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By Chang Chia -Fu

The generic structure of our bimesogens is shown in and for a typical blue-phase mixture of the type we describe here. We use mixtures of the ratio 33.4% (n =2.6), 34.1% (n =6.57), 36.6% (n= 11.15) with of the high twisted power (HTP) agent BD H1381(available from Merck Chemicals and described in ref. We then studied the electric-field dependency of the selective reflection in BP I* at 20.7 °C by applying increasing and the decreasing pulsed alternating current (a.c.) electric fields (100 Hz).

Jan 1, 2006

By C. Hennesmann, D. Maijer, S. L. Cockcroft, P. Yo

"Die cast aluminum wheels are one of the most difficult automotive castings to produce because of stringent cast surface and internal quality requirements. As part of a collaborative research agreement between researchers at the University of British Columbia and Canadian Auto Parts Toyota Incorporated, work has been underway to predict heat transport and porosity formation in die cast A356 wheels. The basic heat transfer equations have been solved using the commercial finite element package ABAQUS to which specialized routines have been added to predict porosity. Preliminary work on predicting porosity formation focused on using the Niyama parameter as a measure of the probability of porosity. The latest version of the model incorporates a new fundamentally based porosity criterion, which takes into account the effect of hydrogen concentration. The development of this model together with its application to a series of cylindrical test castings as well as a production cast wheel are presented.I. IntroductionDie cast aluminum wheels are one of the most difficult automotive castings to produce because of stringent cast surface and internal quality requirements. Microporosity, in particular, is a common defect that can adversely affect wheel quality. The mechanism of microporosity formation in aluminum alloys is complex owing to its dependence on the interaction of a number of phenomena occurring during solidification including the decrease in hydrogen solubility, the decrease in volume, the development of the solidification structure, and the increase in difficulty in interdendritic feeding [1]. As a result, the amount, size, and distribution of microporosity is affected by a large number of casting parameters including thermal variables, melt composition, grain structure, modification, and inclusion content, making optimization by trial-and-error methodologies difficult.The use of criteria functions, based on thermal conditions during casting, offers a relatively simple approach to predicting microporosity. In practical terms, they are useful because they provide a straightforward method of assessing the impact of varying casting parameters on porosity through various thermal parametersl21 such as thermal gradient, cooling rate, solidification time, and solidus velocity. Drawbacks of criteria functions include insensitivity to varying hydrogen concentration and the limitation to qualitative predictions. Consequently, in aluminum alloys, attempts have been made to develop models incorporating the effects of hydrogen gas and microstructure evolution. However, these types of models represent a significant increase in complexity and sacrifice the simplicity and ease of application of the thermally based criteria functions."

Jan 1, 2001

By K. J. Martchek

"This introductory presentation will highlight recent efforts to quantify the positive value of recycling metals such as aluminum, magnesium, lead, zinc, nickel and copper in relation to the three pillars of ""sustainable development"" - environmental protection, economic development and improve social consequences.This presentation will provide an overview of life cycle assessment profiles increasingly being utilized by customers, regulators and environmental advocacy groups to holistically evaluate the environmental performance of materials and products. The environmental profiles of prodi.lcts containing recycled metal will be presented based on rules established by the International Organization for Standardization (ISO).Significant to the life cycle profile of metal products is recent confirmation. that recycling has the potential to reduce materials production energy consumption by 95% for aluminum, 80""/o for magnesium and lead, 75% for zinc, and 70% for copper. Furthermore, . ""metals are eminently and repeatedly recyclable, while maintaining all their properties (1 ). "" Their durability relative to many hydrocarbon based materials enhance .their life cycle performance. However, the persistence of metals when dispersed into our natural environmental makes recovery and recycling particularly important Overall, when considering life cycle effects, recycling is critical to a sustainable future for metal products.Finally, regional and international regulations will be highlighted which will effect the efficient recovery and recycle of metals and their overall contribution to environinental protection, economic development and the enhancement of society."

Jan 1, 2000

By Bror Nyrnan

Solvent extraction technology and equipment have been developed within Outokumpu since the early seventies. During this period altogether nine solvent extraction processes for molybdenium, zinc, rhenium, cobalt, nickel, calcium and magnesium have been commercially adopted in Outokumpu's metallurgical plants. During last years a new mixer-settler concept based on a "Vertical Smooth Flow" (VSF) principle has been developed. It has also been found to be a good method for copper solvent extraction, decreasing essentially the crud formation and the organic and aqueous entrainments.

