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By P. C. Richards

"Future Integrated Gasification Combined Cycle (IGCC) power plants will have superior environmental performance and unmatched efficiency.The Shell Coal Gasification Process (SCGP) is a clean coal technology, which can convert a wide range of coals into clean syngas for high efficiency electricity generation in an IGCC plant. SCGP flexibility has been demonstrated for feeds ranging from bituminous coals to lignites and petroleum coke, and the process is ideally suited for combined cycle power generation, resulting in efficiencies of 42% to 46% (LHV).In the Netherlands, a 250 MWe coal gasification combined cycle plant based on Shell technology is being built by Demkolec, a development partnership of the Dutch Electricity Generating Board (N. V. Sep). The plant is scheduled to start up in 1993. IntroductionBasic ConceptShell's experience with gasification dates back to the 1950s, when the first Shell Gasification Process was commissioned with oil as feedstock. There are now over 140 SGP gasifiers licensed. The experience gained on oil gasification provided a firm theoretical and practical base for the start of coal gasification process development in 1972.At that time, there were serious concerns about the future availability and price of crude oil. Coal gasification (making carbon monoxide and hydrogen by the partial oxidation of coal) was considered to be an important option for refinery applications, because the synthesis gas (syngas) produced can be used as:• a chemical feedstock for making transportation fuels and chemicals;• a source of hydrogen (making use of the water gas shift reaction) for upgrading petroleum products; and• a fuel for heating process streams and/or generating electricity."

Jan 1, 1994

By Susan W. Campbell, Bruce Regensburg

"The CIM Careers Task Force has addressed industry's concern of a perceived shortage of skilled personnel over the coming decade. The industry is faced with a fundamental shift by young Canadians away from scientific and engineering careers, coupled with the fact that today 's students know little about the minerals industry and have a poor image of it.The responses to two questionnaires which were distributed to CIM members, government, professional associations, and educational institutions, formed the backbone of the Task Force position paper, which presents a shopping list of ideas and initiatives for consideration and to facilitation by the various organizations concerned.Tackling the image of the minerals industry is part of the answer to the careers crisis. On the positive side, the minerals industry provides the allure of a treasure hunt for young people and is seen as a significant contributor to the economy. It is understood to be well paying, provide good opportunities for advancement, individualism, and travel, and to be rich in esprit de corps. Enhancement of these positive aspects of the image can take place at all student age levels.Numerous initiatives tackle the negative aspects of the image. Young people perceive the industry to be environmentally damaging, which is the most crucial aspect that needs to be addressed. The industry is seen as still in the pick-and-shovel days and as a sunset industry that is running out of ore. Work in the minerals industry is perceived as dangerous and lacking glamour. And finally, the perceived remoteness of operations and exploration is seen as a drawback to a largely urbanized student group.Tackling young peoples' curiosity and interest in the minerals industry throughout grade school and encouraging postsecondary science and engineering students to enter the minerals industry by ensuring summer employment is the second part of the equation.The CIM Careers Task Force position paper develops strategy to attract and maintain interest of students in grade school, junior high, senior high school, and in post-secondary levels. The strategy outlines initiatives targetted at each of the educational levels and action plans to accomplish the objectives."

Jan 1, 1993

By D. Saramak, T. Gawenda, Z. Naziemiec, A. Saramak

"Crushing and grinding operations are burdensome to the environment due to generating large amounts of dust, noise and waste during course of comminution operations. An indirect negative contribution of industrial crushing processes is an increase of carbon dioxide emissions, which is a byproduct in energy production processes. On the other hand comminution processes in ore enrichment technology are essential due to liberation the useful minerals from the gangue, and producing the demanded particle size fractions of products. The article concerns investigation over negative influence of comminution devices on environment in terms of dust and noise emissions. Several various crushing devices were under investigations, both in laboratory and in industrial scale.The obtained results were analyzed in terms throughput and energy consumption achieved in various crushing devices. The test results allow to conclude that an intensity of dust generation for individual types of crushing devices is varied. An additional aim of this article is to link the aspect of mineral processing with its environmental impact and hence an influence of raw materials beneficiation industry on the quality of life of residents in immediate and close vicinity.INTRODUCTIONMineral raw materials beneficiation processes are an integral part of multi-stage processing of coal, iron ore and non-ferrous metals, production of aggregates, cement, or precious metals and stones. One of the common features of all beneficiation operations is their high energy consumption, which is mainly connected with various operations of feed particle size reduction. Comminution processes in ore enrichment technology are essential to expose and liberate the useful minerals from the gangue, while in aggregate production processes – to obtain the demanded particle size fractions of products. Crushing operations are characterized by a high degree of negative impact to the environment and humans, mainly due to:• High electricity consumption, which indirectly contributes to the increased emissions of carbon dioxide into the atmosphere, since CO2 is often one of the byproducts of energy production;• Relatively rapid wear of device working parts, what forces a production of spare parts and involvement of steel industry;• Intense dust pollution generated during crushing and grinding processes. This is one of the factors affecting the air quality and the consequent deterioration of the living conditions of inhabitants near mines and processing plants; and • Excessive noise emissions."

