects.Early geological work along the belt was done by A. W. Jolliffe who first recognized a number of great faults, the largest of which is the West Bay fault with a horizontal movement of more than 3 miles. In 1943, A. S. Dadson, following an examination of the Giant-Yellowknife property, advanced the hypothesis that Baker Creek valley was underlain by a series of major gold-bearing shear zones. Subsequent diamond drilling in 1944 bore out the correctness of this view and outlined the great ore-bearing shear zones that are now being developed and mined by Giant Yellowknife Gold Mines. Near the south boundary of the Giant property, the shear zones are cut off by the West Bay fault. This prompted Neil Campbell, District Geologist for the Consolidated Mining and Smelting Company, to make a detailed study of the geology along the West Bay fault in the hope of finding the faulted extension of the Giant shear-zone system on the west side of this fault. In this he was entirely successful. By careful geological mapping he matched several faulted diabase dykes on both sides of the fault and, knowing their dip, determined the horizontal and vertical components of movement along the fault. Subsequent •diamond drilling based on Campbell's work located the presumed correlative of the Giant shear-zone system on the Con-Rycon and Negus properties, where it has been named the Campbell zone or system. At the present time, all production at the Negus Mines property is coming from orebodies along the Campbell zone."

Jan 1, 1950

By Rolf Andreas Lauten, Guy Kluck

"Formation of scales may have important detrimental effects in many mineral processing applications. A well-known problem is the need for frequent maintenance to remove scale from processing equipment. Another challenge may relate to encapsulation of valuable minerals in precipitating scale. In this work, we explore the ability of some crystal growth inhibitors to prevent or lower the degree of scale precipitation. In many situations pregnant leach solutions contains substantial concentrations of calcium, magnesium, sulfate and carbonate in addition to dissolved valuable elements, e.g. gold, copper, zinc. Together with non-dissolved gangue minerals, some slurries may also contain particulate gold, copper etc. During normal processing of the pregnant leach solution it may be exposed to temperature gradients or similar promoting precipitation of various scales. Valuable minerals may become entrapped in precipitates and thus become inaccessible to the lixiviant. Use of a crystal growth inhibitor may lower the degree of encapsulation of valuable elements.Using a simple model system, supersaturated with respect to gypsum, the effect of some crystal growth inhibitors on the prevention of scale is evaluated in terms of amount precipitated gypsum, the particle size of the precipitated gypsum and the carbon gold loading capacity.INTRODUCTIONGold bearing sulfide ores are often roasted or pressure oxidised prior to leaching. The purpose of this unit operation is to prevent loading the leaching circuit with sulfides that consume cyanide. Pressure oxidation or roasting chemically converts the sulfides into sulfates and at the same time, the pH of the slurry ends up in the acidic range. Typically, lime addition is the preferred means to raise the pH to around 10 where gold leaching takes place. Combination of large amounts of calcium ions from the lime with sulfate ions from the ore induces precipitation of gypsum. Compounds like calcium carbonate may also precipitate if carbonate ions are present in the slurry. Depending upon the composition of the ore, compounds like calcium carbonate and other types of scale may also precipitate on gold surfaces on the slurry particles. A layer of scale on top of exposed gold surfaces will prevent dissolution in the cyanidation that takes place during leaching. Naturally, such a precipitation may lower the gold recovery."