Jan 1, 1994

By Yasuo Ojima

The mainstream of copper smelting processes in the world today is a combination of Outokumpu type Flash smelting and PS (Pierse Smith) converting process. Presently it can be estimated that about 50% of the worldwide copper production is produced by the Flash smelting process and 80% by the PS converting process. PS converting process due to its operational flexibility and despite its batch character of operation has been widely used in many smelters for more than 100 years. However, an environmental issue has been pointed out related to this process because of the difficulty of handling the fugitive gases. Recently several copper smelters in the world have been newly construeted and others have executed major modification and modernization. The continuous converting process has been applied in many of them instead of PS converting process. This paper compares PS to the emerging continuous converting process and makes a prospect of the future of the copper converting process.

Jan 1, 2003

By Florian Kongoli

Converters have been playing an important role in the extraction and processing of metals ever since the first type of converter was invented about 100 years ago. Historically their operation has been mainly based on the experience of talented operators rather than on strict control and optimization technologies. However, in the new realities of unavoidable necessity to increase productivity and in the conditions of diversification of primary materials from various geographical areas, improving control and optimization techniques have become indispensable. In this paper a review of the authors? previous work in terms of improving control and optimization of converter operational practices related to magnetite content and precipitation, slag and metal blows, problematic and dangerous elements such as As, Sb etc. has been described by highlighting the advantages that the new control and optimization methods and tools bring to everyday converter practices. Several examples are given and future work is underlined

Jan 1, 2005

By W. -D. Schneider, B. Schwab

Like all metals, zinc can be recycled theoretically without end. To demonstrate environmentally friendly use of zinc, it is necessary to increase the recycling rate. In this regard, the Imperial Smelting Process developed in the forties and fifties in the United Kingdom has become more and more important. This unique process combined with a sinter plant, hot briquetting, and direct injection through the ISP furnace tuyeres offers ideal possibilities to recycle all kinds of zinc and lead bearing materials. Possible secondary materials include Electric Arc Furnace (EAF) dust, zinc-containing sludges and even zinc/carbon batteries. This high temperature process also destroys all organic materials, like dioxin, and can be seen as a sink for many harmful substances.

Jan 1, 2000

By J. David Chapman

There are a variety of choices of materials for mineral extraction processing. Traditionally, end users have used metallic piping for fluid handling and little is known about the advantages (or limitations) of non-metallic piping systems. This presentation will review custom FRP pipe systems and their use in severe corrosive and erosive process streams. These systems can be designed to various pressure and temperature ratings and different components (such as resin and glass type) can be varied to suit the process conditions

By Zhongning Shi, Ramana G. Reddy

"By cyclic voltammetry and potentiostat electrodeposition using Potentiostat/Galvanstat, electrochemical behavior on Ag electrode in electrolyte 0.2M NaOH+0.01MPb(NO3)2-0.01M TeO2 -0.01M TlNO3 solution were also carried out at 298K. The processes of electrodeposition of Tl2Te3 and PbTl4Te3, a thermoelectric material, are reported along with analysis of the composition of the obtained deposits. The results showed that two different underlying processes are occurring depending on deposition potential. One process involves the reduction of TeO3 2- and Tl+ to Tl2Te3 in a potential interval of -0.70V < E < - 0.89V (vs. Hg/HgO). A second process at more negative reduction potentials involves reduction of TeO3 2-, Pb2+ and Tl+ to PbTl4Te3 in a potential interval of -1.02V < E < - 1.19V. The crystalline Tl2Te3 and PbTl2Te3 were deposited electrochemically on Ag substrates at -0.84V and -1.10V respectively. Thermoelectric (TE) material can form a temperature gradient across the material to make electric voltage, which is popular in waste heat utilization and recovery industry. Lead telluride, PbTe, is a small band gap semiconductor of 0.32eV at 300K. PbTe can change its n-type semiconductors with Pb-rich to p-type semiconductors with Te-rich[1]. And it is one of the best TE materials used in thermoelectric generators working between 500K and 600K, or even at a higher temperature of 800K.Three facto,rs play a role in the performance of a thermoelectric material: electrical conductivity (s), thermal conductivity(?), and the Seebeck coefficient (S). These can be combined with absolute temperature (T) to give a figure of merit (ZT) for the material, ZT = s2sT/?. By increasing the electrical conductivity and decreasing the thermal conductivity, which can enhance the ZT value, many efforts, such as alloying with other elements and making the materials nano-sized, have been done to improve its properties recently. Hsu et al. reported that the ZT value of Cubic AgPbmSbTe2+m is increased to 2.2 by doping Ag-Sb to PbTe.[2]."