Jan 1, 2016

By R. F. Baxter, C. M. Read, R. I. McCulloch

"Globalization of the aluminium industry continues to increase the pace of change and the intensity of competition, while simultaneously, society demands better products, cleaner technologies and sustainable industries. Bechtel, a global engineering, construction and project management company, is not immune to either the opportunities or the challenges created by globalization. However, and not withstanding the challenges, for aluminium industry ""players"" with a true global perspective, globalization presents very real opportunities that may be leveraged to deliver value creating goods and services. The following paper will focus on the exploitation of one of the opportunities created by globalization in the Knowledge Management domain - the application of high level tools and methodologies to improve global delivery of greenfield and brownfield aluminium smelter construction projects. Specific examples will be presented of value driven solutions that were delivered at the early stages of project engineering."

Jan 1, 2006

By S. Hussien, P. Somasundaran, P. Patra

"Rare earth elements (REEs) are essential for many applications in electronics, energy harvesting, and defense. The common resources for economic extraction of REEs are oxides such as bastnaesite and monazite, which are scarcely available in the earth’s crust. On the other hand, REEs are available in many clay and phosphate ores where REEs substitute Ca or Si in the mineral lattices or as physically adsorbed cations at negatively charged sites on the clay surface. While REE oxides readily dissolve in acid, making the chemical leaching of REEs an economically viable option, adopting a similar approach for leaching of silicates and phosphate ores is unfeasible because of significantly low REEs content in these ore deposits. Bio-leaching approaches are environmentally benign and economically viable. We investigated the bio-leaching (Acidothiobacillus ferrooxidans (Af) and the fungal Aspergillus niger (An)) of REEs from a phosphate ore, and examined the factors governing the leaching processes. Based on the shake flask leaching studies, an increase in surface area combined with an increase in pulp density (1-15 wt. %) was found to lead to an increase in the amount of REEs leached. In contrast, an increase in the surface area by reducing the particle size from 75 to 35 led to a decrease in the amount of REEs leached. These differing attributes are proposed to be due to the poor bacterial growth/activity with high F- ions in the leaching media, F- released from the edge-sites of the smaller particles. On the other hand, several advantages that associate with the Af bacterial bio-leaching processes relate to the media composition (Mg2+ and (NH4)+) and phenomena occurring at the electrical double layers of the mineral and bacterial- water interfaces. These studies suggested that leaching of particles occur in a layer-by-layer manner.INTRODUCTIONRare Earth Elements (REEs) are essential for many important applications, such as in electronics, energy generation, and defense. The common resources for economic extraction of REEs are typically carbonates such as bastnaesite and monazite, which are scarcely available in the earth’s crust (Y. Kanazawa and M. Kamitani, 2006). REEs are abundantly available in many clay and phosphate ores where REEs substitute Ca or Si of the mineral lattices. Conventional acid leaching of REEs from oxides is not economically feasible for clay and phosphate ores because of significantly low REE content (parts per billion) in these ores (Tian, J., Chi, R., Yin, J., 2010a; Moldoveanu G. A. and Papangelakis V. G., 2013; WK Goyne, LS Brantley and J Chorover, 2010). In some cases, REEs could be extracted from these ores via chemical leaching routes as they constitute reasonable amounts of REEs (0.1 - 1% REEs). A major challenge faced in general in chemical leaching processes (Chi, R., 1988) is the loss of REEs in the phosphate/gypsum precipitates/crystals, which are overcome in a step-by-step manner by sequentially removing impurities such as fluorine and calcium, including steps carried out at elevated temperatures. On the other hand, bio-leaching approaches provide environmentally benign and economical alternatives. Acidophilic bacteria are currently being used for industrial scale bio-leaching of Au/Cu/Ni from low grade ores. Studies on bioleaching of REEs from red mud (Al2O3) using Penicillium tricolor and Aspergilus niger (An), and, of bio-leaching (lab-scale) of phosphate rocks using Acidithiobacillus ferrooxidans (Af) have been reported (Boon, M., Heijnen, J.J., 1993; Qu, Y. and Lian, B., 2013). We conducted bacterial (Af) bio-leaching of REEs from a phosphate ore in shake flasks and columns, while examining the key factors that govern leaching kinetics."

