Search Documents

By N. Sauret-Szczepanski, G. Patry, S. Gauthier, G. Potvin, C. Munger

Adsorption/thermal desorption with sorbent cartridges and analytical method using gas chromatography coupled to mass spectrometry (GC/MS) was developed for the determination of tetrafluoromethane (CF4) and hexafluoroethane (C2F6) emitted from primary aluminum smelters. A customized cartridge was built like a packed column with a stainless steel tube filled with a specific resin. The optimization of adsorption and desorption parameters was carried out to support the PFC sampling for all aluminum production technologies. The proposed method showed good linearity for concentrations ranging from 10 to 500 ppbv for CF4 and from 5 to 500 ppbv for C2F6 with correlation coefficients above 0.999. In certain conditions, the detection limits of the analytical method reached 0.3 ppbv for CF4 and 0.15 ppbv for C2F6- Using this methodology, a field campaign was carried out using a sequential sampler allowing the simultaneous sampling of PFC with cartridges and sampling bags. The results showed no significant difference (t-test) between the two sampling technologies and no breakthrough was observed from the cartridges .

Jan 1, 2006

By Ken Wood

"A reliable source of water of an acceptable quality is vital to the success of any mineral processing plant using wet methods. For Cerro Verde, a new 108,000 t/d copper mill in southern Peru, the main source of raw water is the Chili River. The Chili River is heavily contaminated with raw sewage, industrial wastewater and agricultural runoff, and can also receive high sediment loads during the rainy season. The initial water treatment plant could not supply design flows of water due to the exceptionally poor water quality. Problems with treated water quality caused significant difficulties with water consuming equipment, such as the plant cooling systems. This paper details the Cerro Verde water system and changes from design through to start up from a mineral processing perspective.INTRODUCTIONMining, and mineral processing in particular, is a water intensive activity. Improving water system design and practice are key strategic requirements in moving toward a more sustainable mining industry. This case study forms a basis for ongoing research into water use and reuse at mines and mineral process plants, conducted by AJ Gunson, under the supervision of Dr. Bern Klein and Dr. Marcello Veiga at the University of British Columbia. The case study material was gathered through involvement with the design, startup, and redesign of the Cerro Verde water system.Cerro Verde is a low-grade copper porphyry mine, located near the city of Arequipa in southern Peru, at an elevation approaching 2,800 m. In 1972, one of the world’s first copper Solvent Extraction – Electrowinning (SX/EW) facilities was built on the site, processing oxide ore from two main open pits. In 2004, the operator, Sociedad Minera Cerro Verde S.A.A. (SMCV), approved a 108,000 t/d expansion project to process sulfide ore reserves through a new concentrator plant. The plant was designed under extremely tight schedule and capital constraints, with a mandate to intentionally avoid any overdesign."

Jan 1, 2008

By Wei Sun, Jaewon Choung, Zhenghe Xu, Zhangming Cui

"High intensity conditioning has been demonstrated in a number of cases to enhance fine particle flotation. The improvement could be attributed to the enhanced formation of particle aggregates. However, the understanding of aggregation mechanisms remains rather limited. Recently, an enhanced particle aggregation was observed by the formation of small air bubbles resulting from high intensity agitations (HIA). In this study, a novel visualization system is designed and constructed for characterizing the fine bubbles formed in an HIA cell. The new design allows determination of gas evolution and bubble size distribution. With this system, the effect of dissolved air on fine bubble generation by HIA is investigated. The results show that HIA creates a favorable environment for the formation of gas nuclei and small size bubbles due to hydrodynamic cavitation.INTRODUCTIONFlotation is a dominant separation technique employed by mineral industry to recover the valuable mineral particles. However, in general, particles finer than approximately 10 µm are not effectively recovered by conventional froth flotation technique due to their low inertia and high specific surface area (Fuerstenau, 1988). Therefore, the fine particle flotation has been considered as the central challenge of flotation research. Substantial advances have been made for fine particle flotation from both a theoretical and technological point of view (Fuerstenau et al., 1979; Song and Lu, 1990; Subrahmanyam and Forssberg, 1990; Sivamohan, 1990; Sedat and Barry, 1991; Matis, 1995). High intensity agitation (HIA), for example, has found some success to improve fine particle flotation kinetics in laboratory tests (Chen et al., 1999a and 1999b; Valderrama and Rubio, 1998; Rubio and De Brum, 1994).The effect of mechanical agitation on flotation kinetics has been recognized for many years. In mid-1970s, Warren (1975) reported that increasing the shear rate of the pulp could improve the efficiency of ultra fine particle flotation. He attributed this improvement in flotation to the formation of aggregates. This concept of aggregation has been extended by Rubio (1978), and Bulatovic and Salter (1989), who employed high intensity agitation (HIA) method to promote aggregation. They found that HIA with the addition of collectors, frothers and suitable modifiers significantly improved both the flotation recovery and selectivity of ultra fine sulphide minerals. The improvement was explained by warren’s shear flocculation theory. Till now, many studies (Chen et al., 1999a and 1999b; Valderrama and Rubio, 1998) have been undertaken to improve fine particle flotation by HIA. However, most of these studies were focused on the relation between energy input and flotation efficiency. Less information was available for describing how the aggregate formed during HIA process."