Jan 1, 2011

By Ragnhild E. Aune, Mark William Kennedy, Shahid Akhtar, Jon Arne Bakken

"In the present study classical induction design tools are applied to the problem of heating nonmagnetic metal billets, using 50 Hz AC. As an example of great practical industrial interest, the induction heating of aluminum billets is addressed specifically. The predicted work piece power is compared with the measured work piece power for a long and a short coil, using well established methods, such as those of Burch and Davis, introduced in 1926/28, Dwight and Bagai in 1935, Baker in 1944/57, Vaughan and Williamson in 1945, and by Tudbury in 1960. A calculation methodology based on a combination of the available tools is also introduced and discussed. The method has proven to give an error of <10% of the actual work piece power. An equation for Tudbury's work piece shortness correction factor is disclosed for the first time.IntroductionInduction heating of metal billets is a practical problem, with a geometry suitable for solution using analytical methods. This paper will examine solutions related specifically to round work pieces in round coils, although the methods presented can be extended to other regular shapes of work pieces and coils[l]. The methods can also be extended to ferromagnetic materials with slight changes[2-3]. It is assumed that the coil and work piece have a consistent diameter over their entire length and that the work piece is at least as long as the coil. Correction factors can be derived for the cases where the work piece is shorter than the coil.The study of induction heating by coils began in the late 19th century with theoreticians like Heaviside[ 4]. The work of Burch and Davis[ 5-7] in the 1920' s greatly improved the theoretical understanding of induction applied to metallurgy. Many investigators in the 1930's-1950's: Dwight and Bagai[8], Baker[l-2, 9], Vaughan and Williamson[3, 10] and others[l 1-12] added to our understanding with clearer mathematics, solutions for specific applications, semi-empirical modifications and practical design tools. Much of the accumulated knowledge is available in books, such as Tudbury's practical text or Simpson's engineering guide from 1960[13-14]. Perhaps the best description and derivation of the theoretical and semi-empirical solutions can be found in Davies[15]."

Jan 1, 2011

By Kenneth L. Driggs

The Environmental Protection Agency&apos;s Clean Air Act of .1970 provided the driving force for the current Magma Smelter configuration. The historical and technical perspectives of those process developments are reviewed. Innovations in procedures and equipment have allowed compliance with the requirements of the regulating authorities. The wet scrubbing of converter gasses and the monitoring of converter operations by a controlling foreman are two of the major contributors to these successes. The Clean Air Act Amendments of 1990 have posed many new concerns for all U.S. industry, including the few (seven) primary copper smelters remaining. Future concerns include tightening the sulfur dioxide ambient standard from the current three-hour averaging period to one hour"

Jan 1, 1992

By P. T. Velu, R. G. Reddy

"The use of emf measurements to derive classical thermochemical data has been in use for many years. The reaction associated with electrochemical process is harnessed in a galvanic cell and energy involved measured in terms of electromotive force. The property requirements of sensor electrodes used differ for various aqueous, molten salt and solid electrolyte systems. The electrodes for molten salt electrolytes need special care for construction. This paper describes the studies carried out using an Ag/ AgCI reference electrode. This electrode was used to measure the solubility of compounds in molten salt electrolytes. The results obtained using this electrode are in excellent agreement with the values from chemical analysis method.I. IntroductionThe technique of obtaining a metal from its oxides by electrolysis is more than a century old process now. In these processes, it has been well established that for halide electrolytes, only the dissolved oxides are available for the dissociation at the electrode to release the metal during electrolysis. Therefore, the solubility of metallic oxides in the molten salt electrolytes is an important parameter which determines the economical and technical viability of these processes. The widely used molten salts systems in halides are fluorides and chlorides. The fluoride electrolyte system is used in our present study.The viability of obtaining aluminum alloys by in-situ electrochemical processing has been outlined in our earlier publications[1-8]. Studies on the solubility of various alloying element compounds is a part of our ongoing research efforts for the direct production of Al-Li alloys. As mentioned above, the solubility of lithium oxide and lithium carbonate compounds in molten fluoride electrolyte system have studied using EMF technique. The change in potential of the molten electrolyte was measured by a working electrode against the reference electrode with the addition of lithium compound."

