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By J. C. Gerdeen

A new analytical model for the shear stiffness at a joint of the fully-grouted resin roofbolt is developed using the Theory of Elasticity and an analogy to a beam on an elastic foundation, Gerdeen [2]. The model developed in this study treats the elastic foundation modulus of the resin as being composed of both an elastic rock and an elastic resin. All previous attempts have neglected the elasticity of the rock and treated only the resin. A three dimensional finite element model of the bolt-resin-rock system is developed also and comparisons are made between the predictions made by it and the analytical solution. It is found that the agreement between the two representations ranges between 1.2% and 10.5%, with the greater differences being observed for systems of very large or very small bolt diameters and resin annulus thicknesses. Since such configurations are not the rule in practice parameter studies are performed using the analytical solution with the finite element solution being used as a check. For a 0.75 in. bolt, a resin annulus thickness of 0.1375 in., a resin with E = 7 x 105 psi and -1) = 0.210, and a rock of modulus E = 6.8 x 106 psi and V = 0.159 the shear stiffness is found to be 1.220 x 106 lb,/in, from the analytical solution and 1.245 x 106 lb,/in, from the finite element model. Applying the finite element model to the problem of the axial stiffness of the fully-grouted resin roofbolt a value of 6.002 x 106 lb./in. is obtained which proves to be at least 50% higher than any of the now existing analytical predictions.

Jan 1, 1976

By E. C. Lane

This paper is the first putt of a report giving the results of the Bureau of Mines' twenty-third semiannual survey of motor gasoline marketed in the United States. A companion report, Part II, is in preparation and will give a more detailed discussion of the whole survey. Results of the determination of copper-strip corrosion, color, sulphur content, copper-dish evaporation residue, and gum content as given by the Bureau of Mines steam-oven method will be presented in the second paper, which will also include the prevailing retail price and the tax at the time the sample was taken. This paper deals specifically with data relative to gravity, Reid vapor pressure,' and distillation (method 100.13).6 The samples tested were divided into "competitive-price gasolines" and "premium-price motor fuels," a method of presentation that was begun with the twenty-second semiannual survey. A total of 312 samples were collected from service station pumps in 20 cities throughout the United States. Of this number of samples, 207 were "com-petitive-price gasolines" and 106 were "premium-price motor fuels." All of the samples were collected in March, 1931, and analyzed at the Petroleum Experiment Station of the United States Bureau of Mines at Bartlesville, Okla. "Competitive-price gasoline" includes those fuels that are sold at the generally recognized local base price and all fuels that are sold below that price. All fuels that are sold at an advance over the generally recognized base price are placed in the class of "premium-price motor fuels." These fuels include Ethyl gasolines, benzol blends, "high-test" fuels, and those fuels that owe their "anti-knock" rating to the process of manufacture rather than to the addition of other material such as Ethyl fluid or benzol. The term "high-test" is generally applied to motor fuels that are more volatile than the regular competitive-price gasolines. "High-test" fuels may also have a high anti-knock rating.

Jan 1, 1931

By P. W. Jeran

The Stereonet Analysis Program (SNAP) is a mathematics tool which, by means of a computer, reproduces mathematically the manual techniques of pre- paring stereograms. This computer program was developed to provide a fast, accurate, and economical means of analyzing fracture orientation data. It is mitten in FORTRAN IV for use on a UNIVAC 1108 operating under an Exec II system, but can be adapted to other systems. SNAP is currently being used to aid in the analysis of cleats and other geologically induced fractures associated with coalbeds that are being mined underground, Methane flows through the coalbed and into these mine workings predominantly through the fracture system. Therefore, knowledge of fracture orientation is an invaluable aid in the development of methane control technology.