Jan 1, 2006

By Patrick Pelletier Jr., Pierre-Alexandre Bossé, Gianni Bartolacci, Ian Orford, Steve Parent

"Over the last decades, many authors have shown the importance of froth in the flotation process. Mineral recovery is related to froth recovery and flotation. Selectivity is affected by froth characteristics, especially structure and loading. The characteristics of froth textures could therefore be used for diagnosing flotation.Machine imaging, especially image texture analysis, allows on-line measurement of important froth characteristics and process state classification. The measured characteristics include froth texture, loading and stability indicators. To extract information from images, texture analysis tools are used as well as a block-matching algorithm (BMA). For process state classification, images are analyzed with the same tools and clustering is done with multivariate data analysis algorithms.Two case studies, Brunswick Mine Concentrator Cu/Pb circuit and LaRonde Mine Zn circuit, are presented to show that these indicators may be used for diagnosis and control. The influence of manipulated variables on measured froth features is shown as well as the relationship between froth characteristics, mineral recovery and flotation selectivity.INTRODUCTIONImaging is a way to depict abstract characteristics of a scene or an object; it is often related to other types of scientific observations, chemical component concentrations, for example (Geladi and Grahn, 1996). In this paper, the scene is flotation froth. Imaging can be especially useful in applications where it is difficult to obtain the measurements needed for process analysis – froth flotation, for example."

Jan 1, 2006

By Trevor Yeomans

"NVI Mining’s Myra Falls Operation is a forty year old underground mining operation feeding a 4000 mtpd concentrator.The current Mill, built in 1985, was designed to process a large massive sulphide ore-body. This ore-body, known as the “HW”, contains about 50% pyrite. Value minerals are chalcopyrite, and sphalerite, with precious metals occurring in all mineral types.By 1997, mining of a new ore-body, known as “Battle-Gap” commenced. Mineralogically complex, the new orebody contains about 15% pyrite, copper minerals including primary chalcopyrite, secondary bornite, chalcocite and tennantite, combined with increased galena and sphalerite.Flotation performance generally decreased with increasing amounts of Battle-Gap ore types, with both copper concentrate quality (increased lead and zinc content) and copper recoveries being affected.Following significant metallurgical testwork, a new fully sequential copper-lead-zinc flotation flowsheet and reagent scheme was developed.This sequential flowsheet was progressively installed and commissioned during 2006.Copper concentrate lead and zinc smelter penalty contents have been reduced by some 40%, whilst increasing copper recovery by 10%.INTRODUCTIONNVI Mining operates the Myra Falls Operation near Campbell River on Vancouver Island, BC. The complex has been in operation since 1966 with mining being predominantly underground. One unique feature of Myra Falls is that the mine operates within a BC Provincial Park.In 1985, a new large massive sulphide ore-body (HW) had been defined, and metallurgically tested. A new concentrator was built based upon this massive pyrite, chalcopyrite, and sphalerite mineralization producing copper and zinc concentrates by conventional flotation methods."

