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By A. McLean, L. Gao, Z. Shi, Y. D. Yang, K. Chattopadhyay, G. F. Zhang

Levitation melting of metals is one of the emerging applications of magnetic and electric fields in liquid metal refining. The varying magnetic field generates induced current inside the metal droplet and leads to the Joule heating effect and Lorentz force against gravity. This contactless process can avoid contamination from the crucible and can be used to produce high-purity materials. Visualization of the levitation melting process is difficult, and thus generally investigated by mathematical modeling. In the present study, a three-dimensional mathematical model of metal levitation was developed using finite element method for proper understanding of the levitation process. The effects of harmonic magnetic field frequency, coils power input, and sample size on levitation nickel droplet were investigated. Temporal evolution of temperature fields were predicted directly though the model. Levitation and balance condition of the droplet were investigated as well.

Jan 1, 2015

By D. S. Hines

The purchase of mechanical equipment for mines is not unlike the purchase of other materials or supplies in general principle, but on account of the major part such equipment plays in the operations, and of the fact that life and valuable property are at stake, the matter demands the most careful attention on the part of the purchaser. The problems and difficulties encountered are dealt with below in their sequence in the purchasing procedure. Requisiting Although it is quite a common practice to submit a tentative specification of requirements to recognized manufacturers of equipment- soliciting alternative propositions or recommendations for study in the selection of certain equipment-as a rule the first step in purchasing procedure is the requisition. Primarily, it is the form that carries to the purchasing department the record of equipment wanted. A full and complete description or specification, and accuracy of record, are the important points to be insisted on in a requisition. Too much attention cannot be given to this detail, as this is one of 'the most important phases of purchasing work. Incomplete information, either in specification or detail, leads to delay in handling the requisition, and, if not detected in the purchasing department, may mean receipt of material which cannot be used for the purpose intended. In addition to description of material or equipment to be ordered, the requisition should also show where or what the equipment is for, whether for operating or new work. If for capital account, the number of the authority for expenditure should be given for record and distribution purposes.

Jan 1, 1930

By A. O. Dufresne

A Step which, it is believed, will prove extremely beneficial to the Quebec asbestos-mining industry was taken during 1931, when the asbestos mine operators of the Province assembled to work out a uniform method of naming the products of their mines. The outcome of several meetings was the drawing-up of a classification which defined, limited, and designated anew the numerous grades of asbestos marketed. It entailed no drastic departure from the existing processes of grading, nor any revolutionary changes in methods of testing, but aimed rather to perfect existing methods. The classification proposed has been accepted by all operators in the Province, who, from January first of this year, began introducing the new nomenclature. Unless one is conversant with the properties and mode of occurrence of chrysotile asbestos, with the unique milling methods devised for its recovery, and with the history of the development of their technique, he may not readily understand the basis of the new classification. For information on these and other data concerning the industry, the reader is referred to a recent publication, Chrysotile Asbestos in (Canada, by James Gordon Ross, issued by the Mines. Branch of the Department of Mines, Ottawa. The object of this paper is to present briefly some of the phases in the evolution of the classification of Canadian chrysotile asbestos, in the hope that the recent effort to standardize the marketable products of one of Canada's most important non-metallic mineral industries will open a field for discussion, fruitful in new ideas and constructive suggestions. The necessity for the grading of asbestos results fundamentally from the fact that the price per ton depends on the length of fibre. At all times in the history of the industry, the very limited available supply of the longer grades, as well as the requirements of the trade, have caused relatively very high prices to be paid for fibre over half an inch in length, while for the shorter grades the price decreases rapidly, and at a rate which bears no proportionate relation to the length of fibre.

