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By T. W. Johnson

One of the common methods of increasing recovery of oil from partly depleted oil sands is to inject natural gas, air, or air-gas mixtures into the sand, thereby supplying energy to move oil into the well bore. Where natural gas is not available, air or an air-gas mixture is used as the repressuring medium. Air-gas mixtures are obtained from the casing-heads of oil-producing wells in the areas repressured with air or air-gas mixtures and consist usually of varying amounts of the hydrocarbon gases, nitrogen, oxygen, and carbon dioxide. Laboratory experiments have been conducted by the Bureau of Mines to determine the effect of air on crude oils.4/ In these experiments the crude oils were oxidized by the air, and the degree of oxidation depended not only upon the chemical composition of the crude oil but also upon the duration and method of contact between the oil and air, the temperature of the fluids and the concentration of the oxygen. When the crude oils were oxidized the following results and changes in the oils were obtained:

Jan 1, 1937

By T. W. Johnson

One of the common methods of increasing recovery of oil from partly depleted oil sands is to inject natural gas, air, or air-gas mixtures into the sand, thereby supplying energy to move oil. into the well bore. Where natural gas is not available, air or an air-gas mixture is used as the repressuring medium. Air-gas mixtures are obtained from the casingheads of oil-producing wells in the areas repressured with air or air-gas mixtures and consist usually of varying amounts of the hydrocarbon gases, nitrogen, oxygen, and carbon dioxide. Laboratory experiments have been conducted by the Bureau of Mines to determine the effect of air on crude oils.4/ In these experiments the crude oils were oxidized by the air, and the degree of oxidation depended not only upon the chemical composition of the crude oil but also upon the duration and method of contact between the oil and air, the temperature of the fluids and the concentration of the oxygen. When the crude oils were oxidized the following results and changes in the oils were obtained:

Jan 1, 1937

By F. E. Block

The reaction between calcined dolomite and ferrosilicon has been studies with the aim of developing a continuous process for magnesium production. Small-scale tests were made in vacuum retorts similar to those used in the vacuum retort process as developed by Pidgeon (1)2/ and operated during the period of World War II in several Government-owned plants. Factors investigated with respect to the silicon efficiency were the reaction temperature, reaction time, amount of excess dolomite in the charge, and effect of adding sodium silicate to the charge to serve as a binder. Additional laboratory tests were made to study the reaction at elevated temperature but at atmospheric pressure. Silicon efficiencies exceeding 80 percent were found to result when operating in the temperature range from 1,750° to 1,800° C. for periods of 20 to 30 minutes.

Jan 1, 1956

By Nan C. Jensen, Oliver Bowles

Stone , the foundation of the continents and the floor of the oceans , is one of the most substantial and enduring of all substances that constitute the material universe . Stone furnished rude shelter for aboriginal man , and through all succeeding ages it has provided a lasting and serviceable structural material . Limestone is one of the most widely used building stones .

Oct 1, 1947

By Michael G. Zabetakis

The autoignition temperatures (A.I.T.'s) of natural and synthetic lubricants in air were generally found to decrease with increasing pressure. Of the two types of fluids, synthetic and natural, studied in some detail, the phosphate esters had higher A.I.T.'s at any pressure between 1 and 200 atmospheres than the mineral oils. Most of the A.I.T. data obtained in this study obeyed the relationship predicted by Semenov's theory of ignition.

Jan 1, 1962

By R. L. Crosby, L. W. Higley

Magnesium- rich magnesium- aluminum- zirconium alloys in the cast and in the extruded and heat- treated condition were studied to identify the phases present and to determine phase distribution . In cast alloys , two intermetallic compounds were identified : ZrAla by X- ray diffraction ; and Mg₁ Al₁₂ by microscopical observation . Based on microscopical comparisons between the known phases in the cast structures and the phases in the structures of extruded and heat - treated rods , ZrAl₂ and Mg1 , Al12 were identified in the structure of the latter . The presence of these intermetallic compounds in rod specimens could not be confirmed by X- ray diffraction . ZrAl₂ was observed in the structure of extruded and heat - treated rod specimens containing as little as 0.01 weight - percent zirconium . The presence of aluminum restricts the solubility of zirconium in magnesium because of the strong tendency to form ZrAla . This intermetallic compound segregated in clusters of small particles in the matrix of cast alloys , and only slight improvement in distribution was noted when the alloying techniques were varied .

