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By Richard J. Mainiero, Michael J. Sapko, Marcia L. Harris

Since 1988, there have been thirteen documented incidents in the United States and Canada in which carbon monoxide (CO) is suspected to have migrated through near surface strata into structures or other enclosed spaces as a result of nearby trench blasting or surface mine blasting. From these incidents, there are thirty suspected or medically verified CO poisonings and one fatality associated with these incidents. To better understand the variables contributing to this hazard, the National Institute for Occupational Safety and Health (NIOSH) carried out a small- scale field study to identify key factors that may contribute to the migration of CO through the ground. NIOSH conducted single- hole heavily confined experimental test shots to measure the radial pressure pulse as it propagated through surrounding monitoring holes to determine if a relationship existed between the pressure pulse and resulting CO measurements afterwards. NIOSH also monitored blasts at an airport construction site. Following the detonations, the concentrations of CO, nitric oxide (NO), and nitrogen dioxide (NO2) were monitored for several days in the surrounding satellite holes. The peak CO measurements relative to distances from the shots were compared. Pressure histories and peak particle velocities (PPV) were measured at monitoring boreholes. It was found that the differential pressures recorded within the boreholes give some indication as to the likelihood of CO appearing, whereas the PPV measurements do not seem to be as good an indicator for potential CO migration. In this limited study, changes in barometric pressure had very little influence on removing the trapped detonation products, whereas applying a vacuum to the monitoring holes was effective in reducing the entrapped CO concentration.

Jan 1, 2005

By Charles Zdazinsky

Over-break is undesirable in underground civil construction because it excessively damages rock along the perimeter of the tunnel, which directly influences the cycle times of advancement. A quicker cycle time for each process is required to optimize the operation and therefore minimizing over-break is essential for operational success.

Jan 1, 2015

By Thomas P. Kwiatkowski, Joginder S. Bhore, Christopher D. Orlandi, Jose Velez

Three case histories of successful TBM tunneling for New York City Water Tunnel No. 3 are presented. The tunnels, costing about one billion dollars total, are the 5-milelong, 18'-11" OD Brooklyn Tunnel; the 5-mile long, 23'-2" OD Queens Tunnel, and the9-mile long, 12'-4" OD Manhattan Tunnel. The three tunnels are the first major tunnels constructed in New York City rock utilizing the TBM method of construction. This paper describes and compares the three tunnel projects in terms of geology, construction methods, TBM’s, rock and groundwater behavior, rates of advance and other performance data, and challenges and solutions encountered during the projects.

Jan 1, 2007

The roasting of sulphide ores and concentrates is often the first step in the production of metals or chemicals. In many processes, the production of sulphuric acid is viewed as a by-product, whereas in some plants production is an important economic factor. Regardless of the purpose, a pyrite roasting plant consists of mainly three plant sections: roasting, gas cleaning and sulphuric acid. With the addition of air, the pyrite concentrates are transformed into solid oxides and gaseous sulphur dioxide at temperatures of 600?1000°C. After cleaning and cooling, the sulphur dioxide in the roasting gas is further processed to sulphuric acid. Two types of reactors are used depending on the application: stationary or circulating fluid bed. For over 60 years, Outotec has progressively been developing the principle of fluidized bed technology in several different reactor types for a multitude of process applications. The versatility of the fluidized bed reactor system has manifested itself in the treatment of minerals, including solid fuels, and for metallurgical processes both in the ferrous and non-ferrous fields. Process applications have included roasting, calcining, combustion and charring of coals, as well as off-gas treatment. This paper provides a summary of the pyrite roasting technology currently used along with a simple cost comparison of pyrite roasting and sulphur burning processes.