Jan 1, 1932

By John Vergunst

"This paper traces the development of Ontario 's cap lamp standard. Over the years, numerous Coroner's Juries investigating fatal mine accidents have made recommendations with respect to underground lighting. As well, recommendations to improve mine lighting have been made by two Commissions, investigating mine safety in Ontario.During the past few years, the performance of any cap lamp worn by miners involved in serious accidents, have been measured by the Mining Heal/h and Safety Branch. Large variations in light output were found between and among cap lamp types. These variations have been attributed to the lack of quality control on the bulbs, design of the cap lamp head piece and in some cases, poor maintenance.In 1986, a series of underground tests were conducted to establish the minimum light output from cap lamps required to visually identify loose ground. The results of these tests indicated that a cap lamp should produce a minimum peak illuminance of 1500 lux measured at 1.2 metres from the light source. On May 30, 1987, Ontario became the first province in Canada to legislate the minimum amount of light required to visually assess ground conditions. INTRODUCTIONPoor lighting has been identified as a factor which can contribute to mining accidents. Over the past decade, several Coroner's Juries as a result of inquests into mining fatalities, have recommended improved lighting in mines.The Joint Federal-Provincial Inquiry Commission into Safety of Mines and Mining Plants in Ontario, was appointed to report upon the adequacy of existing arrangements and practice s that may affect safety. This Commission completed their report in April 1981, and recommended that inadequate lighting be investigated as a possible cause of all reportable underground accidents, and that a comprehensive research programinto mine lighting be undertaken.In response to the first recommendation, the Mining Health and Safety Branch of the Ministry of Labour, hereafter referred to as the Branch, initiated a program to measure lighting levels in all fatal accident investigations where inadequate lighting was a possible factor."

Jan 1, 1989

The primary (sulphide) resources at Aphrodite are refractory in nature, requiring an oxidation process stage to be introduced to facilitate extraction of the gold. The company is investigating the use of pressure oxidation (POX) as the oxidation method for processing of high grade gold bearing concentrate it plans to produce at Aphrodite. POX has been used extensively around the world for the past 30 years and continues to be the favoured option for a number of refractory gold plants currently in the design and construction stages. Initial pressure oxidisation testing investigated the effect of temperature, pressure and grind size on a bulk flotation concentrate prepared from Alpha lode material. The concentrate averaged 47.3 g/t gold and was prepared from a composite of core samples averaging 1.49 g/t gold. Sub-samples of the concentrate were subjected to POX for 1 hour resulting in rapid oxidation during this very short period. Testing undertaken showed that there was a significant increase in sulphide oxidisation at higher temperature (220°C) and pressure (2,500 k/Pa) for the two grind sizes (75 and 20 microns) evaluated. The proposed flowsheet, OPEX and CAPEX are critical aspects for project development.

Jan 1, 2014

By M. Pfeifer, M. N. Brodie, D. J. Barratt

"This paper reviews design trends related to the various SAG mill configuration and drive options available today. The impact of these options on capital and operating costs is assessed, and key technical issues reviewed. The discussion is based on the conventional North American ’pancake’ mill configuration. IntroductionDuring the past decade mill technology has evolved significantly in the following key areas:• improvements in variable speed motors continue with on-going advances in electronics;• ring motors, or gearless drives, are becoming more common in mill sizes 32 ft and larger, with ratings of 10 000 HP and greater;• geared drives have become available up to ratings of 9500 HP per pinion, compared to the earlier 6000 HP guideline;• improvements in speed reducer technology due to the use of carburized and ground precision gearing, make the high speed motor-speed reducer drive more competitive with the direct coupled low speed motor drive;• a unique speed reducer drive is being introduced to this industry which combines ring gear drive pinions with speed reduction. mprovement in gear alignment is claimed, and the overall drive arrangement is more compact than is possible with a conventional speed reducer drive;• the first 38 ft and 40 ft diameter mills have been designed and manufactured; and • application of large multi-shoe bearings have made shell supported mill configurations available for all, including the largest sizes. These designs have flat instead of conical mill shell ends, and have the potential for technical and cost advantages compared to conventional trunnion supported designs.This proliferation of mill design features provides several options to those involved in planning and design of milling plants, and requires more extensive evaluation to optimize mill design features to best suit specific project requirements."

Jan 1, 1999

By W. Beres

Many non-commercial operators are currently faced with the need to operate fleets of legacy gas turbine engines. How long such engines can be kept in service safely, without replacing a significant portion of their aging structural components, has become a growing concern to engine life-cycle managers, due to uncertainties in the remaining lives of critical components of these engines. This paper describes the application of the damage tolerance methodology to predict safe inspection intervals (SII) for critical components of gas turbine engines, using components of a turboprop engine for a transport aircraft as examples. High temperature components of this engine are made of advanced aerospace alloys. The methods of predicting three-dimensional fatigue crack growth at the critical location of turbine discs and spacers using both commercial and in-house developed algorithms are presented. Sensitivity analyses are performed to determine the effect of variations in material parameters on the predicted safe inspection intervals. In addition, spin rig tests performed for both turbine discs and spacers are described. Finally, crack growth rates predicted by numerical analyses are compared to those obtained from spin rig testing and the damage tolerance of the turbine components is assessed.