Jan 1, 2008

By Dave Bulled, Khiratt Husain

"The use of High Pressure Grinding Rolls is gaining significant interest as a replacement for SAG milling in the comminution of hard rock ores because of the potential for reduced costs in terms of energy and grinding ball consumption. Estimation of expected energy consumption for fullscale operations has conventionally involved the testing of a few fairly large samples in pilot scale HPGRs. This paper describes the development of a small-scale batch test method for determining a work index for HPGR of a large number of samples that can be used to show the variability of the ore as an integral part of a geometallurgical approach to circuit design and production forecasting.The test equipment that was developed comprises a hydraulic press with adjustable pressure operating on small batches of ore in a locked cycle test procedure. A work index measurement was determined that links the specific energy consumed in the test to the breakage achieved such that the index can be used to predict comminution energy requirements.The measurements were calibrated against laboratory scale HPGR equipment to develop a model for design and forecasting that includes crushers, HPGRs and ball mills in a complete comminution circuit.INTRODUCTIONEstimation of the expected energy consumption for full-scale HPGR operations has conventionally involved the testing of a few fairly large samples in laboratory and pilot scale machines (Danilkewich, 2006). With the financial input of five mining corporations, SGS Lakefield Research has developed a small scale test capable of providing relevant information on the variability of energy consumption and size reduction from drill core samples. It is our intention that the values measured in the test will be scaled up, through benchmark comparison with pilot sized and full sized HPGR units, to allow plant design and throughput forecast on a block by block basis of the mine plan using a new CEET program. CEET® (an acronym for Comminution Economic Evaluation Tool) is an advanced grinding design and performance predicting tool that uses energy relationships to model the performance of SAG / Ball mill circuits."

Jan 1, 2008

By J. Coffin, R. Multani, C. Deredin

Glencore’s Strathcona Mill has recently evaluated a pyrrhotite depressant combination of diethylenetriamine (DETA) and sodium metabisulfite (SMBS) to improve its overall plant pyrrhotite- pentlandite (Po-Pn) selectivity, with the aim of producing a higher quality nickel concentrate. In a previous paper, key findings from a comprehensive lab-scale program (completed at the XPS Centre) were summarized where, of the depressants tested, DETA/SMBS combination was found to be the most effective in improving the Po-Pn selectivity. The present paper describes the metallurgical program recently completed at Strathcona Mill; DETA/SMBS evaluation on select plant “grab” samples as well as the major results of three DETA/SMBS plant trials conducted on several plant ore feeds (long-term testing). Interestingly, it was found that there was variable success in using DETA/SMBS depressants on the different plant ore feeds; DETA/SMBS (dosage: 25/50 g/t milled feed) on lower Cu feeds demonstrated a ~2% Ni recovery increase at the same Ni grade. On the other hand, higher Cu feeds demonstrated virtually no benefit from DETA/SMBS at the same plant dosage, suggesting that higher DETA/SMBS dosage (at specific locations) than that tested is required to overcome the increased Cu-DETA complexation for these particular feeds. Glencore Nickel – Sudbury Integrated Nickel Operations owns and operates Strathcona Mill which has been processing Ni-Cu ores from the Sudbury Basin since 1968. The valuable sulfides are pentlandite (Pn) – (Ni,Fe)9S8 and chalcopyrite (Cp) – CuFeS2, majority of the sulfide gangue is pyrrhotite (Po) – Fe(1-x)S [0 < x ≤ 0.125] which is present in two forms: hexagonal Po (Fe9S10) and monoclinic Po (Fe7S8) (Multani & Waters, 2017; Lawson et al., 2014). Currently Strathcona Mill processes ore mined from two primary sources from the Sudbury area and produces two concentrate streams: (1) nickel-copper concentrate that is sent to the Sudbury Smelter; and (2) copper concentrate that is shipped to the Fonderie Horne (Glencore Copper, Rouyn-Noranda).

Jan 1, 2019

By R. J. Balfour, T. L. Papucciyan

"INTRODUCTIONCapital Cost considerations are basic to feasibility in the achievement of success for Mineral Processing Projects as much as or more than in many other industries. Capital cost is an important factor ae it 1R the unit of measurement for process engineering economic decisions. As a result of ever increasing complexity, alternatives of process and remoteness of site, there is an ever increasing emphasis on accurate estimating and the attendant cost control systems in the international market of today for the Mineral Industry where initial plant costs are becoming a more important factor than operating costs. An undervaluation means trouble ahead. An over-cautious assessment may bring an unnecessary abandonment of a project. Consequently, the ultimate cost must be predicted early and accurately and must be controlled to this parameter during the design and construction phases. Cost Est!~ mating is one of a variety of project management tools used to assist in planning and achieving the optimum balance between Quality, Cost and Time, the eternal triangle of evaluation, namely obtaining a project of acceptable quality at minimum cost and on time. In order to attain these established objectives, proper planning, organizing, coordinating, monitoring, adjusting and controlling the design, procurement and construction elements of the project are essential.This project management approach based upon the principle of a Task Force under single management, comprising a complete service organization, requires a substantial number of qualified individuals specialized in their own field and capable of working together as a team to perform their various functions effectively. The Task Force is supported by their chiefs of discipline and performs in accordance with established procedures and standards under the leadership of a Project Manager.General Engineering Company Limited with the backing of the full resources of Surveyer, Nenniger & Chenevert and its total staff of approximately 1,0009 offers the complete project management service to the Mineral Processing Industry of North America and the rest of the world. As mine sites become more remote and difficult of access, the need for an experienced team of specialists who work under the Task Force principle, with well established standards and procedures becomes even more important. Our long history of successful pro1ecta in this field has been our training ground for the fulfillment of this need."