Jan 1, 2016

By G. Mucsi, J. Faitli, K. Bohács

"The authors developed an online tube rheometer to supplement a Netzsch MiniCer (Netzsch GmbH, Germany) stirred media mill in order to monitor online the rheological characteristics of the suspension and therefore the result of grinding during the process. Previously it was demonstrated that the above measuring system was working appropriately based on the preliminary tests. The product related stress model was applied for the evaluation of the grinding results. It was found that the suspension concentration and the change of the material properties during grinding, consequently the rheology strongly affects the grinding result, i.e. specific surface area, median particle size as well as specific grinding energy. The tested model limestone – water suspensions behaved Newtonian initially, then after a given grinding time their properties had changed and they become Bingham plastic. INTRODUCTIONStirred media milling now is a common practice to produce fine and ultrafine granular materials for different purposes. With an increasing demand of ultrafine powders for industries (Kwade, 1999), wet and dry ultrafine grinding has been increasingly used in various fields, such as minerals (Mucsi, Rácz, & Mádai, 2013)(Rácz, 2014), ceramic materials (Becker & Schwedes, 1999), pigments (Ohenoja, Illikainen, & Niinimäki, 2013), chemical products (Baláž et al., 2013), microorganisms (Kwade & Schwedes, 2002) and pharmaceutics (Afolabi, Akinlabi, & Bilgili, 2014). It is well known that suspension rheology affects the wet comminution of materials (He, Wang, & Forssberg, 2006a). The rheological behaviour of the suspension containing the ground particles might indicate the level of interparticle interaction or aggregation and therefore it is an important variable factor of the process control (Muster & Prestidge, 1995). The influence of the rheological behaviour of mineral suspensions on their grindability has attracted more and more interests and attention, especially on ultrafine grinding performance (He, Wang, & Forssberg, 2006b) (Bernhardt et al., 1999). However, there are still many issues concerning the machine and the process for the different applications. When grinding is effective and the particle size range decreases significantly, the circulating suspension is becoming typically non-Newtonian. The changed rheological behaviour and the increasing rheological material parameters can negatively affect the grinding efficiency; therefore it is an important issue. Ultrafine stirred media milling as well as solid-liquid two phase flow have been studied for a long time at the Institute of Raw Materials Preparation and Environmental Processing of the University of Miskolc. Regarding ultrafine grinding the research is focusing on the description of materials’ grindability (energetic aspects) both in wet and dry circumstances (Mucsi et al., 2013; Rácz, 2014). Concerning rheology, the three measuring pipes tube rheometer was developed decades ago (Faitli & Gombköto, 2015). So far many different solid materials from all over the world had been tested in this rheometer (Faitli & Gombköto, 2015). Main aim of these tests was to gain basic data for large scale hydraulic transport applications. Among the many stirred media mills there is a Netzsch MiniCer mill at the Institute. It was reasonable to combine the two fields together, and the goal of the research presented in this paper is to develop an online tube rheometer for the Netzsch mill and to carry out grinding and rheological testing simultaneously."