Jan 1, 2015

By Robert Macdonald, William Coombe, John F. Lewry

Gold occurrences have been known in the La Ronge Domain for many year . Mineable reserves have more recently been outlined and there is every prospect of a major gold camp being established in the domain within this decade. The La Ronge Domain lies in the Lower Proterozoic 'Trans-Hudson Orogen' and is part of a collage of Early Proterozoic crust comprising volcanoplutonic arcs, batholiths, associated volcaniclastics and volcanogenic sediments lying between the Superior Craton to the outheast and the reworked Archean basement/Aphebian cover terrain to the northwest. The domain has several lithostructural subdivisions, the most important of whjch , from a gold exploration point of view, is the Central Metavolcanic Belt. This belt is composed dominantly of a range of metavolcanic rocks and gabbroic to granitic intrusives, which geochemically resemble younger subduction-generated 'primitive' arcs developed on oceanic crust. U-Pb zircon geochronology indicates that the arc volcarusm and pre- to late-kjnematic plutonism occurred about 1890 Ma to 1850 Ma ago. The belt has an attained grade of upper greenschist to amphibolite facies and is relatively undeformed , though high strain zones occur locally. Most gold occurrences in the La Ronge Domain have been found in the Star-Waddy Lakes area of the Central Metavolcanic Belt, and in the Sulprude-MacKay Lakes area to the south which is interpreted as a tectonically dismembered part of the main belt. Both tratiformand vein-type gold occurrences are present in the domain; vein-type predominate and form nearly 90 per cent of the occurrences. The stratiform-type occurrences show a regional lithological a sociation with iron-rich sediments within proximal felsic volcanjc sequences. Some vein-type occurrences appear related to brittle fracturing associated with intrusive emplacement (the magmatic-hydrothermal "syn:' and "subvolcanic" veins) and faulting. However, most of the vein-type occurrences exhibit a spatial association with regionalscale ductile shear and other high strain zones, and were probably formed by metamorphichydrothermal processes.

Jan 1, 1986

By C. A. Lavery

A DISCUSSION is presented of natural gas production and field processing equipment as now utilized in the gas producing areas of the United States, with reference to use of such equipment in Canadian gas areas. The scope of the paper is confined to a general description of various types and methods of using surface production equipment. The discussion is divided under two general groups: well-head production equipment, and field processing. The first will be concerned primarily with indirect heaters, separators, knockouts, and special versions of this equipment. The second major group includes the field processing equipment for handling natural gas. A delineation should be made here as to the meaning of field processing as used in this discussion. We will limit our term to mean such processing equipment as may be used in producing fields to process gas or its by products in a manner that does not require conventional plant practices either in operation or supervision. This covers such equipment as is necessary to complete preparation of gas for sale to pipeline and/ or is necessary to recover valuable components. Under this heading we will discuss glycol dehydration, solid desiccant dehydration, low-temperature separation, mechanical refrigeration, and desorbtion-stabilization. These are all processes involved in preparing gas for final sale or disposal. They do not include the more conventional and large-scale plant process systems.

Jan 1, 1956

By P. Dinham, G. C. Summerton, N. McCulloch, S. Dowling, D. C. Craig

"Development of a process for the treatment of a nickel copper matte rich in the minerals heazlewoodite, chalcocite and bornite has demonstrated significant base metal recoveries and metal separation efficiencies. The determination of chemical and mineralogical changes occurring in the individual leaching stages in laboratory experiments has enabled a better understanding of the complex leaching chemistry. The chemistry and mineralogy of the piloting and laboratory processes are discussed.INTRODUCTIONThe nickel-copper sulfide ores of the South African Bushveld Complex are among the most important Platinum Group Metal (PGM) bearing ores, and contain the world’s largest reserves of platinum. The treatment used in the recovery of PGMs from these ores includes three types of processes, namely ore concentration using physical techniques such as flotation and gravity separation, concentration by pyrometallurgical means, hydrometallurgical extraction of the base metals followed by the PGMs. Following milling of the ore, flotation involves the separation of high value minerals from gangue by taking advantage of the differences in their hydrophobicity. These differences are generally maximized through the use of a surfactant or wetting agent. Concentrates are then thermally treated and melted which brings about physical and chemical changes that enable the recovery of base metals and PGMs. The main aim of the smelting and converting process is to separate and eliminate the valuable metals from the bulk of the unwanted gangue and essentially all of the iron and to concentrate the metal VALUES (into a high grade converter matte. The matte can be further enriched by magnetic separation, producing a PGM-rich magnetic fraction and a base metal-rich non-magnetic fraction. The magnetic fraction is treated by hydrometallurgical processes to produce a PGM concentrate which is further refined to separate and purify the individual metals. The non-magnetic fraction is treated to produce marketable metal VALUES (such as nickel, copper, cobalt and to a lesser extent PGMs. The principal objective of any hydrometallurgical extractive process is to leach the desired elements selectively into an aqueous phase so as to separate them from the bulk of the material. (Crundwell, Moats, Ramachandran, Robinson and Davenport, 2011; Hundermark, Mncwango, de Villiers and Nelson, 2011)."

