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By G. W. Jones, F. E. Scott, R. E. Kennedy

Methylene chloride , dichloromethane CH2C12 , a low - boiling and highly volatile organic chlorinated compound, is used extensively as a refrigerant in air conditioning installations , as an intermediate in organic synthesis , and as a solvent for cellulose acetate and other materials . As its vapors are not inflammable in air at ordinary temperatures , it can be used to advantage where it would be highly dangerous to use ordinarily inflammable solvents . The question has been raised as to its inflammable range in pure oxygen and in air enriched with oxygen . To find the answer to this question, tests were carried out with various mixtures of methylene chloride , oxygen, and nitrogen mixtures . It was found that methylene chloride has wide limits of inflammability in pure oxygen . Additional tests were then made to establish the complete range of inflammability of these gases . The methylene chloride employed in the tests was cbtained from the Eastman Kodak Co. It had a reported boiling range of 40.5 ° to 42.0 ° C. and a density of 1.322 at 20 ° C.

Oct 1, 1943

By H. B. Humphrey, F. E. Cash

The following information on accidents in Alabama during 1930 was compiled from data obtained from the companies represented in a course on accident prevention given by the United States Bureau of Mines in Birmingham. These mines produced nearly three-quarters of the tonnage of that State for the year, and included most of the larger operations in the district. The figures are probably representative of the mines which are doing recognized safety work, and are better than the average for all the mines in Alabama. Table 1 lists the days lost in accordance with the weights given to fatalities and permanent disabilities, part and total, which is the scale used in the National Safety Com¬ petition for Mines, conducted by this bureau. By way of explanation, temporary disabilities are weighted according to actual number of calendar days of disability, including Sundays and holidays — that is, all days are counted except the day of accident and day of employee's ability to return to duty. Hernia is classed as a temporary disability to be charged with the actual number of calendar days during which the employee was unable to work. Table 2 gives the number of accidents and the days lost from each cause at 45 coal mines and 7 iron ore mines, also the average frequency and severity rates.

Aug 1, 1931

By William J. Campbell

One of the principal objectives of the Bureau of Mines program for developing super refractory materials is to obtain fundamental data on the physical properties of refractory oxides. This particular investigation obtained accurate thermal expansion coefficients for alpha alumina and evaluated, critically, those coefficients with other published values. High-temperature X-ray diffractometer measurements, by the Bureau, showed that alpha alumina expands anisotropically with expansion parallel to the c axis approximately 10 percent greater than parallel to the a axis. Thermal expansion characteristics of four different alumina samples were determined up to 1,200° C.; the results are presented in both tabular and graphical form. The combined random and systematic errors in the measurements are considered less than 3 percent above 500° C, and approximately 2 percent at 1,000° C. No differences in expansion were observed between the samples or between the heating or cooling cycles.

Jan 1, 1961

By Ott F. Heizer

This paper describing the practice at the tungsten concentrator of the Nevada-Massachusetts Co., Inc., at Mill City, Nev., is one of a series being prepared by the Bureau of Mines on milling practices, methods, and costs in the United States. The ore, which contains about 1.10 per cent of scheelite (CaW04), is concentrated on tables and by means of a magnetic separator and roasters. A product containing 70.43 tungsten trioxide is shipped. The plant was designed for a capacity of 100 tons per 24 hours, but at present 142 tons of ore are milled per day. The author acknowledges the assistance of William O. Vanderburg, associate mining engineer, U. S. Bureau of Mines, in preparing this paper.

Jan 1, 1930

By H. Dale Nichols

[The growing importance of the Sundence (Jurassic) formation an a source of oil, in the Rocky Mountain area has prompted the making of a series of porosity determinations of core samples collected. from the reservoir sands of the Lance Creek oil field, Niobrara. County, Wyo. These analyses are preliminary to a stud of fluid and energy relations in the Basal Sundance reservoir of that field, and the determinations of porosity will be used in subsequent studies requiring, calculations of the volumetric capacity of the reservoir and estimation of the reserves of oil and gas. However, the porosity characteristics an of the Sundance sands in the Lance Creek field are factory that affect the solution of many current practical problems of development and operation. Primarily for that reason but also because it is recognized that porosity values of different oil-production sands are of widespread interest throughout the industry, the results of the initial work have been presented in tabular and graphic form with no attempt to evaluate their significance as they relate to the production history of the field.]