Jan 1, 2009

By Peter Zhang

Shield recovery in a longwall move is normally conducted from tailgate to headgate. However, if the face is wide and the immediate roof is weak, difficult conditions with considerable roof sag, excessive shield load, and local roof falls could occur as the shield recovery proceeds to the middle of the face, causing delays in shield recovery. The situation could be aggravated when a pre-driven longwall recovery room is employed. Alternatively, a bi-directional approach for shield recovery, i.e. shield recovery starting from the middle of the face towards both tailgate and headgate, can alleviate the roof sag significantly by quickly withdrawing the shields towards the lower abutment pressure zones at the headgate and tailgate sides. In this case, the bi-directional shield recovery approach was used in a longwall move for a 1450 ft wide face under weak roof conditions. Shields were successfully withdrawn within five days without experiencing significant roof sag. The time-dependent roof-to-floor convergence, shield pressure, and roof conditions were monitored during shield recovery. 3-D finite element modeling was conducted prior to longwall move to evaluate the difference between a uni-directional and a bi-directional shield recovery during a longwall face move. Vertical stress, yield zone in and around the recovery room, load on the shields, and convergence at the center of the shield canopy were obtained from computer modeling, and compared with the data from field monitoring. Finally, the advantages of the bi-directional shield recovery are discussed.

Jan 1, 2007

By Junji Shibata

It is important to recover and reuse the metal values contained in various industrial wastes in a viewpoint of environmental preservation. Most of industrial products are made through the processes to separate impurities in raw materials, solid and liquid wastes being necessarily discharged as industrial wastes. Chemical methods such as solvent extraction, ion exchange and membrane, and physical methods such as heavy media separation, magnetic separation and electrostatic separation are considered as the methods for separation and recovery of the metal values from the wastes. In this paper, some examples of the application of solvent extraction to the treatment of wastes are introduced. The treatment of solid wastes such as Ni-Co alloy scrap, Sm-Co alloy scrap, fly ash and flue dust, and liquid wastes such as plating solution, the rinse water, etching solution and pickling solution are accomplished using solvent extraction technique.

Jan 1, 1996

By R. Al-Hent, M. Aissa, J. Asfahani

"This paper focuses on determining the favorable geological and hydrogeological conditions for forming uranium occurrences in the Froqlos-Jabal Abou Rabah region, Palmyrides, Syria. Eighty rock samples from this area were analyzed by spectrometric gamma-ray technique to determine the radioactive concentrations of eU and eTh, and of %K. Uranium concentrations in shallow and deep groundwaters were also determined. High uranium concentrations were registered owing to the presence of phosphatic outcrops in the study region. The uranium migration trends and its remobilization were analyzed through the analysis of the behavior of eU, eTh, and their ratio. A positive relationship between eU and eU/eTh, and a negative relationship between eTh and eU/eTh in geological formations of different ages supports the secondary remobilization of uranium. The role of groundwater movement in transportation and redeposition of uranium mineralization is discussed: deep waters are less oxidizing than near-surface waters, and do not appear to have significantly remobilized uranium. This indicates that the source of secondary uranium mineralization is surficial or near surficial, and is mainly related to the leaching of outcropping phosphatic layers.Integration of the results with established radioactive and geological sections reveals four radioactive anomalous zones: north Froqlos, Kherbet Hannora, northwestern flanks of Jabal Abou Rabah (Kherbet Al-Hajar), and the northwestern limit of the Ghuntor depression. The high uranium concentration in north Froqlos is because of its original presence in the phosphate beds and extensive fracturing, which allows groundwaters to penetrate and remobilize the uranium. High uranium concentrations in the other three locations are caused by the presence of evaporites and capillary action, which draws solutions upwards and causes redeposition as surface crusts (gypcrete)."