Jan 1, 2016

By J. D. Gillaspie, D. T. White

"Sulphuric acid atmospheric leaching of nickel saprolite / garnierite ores was proposed in the early twentieth century, prior to the development of the pressure acid leaching process for limonite ores. Sulphuric acid leaching with alkali addition for iron precipitation as jarosite has been considered periodically since the early 1970s, shortly after the development of the jarosite process for iron control in zinc refining. In the late 1990’s a series of flowsheets were proposed and tested involving simultaneous atmospheric leaching, iron precipitation and acid regeneration. These were considered particularly suited to sequential leaching of limonite and saprolite ores. A number of laterite sulphuric acid leaching processes utilising this chemistry have been put into commercial operation. Similar sequential leaching flow sheets involving precipitation of iron as goethite were also developed and piloted. This paper will firstly describe some of the important historical developments of both the jarosite and goethite processes. It will then provide descriptions of the commercialised processes involving alkali jarosite/alunite precipitation, with special emphasis on the downstream impurity removal requirements necessary for efficient recovery of nickel and cobalt from solution.INTRODUCTION This paper is a summary and extension of previous works with which the authors have been involved, on the subject of sulphuric acid leaching of nickel laterites (Adams, et al., 2004), (Liu H. , Gillaspie, Lewis, Neudorf, & Barnett, 2004), (White, Miller, & Napier, 2006), (White, 2009), (White & Gillaspie, 2013), (White & Gillaspie, 2015). Some of the historical developments of both the jarosite and goethite leaching-precipitation processes will be described, followed by a description of the commercialised sequential nickel laterite leaching processes, involving alkali jarosite/alunite precipitation and acid regeneration, with a comparison to the equivalent goethite based processes. These will include Jarosite Atmospheric Leaching (JAL), Goethite Atmospheric Leaching (GAL) and combined Pressure Acid Leaching – Atmospheric Leaching, termed EPAL®. There will also be an explanation of the downstream impurity removal requirements necessary for efficient recovery of nickel and cobalt from solution."

Jan 1, 2016

By W. B. Evans, D. P. Taylor

"ANFO has two major disadvantages as an explosive low density and no water resistance. ANFO can be blended with more dense, water-resistant explosives to form ""Heavy ANFO"". The use of emulsion or slurry explosives as a matrix is an attempt to correct deficiencies on the basic ANFO while maintaining cost effectiveness.This paper will deal with four main topics.1. Product description, general properties, strengths and weaknesses.2. Technology of ""Heavy ANFO"" , the emulsion matrix concept and the range of products.3. Relative performance and economics in various rock types.4: Current status in Canada and worldwide, and the expectations for future use.IntroductionANFO has been in use for roughly three decades and remains the explosive of choice where conditions are suitable. ANFO has not become the universal explosive - despite its undoubted superiority in cost effectiveness - because it has serious flaws as an explosive. The most serious of these flaws are the low density and absence of water resistance in ANFO. Low density implies a low concentration of explosive energy in a borehole. The amount of energy available can be increased by. adding an energetic material, generally aluminum, or by drilling more holes. Both solutions add considerably to the over-all costs. The absence of water resistance in ANFO is inherent and can only be overcome by changing the fundamental nature of the product. The history of research in the explosives industry since the advent of ANFO is mainly the story of the various attempts to overcome one or both of ANFO's shortcomings.Many technologies and products have been developed to compete against ANFO, among them slurries, emulsion s and the so-called Dense ANFOs (ANFO with an extra nitroalkane liquid sensitizer). None of them was cost-competitive with ANFO so their market penetration has been limited to wet holes or specialized applications. The exception to this result is Heavy ANFO. The aim here was to have the best of both worlds, the high density and water resistance of emulsions or slurries plus the low cost of ANFO. The concept is very simple. ANFO is about 50 % air, roughly 30% in the prills and 700,10 between the prills . The air in the prills provides the necessary sensitivity but the air between them is waste volume. If one fills this volume with a high density, waterproof product, the resultant mix will be denser and more water resistant than ANFO and with very little added cost. This basic concept was invented by B. Clay in the 1970s and is covered by Canadian Patent No. 1 115 959. The water resistance and/or density of the mix can be tailored by changing the emulsion level. Because Heavy ANFO is relatively inexpensive while providing good in-hole densities and water resistance, it can compete successfully against all other bulk products. It competes against ANFO and Al / ANFO by allowing pattern expansion and reducing over-all costs while it competes against emulsions and slurries on price."