Jan 1, 2016

By T. Patching

"COAL MINING at Canmore, Alberta, began in 1886 and continued there until July 1979. A comprehensive review of the Canmore operations is not available, but the following notes have been prepared to accompany references where more complete information about the operations and problems encountered may be found. The coal measures at Canmore occur in the Kootenay formation of Lower Cretaceous age, and at least twelve seams of varying thickness and horizontal extent have been recognized. The coal, of high quality, ranges from semi-anthracite in the lower seams to low-volatile bituminous in the upper seams. The strata of the Canmore area form an asymmetric syncline, the western limb being overturned to vertical by the Palaeozoic strata of the Mount Rundle Range. The eastern limb is more gently sloping, its dip ranging from IO to about 40 degrees. Tectonic movements have created a troubled and complex coal field. The seams were initially not regularly or uniformly deposited, and mountain-building activity folded and faulted the strata and in many places sheared and crushed the original structures of the coal(l,2,3,4,5). The lack of continuity of the seams, and changes in thickness and inclination, made longrange mine planning difficult and necessitated flexible methods of work, and the local disturbances sometimes created problems in roof support and contributed to the occurrence of sudden outbursts of coal and gas. Almost all of the coal was produced from underground operations but a few relatively small V-cut mines were worked along surface outcrops. These have all been filled in and revegetated. The basic method of underground work was by room-and-pillar, but many variations in layout and sequences were employed. Gangways were driven along the strike and pillars were formed by raises or slopes and crosscuts. Pillars were recovered to the extent that ground conditions permitted by splitting or taking 'skips' from the sides of the raises or splits or crosscuts. Because of the variety of conditions that existed in the field a considerable range of cutting, loading and support methods were employed, including hand-loading, slushers and scrapers, duckbills and shaker conveyors, mobile loaders and continuous miners. Except for the coal obtained by continuous miners most of the coal was broken out by blasting when driving narrow working places or by air picks when cutting from a face. In the early years hand loading onto cars or conveyors predominated. A continuous miner was introduced into Canmore in 1959 on a trial basis, and another was subsequently acquired, in order to minimize blasting and hand loading, but problems in operating these machines in inclining seams and difficulties in providing safe roof support for the machines and workers restricted their efficient use. Another major difficulty with the use of continuous miners was the problem of ventilating development headings in the very gassy conditions. In the early 1970s they were replaced by electric and compressed air slushers and scrapers, resulting in a general increase in productivity, roof control, safety, and flexibility of operations(1.6,7,8.9)."

Jan 1, 1985

By G. A. McGuffin

"IntroductionWITH the increase in quantity of sour gas reserves in the Province of Alberta, and the wider market for sulphur brought about by mounting world demand and restrictions placed on the principal supply, it was inevitable that this important source of sulphur would be .developed. In the light of these facts, it seems timely that a general paper on sulphur recovery from petroleum gases be presented. This, then, is the purpose of the following text. A short discussion of each of the following subjects is presented:(1) Properties and uses of sulphur(2) Existing sources(3) Market research(4) The recovery process in Turner Valley(5) Hazards of sulphur productionNo pretext of originality of material is made since innumerable reports have been prepared on this and related topics and information contained in these has been used quite liberally.Properties and uses of SulphurSulphur is a non-metallic element having an atomic weight of 32.06. The stable crystalline form at atmospheric temperature is referred to as 'rhombic' sulphur. It is bright yellow and has a specific gravity of 2.05, equivalent to 129.2 lb./cu. Ft. Above 204°F. sulphur has another stable crystalline form, referred to as 'monoclinic'. This is reddish-brown and is slightly less dense than the rhombic variety (122.4 lb./cu. Ft.). Sulphur in bulk form weighs 84 to 90 lb. per cu. Ft. Sulphur melts at approximately 240°F. to a straw coloured liquid which is quite viscous."

Jan 1, 1952

By J. E. Hawley

"The property of Francoeur Gold Mines, Limited, lies directly west of the Armfield mine in Beauchastel township, Abitibi district, and 12 miles west and slightly south of Noranda. The gold deposits are of particular interest because of their replacement character and close association with fault zones. The property was originally staked in 1923 following the discovery oi a mineralized zone near the eastern boundary. This became No. 1 orebody. Later discoveries in 1936 of No. 2 and No. 3 orebodies led to underground development and actual mining in July, 1938. A fourth orebody, No. 8, was found in 1939.The following is the production record up to December 31st, 1947:Beginning in September, 1944, ore was shipped to Noranda as siliceous flux, but late in 1946 milling of low-silica ore from No. 1 orebody was undertaken until operations were temporarily suspended in 1947.The four main ore deposits, Nos. 1, 2, 3, and 8, consist of siliceous ferrocarbonate and albite replacement bodies mineralized with fine pyrite and specularite in schistose fault zones in Keewatin volcanics. Barren to low grade quartz veins though present in some are uncommon, but small stringers of quartz are usually present wherever here and there visible gold is found. Nos. 1, 2, and 3 deposits lie in a major fault zone that extends completely across the property from west to east (over 7,000 feet) and dips N.40° to 50°, and are separated by intervals of 1,800 to 2,000 feet respectively. The fourth lies in a smaller fault zone striking east and dipping on the average 65°S.No. 1 orebody has been explored by mining to a depth of 500 feet, No. 2 to 400 feet, and No. 3 to slightly less than 300 feet . The greater part of No. 8 lies above a depth of 200 feet, but a raise has recently .been driven through from the west end of the 5th level of No. 1 to the 2nd level on No. 8 zone. Most of the ore of No. 8 zone above the 2nd level and of Nos. 2 and 3 above the 3rd levels has been removed."

