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By C. J. Mwenifumbo

Preservation of groundwater quality is a major environmental concern. The disposal of hazardous material from urban waste dumps, milling wastes in tailings ponds, and industrial wastes in injection wells may contaminate potential sources of potable groundwater. The containment or migration of contaminants in the subsurface depends on bedrock characteristics and type of overlying sediments. Fractured bedrock and permeable sediments that may provide pathways for the transport of potentially harmful contaminants should be avoided when selecting a disposal site. The role of borehole geophysics in hazardous waste-site investigations is reviewed in three categories: (I) site selection; (2) determination of the extent of contamination at existing sites; and (3) long-term monitoring of migration of contaminants. In the first category, borehole geophysical techniques developed for lithology and fracture identification, and for porosity determination, provide some of the necessary information for understanding the subsurface hydrogeology. Lithological information can be obtained from gamma-ray, electrical resistivity, induction, magnetic susceptibility, and sometimes induced polarization logs; fracture detection and characterization can be accomplished with the use of caliper, density, resistivity, temperature, and acoustic televiewer logs. Estimates of porosity are derived primarily from neutron-neutron, resistivity, density, and soniclogs. Borehole geophysical techniques used in water quality determinations include self-potential, fluid resistivity, Eh (redox potentials) and pH measurements, and these can be used to map the extent of contamination at an existing waste site. Cross borehole and borehole-to-surface electrical methods can also be used in this application. Long-term monitoring of contaminant migration in boreholes can be accomplished with techniques that respond to changes in electrical conductivity, temperature and fluid chemistry caused by the presence of contaminants.

Jan 1, 1993

By D. L. Churcher, R. J. Perry

"In recent years much work has been don e to examine alternate underground backfill support systems with the objectives of improving ground support and reducing mining costs. This report deals with the work conducted at Placer Dome Inc.’s Dome Mine to develop a high density backfill system, taking advantage of the unique properties of this fill material, to address a backlog of large open stopes to sustain stable minewide ground conditions for future generations of Dome miners.IntroductionDome Mine began its existence in 1909 with the discovery of visible gold on a dome shaped outcrop located west of Porcupine Lake in northern Ontario. The orebody beneath this outcrop has supported one of Canada’s premier gold mining operations for 80 years. Production during this time of over 46 000 000 tons of ore has resulted in the recovery of II 500 000 ounces of gold and 2 000 000 ounces of silver. Mining continues today at a production rate of 3500 tons per day, with ore coming from both underground and open pit operations.During the life of the mine, different underground mining methods have been used to extract the ore from a complex deposit consisting of single and multiple vein structures.Cut-and-fill mining was introduced in the 1930s using sand fill and later hydraulic fill for support and to provide a working platform. A total of 1 800 000 tons of sand fill and 7 300 000 tons of hydraulic fill have been placed underground in cut-and-fill stopes. Until the late 1960sshrinkage mining was used extensively, particularly in narrow, steeply dipping zones. Bulk mining with small diameter longholes was introduced about this time, to take advantage of low production costs. Longhole blasting has often been used to recover low grade ore from the walls or sills of old shrink stopes, resulting in large open stopes. Backfilling of these open holes has been restricted to smaller stopes and associated with local ground conditions.In the late 1970s it was recognized that the number of large open holes which were being generated presented serious regional and minewide stability problems for future operations. With higher gold prices, economic ore reserves were being tied up in areas adjacent to multi-level open stope complexes. To stabilize these stopes and allow access, backfilling would be required."

Jan 1, 1990

By W. Gan

The interactions between bitumen and quartz sands in aqueous solutions were studied with the objective of recovering residual bitumen from Athabasca oil sands froth treatment tailings. It was observed that the presence of various multivalent metal cation (Fe3-, Fe2+, Mg2+,Ca2+, etc.) increased the mutual coagulation between quartz particles and oil or bitumen droplets within certain pH ranges. While the increased coagulation was detrimental to the recovery of the bitumen since it lowered the degree of bitumen liberation from sands, this effect could be reduced or eliminated by the addition of organic chemicals such as citric acid, oxalic acid and EDTA. Among these organic chemicals, citric acid was found particularly effective even at very low concentration.