Jan 1, 1938

By Gerrit V. R. Goodman

Future coal mining systems will be able to cut from crosscut to crosscut where advances could exceed 100 ft. However, limitations arise when ventilating such mining systems. In deep advance mining, there would be no workers at the face to advance ventilation tubing or curtain manually. Traditional methods also provide no means for maintaining face ventilation after the miner backs away from the face. U.S. Bureau of Mines research is studying means to provide effective ventilation at cut depths beyond the current limit of 4D ft. Several innovative ventilation schemes are currently being considered. One such method is the use of a jet fan to ventilate a deep cut. A jet fan is simply a freestanding fan using little or no ducting to direct the ventilation flow. Jet fan testing in a 90-ft entry revealed that higher exit velocities and greater penetration depth occurred when various configurations were used to confine and direct the air flow. Additional testing also indicated that 2,200 cfm of fresh air was delivered to the face? 90 ft distant when a check curtain was used to limit entrainment around the fan. Without this curtain, this quantity dropped to only 1,000 cfm. This testing indicated that a jet fan was capable of providing ventilation to a distant face area. It also highlighted potential problems, such as recirculation at the fan and reentrainment in the jet flow. Despite these potential problems, jet fans may be adequate for ventilating cuts exceeding 4D ft.

Jan 1, 2010

By J. William Ganser

This paper is one of a series being prepared by the U. S. Bureau of Mines describing mining and milling methods and costs at cement-plant quarries throughout the United States. These papers are designed to disseminate technical information regarding the methods used. The cost tabulations represent local operating expenditures only and not total production costs. It is recognized that publication of total production costs might in many instances cause embarrassment to individual producers as well as to the industry as a whole. On the other hand, operating costs are essential to the technical discussion and study of the methods employed. The attention of the reader is specifically palled to this differentiation in order that no misunderstanding of the scope of the cost tabulations shall ensue. ACKNOWLEDGMENTS The author wishes to acknowledge the assistance of Fred Burkett, civil engineer, and F. O. Londrey, chief clerk, of the Trinity Portland Cement Co., for assistance in preparation of this paper, "The Geology of Dallas County. 1918," Bulletin 1818, Texas Geological Survey, Austin, Tex., by E. W. Shuler, was also freely consulted.

Jan 1, 1931

By E. Morrice

The Bureau of Mines investigated methods for beneficiating platinum-palladium ores from the Stillwater Complex, Montana. Results of bench-scale and pilot-scale studies employing froth flotation to recover sulfide concentrates containing platinum-palladium values from a serpentinized ore are presented. Best results in the pilot mill were obtained with a sodium isobutyl xanthate-normal dodecyl mercaptan col-lector combination at a natural pH of 8.2. A rougher concentrate con-taining 1.7 oz/ton Pt and 4.7 oz/ton Pd was prepared. Recoveries of platinum and palladium were 96 pet and 86 pet, respectively. Batch cleaner flotation of rougher concentrates yielded concentrates contain-ing 3.7 oz/ton Pt and 9.8 oz/ton Pd.

Jan 1, 1984

By H. Kenworthy

Small batches of fluorspar flotation concentrates were made into nodules and pellets on a laboratory scale. Several of these were rated acceptable by laboratory evaluation methods. The most satisfactory pellets were produced by mixing fluorspar with about 12.5 percent of water, by weight, and 4 percent of organic binders. These binders) for the most part) originated from petroleum and wood-pulp industries. They were generally difficult to handle and were not easily incorporated with the fluorspars tested. Most of them seemed to have an aversion for damp fluorspar and had to be forcibly mixed with the fluorspar; which was then formed into pellets by pressure. Substitution of fuel oil in varying amounts in the binders enhanced the mixing and penetrating qualities of these binders but at the same tire tended to make the pellets more porous. Tall oils performed the same function to a lesser degree and usually decreased the water absorbency of the finished pellets. Heat-treating temperatures to set up these binders were moderate -about 5000 F. for 30 to 50 minutes was usually enough for both drying and heat treating. Nodules made with 1-1/2 to 2 percent of bentonite as a binder were easily mixed and formed. They required a high degree of heat (about 1,500° F.) to develop their strength and were quite water-absorbent when finished. Two fluorspars were examined for weight and fluorite loss after heat treatment at similar temperatures. Both showed a definite wej.ght and analytical loss of fluorite. Bentonite was used also as a binder to successfully nodulize finely ground oxides of iron, manganese, and nickel.

Jan 1, 1951

By Vladimir Adamek

This paper describes the Bureau of Mines development of a novel subsidence prediction methodology suitable to the mining and geologic conditions in the Northern Appalachian Coal Region. It describes the computation of vertical and horizontal movements, inclination, curvature, and horizontal strains. The substance of this method is the separation of the effects of lithology by introducing a correlation between hypothetically homogeneous overburden and existing lithologic conditions, while providing for different mining conditions, i.e., underground geometry and overburden thickness. The effects of lithology have been expressed in the form of a variable subsidence coefficient within the subsidence trough. The subsidence co-efficient is considered a constant for other predictive methods. Field data from 16 test sites at 11 Bureau longwall panel studies were used in the analysis. For each panel, the characteristics of the variability of the subsidence coefficient were defined. Regression analysis of the subsidence coefficients from all test sites on their locations relative to the edges of their respective panels yielded a third-degree polynomial equation. The results from additional longwall panel studies, not included in the regression analysis, were used to prove the validity of this method. To facilitate the use of this precalculatlon methodology, a computer program was written in BASIC for use on a personal computer.

