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By Walter I. Enderlin

To economically extract ore from great depths in the earth while sustaining an acceptable working environment will require the development of new technology and equipment, involving large capital expenditures. Moreover, careful analysis and advance planning will be required. But, the literature is lacking in data pertaining; to the thermal properties of various host rocks and to quantities of heat generated by various underground heat sources. This types, of data is required to forecast nine heat loads during advanced planning and design. This thesis sets forth a practical method for evaluating underground sources of heat in deep mines and provides an improved information base. Moreover, seven topics for further research are recommended. The heat sources considered are: wall-rock, ground water, adiabatic compression, equipment, service lines, blasting, metabolism, curing of cement, and oxidation of sulfides and timber. Seven deep metal mines with high production rates and high heat loads were visited to obtain data necessary to assess their thermal environments. Mine records were examined, wall-roc:, temperatures were measured and a survey of the mine ventilating air and mine drainage was performed. Also, the thermal conductivity of wet and dry specimens of the host rock were measured in the laboratory. Data analysis disclosed that rock heat and adiabatic compression account for stout 60 per cent of the mine heat load at depth. Equipment currently contributes approximately 20 per cent; however, to offset increasing costs with depth, increased mechanization is anticipated. The treat from ground water averages 19 per cent and the contribution from blasting, metabolism and cement is negligible. Also, approximately [0] per cent of the increase in the enthalpy of the ventilation air is in the form of latent heat. Moisture, however, did not significantly affect the thermal conductivity of the rock specimens measured in the laboratory. Also, from the data, it is evident that a negative correlation exists between the thermal conductivity of the host rocks and the per cent of the heat load derived from the wail-rock. Furthemore, steady state heat flow renditions may be assumed in airways where there has been no major changes in the ventilation system for a period of two years or more. Under these conditions, the author found it more convenient and reliable to compute heat influx using the steady state equation for heat flow into a cylinder, rather than Carrier's method for transient heat flow, which is so often used.

Jan 1, 1973

THE Synthetic Liquid Fuels Act (30 U.S.C., 321-325, and amendments) became law April 5, 1944, and a period of intensive research and development in this field was begun by the Federal Bureau of Mines. As part of this program, bulletins were published on pressure hydrogenation,3 the Fischer-Tropsch synthesis,4 and nil stifle.5 The. Bureau also has published a short bibliography on coal gasification,6 mostly of a theoretical nature. Because anal gasification is prerequisite to either the Fischer-Tropsch or coal-hydrogenation processes, publishing this sizable collection of technical information in this form Will Ire valuable. The material will he presented in three parts. as follows I. United Stares Patents. II. United Kingdom, Australian, Canadian, and South African Patents. III. Other Foreign Patents. Part I appeared in early 1960. Part II follows.

Jan 1, 1962

By W. R. ARGYLE, R. A. SHERMAN, Henry Kreisinger, John Blizard, B. J. CROSS, A. R. Mumford

On entering the World War the United States was confronted with the necessity of building in a short time a large number of ships of tonnage adequate to transport troops and war materials to Europe and to carry food supplies to the allied countries, whose merchant fleets had suffered greatly by submarine warfare. The necessity of building ships quickly led to the formation of the United States Shipping Board, which was charged with the duty of developing an efficient organization for the purpose. Such an organization was developed under the name of the Emergency Fleet Corporation; it was under the control of the Government, but could conduct its business in the most direct way, like a private corporation. In order to build the largest- number of ships possible without drawing too heavily on the steel industry, which was already taxed heavily by the production of munitions, it was decided to build wooden as well as steel ships. These ships were built from a few standard designs to enable a large number of duplicate parts to be fabricated in inland shops and transported by railroad to the shipyards on the seacoast, where they were assembled into ships. In other words, the plan was to manufacture the ships rather than to build them. The shops on the seacoast were reserved to make those parts of the ships' equipment that could not readily be transported. The inland shops made the parts that could be transported to the seacoast by railroad. Among the more important parts of the ships' equipment to be standardized were the boilers. As the Scotch marine boiler in large units is bulky and can not be transported by railroad, and as, for the same capacity,much more steelis needed in its construction than for water-tube boilers, a few simple designs of water-tube boilers were developed that inland shops having ordinary equipment could make in large quantities.