Jan 1, 1987

By Ron Jessulat

"IntroductionBrunswick Mining and Smelting Corp. Ltd. is a IO 500 tid base metal producer. Development is carried out by Jarvis Clark MJM-21 3-boom development jumbos, using Tamrock E400, 410 and 550 pneumatic drills. Typical drift size is 13 ft by 18 ft with a 12-ft advance per round. Blast holes are 1 ½ in. in diameter while reamed holes are 3 in. in diameter. AN/FO is the principal blasting agent, being loaded by C-I-L model60R intermediate loader. The detonators are NONELS and DETINELS. Sulphide dust explosions occur during blasting when dusts from certain minerals such as pyrite and pyrrhotite are ignited by name from the detonating shots. The result is a secondary unwanted explosion with a characteristic shock wave and name front that are very destructive to mine services such as ventilation ducting, electrical cable, and ventilation control doors.A typical reaction in the Brunswick orebody occurs according to the chemical formula:4FeS 2 + IIOs-2Fe2O3 + 8SO2 + 3458--(Enright , 1988)The hematite (FeO3) is deposited as a red dust in the blast area while the toxic sulphur dioxide gas (S00 contaminates the underground workings . The presence of S02 gas disrupts production until it is purged from the area by the mine ventilation system or dissipates slowly in those areas where the vent ducting has been melted by the name front or torn down by the shock wave.Sulphide dust explosions exact a high economic toll. Direct costs in damaged materials and wages are probably exceeded by the value of lost production and disruption to the mining cycle. In addition, the health and safety concerns associated with sulphide dust explosions cannot be ignored."

Jan 1, 1993

By Gorrell. H. A.

Subsurface water data can be very valuable in .petroleum exploration and research. For the discussion of problems related to subsurface waters uniform nomenclature and classifications are required. The term 'connate water' has frequently been incorrectly used. It should .only be used in its original sense in which it is analagous to 'fossil water'. Classifications .based on origin and on sodium-chloride content are proposed. Present and possible uses of formation water analyses are briefly discussed. Since the potential uses of formation water data are not fully understood, complete analyses of selected samples should be made to insure against future requirements. The subsurface waters of Alberta show considerable regional variation in amount and proportion of dissolved salts.

Jan 1, 1958

By Kazutoshi Haga, Batnasan Altansukh, Atsushi Shibayama, Ryuji Oinuma

"Recently, the arsenic grade in copper ores has been increasing year by year. Arsenic bearing minerals (enargite (Cu3AsS4) and tennantite (Cu12As4S13)) coexist with typical copper minerals such as chalcopyrite (CuFeS2). The removal of arsenic from copper ores that contain relatively high arsenic content is essential due to its adverse impact on the environment and the resulting economic consequences. In this study, arsenic removal and dissolution behaviour of Cu and As from enargite (Cu3AsS4) were investigated using ferric sulphate (Fe2(SO4)3) solutions containing sodium chloride under high pressure oxidation conditions. The effects of numerous parameters including the concentration of Fe2(SO4)3 and NaCl, temperature, total pressure, leaching time and particle size were studied while other variables such as pulp density and stirring speed were fixed at 100 g/L and 750 rpm. The results showed that more than 60% of the copper was dissolved in a 0.1 M ferric sulphate solution under the high pressure oxidative conditions, whereas the leaching rate of arsenic was less than 20%. SEM observation revealed that elemental sulphur was deposited on the surface of enargite forming a passivation layer and the residue was agglomerated. Those phenomena may cause a decrease in the copper leaching rate. It was found that more than 80% of copper was dissolved in the ferric sulphate solution in the presence of 0.34 M sodium chloride under the conditions optimized, whereas the dissolution of arsenic in the mixture did not exceed 2%. XRD analysis of the solid residues from the leaching experiments used ferric sulphate and mixtures of ferric sulphate and sodium chloride showed arsenic to be present as scorodite (FeAsO4).INTRODUCTION In recent years, there has been an increase of the arsenic (As) content of copper ores due to the gradual depletion of high grade copper ores. In some copper deposits, arsenic occurs in the form of minerals such as enargite and tennantite. The removal of arsenic in ores containing copper is critical to the production of pure copper and the management of the environmental challenges caused by the smelting process. Due to the environmental risk caused by arsenic emission and the deteriorated quality of the copper product, smelting of enargite concentrates is not an effective method for the extraction of copper (Padilla et al., 2010; Safarzadeh et al., 2014; Long et al., 2012). Therefore, a number of studies have been carried out to develop arsenic removal technologies from copper ores using various methods such as hydrometallurgy (Curreli et al., 2009; Tongamp et al. 2010), pyrometallurgy (Dalewski., 1999; Padilla. et al, 2012) and bio-oxidation (Ehrlich, 1964; Sasaki et al., 2010). Several hydrometallurgical leaching processes like sulphuric acid, alkaline sodium sulphide and sodium sulphate and ferric sulphate leaching have been developed to treat enargite ores and concentrates. The alkaline sodium sulphide leaching process has been developed for the removal of arsenic from enargite (Anderson, & Twidwell, 2008; Parada et al., 2014). The mechanism of the dissolution of arsenic from enargite in sodium sulphite solution is"