Jan 1, 1970

By D. J. Singleton

Erosion corrosion of 12 alloys in phosphoric acid waste water was studied by the Bureau of Mines. Tests were conducted on oblate spheroids or cylindrical specimens in 12-and 60-cm-diam ball mills by grinding phosphate rock in gypsum pond water with a starting pH of 1.6. For comparison, tests were conducted while grinding phosphate rock in plain water. Static corrosion tests in gypsum pond water also were conducted. For all alloys, the wear by erosion-corrosion (milling with gypsum pond water) was greater than the sum of erosion (milling with water) plus static corrosion. Erosion-corrosion wear was about 1,500 to 3,000 mpy for the alloyed white cast irons, 1,000 to 1,400 mpy for commercial steel ball material and type 316 stainless steel, and 600 to 900 mpy for nickel-base alloys and a high-manganese, nitrided stainless steel. Alloy costs per unit of phosphate rock 'processed favor a low-alloy, high-carbon steel or a high-manganese, nitrided stainless steel.

Jan 1, 1985

By N. S. Dalal, X. Shi

"Electron spin resonance (ESR) measurements on solutions and isolated powders provide direct evidence for the involvement of Cr(V) species in the reduction of Cr(VI) by NAD(P)H. ESR analysis of an isolated Cr(V)NAD( P)H solid yields 6 11 = 1.9831 and 6.i. = 1.9772, indicating that the unpaired electron occupies the d22 orbital of the Cr(V) ion, with square-pyramidal geometry. Addition of hydrogen peroxide (H2 0 2 ) to the N AD(P)HCr( VI) reaction mixtures suppresses the Cr(V) species and generates hydroxyl (""OH) radicals. The ""OH radicals were detected via ESR spin trapping, employing 5,5-dimethyl-1-pyrroline-N-oxide and a-(4-pyridyl-1- oxide)-N-tert-butylnitrone as spin traps. The dependence of Cr(V) and ""OH radical formation on the H20 2 and Cr(VI) concentrations indicates that the Cr(V) species react with H20 2 to generate the ""OH radicals. Similar results were obtained by using various diols (arabinose, cellobiose, FAD, fructose, glyceraldehyde, ribose, and tartaric acid), a-hydroxycarboxylic acids, and glutathione. Investigations with superoxide dismutase showed no significant participation of 02 in the generation of OH radicals. These results thus indicate that the Cr(V) complexes, produced in the reduction of Cr(VI) by cellular reductants, react with H20 2 to generate ""OH radicals, which might be the initiators of the primary events in the Cr(VI) cytotoxicity.In this paper we report an electron spin resonance (ESR)3 spectroscopic detection of Cr(V) species in the reduction of potassium dichromate, henceforth called Cr(VI), by NAD(P)H and other diols. Also reported here is the detection of the hydroxyl (""OH) radical in the reaction between hydrogen peroxide (H2O 2) and a variety of Cr(V) complexes. This work was undertaken because while the reduction of Cr(VI) to lower oxidation states has been suggested as a key step m the mechanism of Cr(VI) toxicity, mutagenicity, and DNA alteration, the details are not yet clear (1-5).Earlier studies on the mechanism of Cr(VI) reduction in cellular systems include those on the reduction of chromate by microsomes (6-8), rat liver DT-diaphorase (9), and aldehyde oxidase (10). All these studies imply that Cr(VI) can be reduced to Cr(Ill) by cellular constituents. Regarding the mechanism of Cr(Vl) carcinogenicity, Jennette postulated that Cr(V) is the ultimate carcinogenic form of chromium compounds (8). This conclusion has led to many further investigations of the formation of Cr(V) in the reduction of Cr(VI) under biologically relevant conditions (11-33). More recently, however, Kawanishi and co-workers (34) have investigated the mechanism of DNA cleavage induced by Cr(VI) in the presence of H20 2 and have argued that it is not Cr(V) itself that is carcinogenic, but it is the reactive oxygenated species (02, 10 2 , ""OH) (produced by the decomposition of the Crv(02) ¾ - ion) that cause the DNA alteration."

Jan 1, 1990

By K. P. V. Lei

The Bureau of Mines investigated molten salt electrorefining 'n helium atmosphere cells as a means for the production of ductile vanadium. 'Electrolytes composed of NaCl-VCl2, LiCl-NaCl-VCl2, BaCl2-KCl-NaCl-VCl2 KCl-LiCl-VCl2, and CaCl2-NaCl-VCl2 were tested. Two electrolytes, KCl-LiCl-VCl2 and CaCl2-NaCl-VC12, were selected for laboratory-scale production tests. A molten salt electrorefining process was developed for the production of ductile 99.6 percent vanadium from a commercial 90-percent grade. Using the CaCl2-NaCl-VC12 electrolyte, an 87-percent recovery of ductile vanadium was made; an 85-percent recovery was made with the KCl-LiCl-VCl2 electrolyte.