Jan 1, 2012

By Anoop Sattineni

Over the past decade the use of BIM in the AEC industry has grown several fold and with it the number of standards available for implementing BIM. The ?National BIM Standard? by buildSmart Alliance, the ?Contractor Guide to BIM? by the Associated General Contractors of America, the ?BIM Project Execution Planning Guide and Templates? from Penn State University, the ?BIM Roadmap? by the US Army Corps of Engineers are some of the several BIM guidelines that are currently available to the AEC industry practitioners. Some of these guidelines are as comprehensive as defining BIM and the associated taxonomy while others are meant to be used on an individual project basis. From a contractor?s perspective one of the key benefits of using BIM is for the purpose of collision detection and coordination. This research has found that currently available guidelines do not address these issues adequately. For instance, the currently available guidelines do not allow the subcontractor to quickly communicate issues such as naming conventions and color schemes within the model, to the general contractor. Consequently general contractors and sub-contractors find themselves making changes to their BIM deliverables based on each other?s abilities and levels of adoption, apart from reason?s stemming from use of different software platforms. This paper describes how a group of contractors and subcontractors from Atlanta and Birmingham in the United States came together to create and adopt a ?Coordination Guidelines for Virtual Design and Construction?. These guidelines were specifically created with the purpose of streamlining the construction coordination process using BIM. This paper describes how the guidelines created differ from other guidelines currently available in the industry.

Aug 1, 2013

By Howard J. Handewith

"Tunnel boring machines have been tried in underground mining applications as early as 1957. Although tunneling machines hardly threaten to supplant traditional drill-blast-muck operations for drifting, the latest modern machines offer substantial improvements in progress rates over traditional methods under certain conditions.An evaluation guide is offered which identifies conditions that favour machine boring. Different types of costs related to the use of a tunnel machine are discussed. The advantages of the tunnel machine over the traditional method are reviewed. IntroductionThe first tunnel boring machine ever used in a mine was in Quebec in the year 1957. Although less than successful at the time, this experiment served to illustrate the mining industry' s willingness to try new ideas. Since 1957, the manufacture of tunnel boring machines has developed into a full-size industry. Most contractors in Europe and North America will now consider the use of a tunnel boring machine first on any long tunnel that can have a circular section.The modern tunneling machine offers a great potential to the mining industry. Just as the blasthole and raise drill machines have revolutionized mining in the last decade, it is expected that tunnel boring machines will make an equal impact in the future.This is not to suggest that tunnel boring machines will replace explosives in the foreseeable future, but they can supplement drill-and-blast operations. In areas where long drifts, inclines, declines or cross-cuts are needed in a hurry, the tunnel boring machines offer the fastest way to a production return on investment. Figure 1 shows the range of production that two types of tunnel machines have produced as compared with conventional excavation methods in various ground conditions.Rotary hard-rock tunnel boring machines (Fig. 2) commonly produce progress rates in excess of 20 metres per day in uniform ground from 300 to over 2,000 kgl cm2 in unconfined compression strength . These averages are for the completed tunnels. One 7. I6-metre-diameter tunnel boring machine just completed a 1O.7-km tunnel in hard rock of 700 to 2,800 kg/cm>, The last eight months of production averaged 30 metres per day."

Jan 1, 1980

By F. E. Senftle

Introduction The usual laboratory methods of uranium analysis are either tedious, time-consuming chemical procedures or elaborate physical methods requiring sensitive equipment. There is thus an urgent need for a method of estimating the uranium content of ore samples by approximate analysis in the field. When a new property is being developed, it is desirable to know, with the least possible delay, the uranium content of channel samples in order to guide the diamond drilling and digging operations. Prospectors, too, require approximate analyses of their hand specimens to evaluate their discoveries. To satisfy the demand for these types of analyses, several field procedures have been tried. Two general plans can be followed. One is fast but will yield only a rough estimate. The other is slightly longer but, if done carefully, will give an assay probably within 10 per cent of the true value. For field operation it is necessary to strip the more accurate laboratory methods of analysis of all refinements because of the limited equipment and skilled techniques at hand. Most of the corrections normally applied, with the exception of that for equilibrium, will not alter the gross analysis to any appreciable extent. When uranium atoms in pitchblende disintegrate, they break down into other radioactive elements, and eventually the number of elements being formed is equal to the number breaking down. The ore is then said to be in equilibrium. Certain geological processes, however, such as leaching, may selectively remove some of these elements and hence reduce the radioactivity of the ore sample. The ore is then said to be out of equilibrium. The field analysis may then be in error by as much as 50 per cent since the apparatus is calibrated with standards that are in equilibrium. However, such a large error due to loss of equilibrium is the exception, and in most cases uncorrected field types of analyr.is are justified.