Jan 1, 1924

By Joseph Coffman

There are 14 operations that supply 97% of the Market Economy Country (MEC) manganese and contain nearly all of its resources. Six mines account for about 70% of the production and 85% of the resources; there are no known resources that are economically close to those that are currently being mined. Costs (January 1989 dollars) of producing manganese concentrates from the operations evaluated are estimated to range from $ 0.96 to $ 1.86 per long ton unit (ltu or 22.4 lb) of contained manganese. Total MEC demonstrated resources evaluated amount to about 1.2 billion tons of in situ ore containing 474 million tons of manganese. Identified resources amount to about 1.8 billion tons of in situ material. Key results of the study indicate the following: 1. The MEC supply of manganese will be from the currently mined resources well into the next century. 2. Centrally Planned Economy Countries (CPEC's) will be increasingly dependent on MEC manganese ore and concentrate in the future. 3. At the 1976 to 1987 demand increase rate, total MEC resource needed through the year 2000 would be about 282 million tons of in situ material. 4. Transportation and infrastructure support will continue to be major elements of production costs.

Jan 1, 1992

By M. Hertzberg

This Bureau of Mines report describes experimental and theoretical studies of diffusion flames in free convection. The cross-coupling between buoyancy-induced flows and the combustion process is explored as it relates to the size, structure, and radiative balance of flames. New data are presented for the size-dependent radiance oscillations of diffusion flames and for the angular distribution of the total radiant intensity from a small methanol pool flame. Both amplitude and frequency of the measured oscillations are compared with theoretical predictions that are based on a new view of the structure of diffusion flames. This new view, which is at variance with the traditional one, assumes uniform reaction in the diffusive mixing zone, and recognizes the significance of the role played by convective buoyancy and its duality in both aiding and impeding flame propagation. Buoyancy quenches propagation at low burning velocities, introducing a real discontinuity in the combustion rate. A "flammable volume" is thus defined as that bound between lean- and rich-limit contours. However, in the flow disturbances generated by combustion waves that consume that volume, buoyancy aids propagation by promoting the convective mixing of a new flammable volume. The measured radiance oscillations are manifestations of these propagation and remixing cycles.

Jan 1, 1978

By R. W. Watson

In January 1980, the Bureau of Mines initiated an experimental program to examine the fire and explosion hazards of one-hour self-contained self rescuers (SSRs). This action was prompted by a growing concern on the part of government and industrial safety officials over the potential hazards of these devices when deployed on a large scale in underground coal mines. Prior evaluation of the safety of these devices had been at best sporadic and usually limited to experimental models. The recent availability of preproduction models of a l-hour SSR fabricated by the Mine Safety Appliance Company* and a production model manufactured by Dragerwerk Ag Lubeck of the Federal Republic of Germany allowed for a more comprehensive and meaningful evaluation of their safety in underground coal mines. This report summarizes the results of a 5-month study of the potential hazards of these two items. During the course of the work, periodic progress reports were presented to officials of the Mine Safety and Health Administration and various mining organizations including the American Mining Congress, Bituminous Coal Operators of America. National Independent Coal Operators Association, and the United Mine Workers of America. The free exchange of ideas that occurred during these meetings had a significant impact on the direction of this study and a serious attempt was made to address all of the issues that were raised at these meetings. The authors are extremely grateful to the individuals that participated in defining the specific problems that could arise as a result of deploying the self-contained self rescuers in an underground coal mine environment.

Jan 1, 1980

By James R. Boyle

The value of Alabama's nonfuel mineral production in 1982 was $299.4 million, a decrease of $14.4 million from that of 1981; the decrease continued a downward trend that started in 1980. Output of most nonfuel minerals declined; cement, crushed stone, lime, sand and gravel, and clays were the major commodities produced in the State. Despite the decrease in mineral output, Alabama led the Nation in the production of crushed marble; was second in bauxite; third in ferroalloys and oyster shell; fourth in bentonite and dimension marble; fifth in common clay. fire clay, and kaolin; and sixth in masonry cement and lime.