Jan 1, 1967

By Ernest W. Johnson, F. E. Cash

"INTRODUCTION Mine operators have long realized the importance of providing a satisfactory and dependable means of giving prompt warning to underground mine workers at the occurrence of a mine fire or other threatened disaster.Most underground mines of the Lake Superior district are prepared to inject a stench liquid into the compressed-air system quickly to give such warning. The liquid evaporates quickly and gives off an intense and easily recognizable odor even when present in minute quantities in the mine air. Workers in the mines studied have been fairly generally familiarized with the odor and instructed as to evacuation procedure when the warning odor is detected.In some mines provided throughout with electric lighting, including working faces, a prearranged light-flashing signal is given as a warning supplementary to that received from the stench.In a few mines, workers have been instructed to evacuate the mine immediately in the event the compressed-air supply is cut off, regardless of whether mechanical failure may be involved.Information obtained in observing a number of stench-injection tests is compiled and presented in the hope-that it will serve as an incentive to provide means of making stench injections at mines not now so equipped and for making similar tests at other underground mines, so that in case unsatisfactory results are obtained rectifying adjustments or changes may be made in time. It is further hoped that this paper will bring out the real importance of repeating these tests from time to time, at least once a year on each operating shift, so that in the event of an actual emergency, underground employees will receive a prompt warning."

Nov 1, 1945

By Merwin H. Howes

In constructing the NORAD Combat Operations Center, controlled blasting techniques were employed to achieve smooth walls and to avoid shattering the rock beyond excavation lines. Extraordinary measures were taken to stabilize the rock to permanently preserve the openings. Rock stabilization was accomplished by means of reinforced concrete and gunite linings, rock boltings, installation of chain-link fabric, and epoxy resin and cement grouting. A particular zone of weakness at B vital location was supported by exceptionally thick reinforced concrete lining, rock bolts, and cement grout.

Jan 1, 1966

By F. J. Perzak

The Bureau of Mines conducted a study to develop a standard fire test for 5-gal containers used for storing combustible fluids in underground coal mines. A standard test method was developed which evaluates the performance of the container in a 4-min tray fire. Bureau investigators used the standard test method to evaluate several types of closed 5-gal plastic and metal cans in outdoor tests. Each can tested contained 1 gal of nonfire-resistant (NFR) hydraulic oil. A container failed the test if it lost its contents in any of seven trials. Contents spilled either as a result of thermal rupture or melting. Fewer than 10 pct of the metal containers failed this criterion, but all the plastic containers failed. The metal container failures were usual-ly due to tipping over during pressure relief, which spilled the NFR oil. Replacing the NFR oil in the container with kerosene resulted in failure of more than 30 pct of the metal containers. The standard tests and preliminary tests showed that plastic containers are not equivalent to metal containers in their ability to contain combustibles such as lubricants and greases in a fire. For solvents and lubricants more volatile than NFR hydraulic oil, approved metal safety containers are recommended.

Jan 1, 1985

By G. E. McElory

"INTRODUCTION The subject of mine and tunnel ventilation has two broad aspects - (1) what atmospheric conditions to obtain in underground openings and (2) how to maintain the desired conditions efficiently. The first relates primarily to quantity requirements of ventilating systems, whereas the second relates more particularly to pressure requirements. Both, therefore, determine power requirements, which is the deciding factor in any system of mine or tunnel ventilation.Both divisions of the subject have received considerable attention from the Bureau of Mines since its inception in 1910 in the form of research, service, and correlation and dissemination of information. Numerous papers on various Phases of the subject have been published, of which a selected list, numbered and arranged in chronological order by type of publication, will be found at the end of this Paper. One of these, Technical Paper 705 (25) 2/ gives a complete bibliography of Bureau of Mines publications dealing with health and safety. As indicated by the selected list of publications accompanying this paper, the health and safety aspects have received most of the attention devoted to this work, chiefly because these have been dominant factors in Bureau policy, but partly because these aspects lend themselves to laboratory research and small-scale field studies. Although considerable attention has also been devoted to the engineering aspects of mine and tunnel ventilation, there has been, in the opinion of the author, who has been engaged on this phase almost continuously for the last 30 years, only sporadic recognition of the vital effect this phase of the work could have on improving health and safety conditions. As a matter of fact, ventilation activities have constituted but a very minor part of the total work of the Bureau of Mines, as, except for a few years in the nineteen twenties, there have been only a few short intervals when more than two or three men were engaged in field work and a similar number in laboratory research directly related to mine gases or mine air."