Jan 1, 2016

By J. E. Zajic, E. A. Sullivan, T. R. Jack

"The release of vanadium, iron, nickel and titanium from the cokes produced in the upgrading of Alberta oil sands bitumen has been assessed for simple chemical leaching processes. Flexicoker coke (Exxon Engineering and Research) has been found to be quite amenable to the recovery of vanadium as well as nickel, iron and some titanium by these techniques, whereas fluid coker coke (Syncrude) and delayed coker coke (Great Canadian Oil Sands) are relatively intractable under the mild conditions employed. The factors affecting the extent of vanadium release are discussed in terms of the surface area accessible, the wettability of the material, and the chemical and physical composition of the coke particles in each case.A novel biologically assisted heap leaching procedure for f1exicoker coke is also described, based on the growth of the chemolithotrophic bacteria, Thiobacillus thiooxidans A TCC 8085, on elemental sulphur added to the coke."

Jan 1, 1980

By C. I. Walker

Field tests at a number of large mineral processing operations have been undertaken to better understand the wear life impact of different aspects of pump design, materials of construction and maintenance procedures. Data are presented for wear rates, and typical result variability is explored. To improve the availability of pumping equipment in a milling circuit it is not only important to improve the wear life, but also reduce the variability in the wear life of components so that the incidence of premature failure is lessened. Localised gouging wear due to flow separation and turbulent eddy formation is often the point at which part-holing occurs. A number of improvements to the design of pump impeller and throatbush (suction side liners) to reduce the localised gouging wear are outlined. Also, results are presented on the use of composite materials (mix of metal, rubber and ceramic) for throatbush materials to protect specific areas against wear.

Jan 1, 2012

By K. Mayhew, A. Lossin, H. Salomon-de-Friedberg

"The proportion of arsenic-bearing copper concentrates that supply the copper industry is on the increase. The current strategy of miners and smelters to blend feeds to reduce average arsenic levels is rapidly becoming unsustainable as more concentrates with even higher arsenic levels enter the marketplace. In addition, the capability of smelters to manage increasing arsenic levels to more stringent and restrictive environmental standards is limited by available process technologies.CESL Cu-As Technology is a viable technical and economic alternative to traditional smelting. It offers the advantage of simultaneous leaching and precipitation of the arsenic in a single processing step while achieving high copper extractions. The process has been piloted in six separate, fully-integrated pilot campaigns for feeds ranging from ~1% to 12% arsenic in concentration. This paper will focus on the behaviour of arsenic in CESL’s leaching/precipitation step and operational factors that influence it, and on the chemical and physical characteristics of the subsequent iron-arsenic residue that represents today’s best available technology from a long-term sustainable (capital/operating costs, metal recovery, safety, environmental) perspective.The examples provided will demonstrate copper extractions approaching 99% and arsenic deportment to residue of 99%. Instantaneous settling rates of the residue were measured at 15+ m/hr. Data from subsequent short and long-term stability testing of the residue confidently support the view that the scorodite-bearing residues from the process will be stable and provide an acceptable arsenic management practice. The technology offers increased revenue and environmental certainty for miners, smelters & refiners to support the development of metallurgically challenged copper-arsenic deposits. Furthermore, results will be presented demonstrating the technology’s ability to successfully incorporate hazardous arsenic containing smelter by-products such as dust into the process feed and simultaneously extract copper value while fixing the arsenic in a stable residue."