Jan 1, 1954

By MaryAnn E. Crichton, David G. C. Clarry

"Environmental risk is becoming more important in debt and equity financing decisions in the mining industry worldwide. Demonstration of good environmental management practices and management systems has a direct impact on the ability of mine developers, operators and investors to raise financing. Based on experience in providing due diligence services, there are a number of factors that are important in assessing financial risks related to environmental issues in either new projects or existing facilities. A frame-work for understanding the importance and priorities of each element of environmental management is presented.IntroductionIn the context of lending money to a corporation, environmental issues represent another aspect of credit risk (Henry, 1989). These issues, because of their nature, represent the potential for large unforeseen expenditures if they are not known or acknowledged and are not being proactively managed. Lenders, other investors and their advisors, are becoming increasingly aware of the potential financial impact of environmental issues. Consequently, they are increasing their requirements for environmental audits to review the environmental issues, management practices and systems when they are considering financing mining and/or metallurgical processing operations worldwide.Many banks have signed the United Nations Environment Program (UNEP) Statement by Banks on Environment and Sustainable Development. Banks in this category include National Westminster Bank, the Union Bank of Switzerland, Deutsche Bank, and the Royal Bank of Canada."

Jan 1, 1997

By Leopoldo Gutierrez, Sergio Castro, Lina M. Uribe, Janusz S. Laskowski

"The effect of sulfite and metabisulfite ions on the amyl xanthate flotation of copper-activated pyrite, in distilled water and seawater, has been studied by micro-flotation tests and redox potential measurements. The activation of pyrite was carried out varying copper ions concentration. It was found that in the presence of copper ions in solution, sulfite and metabisulfite are able to depress copper-activated pyrite at neutral or slightly acid pH. After the addition of sulfite or metabisulfite ions the resulting pH is more acidic with metabisulfite ions. A significant increase of the redox potential of the solution was observed as copper ions concentration increased. Then, the initial reducing conditions brought about by sulfite and metabisulfite ions, change abruptly to oxidizing conditions in the presence of copper ions. Under these oxidizing conditions, the metabisulfite showed to be an effective depressant for pyrite mainly in seawater. However, sulfite was a pyrite depressant in both distilled water and seawater. Based on these results, the pyrite depression by sulfoxy-depressants during the flotation of Cu/Mo ores in distilled water and seawater is discussed.INTRODUCTIONDepression of pyrite by sulfoxy-depressants (sulfite and metabisulfite) in the presence of copper ions is an important issue. This is particularly true when pyrite depression in the flotation of Cu/Mo sulfide ores is carried out in seawater. The use of lime in seawater must be avoided because the formation of magnesium hydroxy-complexes and precipitating magnesium hydroxide strongly depresses molybdenite flotation (Castro et al., 2014). In order to solve this problem, one large plant in Chile uses sodium metabisulfite (MBS) instead of lime to depress pyrite in seawater. In plant practice, this also improves molybdenite flotation since with the use of MBS the pyrite depression is carried out at pH 6-7, instead the pH 11-12 usually employed with lime.From a general point of view, pyrite exhibits some natural floatability over acidic pH ranges and may be partially floated without thiol collectors (a coating of sulfur/polysulfides has been claimed). Therefore, pyrite flotation with xanthates is usually high in the acidic pH region, but decreases greatly at alkaline pH (Leppinen, 1990; Fornasiero and Ralston, 1992; Zhang et al., 1997)."