Jan 1, 1964

By J. A. Herdlick

Under authority of the Strategic Materials Act of June 1939, the Federal Bureau of Mines, in cooperation with the Geological Survey, began a broad program of investigation of the strategically important chromite deposits in Sweetgrass, Stillwater, and Carbon Counties, Mont. Extensive occurrences of chromite along the Stillwater Complex in Stillwater County were investigated. The two principal deposits, The Mouat-Sampson and Benbow mines, ultimately were developed and placed in production by the Federal Government. As a part of this general development program, the Carbon County chromite deposits near Red Lodge were examined by Bureau of Mines engineers in 1940, and by the Geological Survey .1-1 1942. The district was examined earlier by Schafer, and the Four Chromes area is mentioned briefly by Westgate. Although the Red Ledge deposits were considered to be of minor importance as compared to those of the Stillwater Complex, several of the ore bodies were adaptable to open-pit mining' methods, and one large deposit on Line Creek Plateau was readily accessible to the Red Lodge-Cooke highway. In 1941, the U. 3. Vanadium Corp. began mining crude lump-chrome ore from the deposit on Line Creek Plateau to supplement national stockpiles, which were being depleted by the rearmament program and the disruption of chrome-ore imports by the European war. Access roads gore constricted to Hellroaring Plateau, and the mining operations were extended to that area. A gravity concentrator with a capacity of 200 tons per day was built and operated at Red Lodge to beneficiate lower-grade ore from the district.

Jan 1, 1948

By E. F. Foerster

The Bureau of Mines used a diphenyl ether calorimeter to determine the heat contents of natural and synthetic blast-furnace slags. For solid slags, enthalpy (HT-H298) at 1,448° to 1,680° K ranged from 282.1 to 348.5 cal/g (±3 percent); liquid slag values were 400.1 to 514 cal/g (±3 percent) in the temperature range between 1,626° and 1,890° K. Experimental results for liquid slags were 14.3 to 16.2 percent higher than the enthalpies calculated from thermodynamic tables; values for solid slags ranged from 5.3 percent lower to 3.9 percent higher than calculated values. Experimental results for liquid synthetic slags ranged from 14.9 to 24.3 percent higher than the calculated enthalpies; values for solid synthetic slags were from 1.0 to 3.4 percent higher.

Jan 1, 1967

To precondition a stope in advance of mining and thus reduce or prevent rock bursts. Approach Drill deep holes from a mine opening in a radial pattern in the vein and load and blast to fracture, the rock prior to production mining How It Works Preconditioning of a sphalerite galena vein in a hard gangue of quartz and quartzite creates a zone of softer rock that fails by displacement rather than violently as an elastic-battle mass. However, the entire area must he analyzed carefully so that the stress transfer does not cause problems in other workings of the mine A typical drill hole pattern and explosive loading is shown in the sketch. Hole diameter is about 4 inches and a down-the-hole, type drill is used. Drilling speed in hard quartzite is about 12 inches per minute High pressure compressed air (250 psi) is used to run the drill. An overhand cut-and-fill stoping area on the 7700 level of Hecla Mining Company's Star Mine in Burke, Idaho was preconditioned above and below the

Jan 1, 1981

By Russell R. Trengove

Bureau of Mines exploration at the property of the Tulare County Tungsten Mines was by core drilling from the surface from May 16, 1950, to July 13, 1950. The property is in the western foothills of the Sierra Nevada Range, 18 miles northeast of Lindsay, Calif. It has been in almost continuous production since 1942 and has produced 40,831 units of tungsten trioxide (W03) with a grade of approximately 67 percent. The work performed comprised a study of the geology, mapping the area, sampling the outcrops, and diamond drilling the area adjacent to the mine workings. Ten holes were drilled for a total of 1,824 feet. Ore reserves were found to be confined to tactite zones in a surface area approximately 250 by 400 feet and extending downward about 350 feet.

Jan 1, 1956

By G. M. Potter

During investigation of the occurrence of manganese deposits in the western United States, the Bureau of Mines collected 2-ton samples of 4 ores from 3 properties in northeastern Nevada. Laboratory tests were made to determine the amenability of these ores to ore-dressing methods of concentration. The Caviglia-Vietti property is situated 11 miles southeast of Ely, White Pine County, Nev. The ore deposits are lenticular veins and irregular masses found in limestone fracture zones and along the contact of limestone and underlying shale. Two samples, of the ore were tested: Lot A, from the Vietti shaft, and lot B, from the. Caviglia shaft.

Jan 1, 1954

By David Schlain

"INTRODUCTION Electrolytic manganese is produced by electrolysis of a solution of manganese sulfate and ammonium sulfate in a diaphragm-type cell, metallic manganoese being deposited on the cathodes and sulfuric acid produced at the anodes. The spent electrolyte is used to leach fresh ore that has previously been subjected to a reducing roast; the resulting leach liquor is purified and returned to the cell.The leach liquor produced at the Bureau of Mines pilot plant 3/ at Boulder City, Nev., contains 135 to 140 grams of ammonium sulfate and 32 to 36 grams of manganese (as sulfate) per liter, and has a pH of about 2.5. After neutralization to a pH of 6.4 to 6.6 with ammonia and thickening, 0.10 to 0.15 gram of hydrogen sulfide per liter is added to the liquor to precipitate the heavy metals, and after 15 to 30 minutes the precipitate is filtered off. Residual sulfides and colloidal material are removed by ferric hydroxide formed by adding a small amount of ferrous sulfate to the solution at a pH of 6.5 to 7.0 and passing air through it. The solution is then filtered and clarified as a precoat filter. Finally, 0.1 gram of sulfur dioxide per liter is added, and the solution is electrolyzed in an anode-in-diaphragm cell. The spent electrolyte coming from the cell contains approximately 10 grams manganese, 135 grams ammonium sulfate, and 45 grams sulfuric acid per liter."