Jan 1, 2016

By Chuck Crowell

ISO Standards ?Provide Information to Address Commercial and Safety Needs for Standardization: ?Definitions and Terminology ?Test Methods ?Performance Criteria ?Conformity Assessment Process ?Developed by Global Experts ?Promote Global Harmonization

May 1, 2013

By E. Ghali, W. Zhang, M. Robichaud, G. Houlachi

"The performances of six mesh and one plate dimensionally stable anodes have been investigated in the zinc electrolyte at 38oC and compared to conventional silver-lead alloy anodes. The electrochemical behaviour of these anodes was studied by cyclic voltammetry, galvanostatic, potentiodynamic, open circuit potential and electrochemical noise measurements. It was observed that at the end of 24 h of galvanostatic polarization at a current density of 50 mA/cm2 in the zinc electrolyte at 38oC, the mesh V had the lowest potential followed by mesh III, mesh VI, plate-V, mesh IV, mesh I, and mesh II electrode. When the potentials for mesh I, mesh III, mesh IV, VI and plate-V, mesh V were compared with that of the Pb-0.7%Ag anode (1920 mV/SHE), they were found to be 6%, 16%, 7% 10%, 17% lower, respectively.After 16 h decay following the 24 h polarization, the mesh III had the lowest corrosion rate (51 mS/cm2) among the seven specimens, followed by the plate-V, mesh V, VI, IV, I and II (221 mS/cm2). For the fresh surface as received, after two hour open circuit potential measurements, mesh I had the most positive (noble) potential (1382 mV/SHE) among the seven electrodes followed by the plate-V electrode, mesh V, mesh IV, mesh VI, mesh III and mesh II (751 mV/SHE). After consecutive series of electrochemical testing, mesh V, mesh III, mesh VI had lower corrosion rates (~ 343± 6 µA/cm2) than that of mesh IV, mesh I, plate-V, and mesh II (~ 644± 143 µA/cm2).INTRODUCTIONThe continued use of lead based anodes in the electrowinning process has been mainly due to their relatively low cost as compared to other materials (Msindo, Sibanda, & Potgieter, 2010). They have good electrical conductivity, stability during electrolysis, very good corrosion and wear resistance (Ivanov, Stefanov, Noncheva, Petrova, Dobrev, Mirkova, Vermeersch, & Damaerel, 2010). However, lead-based anodes give their high energy consumption and low corrosion resistance for electrowinning. To overcome these problems, Dimensionally Stable Anodes (DSAs) has been chosen (Msindo et al., 2010). Comparing to the traditional lead anodes, the DSA anodes have many advantages: (1) no contamination; (2) no loss of anode material, pure electrolyte; (3) lower gas bubble effect through special anode designs; (4) use of higher current densities (Msindo et al., 2010). The success of DSA anodes has been attributed to their chemical stability that allows them to maintain nearly constant dimensions during the life of the anode even when operating in environment with low pH values. Due to their stability, the consumption rates of DSA are as low as 1 mg/amp.y (Alfantazi & Moskalyk, 2003)."

Jan 1, 2016

By H. R. Manouchehri

"It is well understood that, apart from particle hydrophobicity, the flotation process is strongly influenced by the cell hydrodynamics. Once the chemical conditions were optimized and fixed, the flotation rate is essentially determined by impeller speed and the air flow rate.The collection efficiency in flotation is a product of collision, attachment and stability/detachment efficiencies. The collision efficiency for a given particle diameter is increased by decreasing the bubble size and bubble velocity as well as increasing the power input to the cell. The attachment efficiency, however, is defined by bubble size and its velocity. The detachment/stability depends on the relative magnitudes of the attachment force between the bubble and particles and the detachment force acting on the bubble-particle aggregates. For the particles having specific contact angle, the stability decreases as the energy input increases. Therefore, there must be an optimum energy dissipation to maximize recover of defined size fraction.A comprehensive laboratory study was devoted to determine the effect of power input in recovery of finely grind Cu-Ni bearing ore. Several flotation tests were conducted to define the hydrodynamic parameters for a laboratory scale Runge cell under different impeller speeds. An increase in flotation recovery of finely ground ore was observed when the impeller speed was increased from 450 to 1,200 rpm. The experimental results have shown increasing in water recovery and improving in flotation kinetics of fines by increasing the power input to the flotation cell. Implementation of the Wark flotation model to the experimental data revealed a good correlation between the experimental data and the model. For the particles having enough hydrophobicity the flotation rate increases by increasing the impeller speed due to a higher value for collision efficiency within the cell."