Mar 1, 1950

By Kenneth Eilerts

[Efficient and econonic production of ?etroleum requiros knowledge of the propertios of rescrvoir fluids a:$. their characterintics of flow throayh porous forclntions. The cllanga in propertie s and flow characteri s- tics of fluids when their corosition is altercd cs a rnsult of reservoir- pressure decliae is of 'mecial i~ortenct? ir, planning wall-spaAng pro.yama and production schedules. Rct~ntion of the ~eatent poscible quantity of dissolved gac in the rescrvoir liquid gnneml'y is recognized cs ess~ntisl to mxim ultimzte recoverj of oil fro3 the underground reecrvoir. Ilo:rever, pro6uction mothodn tending to mintain gis in solution in the oil and re- sulting in the optimm ocolo~ic recgvery of oil not only vary from field to fiold but also my have to be changed from time to time in a given field as it is being depleted of its recoveraklo oil. Const vestly there is need tc investigztc tY.e propertiec of resa:-voir f kids corresponding to successivc stages of reservoir depleJ&ion with the view of obtnining infomation oacential to efficient prcriuctian practices.]

Jan 1, 1939

By H. J. Kelly

[This investigation of the refractory properties of seven Pacific Northwest chrome ores and concentrates has shown that five of the ores and one of the concentrates are suitable for making refractories and that all may be used in combination with high-grade chromite. The specific objectives of the investigation were to determine the inherent physic al and chemical characteristics, to shapes using each of the chrome ores and concentrates, to compare the refractory qualities of the laboratory-prepared with commercial chrome refractories. As far as possible, standard tests were used as criteria.]

Jan 1, 1952

By C. F. Winquist

The Bureau of Mines is engaged in research to evaluate the effects of cutter bit wear at coal mine faces. This paper addresses one element of conical bit wear, bit rotation. A discussion on mounting configura-tion and bit forces and their effects on rotation is presented. The effects on rotation and bit forces of bit attack angle, cutting depth, and skew are determined for two types of conical bits during linear cutting of sandstone-inclusive rock. The results indicate that a 10° negative skew angle and 35° attack angle produce the maximum rotation of 17.5° for each foot of cutting. Data on bit rotation and bit forces are presented in an appendix.

Jan 1, 1985

By T. F. Mitchell, J. V. Batty, R. R. Wells, R. Havens

"INTRODUCTION )ne of the most important wartime activities of the Bureau of Mines was the search for new sources of minerals necessary to the prosecution of the war. As a part of the investigation of strategic mineral deposits in the United States under the Strategic Minerals Act (Public 117, 76th Cong., 1st Sess., Ch. 190), examining engineers of the Bureau of Mines investigated and sampled various deposits of chrome ore in California, Idaho, Montana, Oregon, and Washington, and those deposits that warranted further study were explored by diamond drilling, trenching, and drifting, as re¬quired. During these investigations, samples were submitted to the Ore Dressing Section of the Salt Lake City Station for metallurgical testing. This paper gives data summarizing results obtained from laboratory ore-dressing studies of the chrome ores submitted.Although the deposits range widely in geographical location, the mineral occurrence of all of them is strikingly similar. Chromium, in all of the ores tested, is present as impure chromite or chromium spinel. Although pure chromite (FeCr204 or FeO.Cr203) contains 68 percent chromic oxide, the iron may be replaced in varying amounts of magnesium, and the chromium may be replaced similarly by aluminum and ferric iron. In studying concentration methods as applied to chrome ores, the composition of the chrome mineral is of fundamental importance, because it is manifestly impossible to produce a high-chrome concentrate from a low-chrome chromite by any mechanical process.In all but one of the ores, the gangue material consists of olivine or altered olivine minerals such as serpentine, antigorite, and chrysotile. The exception, the Antelope or from Montana, has a gangue chiefly composed of actinolite, chlorite, and talc."