Jan 1, 2006

By John E. Udd

"Mining research at CANMET is delivered by the Mining Research Laboratories Division (MRL), with facilities in Sydney, Nova Scotia; Bells Comers, Elliot Lake, and Sudbury, Ontario; and Val d'Or, Quebec. This paper gives an overview of the work of the Division as of early 1993. An addendum, at the end of this paper, describes the organizational changes that will take place in April 1994. IntroductionCANMET, the acronym for the Canada Centre for Mineral and Energy Technology, is the name by which the organization founded in 1907 as the federal Mines Branch is presently known. The name was changed in 1974, in order to give recognition to the importance of both minerals and energy technologies in the activities of the Branch. Further reorganizations have taken place since 1987. As a result of these, CANMET has assumed the status of a Sector (equivalent to the Geological Survey of Canada) and has been organized into four branches.The organization as a whole functions in an environment of semi-matrix management. Some of the ""line"" Divisions report to Directors-General for the appropriate branches while other, larger divisions, report directly to the Assistant Deputy Minister.The second dimension of the organizational matrix is composed of a number of ""staff' divisions which report to the DirectorGeneral for Policy and Planning. Each of these Divisions performs a function which is common to all of the ""line"" divisions. For example, the Research Projects Office is responsible for monitoring the range of research activities of CANMET and for recommending allocations of funds for both research contracts and operating budgets. The Library and Documentation Services Division is responsible for CANMET publications and information services. Likewise, the Engineering and Technical Services Division provides support through, among other services, the construction of specialized laboratory equipment."

Jan 1, 1994

By P. O. Rag, Daniel E. Walsh

"Gravity concentrators are evaluated either in closed or open circuit. The process developed by MIRL employs the use of neutron activated gold (/98Au) and radiation detection circuits which monitor the concentrator's product pulp streams. Concentrator recovery is determined from the ratio of the number of gold particles detected as passing into the concentrate to the total number of gold particles detected over all monitored pulp streams. This system eliminates the experimental errors introduced by sampling, sample reduction, and assaying and allows recovery to be evaluated for gold particles of specific sizes, shapes, and flatness. In addition to allowing for a more accurate and detailed recovery analysis, this process significantly reduces the time and cost required for unit evaluation when compared to other gold recovery analysis procedures. This system enjoys its greatest utility where a large number of tests are to be run in order to evaluate a concentrator over a variety of operational settings, i.e. factorial designs, and allows accurate testing of concentrators operated in closed circuit systems.IntroductionThe surge in gold prices of the late 1970s and early 1980s was followed closely by a renewed interest in gravity concentration processes, especially in concentrators claiming efficient recovery of fine placer gold. Cones, spirals, spinning bowls, jigs and cyclones are all considered potential fine gold concentrators. Fine gold, in this context, is defined as not only that gold finer than 250 um (60 mesh""), but also coarser gold, whose low shape factor may decrease its recovery by conventional, large-scale sluicing operations.Adoption of fine gold concentrators by the Alaskan placer milling industry was retarded by the lack of reliable, accurate, and reproducible data on concentrator efficiency with respect to fine placer gold recovery. In most cases, concentrator performance was based on a limited number of tests run on placer material, about which only slight knowledge of gold size and shape characteristics existed. In order to be prepared for the resurgence of interest in fine gold concentrators, which will follow the next upturn in gold prices, a detailed study of the fine gold recovery characteristics of gravity concentrators needs to be conducted."