Jan 1, 1972

By J. S. Phipps, D. R. Skuse

"Aqueous slurries of fine particle size calcium carbonate are used in a diverse range of end-use products. In many cases, the end use performance is governed by the fineness of the particle size distribution. In turn, the maximum fineness of the particle size distribution is primarily determined by the efficiency of the dispersants used during the production process. Here we report the sodium polyacrylate mediated dispersion of calcite and kaolin. Firstly, we report a colloid chemical description of the dispersant behaviour and attribute the stabilisation to both steric and electrostatic mechanisms. Secondly, we describe how the understanding developed in the first part of the study can be utilised to produce more effective dispersant systems which allow the preparation of, added value, higher solids and finer particle size calcium carbonate slurry products.INTRODUCTIONConcentrated aqueous dispersions of fine, particulate kaolin and calcium carbonate are used extensively in the coating of paper. Currently more than 10 million tonnes of such dispersions are used annually in North America and Europe alone, and worldwide consumption is growing at around 3% per year.Generally, paper is coated to enhance its visual appearance. Firstly, coatings improve the optical properties of the blank sheet, i.e. its brightness (or whiteness), opacity and gloss. Secondly, they improve the physical properties of the sheet that will influence the quality of the final printed image, such as surface smoothness, porosity, and ink absorption. In order to achieve these aims economically, paper coatings must be applied at high speeds and with minimal drying costs.Kaolin and calcium carbonate pigments are the major components of most paper coating formulations. Particle size distributions are chosen to maximise the optical benefits that they confer, and to allow the production of formulations that can be easily pumped, handled and coated. Coating pigments are generally produced and transported as slurries, and so it is important to obtain dispersions with the highest possible solids content, both to minimise drying costs and the quantity of water transported. This paper examines the dispersant technology that is currently used in the industry and the mechanisms by which it functions, and illustrates ways in which this technology has developed and could be further improved in the future."

Jan 1, 2003

By Yves Gratton

The International Commission on Large Dams (ICOLD) is a non-governmental International Organization which provides a forum for the exchange of knowledge and experience in dam engineering. It is the world&apos;s leading professional organization dedicated to advancing the technology of dam engineering and supporting socially and environmentally responsible development and management of the world&apos;s water resources. ICOLD was founded in 1928 and has National Committees in 82 countries with approximately 7,000 individual members who are engineers, geologists and scientists from governmental and private organizations, consulting firms universities, laboratories and construction companies. Its original aim was to encourage progession in planning, design, construction, operation and maintenance of large dams and associated civil works by collecting and disseminating relevant information and by studying related technical questions. Since the late sixties, focus was put on subjects of current concern such as dam safety, monitoring of performance, reanalysis of older dams and spillways, effects of ageing and environmental impacts. More recently, additional subjects have included cost studies at the planning and construction stages, harnessing international rivers, information for the public at large, and financing.

May 1, 2002

By C. J. Martin, M. P. Hay

"A methodology was developed in the mid-1980’s to predict plant performance from standard laboratory flotation tests. The technique is based on a simple, empirical kinetics model, and is tailored for use by the practical metallurgist.To date the performance of more than 20 flotation plants has been predicted, including copper, lead, zinc, phosphate, pyrite, graphite, cassiterite, platinum, nickel and various slags. The method has successfully been used to predict and size four flotation plants directly from bench-scale laboratory flotation testwork. All have since been commissioned, and have performed as predicted.The technique has now received broad acceptance within the South African mining industry, for example in the last year alone it has been used to drive flowsheet development for at least seven new plants. It is also being used to assist in the optimisation of existing operating plants.The methodology is described in this paper and verification of the methodology is presented using case studies of porphyry, polymetallic and PGM operations.INTRODUCTIONThere is considerable interest these days in the use of modelling to simulate flotation circuits, for process design and plant optimisation purposes. Although these models are proving to be useful tools for plant design and optimisation, their complexity can make them cumbersome – expensive to use and difficult for metallurgists to visualise and mentally absorb, without a background in each specific technique. In “SUPASIM” no attempt is made to measure flotation fundamentals, rather to use empirical relationships between laboratory flotation kinetics and plant performance – relationships that hold up well to validation exercises as will be demonstrated later in this paper. Although not designed to be as comprehensive as other models, “SUPASIM” is easily understood by the operating metallurgist and can be quickly and easily applied."