Jun 1, 1947

By D. J. Stoops, H. Kato, M. D. Carver

The effects of impurity elements silicon , aluminum, copper , nitrogen , and manganese , at 50 to 300 ppm, on properties of the zirconium alloy Zircaloy 2 were investigated . Variations in microstructure , mechanical properties , and corrosion behavior in some inorganic acid and salt solutions were observed with variations in level of impurity element . Corrodents were solutions of sulfuric acid , phosphoric acid , copper chloride , and iron chloride . Silicon was found to modify annealed microstructures by spheroidizing and dispersion of secondphase material throughout grains . Silicon or manganese improved ultimate and yield strength of the alloy without loss in ductility . All five elements affected corrosion rates of the alloy , the effect being generally different for each element .

Jan 1, 1964

By L. H. ADAMS, C. N. HASKINS, J. K. CLEMENT

In the course of its investigations of the fuel resources in the United States and of the methods by which these resources could be utilized with greatest efficiency, the United States Geological Survey tested a great variety of coals and lignites as gas-producer fuel. Early in these testa it was found that many factors controlling the formation of gas in the generating chamber of the producer and, consequently, having a direct bearing on the management of producer-gas plants, were not as well understood as they should be. The Geological Survey therefore took up a detailed investigation of the chemical and physical processes that take place in the producer, keeping in view not only the possibility of increasing the efficiency of the producer as a source of energy, and the ensuing benefits to the public of cheaper power and greater utilization of low-grade fuels, but also the application of the results to the problems of boiler-furnace operations. - The Bureau of Mines, to which the testing and analyzing of fuels as carried on by the United States Geological Survey has been transferred, is continuing producer-gas investigations at the testing station at Pittsburg, Pa. Results of the gas-producer tests a made at the coal-testing plant erected at St. Louis, Mo., and of a study of some of the problems° that came up in the tests have been published by the Geological Survey. Results of the tests made at Norfolk, Va., and Pittsburg, Pa., and of further studies of particular problems, will be published by the Bureau of Mines. In the gas producer solid fuel is transformed into more readily combustible gaseous fuel. The transformation is relatively slow and consists of several processes: 1. The distillation of the volatile hydrocarbons from the freshly fired fuel at relatively low temperatures. 2. The combustion of the fuel by its combining with the oxygen of the air forming carbon dioxide (COO. 3. The formation of carbon monoxide (CO) and hydrogen (11 3), the essential constituents of producer gas, in accordance with the equations:

Jan 1, 1911

By L. A. Stinnett

An investigation of hazardous surface openings of abandoned and inactive underground mines in the Black Hills area of South Dakota has revealed: (1) tracing legal ownership of mineral claims via county courthouses is confusing, complex, and oftentimes misleading, (2 ) in general, the selected mine openings in this investigation are to be considered relatively high in risks and hazard potential which poses a threat to the general public, (3) mine closure procedures and designs can generally be categorically implemented depending on the overall situation of the particular mine opening with subsequent unit costs' estimates, (4) few preventive state or federal legal measures exist to date concerning mine closures, and (5) liability damages relating to mine opening accidents usually involve expensive and complex common law cases.