Jan 1, 1997

By Pier-Lorenzo Solari, Philippe Moisy, Michel Schlegel, Stephane Pellet-Rostaing, Eric Mendes, David Bengio, Richard Husar, Thomas Dumas

Ionic liquids (ILs) are molten salts composed of an organic cation that are liquid below 100 °C. They demonstrate unique physico-chemical properties such as good conductivity, negligible vapor pressure and non-flammability. As a consequence, they are often regarded as green solvents and could become an alternative to the use of both high-temperature molten salts and volatile organic solvents in rare-earth elements processing and recycling. The diversity of interactions existing in an ionic liquid allows the solubilization of both polar and apolar compounds. Moreover, coordinating functions on their composing ions can lead to stabilization of some species. For instance, in non-aqueous media, europium exists in the (II) oxidation state which is not stable in aqueous solutions. Understanding the mechanism of Eu(III) electrochemical reduction to Eu(II) and the stabilization of Eu(II) species in IL media could be of major interest for the development of innovative recycling processes. Using transient electrochemistry and UV-Vis spectroscopy we could get valuable information on the redox behavior of the Eu(III)/(II) couple in the ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ([EMIm][NTf2]). Reduction of Eu(III) to Eu(II) and stability of Eu(II) was also studied thanks to a XAS-spectroelectrochemistry set up used to follow in situ the evolution of the XANES spectrum around the L3 edge of Eu during electrolysis.

Mar 1, 2018

By Levente Becze

The zinc bottom dross is obtained as a by-product from hot dip galvanizing operations and contains at least 92 % zinc, which is recycled mainly by pyrometallurgical processes. The overall costs of such a treatment, however, are often relatively high, and the very strict environmental protection regulations might also cause additional difficulties for the high temperature procedures in the future. Therefore, a novel hydro-electrometallurgical process has been developed in our laboratory, by which one can reclaim zinc of high purity, while attempting to achieve low energy consumption and making allowances for all the environmental restrictions. This aqueous processing technique, based on electrolytic refining in a cell equipped with anion-exchange membrane to separate the anode and cathode compartments, allows the indirect purification of the anolyte. Zinc is dissolved from the anode along with some of the impurity elements, while the intermetallic compounds (Fe-Zn, Fe-AI- Zn) are accumulated in the anode slime.

Jan 1, 2003

By Filippos Patsiogiannis

Laboratory size (5 kg) aluminum killed low carbon steel melts were desulfurized with synthetic fluxes in zirconia crucibles. The sulfur, oxygen, aluminum, silicon, and manganese contents in the melt were determined as a function of refining time and temperature. With a good argon shield and synthetic flux cover, melt reoxidation was not observed. Sulfur removal followed first order reaction kinetics. The effectiveness of calcia saturated calcium-aluminate (12CaO.7Al2O3) based fluxes in desulfurizing the steel melts was evaluated. The effects of initial sulfur level of the melt, weight of the flux (slag), and additions of tellurium, fluorspar, and barium oxide to the melt on the kinetics of desulfurization were also studied.

Jan 1, 1993

Based on experimental and computer simulation results from our group, we report a systematic, atomic level analysis of carbon dissolution from carbonaceous materials in molten iron. Experimental results on graphite/Fe-C-S system were obtained using carbon dissolution studies, XRD and FESEM investigations and were supplemented with Monte Carlo simulations. Three basic mechanisms, namely carbon atom dissociation rate, interfacial phenomena and mass transfer in the melt were found to be responsible for the overall dissolution process. While mass transfer in the melt is governed by the concentration gradients, melt composition and temperature; impurities present in ash play a significant role in the interfacial phenomena. For less ordered forms of carbonaceous materials, carbon atom dissociation rate depends strongly on the degree of long-range order and is an important rate controlling mechanism in the overall dissolution process. A systematic comparison of dissolution rates for a variety of coal-chars, natural and synthetic graphites has been carried out in an attempt to identify rate-controlling mechanisms. The structure of the carbonaceous material appears to be an important underlying factor in the carbon dissolution process.