Jan 1, 2004

"The effective thermal conductivity (ETC) is one of the most important thermo-physical properties of porous media. Due to the lack of higher precision influence of temperature on thermal conductivity, we took 6 groups of experiments on rock samples (including igneous rock, sedimentary rock and metamorphic rock) under different operating temperatures from 20? to 50? by 7 acquisition points. The general equation of thermal conductivity drives the value of it increasing along with the decreases of the temperature. While in our experiments, it is easy to find a singularity among them for each sample. The experimental investigations we attempted to observe and interpret the alteration mechanism. According to the Heat Capacity Theory in solid state physics, this research gives the explanation about the “singularity” from 3 understanding of specific heat, average free path, and thermal conductivity. Our research divided the condition of the rock thermal conductivity into 3 different types. INTRODUCTION The effective thermal conductivity (ETC) is one of the most important thermo-physical properties of porous media(Huang & Han ,1988; Peierles ,1955). This parameter is necessary for analysis of heat transfer(Vaferi et al, 2014;Hans-Dieter & Rudiger,2003). It’s well known that a general equation for ?(T) was set by Sass et al. (1992) which based on the coupled effect of composition and temperature on the thermal conductivity(Jesse et al, 2013; Mongelli et al,1982).The equation was further successfully verified for other rock (Zumrud et al,2010;Abdulagatova et al,2009;Seipold& Huenges,1998).Thermal conductivity is also related to other physical proper ties of porous rock, such as thermal diffusivity, heat capacity(Brettmann et al,2011;Abuel-Naga et al,2008). It is well known that ETC and other thermo physical properties of rock materials are affected by various factors, such as temperature, pressure, mineralogical composition, porosity, stratification, size and shape of the components, and nature of pore fluid, etc. (Tiedje & Guo, 2014; Touloukian et al,1970).The understanding of heat transport processes still requires the knowledge of thermal properties of rocks."

Jan 1, 2015

By J. K. Afidenyo, J. Osei-Owusu

"The Obuasi Mine of AngloGold Ashanti Limited has been operating the world’s largest Biooxidation Plant at its Sulfide Treatment Plant (STP) in Ghana, using the Gencor Biox® technology since February 1994. The Biox® technology was preferred to other alternative methods of treating refractory sulfide ores such as roasting, pressure oxidation and nitric acid leaching due to among other reasons, its lower capital and operating costs, reduced technical risk, relatively benign environmental impact and its ease of operation and maintenance in a remote location.STP has since commissioning succeeded in operating this technology successfully but not without some operational problems. The Plant has seen a number of upgrades and modifications in its circuits which were motivated by cost, operational and throughput constraints.The objective of this paper is therefore to highlight the mine’s experience in the treatment of its complex carbonaceous refractory sulfide gold ores with emphasis on plant operations and improvements such as the Biox® reactors expansion, flotation concentrate upgrade project and neutralization circuit modifications. The Biox® Plant operating cost is also discussed.INTRODUCTIONThe Obuasi mine forms part of the AngloGold Ashanti Group of Gold Mines. It is located in the Adansi West District of the Republic of Ghana. The mine is primarily an underground operation, although some surface mining still takes place. Ore is processed by two main treatment plants: the Sulfide Treatment Plant (for underground ore) and the Tailings plant (for tailings reclamation operations). A third plant, the Oxide Plant, is used to batch-treat remnant opencast ore and stockpiles, of which there are adequate tonnages to keep the plant operational until 2008.Though reference is made in this paper to the Tailings and Oxide Treatment Plants, the main focus will be on the Sulfide Treatment Plant."