Jan 1, 2016

By C. R. Fast, G. C. Howard

The loss of fluid to the formation adjacent a fracture governs the areal extent of the fracture and the success of hydraulic fracturing as a production stimulation technique. The three flow mechanisms which control this loss are the result of the viscosity of the fracturing fluid and the permeability of the formation to the fracturing fluid, its wall building properties, and the combined effects of viscosity and compressibility of the reservoir fluid. The effects of these flow mechanisms can be evaluated in terms of a fracturing fluid coefficient, the fundamental concepts of which are developed in the paper. The fracturing fluid coefficient, which may be used in calculating the areal extent of fracturing, affords a direct measure of the effectiveness of fracturing fluids. The area of hydraulically created fractures is in-creased as the coefficient is de-creased. The fifteen-fold variation noted in this coefficient for the commercially available fracturing fluids tested resulted in a six-fold difference m the calculated areal extent of the fracture system.

Jan 1, 1961

By T. L. Lee, D. Y. Tan, J. Mi

Considerable progress has been made in studying the mechanism and effectiveness of using ultrasound waves to manipulate alloy solidification microstructure, However, uncertainties remain in both the underlying physics of how microstructure evolve under ultrasonic waves, and the best technological approach to control the final microstructure and properties. We used the ultrafast synchrotron X-ray phase contrast imaging facility housed at the Advanced Photon Source, Argonne National Laboratory, USA to study in-situ the highly transient and dynamic interactions between the liquid metal and ultrasonic waves/bubbles. The dynamics of ultrasonic bubbles in liquid metal and their interactions with the solidifying phases were captured in-situ for the first time. The experiments were complemented by the simulations of the acoustic pressure field, the pulsing of the bubbles and the associated forces acting onto the solidifying phases, providing more quantitative understanding for using ultrasound to control the growth of dendritic grains and to enhance grain multiplication effects for grain refinement.

Jan 1, 2014

By Alexander Potapov, Lawrence Nordell

A Conjugate Anvil-Hammer Mill (CAHM) has the potential to replace conventional crushers and SAG mills, with their respective conveyors and stockpiles, in a SABC circuit. It may improve comminution circuit efficiency by 100%. CAHM compresses rock in a more efficient way, similar to 19th century stamp mills, which follows the fundamental research of Schönert (1990 & 1996). CAHM efficiency is being proven through the use of ROCKY (2011) Discrete Element Method (DEM). ROCKY features allow it to simulate realistic comminution. CAHM is customizable with many geometries that are rock-property specific. ROCKY’s wear modeling compliments the structural integrity of the design.

Jan 1, 2012

By J. M. R. Carvalho, M. T. A. Reis, M. R. C. Ismael, M. J. N. Correia, S. M. C. Santos, J. M. Carvajal

A sulphide zinc concentrate (Zn-40%) has been leached in sulphuric and chloride media to optimize the conditions for the recovery of zinc and copper. Previous results showed that extractions of 95% zinc and 20% copper can be achieved in just one stage, after two hours of leaching at 80°C with a solution 0.5M in Fe2(SO4)3 and H2SO4 and a solid/liquid ratio of 5%. This work presents the results obtained in the leaching experiments carried out in sulphuric and chloride media using two and three crosscurrent stages and a countercurrent process simulation for a solid/liquid ratio of 10%.

Jan 1, 2008

By H. Nouranian, M. Askari

GOLGOHAR Mining & Industrial Co., with annual production of 16 million tons, is one of the largest pelletizing and iron ore supplier in Iran that recently this year, because of using mineral processing techniques and extraction of ore body positioning between the metamorphic rocks, about 150 million tons of dry tailings has been created as a result of concentrate production. On the other hand, many environmental issues such as groundwater pollution have been developed by sulfide and silicate gangue minerals, which containing heavy metals such as mercury and arsenic. In this study, a new product with high added value has been introduced for the company by identification and extraction of industrial minerals in dry tailings. Also, by removing large masses of dry tailings, environmental pollution sources were gradually eliminated. This method can be used as a modern waste management approach in the world.