Jan 1, 1984

By H. M. Thorne

Oil shale, a potential source of products presently obtained from petroleum, is found in many countries. The most extensive known deposits from the standpoint of potential shale oil in place are those in Brazil and the United States of America. Mining methods used for oil shale range from open-pit operations for shallow deposits to room-and-pillar and longwall techniques for deposits with thick overburdens. Oil shales from different sources vary greatly in the amounts and types of organic and inorganic constituents. By retorting, the organic material is converted to oil, gas, and coke. The largest percentages of oil are obtained from materials having the highest hydrogen content. Over 2,000 retorting systems have been patented, but only a few have been used industrially, and no single process seems best for all types of shales or economic conditions. Shale oils have different characteristics, depending on the source rock and method of retorting. They contain large quantities of olefinic hydrocarbons and more oxygen, nitrogen, and sulfur derivatives of hydrocarbons than most petroleums. Consequently, petroleum refining methods usually must be modified for shale oil. This is particularly true in catalytic processing. Hydrogenation, even under mild conditions, improves shale-oil refinability. Several byproducts may be obtained from both the retorting and refining steps,

Jan 1, 1964

By Roy E. Williams

1. The major sources of heavy metal ions in wastewaters of the Coeur d'Alene Mining District are effluents from metallurgical processing plants. Effluents from mine operations provide a secondary source for heavy metal ions. Based on data analyzed by the Federal Water Quality Administration, mercury and arsenic are escaping from some mill waste ponds, but they are in the suspended phase. 2. Metallurgical process effluents are combined with mine waste effluents in tailings ponds, consequently, the quality of the tailings pond decant water is highly degraded. The major effect of combining metallurgical process effluents with mill wastes is a drastic change of pH in the tailings pond. This chance may be an increase or a decrease depending on the metallurgical process. The effluent from an electrolytic antimony plant drastically increases the pH in the tailings pond permitting the removal in solution of antimony via the pond decant system. The addition of low pH effluents to the tailings ponds results in a net decrease in pH which makes lead, zinc, cadmium, and copper more soluble, thereby permitting their removal from the pond via the decant system.

Jan 1, 2011

By Sidney Katell

This report covers the period January 1963 through December 1963; it is a continuation of the series that began with the publication of Information Circular 7516 in October 1949. Also, it is the fifth in a series of reports prepared under a cooperative agreement between the Bureau of Mines and the American Association of Cost Engineers. The agreement provides for the publication of an annual cost bibliography with the work load involved in the preparation shared equally. The abstracted articles, concerned with all facets of cost engineering in the field of chemical and petroleum plants and related subjects, are from the following sources:

Jan 1, 1964

By Lewis M. McNay

The Bureau of Hines and industry (mining and private) have studied the placement of hydraulic sandfill in deep-vein mines to identify existing problems and to develop techniques to strengthen the support characteristics of the sandfill. The hydraulic sandfill system, physical properties of typical classified mill tailings, and properties of sandfill modified by various techniques are discussed. Computer analysis has defined the support capability of various sandfills using actual mine field data as a reference base. High-modulus sandfill can provide adequate support in deep-vein mines to alleviate rock and pillar stresses and to reduce rock-burst incidence.

Jan 1, 1975

By Paul Hatmaker

This paper covers briefly the particular field of dolomite and magnesium limestone; certain uses of high-calcium limestone are mentioned only to show more clearly the limita¬ tions of the magnesian rocks. Such a comparison is helpful because magnesium carbonate is essential for some uses; for others it is immaterial; and for many its presence in an appreciable amount is objectionable. Magnesium carbonate, occurring as a rock resembling limestone or dolomite, is described in United States Bureau of Mines Information Circular 6437, Magnesite. Other com¬ pounds of magnesium are described in United States Bureau of Mines Information Circular 6406, Magnesium Compounds (Other Than Magnesite). Limestone, geologically, is a rock composed essentially of calcium carbonate; commercially, however, the term may include dolomite and magnesium limestone.

Sep 1, 1931

By Keith S. Olson

During 1982 and 1983, the Bureau of Mines concentrated its fugitive dust control research on haulage road dust suppression by newer chemi-cals relatively unknown in the mineral industry, innovative dust control designs for haulage trucks, chemical tailing basin stabilization, and combined chemical and vegetation tailing basin stabilization. Relatively unknown dust suppression chemicals and innovative aerodynamic modifications to haulage truck fender designs were tested on a Minnesota sand and gravel operation haulage road. Magnesium chloride salt at 95-pct control efficiency and a petroleum derivative at 70-pct control efficiency were effective in suppressing dust generated by haulage vehicles; however, none of the fender modifications were successful. Commonly used dust suppressant chemicals were tested on a Minnesota taconite tailing basin to reduce the dust lift-off during the spring and fall dry seasons. The most successful chemical was lignin sulfonate with a seasonal cost of less than $200 per acre to achieve 90-pct dust control. When chemical treatments for immediate dust control were com-bined with revegetation for permanent control, the most promising chemical treatment based on vegetation response was lime-neutralized lignin sulfonate.