Jan 1, 1986

By R. W. Luhning, S. D. Gittins, J .. A. Haston

"The Underground Test Facility (UTF) project operated by the Alberta Oil Sands Technology and Research Authority (AOSTRA) north of Fort McMurray has achieved marked success in field testing mining access and horizontal well in situ recovery of bitumen from the Athabasca oil sands.Mine access has provided for effective placing and operation of horizontal wells in the oil sands from a tunnel system in the underlying limestone. Performance of the in situ recovery process, Steam Assisted Gravity Drainage, has substantially exceeded forecasts made at the start of the project. Over-all results of the program to date show great promise for horizontal well in situ technology as a competitive source of bitumen from Alberta's vast oil sands deposits. The potential economics of a commercial expansion at the site are reviewed in this paper.IntroductionIn situ recovery o f bitumen from the Athabasca oil sands has puzzled the oil industry for many year s, but a breakthrough appears close at hand. The Underground Test Facility (UTF) project initiated by the Alberta Oil Sands Technology and Research Authority (AOSTRA) has had notable success in the piloting of horizontal well processes, which offer prospects for commercial development even under the highly competitive situation facing the Canadian industry . This paper describes the project briefly and presents the potential economics of commercial development on the UTF lease."

Jan 1, 1990

By Bertrand Wolfman, William E. Stanley

"This paper reviews the traditional mine accounting systems, including ""custodial accounting"" and unit costing, and then suggests that the use of flexible budgets represents a more suitable method of reporting costs in order to assist the mine manager in improving productivity. Examples of various applications are given to show that the result is a clear reporting structure.Custodial Accounting is Emphasized in Traditional SystemsTraditional mine accounting has been mainly concerned with the accuracy of financial reporting to ""head office"" for the use of the directors and the company's bankers and shareholders. This is often called custodial accounting and it represented the main purpose of accounting when first developed in Europe hundreds of years ago. This important development permitted the establishment of enterprises which were separated from their owners because they could rely on accurate financial reports of management's stewardship.As custodial accounting is fairly broad and historical in nature, it is often not very useful to the mine manager for ongoing monitoring of performance of mining, milling, maintenance, and other support and staff groups. In spite of the considerable investment in accounting staff and computer support, many accounting systems have not been upgraded so that they accurately reflect workplace performance on a weekly or monthly basis.Budgets are Often FixedMany mines today also still emphasize fixed budgets. Thus, the mine plan which is set in the fall of one year is converted to a monthly tonnage and detailed dollar budget for periods of up to sixteen months in the future. The only certainty in this plan is that actual events will differ; timing, mix of mining methods and production volumes will differ on a monthly basis.Unfortunately, the fixed budget has no capability to reflect these operational changes. It is frozen for the full year. The result is that actual results will inevitably be compared to an outdated target."

Jan 1, 1982

By Z. M. Zavodni, C. D. Broadbent

"Major rock slides in open-pit mines are rare, but they can develop in spite of sophisticated slope engineering design practice. Experience has shown that, except under high seismic load conditions, the serious slope instability condition is almost always accompanied by the gradual development of one or more tension cracks behind the slope crest, allowing for time-displacement monitoring. Continuous surface displacement measurements with attendant prompt analyses are usually adequate for the prediction of slope behaviour.This paper describes efforts that have been made to quantify parameters associated with slide movement, and compares the displacement records of several large-scale open-pit porphyry copper mine slope failures. Two principal failure stages are recognized in the typical slope failure leading to total collapse: (a) REGRESSIVE STAGE, during which the failure will re-stabilize if some disturbance external to the rock and structure is removed; and (b) PROGRESSIVE STAGE. during which the failure will gradually displace at an accelerating rate to the point of total collapse unless active control measures are taken. Over-all displacement records in both failure stages are apparently of simple exponential form. with a definite break occurring at the onset-of-failure point.Certain common empirical relationships are suggested for the large-scale slope failures analyzed in this study. Based on plots of displacement rate vs time prior to collapse, a semi quantitative empirical relationship is presented for failure collapse prediction. The comparison of historical slide displacement records furnishes the operating engineer with practical guidelines to estimate the characteristics of future large-scale slope failures."