Jan 1, 2009

IN the recent monograph on Broken Hill, N.S.W., by E. C. Andrews,* two independent petrological reports appear as Appendices 1 and n, by W. R. Browne and F. L. Stillwell respectively. In these considerable differences of opinion occur. Andrews contributes to some of the questions at issue, but no analytical review of the differences appears in the body of the report. Their development may invite question, and the following notes have been prepared partly in explanation and partly as a summary of some of the divergences. The soope of Browne's report extends over the whole district of Broken Hill, while Stillwell's deals with the rocks within 25 chains of the main lode. The more difficult and important rock-types occur in both areas, raising similar questions. In both cases observations extended beyond the limits of the prescribed areas. Broadly, Browne faces his problem as a study of a series of primary igneous rooks, acid and basio, whioh are intrusive into a series of sillimanite gneisses. The development of the sillimanite gneisses is regarded as belonging to an earlier period than the intrusion of the igneous rooks, while the gneissio structures of the latter are features which are incidental to their orystallization, and are not acquired subsequent to their consolidation. He finally produoes a picture in which his views of igneous injection and differentiation takes a prominent place. One direct result is the claim that three separate periods of metamorphism have oocurred in the Broken Hill area. Stillwell primarily examines the rooks as schists and gneisses since their present dominating features have been acquired during metamorphism. The effort is made to understand suoh differences as might arise from differing conditions of metamorphism upon rocks of similar and different oonstitution. The aim is to divest the rocks of those oharaoters which are due to metamorphism before approaching the questions of intrusive relatio'nships between igneous rocks andsediments.

Jan 1, 1924

From time to time efforts have been made to classify rocks according to their hardness, toughness and abrasiveness, and to use these classifications to provide an indication of the ease or difficulty with which they may be drilled. However, rocks classified as of similar type on this basis may vary considerably in their .resistance to the penetration of a rock drill bit due to differences in their physical state.For instance, fine grained rocks of granular texture are more difficult to drill than equivalent' rocks of coarser structure, altered rocks drill more readily than unaltered ones, and silicified rocks usually exceedingly hard and tough may be so shattered by movement as to be drilled at a rate comparable to quite soft rocks. Therefore, considerable latitude has existed in this method of defining their drillability, and no values generally acceptable have materiaJised; so that, when the drilling properties of rocks are discussed, it is common practice to refer to their hardness or toughness in a greater or lesser degree depending to some extent on the emotional state of the drill runner.REFERENCES AND STANDARDSThe 'introduction of tungsten-carbide tipped rock-drill bits for use with percussion rock-drills has thrown increasing emphasis on the need for defining a rock's resistance to penetration in a more concise and generally acceptable...

Jan 1, 1950

By C. Slotta, F. Charlier, P. Blomen

"Within the energy concept of the German government, the operating time of nuclear power plants was initially extended from about 8 to 14 years. It is planned, however, that every power plant will gradually be decommissioned until 2025 and that simultaneously the amount of renewable energies will successively be expanded. According to the political state, nuclear energy is a discontinued model. Looking at the global energy market, though, an obviously opposed development can be observed. At the moment, 443 nuclear power plants are running worldwide and further 62 facilities are being built. These about 500 nuclear power stations have to be supplied with nuclear fuel right now and in the future. The present paper will describe the worldwide use of nuclear energy, the extraction of the nuclear fuel uranium and in detail the available and predicted resources of uranium. The conclusion of the paper is the statement that uranium as nuclear fuel is no scarce resource but sufficiently available."