Jan 1, 2017

By W G. Forbes

SOME 20 years ago, upon finishing second year at the University of Manitoba, I was faced with the choice of whether I wanted to be a geologist or a chemist. Accordingly, I sought out Professor Brownell, Head of the Department of Geology, to ask him what a geologist did. His reply contained the statement that following graduation one went out into the field in northern Canada for 5 to 15 years to reduce to practice what had been learned at university. To a young man, very socially conscious, even one year, let alone 5 to 10, in a small mining community sounded like being banished to a monastery in the Himalayas and thus I turned to chemistry. Moving to the present, last month I asked a geologist, and then a mining engineer, what does the fresh graduate in their field do these days? The reply was: usually serve an apprenticeship for an indeterminate period either underground or in the field learning the job.

Jan 1, 1965

By I. S. Zajac, Y. O. Oyediran, M. C. Robart

This paper presents an overview of the metallurgical work on the Strange Lake Alkalic Complex (SLAC), from historical development of the "Main Zone" to present day develoment of the "B Zone". The SLAC, originally discovered by the Iron Ore Company of Canada (IOC) in the northeastern Canadian Shield of Québec and Labrador, is one of the world’s largest deposits of rare earth elements (REE) including yttrium and high field strength elements (HFSE) including zirconium, niobium, and titanium. It is part of a Precambrian, post-tectonic complex of peralkaline granites which intruded along the contact between gneisses and monzonites of the Churchill Province of the Canadian Shield. Mineralization of interest at Strange Lake principally occurs within peralkaline granite-hosted pegmatite and aplite sheets and, to a lesser degree, within the host granites, particularly in intra-pegmatitic granites. The highest grade and metallurgically most favorable mineralization is in the upper, open pit mineable parts of the SLAC. Metallurgical development has been conducted under a number of mining companies, and various value metals have been targeted throughout the history of the deposit, including yttrium, zirconium, niobium, and rare earths. Historic processing routes tested have included ore beneficiation, atmospheric leaching, solvent extraction (SX), and metal precipitation. This paper also presents the metallurgical development supporting Quest Rare Minerals Ltd.’s (Quest) 2013 Pre-Feasibility Study (PFS) and 2014 Preliminary Economic Assessment (PEA).

Jan 1, 2014

By Jose A. Jimenez

"Mining operations generate an enormous amount of data that is difficult to organize, analyze and act on. These data require an extremely broad range of experts to investigate and manage the cross-disciplinary information. The data collects in paper files, diverse databases, historians, stand-alone applications, and excel files. This collection of sources represents everything from monthly, weekly, or daily inputs to real-time feeds or sporadic unscheduled entries. With the operational complexities ever increasing and fewer engineers per mine, an efficient operation is becoming more and more challenging. Engineers are typically burdened with data collection, clean up, and administrative efforts leaving very limited time for engineering assessment and/or optimization analysis. Often optimization becomes limited to the analysis of equipment uptime through existing field automation systems. A great portion of the field data is tucked away in historians seldom reaching those engineers who might leverage the data. Few mine operators have the time or budget to re-architect their operations data collection or management practice, so solutions must enable improvements without requiring expensive or time-consuming implementation. This presentation highlights examples where the aforementioned challenges are addressed using a solution framework designed to enable: 1) data integration and connectivity, 2) monitoring and opportunity recognition, and 3) engineering workflow automation. The initiative extends the concepts and success proven in the automation market segment to all disciplines across the mine operations. INTRODUCTIONThe mining industry by its very nature spends a great deal of its capital on equipment maintenance and replacement. In addition, periodic shutdowns due to equipment failure are typically very costly in terms of interrupted operations. Keeping mining equipment running at peak performance and avoiding costly shutdowns can make a huge difference in the overall return from mining operations. Today, information can be make available that can go a long way towards spotting equipment issues and permitting timely intervention to avoid costly unplanned shutdowns. That said, gathering all of the information from numerous points on many different pieces of equipment necessary to enhance overall equipment effectiveness presents its own daunting issues."

