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The teaching of geophysics in Canada at the present time presents a variety of approaches to the subject, and the different paths adopted imply, in turn, an uncertainty in the minds of some educators as to the role this science is to play in the future progress of geology, and a hesitancy to commit themselves to foster its development. The pedagogical attitudes vary from a whole-hearted acknowledgment that the science of geophysics is fundamental to the understanding of terrestrial phenomena (including, of course, geological processes) to a hesitant immersion of the toe to test the water's temperature (which is, of course, essentially a geophysical experiment) before deciding whether or not the time is ripe for total immersion. The present discussion has been organized in the hope that it will help to clarify the roads to geophysics and assist educators in making a more understanding choice of the best paths for them to follow, according to their particular requirements and objectives. Before proceeding further, however, it is necessary to define the term geophysics and circumscribe the field it covers. In the first place, it should be emphasized that geophysics is NOT confined to the art of geophysical prospecting. The popularization of geophysics has unfortunately engendered a general misconception of the word, and consequently a tendency to ignore the wider meaning of the term. Etymologically, geophysics means the physics of the earth. It is so understood by the International Union of Geodesy and Geophysics and the various geophysical societies which adhere thereto. To them, geophysical prospecting is but a very small field indeed, which they consider had best be left to engineering and prospecting organizations.

Jan 1, 1951

By Raymond B. Hryciuk

Environmental auditing has evolved rapidly over the last decade — first in North America, then Europe, and most recently in Asia — into a widely practiced discipline designed to provide senior management with assurance that operations are being managed in compliance with established governmental standards, internal company policies, and good industry practices. This paper first examines the evolution of environmental auditing, focusing in particular on three interlocking driving forces: company initiatives, collaborative industry initiatives, and government initiatives. Characteristics of effective audit programs, those that have emerged among the leaders, are discussed, including: objectives, scope, coverage, approach, staffing, and organizational considerations. The author then addresses important future trends and developments for environmental audit program design, content, and coverage.

Jan 1, 1996

By E. Poiate, P. A. L. P. Firme, D. Roehl, M. A. Carrion, A. M. Costa

Drilling high-pressure/high-temperature wells in salt rock formations is still a challenge for the energy industry. Creep and solubility is part of the salt rock physical-chemical behaviour, which must be considered in the design of the wells. The stress redistribution caused by drilling, in addition to thermallyactivated processes, triggers creep deformation, leading to borehole closure and the imposition of loads on the casing. The drilling fluid is designed by computer modeling in order to control the creep strain rate to a limit which allows the drilling operations and the casing setting. Depending upon the composition of the drilling fluid, chemical reactions on the salt wall may occur, especially in case of water-based fluids in highly soluble salt rocks. In those cases, cavities by dissolution (washouts) can be generated and the casing column remains uncovered by the cementation and laterally unconfined along the cavity length. This scenario is propitious to the loss of integrity of the casing due to phenomena such as plastic collapse, buckling and non-uniform loading on the casing provoked by the closure of salt formation around it. The casing should remain intact during the wellbore life-time. In this work, a section of a typical well crossing salt formation composed by halite and carnallite is considered. An idealized-cylindrical washout cavity inside a highly soluble salt layer is assumed. The purpose here is to evaluate the effect of the dimensions of the cavity on the integrity of the casing. Several typical diameters and lengths of the cavity are adopted. Numerical analyses are carried out with an in-house finite-element system composed by the pre-processor MTOOL 3D®, the simulator ANVEC 3D® and the post-processor POS 3D®. Salt rocks are modeled as visco-elastic materials. Creep is simulated by the Double Mechanism Creep Law, widely employed in Brazilian salt rock mechanics research. Cement and casing (steel) are modeled as elasto-plastic materials described by the Mohr-Coulomb and the von Mises criteria, respectively. Casing integrity is evaluated with respect to vertical and horizontal displacements. Vertical displacements imposed to the casing can provoke the failure of the column by plastic collapse or by buckling. Besides that, horizontal displacements of salt due to creep closure shall lead to the undesirable contact with the casing. Failure envelopes based on displacements are generated. The results of the simulations have shown that the casing failure by plastic collapse occurs preferentially in short columns, as well as buckling occurs in long and slender columns. The occurrence of both failure modes is more frequent in large-diameter cavities. Additionally, failure caused by contact between salt and casing occurs preferentially in short-diameter cavities.