Jan 1, 2011

By Jack S. Watson, Rasika Nimkar, Robert M. Counce, Matthew Gordy, Patrick Zhang

Waste phosphatic clay presents a difficult disposal problem and a significant loss of P2O5. Recent developments make this study on the use of phosphatic clay as a feed material for H3PO4 production worthwhile. (a) New data from Florida Industrial and Phosphate Research Institute (FIPR) suggest that the Bclay^ waste can be effectively treated by improved solid separation coupled with flotation to produce feed material for recovering additional phosphate. (b) The use of BOLI Flowsheet^ provides capability to predict performance of aqueous-based processes for a range of possible operating conditions. Using the new FIPR data and BOLI Flowsheet^ enabled the design of a new process that can potentially extend the usefulness of current P2O5 ore deposits. Predictions using OLI Flowsheet were able to identify process conditions that effectively overcome the difficulty of high Mg content of phosphatic clay. Estimated manufacturing cost in the current study lead to valuation of the P2O5 content of the phosphatic clay recovered/utilized at 60 to 70% of that of the phosphate rock feed material currently used. Phosphatic clay should be considered as a valuable material that is currently given zero value. The new FIPR data and BOLI Flowsheet^ enables the design of a new process that can potentially extend the usefulness of current phosphate ore deposits by extending the fraction P2O5 of recovered

By Christopher Mark

Knowledge of in situ stresses is fundamental to many studies in earth sciences, and coal mine ground control is no exception. During the past 20 years, it has become clear that horizontal stress is a critical factor affecting roof stability in underground coal mines. The theory of plate tectonics and the World Stress Map (WSM) project has been extremely helpful in explaining the sources and the orientations of the horizontal stresses observed underground. Recently, WSM geophysicists studying deep-seated stresses have developed a model of how stress magnitudes vary with depth in the crust. They have devoted relatively little attention to near-surface stresses, however. This paper explores the relationships between deep-seated and shallow in situ stresses in several of the world?s coalfields, using a data base of more than 350 stress measurements from underground coal mines. The analysis indicates that distinct regional trends exist, corresponding roughly to the regional stress fields identified by the WSM. The paper presents equations for estimating stress magnitudes that were developed by treating depth and elastic modulus as independent variables in regression analysis. The magnitude of the horizontal stress increases with depth, at rates that range from 0.8 to 2.0 times the vertical stress, just as the WSM ?critically stressed crust? model predicts. Overall, it seems that the stress regimes encountered in underground coal mines are closely linked to those that exist deep in the earth?s crust.

Jan 1, 2008

By Parker A. J, Muir D. M

Solutions of acetonitrile in water dissolve water soluble copper(I) chloride. Removal of volatile acetonitrile from the resulting solutions, by distillation with low grade steam, precipitates pure copper(I) chloride. This is used to purify a crude copper chloride sublimate from the chlorination of nickel matte but is applicable to other sources of copper(I) chloride. The pure product can be converted to pure copper(I) oxide, copper(II) oxychloride or pure copper metal directly.

Jan 1, 1980

By J. E. Urosek

Decisions made during a response to a mine fire or an explosion greatly affect the final outcome. The safety of miners should be the primary concern with accounting for all of the miners the first issue for resolution. If miners have not safely evacuated from the mine, the last known location of the miners at the time of the event and anticipated travel routes are primary exploration areas. After the mine is evacuated, there are many very important decisions that must be made quickly and often under great stress. It is critical that the mine operator establish an orderly method to direct the mine emergency response. Designation of a Command Center, staffed with personnel charged with developing plans, is a common method of establishing control. Scheduling of key mine managers will be critical, since decisions must be made 24 hours a day and people working for extended periods with little or no sleep do not always make clear or cognizant decisions. Internal communications, passing information on to subsequent shifts, and external communications with families and media must be accurate and timely. Assembling resources for responding to the mine emergency is critical for an effective response, and pre-planning can pave the way to a successful recovery. Sampling mine gasses and accurately determining the composition of gas mixtures is a common tool used to develop response plans in all fires and explosions. It is essential that preparations for emergency situations are made well in advance of a disaster. Effective communications are essential for mine management to successfully respond to a mine emergency. This paper discusses some considerations which need to be addressed in directing a response to a mine fire or explosion.

Jan 1, 2009

By James P. Stewart

This case history describes the engineering design and construction for the Contractor of a 35-ft-deep excavation for an 800-square-foot addition to an existing sewage pump station. The site posed unexpected geotechnical complications that included deep gravelly soil, a history of local construction difficulties, groundwater consisting of heavy salt brine, and the need to underpin the existing pump station. The project took an interesting twist when the Owner issued a change order limiting the dewatering discharge to a fraction of that required to lower the water table. This documents the interesting circumstances of this job and documents the unusual subsurface conditions in the Syracuse, NY Lakefront area.