Jan 1, 2016

By G. W. H. Norman

"During the past few years emphasis has been placed on the importance of major faults, fault zones, and associated structures in localizing ore deposition. This interest has developed partly through experience in mining camps in other parts of the world, and partly by the discovery of such structures associated with ore deposits in the Abitibi region, northwestern Quebec. The recognition of these structures has been brought about chiefly by detailed mapping that has been gradually extended along most of the southern gold belt of Quebec and across adjacent parts of Ontario. In the Chibougamau region of northern Abitibi, progress has been made in mapping major faults by using aeroplane photographs with a scale of about 1,000 feet to 1 inch for field mapping. These studies have shown that many large faults occur in the Abitibi region; also that there is a relationship, direct or indirect, between faults and mineral deposition. The faults are, however, of more than one type and age, and this should be clearly appreciated in any planned programme for prospecting this great region adequately.Geology of the Abitibi RegionGeneral GeologyFaults of more than one age and type occur in the Abitibi region. In order to appreciate some of the age relationships of the faults, a brief summary of the historical aspects and major structural features of the geology (fig. 1) is necessary. These historical aspects may be briefly summarized in chronological order as follows:(1) Accumulation of Archæan lavas and associated pyroclastic rocks, either alternating with, or essentially followed by, deposition of sedimentary rocks, and interrupted at least once by local and perhaps regional folding and erosion."

Jan 1, 1954

By O. Schnake, M. Isakson, C. A. Landolt

The paper presents the conceptual basis for the development of an Activity Based Costing system (ABC) for the analysis and estimation of process costs in mining and metallurgy. In particular, it discusses three major thrusts towards attaining increased efficiency in extraction and processing systems: (a) understanding the link between process and expenses, (b) identifying the chemical and physical factors that govern process costs and ( c) using process and cost models of the production systems. The authors have developed computer techniques to analyze data from conventional accounting and apply them to the development of process based ABC systems. The cost causing activities are linked to management units patterned after the organizational structure of the production system. All costs are associated with specific process functions such as charge preparation, smelting, refining, etc. The level of detail is determined by the quality of data available in conventional accounting systems. The system permits data analysis of historical cases and the projection of costs for new production schemes. Results can be presented in various levels of aggregation, following organizational and/or functional structures. The outputs of the system are tabular and graphical, typically following Pareto analysis concepts.

Jan 1, 2007

By I. Osvath, I. Gombköto, G. Mucsi, Z. Molnár

"In the present research, a deposited brown coal fly ash was used as raw material for geopolymer. The reactivity of the fly ash was altered using mechanical activation, which is one of the promising methods to improve bulk and surface reactivity. The mechanical activation experiments were carried out in a high energy density mill using 5 m/s circumferential speed, and various residence times (1, 3, 5, 10, 15 and 60 min). The effect of mechanical activation on particle size distribution was measured by a laser particle size analyzer and structural changes using FT-IR. Geopolymer samples were prepared from mechanically activated fly ash with an alkali solution. The progress of geopolymerisation was monitored using an Isothermal Conduction Calorimeter. The heat flow curve obtained indicated that reactions were more prominent and started much earlier in the mechanically activated samples. This observation is further supported by the compressive strength results which also improved in geopolymers using mechanically activated fly ash. Based on the obtained results, it can be inferred that mechanical activation is a possible way to enhance the reactivity of fly ash and consequently properties of resulting geopolymers.INTRODUCTIONCoal fired power plants generate fly ash and slag in huge amount worldwide, about 780 million tons/year (Heidrich et al. 2013). Due to the relatively low utilization rate, enormous quantities of these wastes are landfilled in ponds. The fly ash is the finest grained particle fraction of the solid ash, which is transported with flue gas, and removed by electrostatic or bag filters. The fly ash has pozzolanic activity, it does not react with water, but in the presence of calcium hydroxide solution hardens and solidifies, producing a reaction product practically insoluble in water (Opoczky, 2001). The most important property of the fly ash regarding geopolymerization is its reactivity, which depends on the chemical and phase composition, the dispersity (specific surface area, particle size distribution), and the morphology of the fly ash particles, and determined by the physical properties and chemical composition of the fly ash. Geopolymers concerning their chemical structure are polysialates, where the sialate (silicon-oxoaluminate) network is built up from the bonds of Si-oxide and Al-oxide by sharing oxygen atoms (Davidovits, 1988)."

Jan 1, 2016