Jan 1, 2016

By Andrew Popko

Introducing EnCana ?? A leading North American Oil and Gas company ?? Focused on natural gas and oil sands development in 12 key resource play areas across North America ?? In 2007, over 4300 wells drilled, producing about Enterprise value of approximately $50 billion ?? Invest between $5.8 Billion in 2007 ?? Over 7500 employees ?? Headquarters ? Calgary, AB

May 1, 2008

By Ngonidzashe Chimwani, David Glasser, Diane Hildebrandt

"Milling circuits play an important role in achieving the desired product; tonnage, size distribution and properties, since they are directly linked to the comminution energy consumption for the whole process. A grinding model with a mathematical simulation was developed for an open milling circuit with a scalped feed from a hydro-cyclone. The circuit was optimized by determining the optimal conditions in terms of energy consumption which would produce a floatable product having a desired size range (i.e. -75 +9 µm) for a platinum-bearing ore. The simulation results showed an operating region comprising the best combination of the ball filling and mill speed to achieve the highest production of a floatable size class, with the minimum energy consumption.INTRODUCTIONBall milling is usually conducted in closed circuits in order to achieve a desired product size without material overgrinding. The technological importance of optimising milling circuits cannot be overemphasised (Toneva and Peukert, 2007). Previous work has brought significant insights into the benefits of modelling milling circuits (Austin et al., 1984; King, 2012; Toneva and Peukert, 2007). However, the ability to model these circuits is dependent on the performance of the classifiers and the fidelity of the grinding mill model used compared to the actual circuit (Toneva and Peukert, 2007). Austin et al. (1984) identified five types of milling circuits as shown in Figure 1 namely; the grinding circuits employing mill in an open circuit, normal closed circuit, reverse closed circuit, open circuit with scalped feed, and, the combined closed circuit. Depending on the presence of the first classifier, the second, or both as well as their corresponding loops (streams), the combined circuit (e) can reduce to; an open (d), a normal closed (b), an open circuit with scalped feed (c) or a reverse closed circuit (a). In the case of an open circuit, the mill is operated without being directly influenced by a classifier. The normal closed circuit does not have the first classifier and therefore the make-up feed is the actual feed stream. Conversely, the reverse closed circuit keeps only the first classifier. The open circuited with scalped feed has only the first classifier but does not have the second one. The overflow stream from the classifier is mixed with the mill product to form the final product for the downstream process."

Jan 1, 2016

By G. N. Nnadi, R. J. Mitchell

"The response of cemented backfills subjected to simulated blast loadings is studied using centrifugal modelling techniques. Scaling requirements for centrifugal modelling are developed and the results of the similitude analysis show that an acceleration field is required to capture the true dynamic response of backfill models. Experiments have been conducted at various centrifugal accelerations. The effects of ring blasting were simulated by an impact loading on the exposed fill face. The behaviour of the cemented backfill was monitored with accelerometers as well as dynamic stress gauges.Cemented backfill response to impact loadings was found to depend strongly on simulated gravitational stress level. Results also show that the characteristics of the response changes with distance from the impact. Finally, the results of the models were used to predict prototype peak accelerations, velocities and displacements. The results reported in this study indicate that centrifuge modelling may be a useful tool for dynamic studies of blast damage to backfills. Centrifuge modelling can be carried out at low costs and can be used to design prototype instrumentation systems. IntroductionThe response of cemented mine backfills to blast loadings is of concern to the mining industry because these backfills provide local and regional support during ore pillar extraction. Considerable research has been reported on the static stability (Smith et al., 1983) and on effects of reinforcements on cemented backfills (Mitchell, 1989). However, information regarding dynamic aspects of cemented backfill is limited. O'Hearn and Swan (1989) reported on the response of cemented backfill to blast loading, but these blasts were not very dose to the backfill . A schematic representation of a rock-backfill system is shown in Figure I.The mechanics of transfer of explosive energy to rock and subsequently to the backfill, and the resulting responses, are complex. Achison (1968) listed more than twenty factor s affecting the blast fragmentation of rock and grouped these into the categories of explosive parameters, charge parameters and rock parameters. Although significant advances have been made, during the past two decades, in understanding the mechanics of blasting, the degree of uncertainty associated with predicting the behaviour of backfills subjected to dynamic loadings makes the application of simple design safety factors insufficient. Comprehensive testing programs or prototype instrumentation is required to evaluate the risks associated with blast or earthquake loadings on backfill."

Jan 1, 1991