Jan 1, 1987

By James J. Dowd

The investigation to evaluate the reserves of coking coal in the United States suitable for the manufacture of metallurgical coke is being made by the Bureau of Mines in three parts: (1) To estimate known measured and indicated recoverable reserves of all coking coal; (2) to upgrade marginal coals through effective preparation; and (3) to study the carbonizing properties of coals and coal blends not now widely used for metallurgical coke making. This is the eighth of a series of reports giving the results of studies by counties under part (1) of the investigation. (See appendix.) This report covers Jefferson County, Pa., which comprises parts of Marienville, Hallton, Ridgway, Brookville, DuBois, Penfield, Smicksburg, and Punxsutawney quadrangles. (See fig. 1.) A short resume of the chemical and carbonizing properties of the coals is included. Data on the coal beds in the county were obtained from mining companies, land companies, individual landowners, and other sources of authentic information. A base map for each bed in each quadrangle was made to the scale 1 inch equals 1,200 feet. Maps of mines, locations of drill holes, bed and total coal thicknesses, and the outcrop of the bed were plotted on the maps. With all available data plotted, isopach lines were drawn to limit areas of known unmined reserves in beds 0 to 14 inches thick, 14 to 28 inches thick, 28 to 42 inches thick, and over 42 inches thick, These areas of coal reserves also were divided into "measured" and "indicated" categories. All areas in each thickness range and in each category, mined-out areas, areas excluded from the estimate, and areas outside of the outcrop were measured by planimeter on the base maps. Estimates of total reserves 14 inches and more thick and maps for individual beds were prepared from these data.

Jan 1, 1952

By Joseph A. DeCarlo

The rapid growth of the organic chemical industry in the United States and abroad has focused attention on the future raw-material sources for this important industry. Chemical products are essential to modern civilization; and millions of tons of organic chemicals are used annually, ranging from basic raw materials to finished chemical products such as drugs, cosmetics, and soaps. Hundreds of chemical products are made directly or indirectly from coal, but in this report "coal chemicals" will be limited to crude tar, crud light oil, and ammonia recovered in the high-temperature carbonization of bituminous coal and the important principal products obtained by processing these materials. Specifically these include benzene} toluene, xylene, naphthalene, creosote oil, tar acid oil, pitch, and ammonium sulfate. Therefore the term "coal chemicals", wherever used in this report, includes only these products and does not include the secondary or intermediate products such as styrene, synthetic phenol, aniline, phthalic anhydride, or finished products made from these, such as synthetic rubber, plastics, and dyes. The United States leads the world in production and consumption of coal chemicals. In the past five years nearly one-fourth of the total output of coal-tar crudes in the world was produced in the United States. Consumption of some of the more important products derived from these crudes such as benzene, toluene, xylene, and naphthalene, however, ranged from about one-third to one-half of the world total because of imports and production of benzene, toluene, and xylene from petroleum. The synthetic organic chemical industry of the United States was established during World War I on chemical raw materials obtained by the high-temperature carbonization of bituminous coal but this source of supply currently furnishes less than 40 percent. More than 60 percent of the chemical raw materials used to produce organic and inorganic chemical is supplied by the petroleum industry and production of petrochemicals is rising rapidly.