Jan 1, 2015

By S. Perkins, E. Young, L. Dufour, K. McVey, L. Rolandi

This paper presents a review of plant layout considerations incorporated into recent designs of SAG/Ball mill circuits for two medium sized concentrators. The plant layouts presented and the design concepts discussed, relate to smaller SAG circuits, but can equally apply to larger milling circuits. Included are design concepts and ideas introduced by the various project teams, and the focus is on the primary factors of any layout design which are safety, constructability, operability, and capital cost.

Jan 1, 2012

By Joseph W. Mills

"The Mic Mac property comprises 994 acres held under mining concession and approximately 2,000 acres held under development licenses in Bousquet township, Abitibi county, western Quebec.Gold was first discovered in this locality by Tom Duval in June, 1936. In February, 1937, Cassels Duval Mines, Limited, was incorporated under Quebec charter to take over the property. In September, 1937, the property was examined by Agaura Explorations, Limited, and an option agreement was signed on October 6th, 1937. In June, 1938, an option for complete ownership was taken on adjoining claims belonging to Norgold Mines, Limited, and in September, 1938, a mining plant was installed and the sinking of a 3-compartment shaft begun. In June, 1939, an option was taken by Mic Mac Explorations, Limited, on seven claims of Mooshla Gold Mines Company, Limited, that adjoined the Norgold block to the east. In December, 1939, a new company, Mic Mac Mines, Limited, was formed, amalgamating the Cassels Duval, Norgold, and Mooshla claims, as well as two claim groups to the west of the mine known as the Vaughan and West Cassels groups."

Jan 1, 1954

By C. S. Parsons

Custom milling-plants have been operated successfully for a great many years on this continent. One of the outstanding examples in the United States is the Golden Cycle mill at Colorado Springs, which mills the gold-telluride ores from the Cripple Creek district. In eastern Canada, the Northern Custom Concentrators, Limited, at Cobalt, successfully treated the cobalt-silver ores of that area for a number of years. Flotation plants have entered the custom field in the past few years. The building of flotation concentrators to treat ores on a custom basis indicates the advance which has been made in flotation. In fact, three years ago it was considered almost impossible to treat successfully a mixture of miscellaneous ores by flotation. The methods used at that time were considered so delicate that any change, even in a single ore, would usually result in decreasing the effectiveness of the separation. Today we find four large custom flotation plants in the United States and one in Canada for treating complex lead-zinc ores from many different localities. The advent of these mills was brought about by the serious problem confronting the lead-smelting plants due to increasing amounts of zinc in the ores presented for treatment. It was necessary to penalize the mines shipping high-zinc ores. The penalty is justified, because high zinc in the lead blast-furnace charge not only decreases the tonnage of the furnace but increases the amount of flux necessary, as well as increasing the metal loss in the slag. It has been estimated that in the Salt Lake valley alone, 75,000,000 pounds of zinc was lost in the slag-dumps from the operations of three large lead blast-furnace plants. It has also been estimated that $150,000 worth of additional flux was required to slag this zinc. It was to avoid at least a part of this wste and to help maintain an ore supply that custom flotation concentrators were built by the smelters.

Jan 1, 1928

By C. H. Hopper, D. R. Derry, H. S. McGowan

"The property of Matachewan Consolidated Mines is in the Matachewan area on the west side of Montreal river. It lies in the western extension of the Kirkland Lake sedimentary belt. The first discovery of gold on the property was made by S. Otisse, in 1916. The property was taken over by Ventures, Limited, in 1933 and production commenced in late 1934. To date (December 31st, 1947) it has amounted to 2,308,800 tons, from which gold and silver to the value of $9,567,600 has been recovered. The mill is currently treating 650 tons of ore a day.GENERAL GEOLOGYThe deposits lie close to the south contact of a belt of sediments striking in a general east-west direction. The sediments, presumed to be of Timiskaming age, consist of light buff arkose and greywacke, containing small pebbles. The Keewatin volcanic rocks to the south are andesites or basalts with cuff and agglomerate bands developed especially near the contact with the sediments. The lavas and sediments are overlain by relatively flat-lying sediments of the Cobalt series to the south and west of the mine, but these later sediments are not involved in the mineralization under discussion. The Keewatin lavas and Timiskaming sediments are intruded by dykes and lenses of red syenite porphyry that have approximately the same strike and dip as the invaded rocks. Later diabase dykes, apparently post-ore, run in a north-south direction and cut all rocks except the Cobalt series.OREBODIESThe gold-bearing mineralization forms bodies of two different types: (1) Within the volcanic rocks irregular orebodies with limited vertical extent. These consist of a series of flat-dipping quartz stringers and adjacent lavas and /or cuffs fractured, bleached, and mineralized with pyrite and gold. They are higher grade than the second type (average about 0.16 oz. gold a ton) and formed the main source of ore for the first 5 years of production. They are described in more detail than can be given here in an article by C. H. Hopper (4). More recent work on deeper levels has failed so far to find orebodies of comparable grade, though low-grade mineralization of a similar type does occur on the projected rake of the main group of the 'basalt type' of orebodies."