Oct 1, 1946

By J. J. Shields

This is the Seventh of a series of publications that describe methods and practices used in mining bituminous coal mechanically.3/ This report deals with the operation referred to in coal mining as continuous mining, and the interest shown by mining companies in this method is the reason for this study. Only continuous mining as it applies to the room-and-pillar system of mining, or a modification thereon, is discussed in detail in this report. Although not always as continuous as the name implies, it is a system of mining in which a machine is used to cut and load coal in one continuous operation without drilling and blasting the coal. With the mining equipment in most general use today, the usual cycle of operation in mining of coal is: (1) Timber, (2) cut, (3) drill, (4) blast, and (5) load. As the phases of this type cycle cannot be performed simultaneously in the same working place, it is necessary to operate from 3 to 7 working places so that at least 1 place is available for coal loading at all times. Even if the schedule of the phases in a cycle is maintained, coal production ceases during the time required to move the loading equipment from one loading place to the next. In 1920 a continuous-type mining machine4/ was installed in an Illinois coal mine to drive entries. Several other companies used these entry drivers for short periods in the following few years. In 1927 a southern Illinois coal company installed 2 of these machines which, in the next 25 years, were reported to have driven over 200 miles of entries. The machines did not attain widespread usage.

Jan 1, 1954

By John T. Metcalf

The assembly procedures for nine different wire rope terminations used in the mining industry are presented in a format and manner to facilitate training and to provide points where inspection of the termination should be performed. The nine terminations addressed are: Flemish Loop with Steel Sleeve & Thimble, Flemish Loop with Steel Sleeve, Wedge Socket, Swaged Socket, Turn Back Loop with Sleeve & Thimble, Thimble Splice with Four Tucks, U-Bolt Clip & Thimble, Zinc Poured Socket, and Epoxy Resin Poured Socket. The manual was prepared to be used primarily for field type mining operations or training where high capacity machinery is quite limited. It is nut the intent of this manual to suggest that the procedures presented are those to be used by manufacturers or other commercial enterprizes. A different set of procedures may be more appropriate where ideal space and equipment resources are available. The assembly procedures were derived from standard industrial practice, manufacturer's recommendations, and the open literature on the subject. These same procedures were used to prapare test specimens for an extensive series of pull and axial fatigue tests. The results of these tests indicate that these procedures are satisfactory in all respects. This manual is to be used as part of a complete training program. Although a brief glossary is included, there has been no attempt to make this a primer on wire rope. The selection of wire rope termination hardware, like the selection of the wire rope, is a subject not covered by this manual. The reader is cautioned that there are various sources for such hardware and this selection must be done carefully.

Jan 1, 1978

By J. A. Lamonica

The Bureau of Mines studied a pulsation damping device designed to smooth pulsating flow in personal respirable dust samplers. The effect on the pulsation dampener efficiency of six parameters was investigated, as follows: Volume, diaphragm elasticity, diaphragm area, center orifice area, inlet-outlet orifice area, and geometry (LID ratio). The results indicate that volume pre-dominates in determining snubber efficiency, while the other parameters become important at small volumes. Geometry has no effect on snubber efficiency. Criteria for an efficient pulsation dampener construction were obtained.

Jan 1, 1971

By Thomas C. Atchison, Joseph M. Pugliese

Six explosives were compared by measuring their strain- producing abilities in limestone . Peak strain , e , varied with scaled distance , R/Ro , according to the following equation : € = Kc (R /R 。)- ". The distance exponent , n , was a constant of the rock and did not depend upon explosive . The strain intercept , Ke , increased with increasing detonation pressure of the explosive . The strain intercept also depended upon the explosive- to - rock impedance ratio . For impedance ratios from 0.53 to 1.38 , the strain intercept was approximately proportional to the medium stress , Pn , as calculated from the explosive detonation pressure , P , and the explosive - torock impedence ratio , Z , by the simple elastic theory relation : P = 2P / ( 1 + Z ) . PD However , the data indicated that , at lower values of impedance ratio , the strain intercept is relatively larger than would be expected from the simple elastic theory . The results presented provide a simple method for predicting the relative effectiveness of different explosives in breaking limestone from the detonation pressures and characteristic impedances of the explosives .