Jan 1, 1987

In presenting this list of permissible explosives and blasting devices, the Bureau of Mines desires to call attention to pages 19 and 24 outlining, the conditions in use under which, and only under which, the explosive or blasting device is permissible. In view of a recent publication recounting trade practice favoring the use of a blasting device without stemming, particular emphasis is placed upon condition 4 on page 19 and condition 2 on page 24. An explosive or a blasting device enumerated in the permissible lists of this Bureau is not permissible in use unless it is properly confined with clay or other incombustible stemming.

Jan 1, 1940

In presenting this list of permissible explosives and blasting devices, the Bureau of Mines desires to call attention to pages 19 and 24 outlining, the conditions in use under which, and only under which, the explosive or blasting device is permissible. In view of a recent publication recounting trade practice favoring the use of a blasting device without stemming, particular emphasis is placed upon condition 4 on page 19 and condition 2 on page 24. An explosive or a blasting device enumerated in the permissible lists of this Bureau is not permissible in use unless it is properly confined with clay or other incombustible stemming.

Jan 1, 1940

By Charles L. Kimbell

The estimated value of world crude mineral production in 1990 exceeded $1,501.5 billion in terms of current (1990) dollars, or almost $1,160 billion in terms of constant 1983 dollars. This latter figure was 0.3% below the 1989 level and about 3.9% below the record high to date of $1,207.1 billion 1983 dollars set in 1980. Table 1 provides the latest available revised time series of the estimated value of world crude mineral production both in terms of 1983 constant dollars and in terms of current dollars. It also provides one of the two statistical bases for this estimation, this being the data on the value of production of a group of key commodities that was compiled for and published in the authoritative French language mineral industry periodical, Annales des Mines, for selected years up to 1983.1 It should be stressed that the values just discussed and those presented in the tabulation are for crude minerals only, and by no means reflect adequately the role of the entire mineral industry in the world economy. These figures represent only the value of mineral materials as they are mined or otherwise extracted from the earth. They do not reflect the value added to these materials through downstream processing within the facilities commonly accepted as mineral industry plants. That is, value added through beneficiation of ores, smelting, refining, and similar processing is not included in these figures. Comprehensive world data on the value added by such processing are not available; however, a conservative estimate of the total value of pro-cessed output from mineral industry plants derived wholly from primary (newly mined) materials would be on the order of about $2,780 billion constant 1983 dollars or $3,600 billion in terms of 1990 dollars.

Jan 1, 1993

By William D. Monaghan

The U.S. Bureau of Mines evaluated a teleoperated continuous mining machine for deep mining in thin-seam applications as low as 1 m. Teleoperation increases the safety of mining machine operators because it removes the operator from the face, an area of immediate hazards to safer outby locations. By using teleoperation, the miner can avoid many including unexpected roof falls that can maim or kill miners instantly, methane and coal dust explosions that can be ignited with just a small spark or flame, adverse health effects from miners breathing coal and silica dust, adverse long-term inner ear damage from loud noise pollution, and other hazards related to heavy mining equipment moving about in confined underground roadways. This report presents the surface evaluation results of a teleoperated control system.

Jan 1, 1994

By K. C. Dean

Fine-sized mineral wastes discarded by ore milling plants require stabilization to prevent air and water pollution. Stabilization has been attained by physical, chemical, vegetative, and combination procedures. Vegetative reclamation is preferred to physical and chemical stabilization but is diffi¬cult to achieve because the wastes are sterile, contain deleterious inorganic salts, and lack the essential nutrients and physical characteristics required for sustaining vegetative growth. Methods now have been developed for attain¬ing vegetative growth on all but excessively acidic, basic, or saline tailings at costs ranging from $120 to $650 per acre. The cost for stabilizing tail¬ings requiring more intensive treatment techniques may range upward to $1,750 per acre. This report summarizes procedures developed by the Bureau of Mines and industry for vegetating amenable tailings, lists costs for the various processes, and suggests procedures that may be applicable for stabilizing saline and pyrite-containing tailings. Ridged planting beds, drip irrigation, and deep-furrow planting techniques are suggested for stabilizing saline wastes. A combination of mill tailings and sewage sludge can be used for pro¬ducing synthetic soils, and layers of sewage sludge buried under a layer of tailings offer promise of inhibiting acid formation from oxidation of sulfides in mineral wastes.