Jan 1, 1949

By J H. Dressel, J. E. Williams

This paper presents a brief review of what coal gasification is, procedures that are available today and processes that may be available in the future. Examples are given as to how the process might be used in power plant applications, the effect on pollution level and power costs, and some thoughts on the added burden that might be placed on mining and coal preparation.

Jan 1, 1973

By A. K. Chetin, W. W. Fitkin

"The reservoirs of Mississippian Mi-dale beds and Frobisher beds found in the Weyburn field lie at the north-western termination of a broad productive belt extending 120 miles along the northeastern rim of the Williston basin. These carbonates, and inter-bedded evaporites, originated during cycles of marine transgression and regression, and were deposited as rock types characteristic of shoal, lagoon, and basinward shelf environments. The Frobisher-Alida Beds, which form a secondary reservoir to the main Midale Beds of producing zone are composed of oolit1c, fragmental-bioclastic, vugular limestone capped by an impervious dolomitic mudstone. Production is controlled by localized structural features resulting from de-positional build-up. Excellent reservoir conditions are accompanied by an active water drive. The Frobisher Evaporite, consisting of massive primary anhydrite with dolomitic veinlets, forms the floor seal for the Midale beds oil accumulation. A significant facies transition into an oolitic, bioclastic, vugular limestone characterizes this unit. Beyond the depositional margin of the evaporitic facies, marked increases in porosity and permeability of the en-tire reservoir are noted. Carbonate units overlying the areal extent of the Frobisher Evaporite exhibit a greater degree of metasomatism, dolomitization, and more abundant secondary anhydrite.Porous carbonates comprising the producing zone of the Midale beds are divided into an oolitic, fragmental bioclastic, vugular limestone, and an overlying granular marly lime-stone unit, capped, by the Midale Evaporite. Oil is accumulated in a stratigraphic trap bounded above and be-low by primary anhydrite and truncated by the post-Mississippian erosional surface. Mississippian strata dip basinward from this erosional surface in a broad homocline exhibiting only minor irregularities. Rapid lateral and vertical porosity and permeability variations are common. Localized, separated, porous lenticles contain interstitial water in areas where the Midale beds are underlain by the Frobisher Evaporite. The major portion of the field, however, is capable of water-free production. Bottom and edge waters are found in certain portions of the field. Productive limits are tentatively defined around most of the present field perimeter. A large area along foe southern edge of the field remains open to future development. Probable ultimate remaining recoverable crude oil reserves, as of September 30th, 1958, were estimated by Mc-Daniel Consultants Ltd. to be in excess of 330 million barrels."

Jan 1, 1959

By G. M. Brownell

A DEPOSIT of hematite occurs on Black island, lake Winnipeg, at a point known locally as Red Rock, on the south shore of the island directly across from Clements point. The mail boat from the Canadian Pacific Railway terminus at Riverton, crossing the lake to Manigotogan twice weekly, passes near Red Rock and provides a convenient means of transportation to this part of Black island (Figure 1). HISTORICAL The occurrence of hematite on Black island has been known for a long time. Dowling's report of 1898 states(1): "An iron-ore deposit on the south side has been known' for many years, and on Jeffrey's map of 1762, showing Canada and northern part of Louisiana, Iron island is shown a short distance south of the narrows, evidently the same as the Black island of today".