Jan 1, 2003

By Qiu Dingfan

The Slurry Electrowinning Process (SEP) is a new hydrometallurgical method and clean technology, Sulfide ores can be treated by the SEP without S02 emission and the sulfur from the sulfides can be recovered in element form which is easy to stockpile and can be transported at low cost. In a special slurry electrowinning cell one can achieve at the same time the leaching of elements from the feed and the electrowinning of metals from the electrolyte, Because the anode reactions are utilized for leaching of some elements the consumption of the energy is decreased, SEP also has the advantage of separation some elements, It is especially suitable for treatment of complex concentrates containing Pb, Cu, Au, Ag and S, which could hardly be accepted by any smelter. In this work, the behavior of different metals in this process has been studied and it was found that the separation of metals in some minerals is possible through the SEP, Beijing General Research Institute of Mining and Metallurgy (BGRIMM) has studied the possibility of the SEP to treat bismuth concentrates containing S, Be and F in laboratory and pilot-test scale as well as in commercial plants, The commercial plant was set up in 1997, It has been in operation since that time, According to the results of laboratory experiments and pilot- plant test, a new plant to treat complex gold minerals was set up in 1998 and is in operation in 1999

Jan 1, 2003

By L. A. Mills

After three years of experience in operating the pilot plant for the Noranda Continuous Smelting Process, the decision was made, in March 1971, to build an 800 ton per day commercial plant at Noranda, Quebec. The de- sign and layout of the plant is discussed and the installed equipment described. Experience previously gained in the pilot plant is mentioned when it has been used in the choice of equipment or plant layout. The full- scale reactor was started up in March 1973 and the operational datacollected and the experience acquired during the first 30 months of operation are described. This includes operation to produce both high grade matte and copper. Areas discussed include refractory wear, fuel consumption and throughput of copper concentrates. Changes made to original equipment and methods of operation are discussed, together with the reasons. The ad- vantages of using solid fuels to handle inert materials and to maximize converting air flowrates and concentrate throughputs are described. Relative efficiencies of oil and natural gas are compared. The addition of oxygen from a 94 ton per day oxygen plant to the reactor converting air was started in August 1975 and the initial operating results are included.

Jan 1, 1976

By Mostafa Maazouz, Jeff Blackwood, Mauricio Gordillo, Sang Hoon Lee, Micah Ledoux, Liang Zhang

To meet rising requirements for the low-damage ultra-fine process with the focused ion beam (FIB) in the materials science and semiconductor industry, the advanced ion column and corresponding advanced applications as a solution are developed and demonstrated. Novel high-speed high kV milling, low kV cleaning and imaging capabilities have enabled the creation of impeccable ultra-thin structures such as TEM samples and nanometer scale structures. Minimizing Ga+ induced sample damage is achieved through the optimized final cleaning at 500 eV ion landing energy with the new ion optics, which utilizes close control of the ion dose, beam incidence angle, spot size, pattern algorithm and imaging performance. Newly introduced process solutions achieve the improved process throughput. Initial demonstration is performed on the latest 14 and 10 nm scale FinFET device. Validation of the thinnest <0.8 nm thick ion damage layer on the <7 nm thick lamella structure was confirmed through TEM analysis.

Mar 1, 2017

By Marcelo B. Mourao

Interactions of carbonaceous materials with liquid Fe-C melts have been investigated experimentally by determining the volatile yield due to rapid devolatilization (Flash Pyrolysis) and rates of dissolution at temperatures ranging from 1623 to 1873 K. The volatile yield increased with increasing the temperature. The comparison of results of different types of carbonaceous materials was possible by expressing the volatile yield in terms of Enhancement Factor, fE. The rates of dissolution of spectroscopic graphite and an industrial coke seemed to obey the correlation for natural convection under turbulent conditions. The experimental data for the graphite suggested that the rate of dissolution was controlled by the mass-transfer in the liquid boundary layer adjacent to the solid sample. The value for the empirical parameter correlating the dissolution coefficient and the operating variables was found to be 0.19 which was close to that reported in the literature. The comparison of the results obtained for the coke samples with those for the graphite revealed that the impurities and the porosity of the samples can effect the dissolution rates.

Jan 1, 1992