Jan 1, 1954

By Matthew Blecha

The Tribag copper deposit is one of the rare examples of mineralized breccias in the Canadian Shield. The breccia is a pipe-like body, and consists of granitic, diabasic and volcanic fragments embedded in a vuggy, quartz-carbonate matrix. The mineralization is essentially chalcopyrite and pyrite, with minor molybdenite, sphalerite, galena and other sulphides. The main ore zone is saddle-like in shape, and is enveloped in a zone of chloritization, sericitization and clay-mineral alteration. It is suggested that the breccia is of the diatreme type. Introduction T HIS paper is based on eighteen months of field work, including surface and underground geological mapping and core logging, and on the survey of relevant literature. No significant amount of laboratory work has been done as yet. Location and Access The Tribag Batchawana property is located 40 miles north of Sault Ste. Marie, Ontario, about 10 miles east of Lake Superior. A 17-mile, all-weather road connects the property to the Trans-Canada highway to the south, and 4 miles of a 12-mile road remain to be completed to link it to the Algoma Central Railway to the northeast.

Jan 1, 1965

By S. S. Yuan, Q. Z. Zhu, J. F. Shao

"This paper aims at enriching a homogenization-based anisotropic damage model for hard rocks under complex loading. A new damage criterion is proposed to capture material strain softening. Within the framework of irreversible thermodynamics, we are particularly concerned with two strongly coupled dissipative mechanisms: frictional sliding and damage by microcracking, which usually take place at cracks within cohesive geomaterials under compression. Focusing on the representative elementary volume containing multiple crack families, the free enthalpy of the matrix-cracks system is obtained. Importantly, a back-stress term is involved in the local stress applied to microcracks. This back stress plays the hardening/softening role in the friction criterion which is formulated at local scale. Strain hardening owns to the accumulation of frictional shearing and dilatancy while strain softening is caused by crack growth. The multiscale damage model is used to simulate laboratory tests on the Westerly granite under true triaxial compressions. INTRODUCTIONWhen subjected to compressive loads, hard rocks present nonlinear mechanical behaviors and induced material anisotropies. In that process, two main dissipative mechanisms have been largely identified: damage by crack growth and frictional sliding along closed crack faces, which are usually strongly coupled to each other on crack scale. Theoretical investigations have shown that the damagefriction coupling analyses allow explaining a large number of experimental phenomena involved in brittle or quasi-brittle materials. Concerning constitutive modeling, the standard Eshelby’s solution-based homogenization procedure for heterogeneous materials was recently applied successfully to describing the mechanical and poromechanical behaviors of cracked frictional solids."

Jan 1, 2015

Safety Leadership The management and leadership of a mining operation is a challenge at all times. The pressure to make production, safety, and environmental goals is intense. At some point mining cycles will put every operator into periods of time where economic issues seem to over-ride all other concerns. This is when leadership is most needed.

May 1, 2009

By S. M. Bulatovic, D. M. Wyslouzil

"This paper presents the results of a study of the effect of flowsheet configurations on metallurgical results and describes a general method for developing and optimizing flowsheets used in the treatment of massive sulphide ores. The flowsheet configuration can have a significant effect on recovery and selectivity between valuable minerals and gangue minerals. Placing of intermediate products within the flowsheet, positioning of various pretreatment units, such as conditioners or regrinding mills, and the ability of the flowsheet to cope with wide swings in the feed grade and composition are the major parameters that determine the optimum flowsheet configuration. The complexity of the flowsheet is largely a function of the ore itself and of the number of final, marketable products that have to be recovered from the ore. INTRODUCTIONTechnological ExpansionThe trend of past decades has been towards larger equipment and a better understanding of the chemistry of the flotation process. Despite appreciable progress in these areas little attention was given to the study of the actual configuration of the flowsheet, although the arrangement of the flotation equipment significantly affects the overall performance of the circuit."