Jan 1, 1960

By R. G. Knickerbocker, David Schlain, F. K. Shelton, J. H. Jacobs

"Many manganese ores contain from 0.1 to several percent cobalt. If such ores arc used for the production of ferromanganese, the cobalt is lost; on the other hand, if they are used for the production of electrolytic manganese, the cobalt can be recovered during the purification of the electrolyte.The production of cobalt in the United States is insignificant compared to the amount consumed, most of which is imported from the Belgian Congo. Cobalt-bearing manganese ores may therefore constitute an important reserve of cobalt in times of emergency. Moreover, the combined value of manganese and cobalt in some ores may be sufficient to warrant the recovery of both metals by the electrolytic manganese process, whereas the recovery of either manganese or cobalt alone might not be economically feasible.In view of the potential importance of manganese ores as a source of cobalt, a survey has boon made of the cobalt content of manganese ores. Most of the data have been obtained from analyses made in the Bureau of Mines, but valuable data have also been obtained from publications of the Geological Survey, various State publications, and other sources. Unfortunately, most published analyses of manganese ores do not include cobalt determinations; when such analyses were fairly detailed, but did not include cobalt, it was presumed that cobalt was not present in significant quantity.Information on the cobalt content of domestic manganese ores is given in table 1. Ores containing 0.1 percent or more cobalt are listed in table 2, and the districts in which such ores occur are shown in figure 1. Most of the known cobalt-bearing manganese ores occur in the southeastern part of the United States. A group of deposits in central Arizona and a few scattered deposits in other States also' contain cobalt."

Apr 1, 1946

By David R. Jessey

This volume contains the detailed mine site reports written by the WAPORA, Inc. and KETRON, Inc. staffs. It is a companion Appendix Volume to Control of Water Pollution from Surface Mining Operations. Copies of this report are maintained on Open File at the U.S. Bureau of Mines Research Center, Spokane, Washington.

Jan 1, 1981

By Paul M. Tyler

Magnesite is of importance primarily as a refractory material for lining steel furnaces , although substantial amounts are used in the production of flooring compositions and other building materials and for certain chemicals , notably epsom salts . Since consumption for all of these purposes is largely in the eastern United States and domestic deposits are situated in California and Washington , this country's magnesite mining industry , which was created largely by war- time conditions , has subsequently been sustained by tariff protection .

May 1, 1931

By S. M. Shelton, W. A. Calhoun, M. M. Fine, T. L. Johnston

"FOREWORDFerrograde manganese ore or its equivalent is essential to the manufacture of every ton of steel produced; although it is well known that there are large deposits of low-grade are in the United States, the production of substantial amounts of ferrograde material from domestic sources presents a problem that becomes more and more critical as the stockpiled ore depleted through inability to procure adequate supplies from foreign sources. Consequently, a program of laboratory,and pilot-plant investigation designed to solve the problem of obtaining a domestic supply of manganese has been undertaken by the Metallurgical Division, Bureau of Mines.This paper is one of a new series that include reports of results obtained in the various investigations conducted under the manganese program. The scope of the program and the organization that was set up to direct and supervise the were discussed in the foreword of the first paper of this series, Report of Investigations 3606 Manganese Investigations. 1. Concentration of Manganese Ores,from the Drum Mountain District, Utah, by S. R. J. D. Vincent, and C. R. Schack. Other reports will be published as the work progresses."

Mar 1, 1942

By S. S. Cole, C. E. Wood, T. L. Joseph

"INTRODUCTION Iron ore containing titanium was first used in blast furnaces over a century ago. It is well known that TiO2 is a slag-forming material that will increase the amount of slag produced by the usual gangue materials, silica and alumina. Increase in the volume of slag due to the presence of TiO2 and a lack of information concerning its effect on the properties of the slag have prevented the general use of titaniferous ore. Also rather com¬mon belief among furnace operators that the bottom of the furnace builds up when ores containing TiO2 are smelted has militated against the use of titaniferous ore. This building up of the hearth has been attributed to the formation of copper-colored crystals of titanium cyanonitride, which have been observed in the salamanders of blast furnaces. Until recently the availability of nontitaniferous iron ore has left little incentive to use ore containing titanium.The presence of vanadium in certain deposits of titaniferous magnetite in New York State has created new interest in problems connected with the use of titanium-bearing ore. It appears that most of the vanadium in this ore can be recovered in pig iron, which can be blown in a converter to produce a slag containing vanadium in amounts suitable for the production of ferrovanadium.The Titanium Division of the National Lead Co. recently erected a largo mill to treat ore from Sanford Hill, in Essex County, New York, about 50 miles west of Port Henry. The ore deposit was acquired from the MacIntyre Iron Co. and is often referred to as Sanford ore. It is one of the largest deposits of Iron-bearing material to be found east of the Lake Superior region and is being mined by open-pit methods."

Jan 1, 1943