Jan 1, 1980

By John Porritt, Alain Dorval

"TioMin Resources Inc. is evaluating the feasibility of exploiting the heavy mineral sands deposit at Natashquan on the north shore of the Gulf of St-Lawrence, Quebec. TioMin holds the exploration rights to 180 square kilometres, on which 1.6 billion tonnes of sands grading approximately 6% heavy minerals were outlined. The heavy minerals of value include magnetite, ilmenite/hematite, garnet, and zircon. An important part of this evaluation is the development and testing of a mineral separation flowsheet. Under a comprehensive mandate from TioMin, the Centre de recherches minerales (CRM) provided technical assistance to build and operate an on site primary concentrator pilot plant. This plant produced a 93 tonne concentrate, providing over 60 % heavy minerals. This concentrate was shipped to the CRM pilot plant in Quebec City. It was used for further flowsheet testing and for preparation of products and concentrates of heavy minerals with regard to marketing possibilities. This paper presents the flowsheet developed to produce these concentrates.IntroductionIn late 1992, an 11 tonne bulk sample of sand was collected from within the mineralized zone of the Natashquan deposit. This sample was processed over conventional spirals and wet tables at the pilot plant facilities of the Centre de recherches minerales (CRM) in Quebec City. A primary concentrate was produced, from which several 20 kg samples were forwarded to five research laboratories in North America and in Australia. Their tasks were to determine the mineralogical composition of this concentrate and the potential for recovery of marketable minerals from the heavy mineral sands. Satisfactory results obtained from this approach encouraged TioMin to proceed with a more detailed pilot plant program."

Jan 1, 1995

By E. Ghali, B. Arsenault

Aluminum alloys play an important role in the manufacturing of air and ground vehicles. However, with such alloys, corrosion damage is often found on structural components subjected to fatigue loading. The alloying provides large benefit in terms of the high specific tensile strength (ultimate strength/density ratio) to the aluminum alloy but causes the aluminum alloy to be more sensitive to localized corrosion due to complex microscopic heterogeneities such as secondary phases. This paper investigates thermal spray coating namely arc spraying to evaluate the protection against environmentally assisted cracking (EAC) and localized corrosion on Aircraft structural 7075 T651 aluminum alloys. In particular, EAC and pitting corrosion at the interface coating-substrate are a challenge for thermal spray protective coatings on aluminum alloys under cyclic load and immersion. To address these issues, different surface preparation techniques prior to arc spraying were considered such as chemical de-oxidation, laser ablation, shot peening and grit blasting. Results indicate that surface preparation and improved coating process parameters play an important role to provide a coating conferring a protection against both localized corrosion and EAC.

Jan 1, 2006

By D. G. Cerigo, D. M. Bryce, P. H. Jennings

This paper summarizes the results of an experimental and economic study undertaken to evaluate the feasibility of treating an oxidized orebody of about 10 million tons, grading about 0.75 per cent copper, by agitation leaching and by percolation leaching.

Jan 1, 1968

By John E. Udd, Peter Leinberger, Roman Kozarycz

"This paper is based on work done by the authors in a study of the structural features at a quarry excavated in Chazy limestone on the Island of Montreal. Observations on failures on the quarry walls and benches were recorded, and back analyses of small-scale failures were carried out, thus enabling an assessment to be made of the in-situ strength properties of the rock. Using this information, and data from shear tests in the laboratory, the authors made an analysis of the stability of the south wall of the quarry.IntroductionQuarrying, and excavating for foundations, in the Montreal area involves the removal of million s of tonnes of rock on an annual basis. Even when compared with the quantities mined at major open-pit mining operations, the production figures are impressive. At present, for example, crushed stone is produced at almost 20 quarrying operations either on, or near, the Island of Montreal. The annual capacities of the larger quarries are in excess of one million tonnes each. Lesser, but still substantial, production is achieved at the smaller quarries.Excavations, for foundations , especially during periods of peak construction activity, must also involve large quantities of rock . The writers, however , are not able to produce an estimate of the actual annual tonnages originating from excavations."