Jan 1, 1989

By W. K. Muwais, R. G. Cuddy

"The Lower Cretaceous McMurray Formation contains the bitumen reserves of the Syncrude Mine in northeastern Alberta. This formation comprises sediments deposited sequentially in fluvial, estuarine and marine depositional environments. The Syncrude Base Mine area consists mostly of estuarine sediments, as much of the original marine sediments have been eroded away. These estuarine deposits consist of channel-fill sediments and interchannel tidal flat sediments with the channel-fills comprising most of the orebody.Channel-fills contain, among other lithologies, interbedded sand, silt and clay rich layers that often occur as sequences of inclined beds with dips up to 25 degrees or more. A detailed knowledge of the distribution of these inclined beds, their lithological characteristics and their continuity is very important in assessing the risk of mine highwall instability . Techniques used to identify and characterize adverse structures are reviewed. INTRODUCTIONGeneralThe Syncrude Canada Ltd. oil sand mine is located within the surface mineable portion of the Athabasca Oil Sands area about 40 kilometres north of Fort McMurray in northeastern Alberta, Canada (Fig. I). The company commenced large-scale strip mining of oil sands in June 1977in the area, referred to as the Base Mine, situated in the southeast corner of the company's two lease areas (Fig. 2).The mining method (Fig. 3) utilizes large electric drag lines operating on a single bench with highwall depths up to 60 metres. Feed grade oil sand (= 6 wt.% bitumen) is mined by draglines and windrowed parallel to the highwall crest. Lower grade oil sand « 6 wt. 0J0 bitumen) occurring as waste bands is selectively mined by the draglines and cast back into the mined out pit or placed on the bench and hauled by truck. The windrowed feed is delivered to the extraction plant by a bucket wheel reclaimer and conveyor system. Stripping of Recent, Pleistocene and Cretaceous overburden units is done outside the conveyor systems by mobile equipment. The 4.5 kilometre long mine is split into four quadrants for planning and scheduling purposes, with each quadrant having an individual dragline-bucketwheel-conveyor system.Surface mining of oil sand at Syncrude requires the removal of vast quantites of material. The design of the open pit mine relies heavily on knowledge of the distribution of ore and waste materials, and on the physical characteristics of these materials.The geology of the oil sand below the dragline bench at the Syncrude Mine is complex. Geological, geotechnical and hydrogeological factors play an important role in the design and operation of the mine. This paper describes aspects of the geology that impact on the design and operation of the mine. Some of the methods and procedures adopted by Syncrude to successfully overcome difficulties that the complex geology creates are discussed."

Jan 1, 1989

By R. C. E. Bray, Peter Price

"The property of Pamour Porcupine Mines, Limited, is in the eastern Porcupine area, about 12 miles northeast of Timmins. It covers parts of lots 3-6 (inclusive), cons. 5 and 6, Whitney tp., Cochrane district, Ontario. It is an amalgamation of the old La Palme, Three Nations, and Porcupine Grande properties.The first discovery on the Pamour was made in 1911. During 1911 to 1914 a small shaft was sunk on the Three Nations vein to the 200-foot level and a 100-ton stamp mill was put in operation, but only a small production was achieved. The property remained idle from 1914 to 1923. In 1924 some diamond drilling was done along the Keewatin-Timiskaming contact with some encouraging results, but the gold mineralization encountered was too low in general at the price of gold then prevailing to warrant further · work. The increase in the price of gold revived interest in the area, and the above noted amalgamation was effected in 1934. Options were taken and successively dropped by two large mining companies. Following this, exploration both on the surface and underground was started by Quebec Gold Mining Corporation, Limited. Diamond drilling in the early part of 1933 showed considerable ore in conglomerate and greywacke to the east. In the middle of 1935 Noranda Mines, Limited, assumed control and management. A new shaft was sunk and the property was ·equipped with a mill having an initial capacity of750 tons a day. This was subsequently enlarged to 1,500 tons a day.From the commencement of milling (May 16, 1936) to the end of 1946, 5,025,545 tons of ore having an average grade of 0.1327 oz. a ton ($4.64 at $35 an oz.) have been mined and milled."