Jan 1, 2008

By Sengpasith Houngaloune

Arsenic, which is a toxic and carcinogenic element, causes serious environmental problems throughout the world. It is also known as a major contaminant in the non-ferrous mining and extractive metallurgical industries, thus its disposal is one of the most important environmental issues for the mining and metallurgical industries. In order to ensure a safe disposal environment for the final wastes, stabilization of arsenic has been studied extensively with various approaches. Solidification/stabilization (S/S) represents one of the most effective methods to reduce the availability of arsenic in soil and waste by transforming toxic or potentially hazardous phases into less hazardous ones. Cement based S/S processes could reduce the solubility of arsenic in solid waste, using inorganic binders such as cement, lime, and pozzolanic materials. A new tailings management technique, called cemented paste backfill (CPB), has become widely employed for improving mining techniques and for tailing storage purpose and this technique could also enhance arsenic stabilization, by fixing the contaminants in the binder matrix. Disposal of arsenic in the form of scorodite (FeAsO4?2H2O) has been widely accepted as currently the most suitable method for stabilization and the safest known storage material. The Bio-scorodite process has been reported to be more economic and environmentally friendly method than the chemical crystallization processes. Retention of arsenic by schwertmannite (Fe8O8(OH)6SO4), a metastable ferric oxyhydroxy sulfate mineral, has gained more attention in the recent years. Schwertmannite has a large specific surface area and high capacity to adsorb arsenic in solution. Several researchers have reported that the transformation of schwertmannite to goethite could be retarded by the presence of adsorbed arsenic; therefore schwertmannite might be viable alternative for long-term storage of arsenic. In this paper, various approaches used in arsenic stabilization are reviewed with emphasis on the development in the recent years.

Aug 1, 2013

By H. O. Ghaffari

A complex network approach on a rough fracture is developed. In this manner, some hidden metric spaces (similarity measurements) between apertures profiles are set up and a general evolutionary network in two directions (in parallel and perpendicular to the shear direction) is constructed. Also, an algorithm (COmplex Networks on Apertures: CONA) is proposed in which evolving of a network is accomplished using preferential detachments and attachments of edges (based on a competition and game manner) while the number of nodes is fixed. Also, evolving of clustering coefficients and number of edges display similar patterns as well as are appeared in shear stress, hydraulic conductivity and dilation changes, which can be engaged to estimate shear strength distribution of asperities.

May 1, 2009

By R. Sharon, P. M. Hawley, X. Ochoa

"Development of Barrick Gold’s Pierina gold mine in north-central Peru requires construction of a waste dump for disposal of nonore grade materials stripped from the open pit to expose the ore. The waste dump site is located near the open pit in a U-shaped valley that is underlain by thin colluvial and morainal soils with locally thick peats and glaciolacustrine deposits. Bedrock underlying the site consists of variably weathered volcanics. The site is subject to moderately high seasonal rainfall and significant seismicity. The geotechnical quality of the waste rock is highly variable, ranging from low-quality, degradable, soil-like materials containing appreciable quantities of silt and clay, to high-quality, hard, durable, blocky waste rock.A hybrid dump design concept was developed that requires in-pit segregation of highand low-quality waste, and selective placement of materials in the dump to maximize stability and enhance internal and subsurface drainage. The design includes a rock drain beneath the dump along the axis of the valley and a series of connected finger drains. Extensive peripheral diversions and stormwater control measures to inhibit infiltration of precipitation are also included.This paper discusses the unique challenges presented by the site and waste materials, the design methodology and stability analyses, and planned monitoring systems."

Jan 1, 2003

By Hua-Zhong Yu

Gold is one of the most widely used substrate materials for self-assembly. Self-assembled monolayers (SAMs) prepared from alkanethiols and their derivatives on gold are the most reliable and well-studied systems to date, which have attracted much attention because of interest in two-dimensional molecular assemblies, and of their potential applications in molecular devices, sensors, and functionalized interfaces. Gold electrodes are also very important in microelectronics and electroanalytical chemistry. This work reports the characterization of a new type of gold substrates for self-assembly. The gold substrates are constructed from recordable compact disks (R-CDs) with simple and straightforward wet-chemical treatment, and can be made at desired sizes and shapes that satisfy different experimental needs. In particular, an easy, inexpensive, and reproducible method to prepare self-assembled monolayers (SAMs) on CD-R gold substrates after removing the protective polymer films with concentrated nitric acid was described.