Jan 1, 1981

By Göckmann. Klau

"IntroductionCopper has been recycled ever since its discovery. Even in Graeco-Roman times recycling of this resistant, and thus valuable material was carried out as a matter of course. Just take, as an early example, the Colossus of Rhodes: after the figure collapsed during an earthquake, the bronze parts were melted down into ingots and sold.Copper is a material which can be recycled again and again because copper produced from recycling is not different from copper originating from primary materials. This is mainly due to electrolytical copper refining whereby not only the base metals but also the precious metals can be removed. In contrast, with aluminum and iron only the more electropositive elements can be removed by refining, and the resultant scrap must, therefore, be sorted mechanically into various alloys for subsequent smelting.The recycling rate for different base metals is given in Table 1. Despite this ideal prerequisite, the generally quoted recycling rate of copper of about 40070 appears rather low. However, it must not be forgotten that the recycling rate is defined as the ratio of the annually utilized quantities of copper scrap and the annual production figures (Table 2). Moreover due to the economic growth over the last 30 years the availability of copper from scrap materials is lower than its consumption because copper is principally employed in very long-life consumer durables and only returns to the recycling circuit after many years. The average time for the copper of some goods to be recycled is detailed in Figure 1."

Jan 1, 1992

By D. Seo, P. Au, S. Yandt, N. Tsuno, A. Sato

Nickel-base single-crystal superalloys are used for gas turbine airfoil applications due to their excellent high temperature properties. A good understanding of the mechanical response of these alloys under different temperature and loading conditions is essential for modeling their behavior. In this study, the low cycle fatigue behavior of CMSX 2 oriented with the loading axis along [001] was investigated under zero-compression strain-controlled loading at 1100°C. The experiments were performed with or without a two-minute dwell (hold) in compression. The microstructure before and after testing was analyzed to understand the deformation characteristics including the effect of dwell.

Jan 1, 2010

By G. Simard, D. Boudeville, A. Leclerc, A. Boivin

"The objective of this work is to study the various parameters that affect the overflow clarity of gravity settlers used in the precipitation circuit of alumina hydrate from the Bayer process. A mathematical model incorporating the size distribution of the feed suspension (Multi Size Group model), its diphasic nature (Schiller Naumann model) and the presence of turbulence (Shear Stress Transport model) has been solved numerically using ANSYS-CFX software. Preliminary results indicate that the overflow clarity is mainly controlled by lateral diffusion of fine particles (~20µm) from the exit of the feed well and by their upward transport from the sediment bed interface. Also the turbulence pattern in the settling zone seems to play a significant role in this vertical transportation. The validity of the model has been verified by comparing the measured solid concentrations from a pilot classifier with the calculated ones. This model could provide mineral processing plant operators and designers with a tool to optimize the configuration of classifiers with respect to the overflow clarity.INTRODUCTIONProblemIn the Bayer process, alumina hydrate precipitation from the saturated liquor is initiated in settler by adding crystallization seeds. Most of the precipitated alumina settles to the bottom of the tank while the liquor and the remaining alumina rise to the top, where they are removed at the overflow. Ideally the overflow clarity, which depends on the operational mode of the classifier, should be controlled within targeted limits."

Jan 1, 2016

By V. Maazallahi, A. Rouleau, A. Saeidi

"The geometry of the terrain topography before and after the failure are the essential factors for analyzing a landslide and for the design of remedial works. This paper presents a method to determine these factors, considering that the determination of the slide surface profile is difficult and costly using traditional methods and the pre-slide topography data is often not available. The presented method to locate the 3-dimensional geometry of the slide surface is based upon determining the slide surface in 2- dimensional vertical sections. This method utilizes post-slide topography of the area to determine the pre-slide topography and uses equations to estimate the pre-slide situation using a statistical process applied to points located on the sliding mass. This method is tested on the Maskun landslide in Iran. The results indicate the applicability of the proposed method to obtain the key factors for the back analysis of a landslide in a cost effective manner.INTRODUCTIONProbably the most reliable method of determining the strength of soil and rock mass is to back analyze a failed or failing slope (Caia et al. 2007; Wyllie & Mah, 2004). This method is used in geotechnics for estimating geotechnical parameters of the rock and soil mass (Sakurai et al., 2003; Frayssines and Hantz, 2009; Cepuritis et al. 2010), but it requires that the failure mode is well established and that there is complete and precise information available on the slide surface and the sliding mass (Sjöberg, 1996). Measurement of the slope profile before failure provides the basic information required for a back analysis (Hock & Bray, 1981). The post-slide topography is another key factor. The back analysis process for determining the actual strength parameters of soil or a decomposed rock mass after a landslide requires knowledge of the sliding mass geometry, both before and after the sliding event. Many studies are reported in the literature about the application of back analysis for determining geotechnical and geomechanical parameters of rock and soil mass (Sakurai et al., 2003; Cepuritis et al. 2010; Frayssines and Hantz, 2009, Hussain and Stark, 2011), but they generally present little information about the geometry of the slide surface, and the weight of rock and soil mass that slid, although these factors are the most important parameters for back analysis process. Liang and Xue-song (2012) determined the slip surface having the minimum factor of safety (called critical slip surface in deterministic analysis of slopes) and the slip surface with the minimum reliability index (called critical reliability slip surface), but they have not considered the actual profile and geometry of the slide surface. Rocscience (2013) proposes the back analysis option in the Slide software for slope stability study, but it requires an imposed slide surface as input; alternatively, one can estimate by a finite element analysis the surface with the minimum factor of safety. However, this estimated surface is very likely different from the actual sliding surface, considering the uncertainties in input data of the finite element method."