Jan 1, 1954

By E. Asselin, P. Sauve, H. Salomon-de-Friedberg

"Residues from the CESL Copper process were leached using the CESL Gold process. The kinetics of reaction were confirmed to be fast with over 50% of the gold consistently extracted within 2 minutes of leaching. Final gold extractions under the conditions tested here were between 80-90% obtained within 90 minutes. A model for the CESL Gold process was developed. This model is slightly different based on whether the copper concentrate leach residue was ground or unground prior to leaching: the gold leaching rate constant is approximately twice as fast for the ground samples. Unground residues had a P80 of 13 ?m whereas ground residues had a P80 of 10 ?m. The model predicts a 43% decrease in leaching time for ground residue versus unground residue to achieve the same extraction under otherwise identical conditions. The model was more accurate for the ground samples. INTRODUCTIONTeck's CESL Process (Jones, 1996) was developed to provide an economically attractive alternative to traditional copper smelting. It has since evolved to also deal with copper concentrates containing valuable impurities such as nickel and undesirable ones, such as arsenic, while reducing downstream costs. Effective recovery of gold and silver is essential to the economics of the CESL Process. The Brook Hunt 2007 copper concentrate assay data (Wood-Mackenzie, 2007) were examined to determine the ratio of gold plus silver value relative to the contained copper. As indicated in Figure 1 below, nearly two-thirds of concentrates have 10% or more of their total value tied up in their precious metals content.CESL has extensively examined the recovery of gold and silver at bench, pilot and demonstration scale, which has culminated in the present CESL Gold Process (Barr et al., 2007). The process targets the precious metal contained in the leach residues produced in the copper portion of the flowsheet. This residue has two primary components which influence downstream processing. The major iron-rich fraction (-75 wt%) of the residue is a mixture of various forms of iron oxide precipitates including hematite and jarosite (Sahu and Asselin, 2011). The iron fraction ranges from amorphous to crystalline in nature depending on the compound precipitated, upstream operating conditions and feed material composition. The lesser, but by no means less important, fraction is a mixture of elemental sulphur and unreacted sulphides (principally pyrite).Elemental sulphur formed during the oxidative leach of the copper concentrate reacts with cyanide to form thiocyanate (SCN-) making a traditional cyanide leach approach too costly. Since the SCN formation reaction strongly depends on contact time with the CESL residues (Po, 2007) short contact times were preferred. This factor guided the development work towards the eventual room temperature, pressure cyanidation process which results in near complete gold dissolution in 90 minutes. A recent CESL gold demonstration campaign treating 1.5 t/d of residue from the copper oxidation step achieved an average gold extraction of 91% (96% maximum)."

Jan 1, 2012

By N. Saracoglu, J. P. Golightly, R. H. Wallis, J. J. Brummer

"In January 1974, the Minerals Division of Canadian Occidental Petroleum Ltd. made the strategic decision to add uranium to its active exploration commodities and through compilation studies selected northern Saskatchewan as the most attractive and cost-effective exploration area in Canada. In August 1974, 100 sq. miles were staked adjacent to Gulf Minerals' Rabbit Lake deposit and east of the Esso Minerals Midwest boulder train. Initial exploration was based on geologic models of the Rabbit Lake deposit.In the summer of 1975, surface surveys delineated radon anomalies which were drilled that winter and found to overlie anomalous concentrations of uranium in the regolith which forms the upper unit of the crystalline basement. Within the crystalline basement, one hole intersected graphite and pyrite with anomalous nickel-cobalt-arsenic. Geochemical and radiometric surveys followed in the summer of 1976. Drilling in the winter of 1977 intersected several zones of graphite and also anomalous, but uneconomic, uranium abundances. Also in 1977, Dahlkamp and Tan (1977) described the coincidence of graphite and uranium at Key Lake and ground EM surveys on CanadianOxy claims detected graphite conductors beneath 250 ft of Athabasca sandstone. Inco Limited joined the project in April 1977 as a 50% partner. The project area was then surveyed using the airborne INPUT EM method, which detected 84 miles of conductors, with associated graphitic metasediments. On the ground these were located with MaxMin surveys, and follow-up drilling located the ""Tent"" Lake uranium zone.In 1978, the Midwest and Dawn Lake discoveries were announced, 7 miles and 2 miles west of the Joint Venture (J.V.) claims; and, in part for this reason, the 1979 winter drilling was concentrated on the deeper west side of the property. Exploration hole 102-79 intersected altered and uraniferous rocks, but stepout holes were barren. Drill hole 153-79 tested an under-snow three-station radon anomaly east of hole 102-79 and intersected 33 feet of 7.51 % U3O8, confirming the disco very of the McClean North zone. The geophysical grid of the McClean North conductor system was extended and detailed a strong, continous conductor to the south, called McClean South. This was drilled in January 1980and hole 1004-80intersected 22 feet of 2.95% U3O8."