Jan 1, 1945

By Jun Xiao, Xiaodong Li, Chunming He, Daixiong Chen

"Benzohydroxamic acid with double dentate can react with copper to form cyclic hydroxyl oxime acid copper chelate, indicating a good selectivity for copper oxide minerals flotation, especially for malachite. The flotation results of the pure malachite mineral show a strong synergistic collecting effect between hydroximic acid and xanthate at a ratio of 3.5:1, achieving a malachite recovery of 95.5% when certain sodium sulphide is used as a sulphidizing agent in the optimal pH range. Thanks to the synergistic collecting effect, the flotation recovery of malachite of a real refractory ore flotation ,can reach over 92% under the optimum condition, a 12% higher than the recovery achieved with the conventional collectors. In industrial application, the flotation of the copper oxide minerals is improved , leading to a high efficiency utilization of copper oxide resources.INTRODUCTIONBeneficiation of copper oxide ore is one of the recognized challenges in mineral processing industry. Copper oxide ore is a vital component of copper resource in the world, which has abundant reserves. Majority of sulphide deposits has oxidized zone on the top, and some deposits are oxidized to become the large and medium-sized oxide deposits (Willam & Chavez, 2001). Most copper oxide ores have problems in processing such as high slime consumption, poor floatability, complex ore property and low flotation recovery, so it is of great significance in beneficiation of copper oxide ores to develop an efficient collector, especially for malachite (Fu & Gu, 1997; Wen, 2010; Riet, Kier & Elford, 1980). At present, sulphidization-xanthate flotation is the most important method for treating copper oxide ore. In recent years, due to the decreasing ore grade, the utilization of refractory copper oxide ore draws more and more attention (Zhou, 2003), except for sulphidization-xanthate method, chelating flotation method (Lu, 2009), chemical beneficiation method (Lenormed, Salman & Yoon, 1979), microwave radiation flotation method, hydrothermal sulphidization-flotation method (Mao, Wen & Fang, 2014) and ammonia leaching of sulphide precipitation-flotation method (Lekang, Stevik & Bomo, 2003) have occurred."

Jan 1, 2016

By P. G. Smith, A. Axiuk

The objective of this paper is to present, from a practical perspective, a review of the most relevant maintenance procedures that are accepted or prescribed to be the most effective in optimising service life potential and to ensure continued safe use of steel wire ropes for shaft mining applications. The paper will address the most common operational issues encountered in the care and operation of shaft ropes for both conventional drum hoists and multi-rope friction winders. For each distinct maintenance procedure presented, a limited amount of theory is discussed to identify the underlying mechanisms at play that must be addressed and to emphasize the logical basis for the recommended course of action. It is recognised that each installation is unique and that the recommended maintenance procedures may not always be practical or cost effective from an operations standpoint under select circumstances, however the intent remains to promote industry best practices for the knowledge and benefit of the mine hoisting community, from experienced maintenance personnel to new entrants to the industry alike.

Jan 1, 2023

By T. Crivits

"Freeze lining technologies are used industrially to protect the integrity of furnace walls in pyrometallurgical reactors. This is achieved by solidifying a protective layer of slag on the inner furnace wall. In the current study, laboratory experiments have been undertaken to produce freeze linings in ‘Cu2232 O’-‘FeO’-MgO-SiO slags under controlled conditions using an air-cooled probe technique. Whilst most thermal models of freeze linings have assumed the freeze lining-bath interface to be at the liquidus temperature of the bulk bath and to be planar in geometry, the current research has demonstrated that this is not the case. Experiments undertaken using this high-temperature slag system have shown the interface at steady state conditions to be at subliquidus temperatures. The solid phases present at the interface do not include the primary phase and the interface is non-planar. The study indicates the need for improved understanding of the fundamentals of freeze lining formation, and of the influence of system properties and process parameters"

Jan 1, 2015

By Roland B. Hoag, Roger G. Webber

Sulphate concentration in groundwater is a good measure of the extent of oxidation of sulphides, provided that sulphide minerals are the primary source of the sulphate. A study was conducted near the Eustis Mine in Quebec to determine where and how the sulphate in groundwaters originated. Atmospheric precipitation is the only source of sulphate other than oxidation of sulphides, and in this study area it is equal to 0.01,. millimole per litre. The oxidation of sulphides can be divided into subsurface oxidation (mainly inorganic processes) and surface oxidation (including both organic and inorganic processes) . The maximum sulphate concentration due to subsurface oxidation of sulphides depends on the solubility of 0 2 in water and is 0.25 millimole per litre. Surface oxidation is, therefore, responsible for any amount greater than atmospheric plus subsurface contributions (0.29 millimole per litre). Surface inorganic oxidation occurs in waters with a pH greater than 15 and is controlled by the kinetics of the oxidation processes. Organic (bacterial) surface oxidation is dominant only in acid (pH< 1.5) waters. The bacterial action accelerates the oxidation of sulphides, and large quanttties of sulphate may be introduced into solution.

Jan 1, 1976