Jan 1, 2015

By James J. Roettger, Robert J. Mitchell

"The results of a series of model stope pours designed to investigate working pressures on bulkheads during hydraulic pouring of classified tailings backfill are reported. Total bulkhead pressures and fill water pressures were monitored under the condition of a fully saturated backfill. Similitude of the model testing is discussed and equations are developed to estimate bulkhead pressures under prototype conditions. The model results show that good base drainage, combined with a bulkhead setback, can reduce the expected bulkhead pressures to values such that timber or concrete block structures should be capable of supporting a saturated backfill. Introduction Bulkheads are used in underground running operations to block drift openings in order that hydraulically placed sand backfill can be contained in stope pours. Whenever possible, the sand fill is designed to have sufficient percolation rate so that excess hydraulic transport water will gravity drain out through the bulk headed drifts. This avoids costly decanting systems. Early bulkhead design assumed that the bulkhead pressure could be as high as 0h = Hy where H is the fill height and ""y is the saturated unit weight of the fill (Thomas et al., 1979)(1). A typical design pressure for a 50 m fill height would be 1250 kPa giving a design force of 12,500 kN on a bulkhead located in a drift of 10m2 in area . Typical bulkheads were 1 m thick heavily reinforced concrete structures formed and poured into a notched drift. Not only were these expensive structures but the associated problems of inside drainage systems and curing time delays increased production costs. As experience with bulkheads for large bulk pours increased and fill pressure measurements became available [see, for examples, Libby et al., 1975(2), Askey et al., 1978(3)] , 'free drainage' timber and concrete block bulkheads were designed. Substantial savings have been realized using these types of bulkheads but greater engineering design and monitoring of backfill pours is necessary to ensure that backfill pressures do not exceed the bulkhead design pressures.The effective and total stress components of fill pressure, the engineering concepts associated with the 'free drainage' design and some detailed design considerations have been discussed by Smith and Mitchell (1982)(4) . It is important to the safe use of these designs, however, that the basic engineering concepts be demonstrated and communicated to those responsible for the day-to-day backfill operations. This paper describes and explains observations from a series of model studies designed to measure bulkhead pressures in a saturated fill."

Jan 1, 1984

By T. Yalcin, S. Brunet

The flocculant-assisted hydrocyclone involves the addition of a flocculant to the cyclone feed for the purpose of obtaining a clear cyclone overflow, and thereby eliminating or reducing thickener requirements in tailings disposal operations. This paper describes the testing of this concept on the iron ore tailings of Quebec Cartier Mining Company's Mount Wright Concentrator. The current practice at Mount Wright makes use of conventional hydrocyclones and thickeners for the disposal of their tailings, which are generated in a spiral gravity separation circuit. The test work was conducted primarily on their cyclone overflow product which becomes the feed to the thickeners. A detailed study was carried out to determine the sedimentation properties of these tailings in terms of their response to a variety of flocculating reagents, and to varying conditions of pH, pulp density and flocculant dosage. The tailings were then processed in a laboratory hydrocyclone with the aid of flocculants. The use of a shear resistant flocculant, in particular, was found to yield cyclone overflows with low solids contents. Based on the test results obtained, a conceptual flow sheet has been proposed for the treatment of the iron ore tailings at the Mount Wright Concentrator.