Jan 1, 1979

By H. Kato, G. Asai, R. Blickensderfer, R. Siemens

Some relationships were established among crystallographic orientation , rollability , deformation texture , annealing behavior , slip planes , and ductile- brittle bend transition temperature of molybdenum single crystals . Six large molybdenum single crystals obtained from an ingot melted by electron beam were oriented by X - ray diffraction and rolled on crystallographic planes of low indices in a known direction . During room temperature rolling , cleavage occurred on 100 type planes . At 300 ° C the crystals were rolled to 95- percent reduction in thickness . The crystals ( 001 ) [ 110 ] and ( 011 ) [ 100 ] were most easily rolled . Pole figures were used to correlate the deformation textures of the rolled crystals with the initial crystallographic orientation . Several of the textures which developed could be explained as a rotation about a < 110 > axis of symmetry . The cube crystal ( 001 ) [ 100 ] retained much of its " cubic " orientation . The (001 ) [ 110 ] crystal developed the simplest texture , whereas the ( 211 ) [ 113 ] and ( 211 ) [ 120 ] crystals developed the most complex textures . The 1 - hour recrystallization temperature of the crystal ( 211 ) [ 113 ] was 700 ° C , which is about 300 ° C lower than that of commercial polycrystalline molybdenum . The poles of the slip planes ( as determined from gross slip lines at relatively low magnification ) tended to lie within 20 to 60 degrees of the pole of the rolling plane . The Knoop hardness was slightly dependent upon crystallographic orientation but more dependent upon rolling direction . The ductile- brittle bend transition temperature was dependent upon the rolling orientation and the dislocation density .

Jan 1, 1964

By H. Leitch

In laboratory experiments, the Bureau of Mines investigated melting, quenching, and sulfuric acid leaching of alumina from mixtures of albite and anorthite, and from anorthosites containing 26 to 32 percent alumina. Variations in pouring temperature, quenching and leaching conditions, were studied with respect to the extraction of alumina and impurities. Virtually all of the alumina was dissolved by leaching melted and quenched California anorthosite in boiling 16-percent sulfuric acid solutions for 15 to 30 minutes. The leach solutions were readily separable from the solid residue by conventional thickening and filtration techniques. Only 2 to 5 grams of SiO2, Fe2O3, or CaO dissolved per 100 grams of alumina. The quantity of SiOz in solution varied inversely with the duration of the leach and with the concentration of the H2SO4 solution used. Melted and quenched Wyoming and Minnesota anorthosites with SiO2:CaO weight ratios of 4.3 and 3.2, respectively, were less amenable to sulfuric acid leaching than California anorthosite with an SiO2:CaO weight ratio of 5.3. However, excellent results were obtained on the Wyoming and Minnesota anorthosites by the addition of SiO2 to these materials before melting, in quantities sufficient to adjust the SiO2:CaO weight ratios of the furnace charges to between 4 and 6.

Jan 1, 1966

By D. Bienstock, R. C. Kurtzrock, E. R. Bauer, J. H. Field

To remove hydrocarbons and carbon monoxide in automotive exhaust by oxidation , a catalyst of 4.2 percent Uз Og , 1.7 percent Cr₂ 0 , and 1.7 percent CuO supported on 1 /8 - inch y- alumina spheres was tested in a reactor in place of the muffler of a 1 / 2 - ton truck . Tests were made with both nonleaded and leaded gasolines . With the engine at operating temperature , tests were made with the engine idling and with the vehicle cruising at 30 mph . Auxiliary air was added to maintain an oxygen concentration of 3 to 4 percent in the gas leaving the catalytic reactor . The vehicle was operated for 83 hours (about 60 percent of the time with the engine idling ) and 525 miles with nonleaded gasoline . Conversions of 98 percent of the hydrocarbons and 100 percent of the carbon monoxide were achieved with the engine idling and with 7,000 ppm carbon atoms and 4- percent carbon monoxide in the feed to the reactor . Hydrocarbon conversions of 75 percent were obtained at cruising speeds of 30 mph with a feed of 1,700 ppm carbon atoms ; the carbon monoxide concentration was less than 0.3 percent in the feed and was unchanged in passage through the reactor . Identical activity was obtained initially in switching to a gasoline containing 1.9 ml tetraethyl lead (TEL) per gallon . However, there was a gradual loss in activity thereafter . Conversions in tests with the engine idling about 50 percent of the time , had decreased by 23 percent for the hydrocarbons and by 25 percent for the carbon monoxide from their initial values after 122 hours and 1,300 miles of operation with leaded gasoline . The levels of radioactive materials in the exhaust of the reactor and the radiation in the vehicle were negligible .

Jan 1, 1963