Jan 1, 2003

By G. S. Scott

In the course of the investigation into the causes, behavior, and control of mine fires, which the Bureau of Mines is now conducting, some attention was given to the subject of spontaneous heating. It is self-evident that the temperature of a pile of broken coal will rice if the rate of generation of heat exceeds the rate of brat dissipation and will fall if the opposite is the case. Factors that affect the rate of generation of heat are:

Jan 1, 1941

On the Role of Dixanthogen in Froth Flotation

Sep 13, 2010

By Aparup Chattopadhyay, Barun K. Gorain

"Porphyry copper deposits are the most important source of copper and also gold within the orogenic belts. These deposits are characterized by low grade copper ore (0.2% to 1% copper) and host precious metals like gold, silver and platinum. A characterization tool has been developed for complex porphyry type copper-gold deposits with an aim to quantify copper and precious metal deportment. This quantification is a challenging task due to low grades and also due to the presence of both visible and invisible precious metal content in different sulphide and non-sulphide phases. Studies were initiated on various complex ore deposits and also on samples representing various processing streams such as flotation and leach products. This paper presents the development of a systematic approach to diagnostic metallurgy using state-of-the-art optical and automated mineralogy, micro-probe, dynamic SIMS and TOF-SIMS analysis for quantification of invisible and visible precious metals content in various species. The relevance of this characterization to metallurgy will also be briefly discussed in this paper.INTRODUCTIONA novel characterization tool has been developed for double refractory gold ores and complex copper-gold ores using state-of-the-art technology for quantitative gold and copper deportment study. The characterization of these ores is a challenging task due to low copper and gold grades in ores, presence of both primary and secondary copper sulphide phases and variable proportion of visible and invisible gold in different sulphides phases (pyrite, chalcopyrite, chalcocite and bornite) and iron oxide phases (magnetite, hematite and goethite). A study was initiated on various ore deposits and also on samples representing various processing streams of pilot plant batches such as flotation concentrates and tailings. This paper attempts to discuss the deportment characterization methodology through presenting results from investigations on four samples from a flotation circuit viz, Feed, Final concentrate, Cleaner Scavenger Tail and Rougher Tail samples. These four samples represent the key streams for a typical copper-gold flotation flow sheet. The key objective of this investigation was to identify and quantify visible and invisible gold along with understanding the morphology and liberation of gold associated with various sulphides, Fe- Oxides and non-sulphide gangue species. In addition, the aim of this study was also to relate this mineralogical and gold deportment information to metallurgical performance."

Jan 1, 2013

By Edgar Carlos García Flores

El presente texto señala al Perú como modelo de sistemas de explotación minera para Bolivia -en tanto desarrolle, prepare y explote las minas con calidad y así incrementar la producción de sus operaciones mineras. Asimismo, describe los procedimientos idóneos para seleccionar las tablas geomecánicas, la ingeniería de explosivos, equipos de acarreo y los elementos de sostenimiento adecuados para las excavaciones subterráneas con el objetivo de tener operaciones de calidad, seguras y óptimas.

Feb 1, 2015

By S. H. Ward

An account of a new method of investigating the electrical .properties J the earth's crust is presented. The method, called AFMAG, employs, as a source, natural alternating magnetic fields of audio and sub-audio frequencies. Measurements of the distortion of these fields caused by geological features are made with the aid of search coil detectors at several discrete frequencies. Many results of field surveys made with the method are presented and they illustrate its advantages and limitations when applied to the search for massive sulphide mineralization. The advantages far outweigh the limitations and in fact indicate that a major breakthrough in geophysical exploration technique and instrumentation has been made.

Jan 1, 1958