Jan 1, 2004

By N. Dave

"IntroductionIn the mineral processing industry, certain minerals such as uranium, thorium and vanadium, etc., are selectively extracted with high degree of purity from solutions containing variety of other impurities by solvent extraction process. This separation process consists of bringing two immiscible or partially soluble liquid phases in contact, where mass transfer of one or more components takes place by ion exchange under certain controlling parameters such as pH, salt concentration and temperature. The processes taking place are primarily physical because the solutes being transferred are ordinarily recovered without chemical change. For efficient extraction more than one stage is required and the solutions are recycled counter currently through other stages. A multi-stage counter current solvent extraction plants essentially consist of four circuits namely: extraction, water wash, stripping, and solvent scrubbing. In extraction circuit the desired mineral is extracted at a certain pH from an aqueous solution onto an organic solvent by bringing them in contact with mixing in large mixer-settler units. The mixed solutions are allowed to settle and separate into component organic and aqueous phases in horizontal settlers by providing sufficient residence time. The solutions are then moved counter currently to other units- the aqueous from the underflow and the solvent organics from the overflow of the settler. The solution streams coming out of extraction circuit are loaded organics and barren aqueous or raffinate solution. The loaded organics are washed with water in a water wash circuit to remove transported impurities from extraction circuit. In the stripping circuit, the desired mineral is stripped selectively from the solvent phase back into an aqueous phase with a stripping agent at a selected pH. The solution stream leaving, stripping circuit are stripped organics and pregnant strip (aqueous) solution. The stripped organics are scrubbed off other loaded impurities with a conditioning solution in, scrubbing circuit and the cleaned solvent is re-used in the extraction circuit.A typical solvent extraction plant for uranium extraction and purification at Agnew Lake Mine is described in this chapter."

Jan 1, 1989

By Erwin L. Zodrow

"For 25 chemical elements in electrostatically precipitated fly ash (Lingan coal-fired power station), concentration changes are studied as a function of increasing proportions of fines (ash particle diameter less than 45 micrometres). Elements that are involved when concentrations increase as the proportions of fines increase are likely to escape into the atmosphere. These are Th, U, As, S, P, Sb, Na, Ag, Zn, Pb, Ni, Ba, Sc, AI, Mo (and Bi, Ge, Ga, F and Li), i.e., more or less highly volatilized elements. Of the less volatilized metals such as Fe, Ca, Cu, Ti, K, Co, Mn (and lanthanides), certain portions presumably also escape as stack emissions. Diadochy and spinel formation in bottom slag is presented as an emission-reducing agent for certain metals.IntroductionThe Lingan coal-fired power generation plant, owned and operated by the Nova Scotia Power Corporation, produces annually about 140,000 metric tons of ash (the residual mineral content after burning coal). The tonnage is based on a 15 per cent average ash content of Cape Breton coal.For purposes of this report, samples of the hard, fused slag (bottom slag) that is accumulated at bottoms of boilers, and electrostatically precipitated fly ash (ep ash), were collected and investigated. Bottom slag is a minor component of the produced ashes.The ashes were surveyed and the presence of over 75 major, minor and trace elements is reported. From this survey, 25 elements were selected to establish elemental enrichment/depletion trends when the proportions of the less than 45 micrometre <45µm) fractions in ep ashes increase. The results are significant in that, taking the case of elemental enrichment, the elements involved are likely to escape into the atmosphere, i.e, highly volatilized elements. Depletion trends for elements are presumably associated with less volatilized elements during coal-firing. Quantification of the emission of atmospheric pollutants is not considered part of this work. ""Igneous"" minerals generated during coal combustion include spinels (found mainly in the bottom slag), quartz, glass and mullite."

Jan 1, 1982