Jan 1, 1974

By C. D. Litton

This Bureau of Mines report presents a set of guidelines for determining the distribution of product-of-combustion fire sensors in underground mines. Sensor spacing is defined in terms of sensor alarm threshold, ventilation flow rate, and mine entry dimensions. Sensor spacing guidelines are presented for detection of fires from two primary combustibles, coal and wood, which are common to the majority of underground mines. The guidelines are based on data from full-scale and intermediate-scale fire tests conducted by the Bureau of Mines.

Jan 1, 1983

By Arthur V. Petty

The Bureau of Mines has investigated the effect of refractory oxide additions, introduced in soluble form, on the refractory properties of 42-, 58-, and 70-pct-A1203 brick. Brick having porosities ranging from 12 to 16 pct were impregnated with solutions containing chrome, chrome-iron, zirconium, calcium, magnesium, cobalt, nickel, tin, and manganese ions. Additions of some of these ions provided dramatic improvements to such properties as hot modulus of rupture, hot load, and particularly slag resistance. These improvements can be related to reduction of porosity, amorphous grain boundary phases, formation of more refractory bond phases, and reduction of the wettability of Al203-containing refractories by metallurgical slags. Fifty-eight-percent-AI203 brick, impregnated with chrome, showed hot modulus of rupture, hot load, and slag resistance two to five times better than those of untreated 70-pct-AI203 brick. This could result in reducing the Nation's dependence on imported refractory-grade bauxite generally required for high-A1203 brick, as domestic alumina resouces could be used to produce the improved refractories.

Jan 1, 1984

By Martin H. Stanczyk

The direct dissolution of a typical zinc sulfide flotation concentrate by elevated temperature and pressure leaching was investigated. The concentrate assayed about 55 percent Zn, 32 percent S, 6 percent Fe, and 1 percent Pb and contained minor quantities of copper and precious metals. The influence of various factors on the dissolution of the zinc in acidic and ammoniacal pulps when using oxygen as the oxidant was determined. The tests revealed that the sphalerite was difficult to oxidize. Complete dissolution of the mineral required vigorous and intimate nixing of the gaseous, liquid, and sold phases. The addition of pyrite or sulfuric acid to water slurries of the concentrate was required to obtain a high zinc extraction when leaching under acidic conditions. The quantity of pyrite and acid used was about 0.125 and 0.25 pound, respectively, per pound of zinc sulfide contained in the leach charge. In tests with acid, about 96 percent of the zinc was extracted from the concentrate in 1 hour at 200° C. when the oxygen partial pressure was 75 pounds per square inch gage or higher. Leaching with a continuous flow of air as the oxidant gave results that were almost as good as those obtained when oxygen was used, In tests with air fed through the autoclave at 320 liters per hour, 95 percent of the zinc was dissolved in 1 hour, Acid leach solutions assaying approximately 58 grams Zn per liter and containing Fe, Ni, Cr, and Cu impurities were produced in the better tests. The leached residue consisted essentially of red iron oxide together with substantially all of the lead and precious metals.

Jan 1, 1961

By V. E. Edlund

Laboratory batch flotation tests were conducted on copper converter slags to evaluate the relative merits of recovering copper from slow-cooled versus water-quenched slags. Three slags containing 1.6, 5.0, and 6.6 percent copper were used. More than 90 percent of the copper was recovered in a rougher concentrate leaving a 0.2- to 0.3-percent copper tailings when treating slow-cooled slag. Lower recoveries and higher copper tailings ranging from 0,5 to 0.6 percent copper were obtained from quenched slag. Grindability studies were made on the respective heat-treated slags. Quenched slags proved more difficult to grind than slow-cooled slags. Cost studies showed that (1) the cost of slow cooling and crushing off-sets any advantages of higher copper recoveries from slow-cooled slag, and (2) water-quenched slag, which requires no crushing preparatory to grinding, could be treated more economically. Costs based on processing 1,000 tons of slag per day would be $1.85 per ton for quenched slag versus $2.37 per ton for slow-cooled slag.

Jan 1, 1971

By Helen E. Edwards

The Bureau of Mines is engaged in a systematic evaluation of the thermodynamic properties of combustion gases. These studies are designed to provide basic thermodynamic information of high accuracy facilitating the theoretical study of flame and combustion phenomena. This report is the third of a series3/ presenting results of the study for particular fuel-oxidant systems. The equilibrium composition of the products of combustion and the adiabatic flame temperatures of specified oxyacetylene systems have been computed.

Jan 1, 1953