Oct 1, 2003

By Jack J. Ayotte, Michael R. Nadon

"Today&apos;s demand for better and more efficient methods inspires new approaches to construction and mine development.A project at Asarco&apos;s Aquarius Mine provided a challenge that resulted in the adaptation of a civil construction technique to a mining application.This paper describes the construction of an escapeway shaft to surface from the mine&apos;s 150m level. The prime consideration was to provide the most cost-effective method of establishing a shaft collar in the 145 ft (44 m) of water-bearing overburden. This problem was resolved with the employment of the drilled in-caisson method.The remainder of the 500ft (152m) deep shaft was raise bored and portable hoisting equipment was used to install a permanentmanway and shaft liner.IntroductionHaving completed the first phase of exploration development in 1982, J.S. Redpath Limited was engaged to carry out an engineering and cost study to investigate the feasibility of re-opening Asarco&apos;s Aquarius Mine near Timmins, Ontario. The scheme was to develop the proven ore reserves and proceed with shrinkage stoping while carrying out further exploration development and diamond drilling.One significant and costly component of the project was the provision of an escapeway shaft to supply additional ventilation as well as a second means of egress from the mine. The major complication to this task was the presence of 145 ft (44 m) of water-bearing overburden at the site. The first and obvious approach was to use conventional ground-freezing methods as had been employed previously on .this property for the initial development shaft. This being the only ""sure"" method available at the time of the budget estimate, it was used as a basis for the study but its considerable projected cost and time demand inspired further investigation into other possible solutions.After considerable research and several brainstorming sessions, a Redpath team came up with an approach whose basic procedures had been used extensively in the civil construction field, although they were novel to the mining industry."

Jan 1, 1987

By L. Su, S. Liu, K. Jiang, K. Xie

The reduction of iron dissolution and acid consumption is fairly important in the extraction of Ni and Co from laterite ores from both economic and efficiency perspectives. BGRIMM conducted detailed research to investigate the behavior of iron in a nickel laterite leaching process. The mineralogy of Ni and Co was studied. In limonite ore about 76% of nickel is present in goethite while in saprolite ore 79% of nickel is associated with magnesium and silicon minerals. Test work revealed that limonite can be decomposed completely with enough acid concentration during atmospheric leaching. More than 98% of Ni and Co were leached into solution while 85% of the iron was also dissolved with 130-140 g/L iron in solution. Iron precipitates as hematite in the temperature range 250-270?C without neutralization reagents. That’s why limonite is treated by high pressure acid leaching (HPAL) technology to achieve nickel extraction and iron precipitation in the same autoclave. BGRIMM’s test results indicated that the remaining acid in atmospheric leaching solution and acid released by iron precipitation at a lower temperature was enough to leach saprolite efficiently. The so-called inverse leaching technology leaches limonite at atmospheric condition and the leaching slurry combined with saprolite is pumped into an autoclave to leach saprolite at 150-170?C. In the autoclave iron precipitates as hematite without acid consumption. Total nickel and cobalt extractions in the test program were more than 90% with iron content in solution below 8 g/L. In this inverse process iron dissolves in the atmospheric leaching stage and precipitates as hematite in the low temperature leaching stage. Compared with HPAL the leaching temperature is reduced to 150-170 ºC from 250-270 ºC. Compared to atmospheric tank leaching acid consumption is reduced from 850-950 kg/t ore (atmospheric) to 550-650 kg/t ore (inverse).

Jan 1, 2016

By D. P. R. Smyth

The limestone reef reservoir at Swan Hills consists essentially of a "buildup" of successively smaller atoll-like layers. Precipitation of calcium carbonate within the lagoonal area of each layer essentially kept pace with growth of the outer organic lattice. Within the reef mass, six de-positional environments characterized by specific suites of fossils (or fossil fragments) and associated limestone textures are recognized as follows: ( 1) Aerated moderately agitated water of normal marine salinity (widespread shelf or submerged reef-built platform). Thamnopora-type corals, Amphipora, "pancake" stroma-toporoids, crinoids, articulate bra-chiopods, rare rugose cup corals, and ostracods occurs in light gray-buff skeletal microgranular limestone of low permeability. (2) Semi-stagnant quiet water of normal marine salinity (leeward side of reef). Crinoids, articulate brachio-pods, rare thamnopora-type corals, Amphipora, pancake and bulbous stromatoporoids, rugose cup corals, ostracods and gastropods occur in impermeable dark brown argillaceous skeletal calcilutite with thin black bituminous shale beds and rare dark chert nodules.

Jan 1, 1961