Jan 1, 1964

By B. J. Dalton

The Bureau of Mines Helium Research Center has developed a computer program for solving two-phase equilibria data for binary mixtures and for evaluating thermodynamic functions of interest, including all critical points. This computer program was used to calculate equilibrium points on the PVTu surface for the helium-nitrogen system as predicted by the Van der Waals equation of state. Numerical values are tabulated and illustrations are presented for 1,279 equilibrium points and for quantities needed to construct Ponchon diagrams. Equilibrium ratios as a function of pressure at constant temperature and of temperature at constant pressure-are also shown graphically. In addition, saturated partial molal volume and partial molal enthalpy data are given. It is shown that the Van der Waals helium-nitrogen system exhibits retro-grade condensation of the second type for liquid helium concentrations of about 0.07 mole fraction or less and pressures below about 45 atm. It is also shown that the critical point is at a -maximum value of pressure (at constant temperature) and of temperature (at constant pressure).

Jan 1, 1971

By A. L. Engel

This report is a compilation of results of preliminary concentration tests of seven manganese-ore samples. Six of the seven samples were submitted through the Mining Division, and 1 from Mexico was submitted by H. A. Doerner, formerly chief metallurgist, Region III. These investigations were made to assist development of mineral resources and particularly to aid economical exploitation of marginal or complex ores, from which strategic or critical minerals may be recovered.

Jan 1, 1953

By S. M. Shelton, A. L. Engel

The carnotite deposits of western Colorado and adjacent sections of Utah and Arizona were formerly an important source of radium and uranium until displaced by the exploitation of foreign deposits in the Congo and northern Canada . Recently interest has been renewed in domestic carnotite ores as a source of vanadium . Carnotite is a canary - yellow, crystalline , pulverulent mineral occurring in sandstones in the Colorado - Utah district as an incrustation on the faces of joints and fractures and deposited around and between individual sand grains , often strongly adhering to the surface of the grains . Chemically, it is a variable combination of potassium, uranium , and vanadium oxides with water of crystallization . It is soft and friable , and occurs in fine - grained or earthy form . In spite of a specific gravity of 4.1 , gravity concentration has not proved practical as a means of beneficiation because of the earthy texture of the mineral . Vanadiferous sandstones occur with minerals ranging from roscoelite (vanadium mica) , containing little uranium , to high- uranium and low -vanadium carnotite . There is considerable local variation in the texture of the ores . The treatment of carnotite ores has been described previously , with attention directed to the elimination of waste in mining and the extraction of radium . The suggested methods included those suitable for the recovery of vanadium , since both radium and vanadium occur in the same minerals . Moore and Kithil suggested crushing from 40- to 80 - mesh with rolls , accompanied by a rubbing action to loosen the carnotite adhering to the sand grains . Fine grinding was to be avoided because it diluted the final product too much . The crushed and rubbed material was to be washed and

May 1, 1942

By W. R. Gilliland, G. W. Jones

"One-phase of the accident prevention program of the Bureau of Mines is the determination of the explosion hazards of various combustible gases and vapors encountered,mining and allied industries and the development of means and methods of eliminating them.Gasoline is foremost among the combustible-liquid's as to quantity used and variety of applications in industry, It is a chief contributor to the causes of fires and explosions, taking an enormous yearly toll in property damage and considerable loss of lives.The results presented in this report evaluate the effect of various gaseous inert substances, which owing to their chemical composition, should be of considerable value in the prevention of gasoline fires and explosions. The substances investigated are as follows: Nitrogen (N2), automobile exhaust gas (85 percent N2 + 15 percent CO2), carbon dioxide(CO2), dichlorodifluoromethane (CCl2F2-Freon-12), trichloremenofluoromethane (CC13F-Freon-11), and dichloromonofluoromethane (CHCl2F-Freon-21).The general term ""gasoline"" designates a combustible liquid of such characteristics as to give satisfactory operation without preheating in spark-ignition-type internal-combustion engine. It comprises a complex hydrocarbon mixture having a limiting distillation range and produced commercially by distilling or ""cracking"" crude petroleum or other various petroleum stocks. Small proportions of other substances may be incorporated in the gasoline to enhance its antiknock properties or operating characteristics in internal-combustion engines and to increase its stability during storage, transportation, and use.It is thus seen that gasoline may have rather wide variations of chemical and physical properties, and it would: appear that the results of any investigation dealing with one particular gasoline might not be applicable to other types. However, as indicated by the results given in this report, the inflammable properties of different gasolines at normal atmospheric temperatures are influenced largely the mars volatile hydrocarbons containing 5, 6, 7 carbon atoms- in the molecule, and that the heavier constituent of higher molecular weight have a minor influence on the inflammable properties at ordinary temperatures."

Apr 1, 1946