Jan 1, 1983

By Lawrence Devon Smith

What is a Failed Project? For mining projects, some key indicators of a ?failed? project are: ? Cost is more than it should be (particularly capital) ? Schedule ? It takes longer to build than expected ? It takes longer to ramp-up than expected ? It does not do what it is supposed to do ? Poor performance; output, product specifications; ? Low revenue ? High costs ? No one is happy about it: Management, Shareholders, Bankers ? Does a project fail if it does not meet expectations that were unrealistic and unattainable? ? Caution: Failure may not become evident until years later

May 1, 2010

By J. R. Maxwell

In 1970 expansion was completed increasing mill capacity from 2,000 to 3,000 T.P.D. Actual grinding capacity is 3,400 T,P,D. at a grind of 60% -200 mesh,The ore bodies are vein type, containing about 12% sulphides, with mill heads averaging 2.25% Cu, 0.015 oz.Au, and O.4O oz, Ag. per ton.Summary and Conclusions:During the period Jnnuar-1 1971 to December 1973 inclusive the use of large cells at Opeminka have shown that metallurgy is comparable to when using conventional cells, Operating and maintenance costs are lower, An on stream analyzer with reagents controlled by computer, are being assessed further.Opej1atljn Of Cells:!lo cell level adjustments are required when tonnage is adjusted 20 to 25%.Depending on mill heads and grade of concentrate reagents are adjusted to the first rougher for metallurgical control. Reagents to second rougher and scavengers are seldom adjusted as feed to this section has a maximum variation of about 0.2'~ Cu.Power – Maintenance and Space Requirement :Our total power consumption for 3,400 T.P,D. flotation circuit for operation and air supply is 280 H.P. Previous power drawn using conventional cells was 400 H.P. at 2,000 T.P.D.Total maintenance costs for flotation circuit has averaged $1,100.00 per year for the 3 years of operation, this cost should remain constant.Floor space required for cells and walkways is 2,000 sq.ft.

Jan 1, 1974

By Matthew Scott

Introduction The refining of precipitate is the final stage of all the processes involved in gold mining and cyanide milling, by which the precious metal is at last obtained in a concentrated form, which can be accurately valued and marketed. Possibly one ought to say, conveniently shipped, for accuracy in valuation depends in many instances on a toughening treatment given the bars as received at the Mint so as to obtain a homogeneous metal that lends itself to representative sampling; which, of course, entails a surcharge on the regular Mint charges for the extra work necessarily undertaken. There are several methods of refining zinc-gold precipitate, each with its advocates; the method employed depending not always on the quality of the bullion produced but on the local exigencies of the case in point. These methods are more or less detailed in various textbooks and it is not the purpose of this paper to discuss them, but to confine ourselves to the specific case as stated in the title of the paper. At the outset, it behooves the writer to express his thanks to Mr. Brigham, the General Manager of the Hollinger Mines, for the kindly consideration and encouragement given in developing this process. This will be better understood when one considers the immense values involved, tending towards conservatism in practice, and making one chary of radical innovations. This process has been in satisfactory operation now for about two and-a half years, during which time over twenty-five million dollars value in fine gold has been produced, so that it may be reasonably held that the process is successful.

Jan 1, 1931

By G. A. Gross

DURING the past 5 years a large amount of money and effort has been expended in exploration of iron-formations and in testing their suitability for beneficiation. Beds of ferruginous material are numerous and widely distributed in the Precambrian rocks of Canada and practically all of the known iron ranges or belts have been examined to a limited degree at least in an effort to evaluate their potential as sources of iron ore. A number of favorable beds have been selected for mining on completion of surface sampling, diamond drilling, extensive metallurgical testing and economic studies, and many other ranges are being studied. There are still a great many iron-formations that have not been evaluated by modern concentration methods and their regional extent is not fully known. The iron-formations are easily located by airborne or ground magnetic surveys but the main task in finding a mineable ore-body of this type amounts to locating a bed sufficiently large for mining which consists of material that can be concentrated economically by modern beneficiating methods. The ease with which an iron-formation can be concentrated to give a marketable ore depends primarily

Jan 1, 1961

By V. Caps

Gold has been often used as an alloying component in order to increase or modify the catalytic properties of an active metal. For example, in the hydroconversion of methylcyclopentane, Riahi et al [1] shown that the addition of gold to palladium or platinum enhances the activity which becomes greater than that of the pure metals whereas the selectivity towards products resulting from ring expansion increases. Molenbroek et al [2] presented a detailed study on Ni-Au catalysts which exhibit activity for steam reforming and have been proved to be more resistant toward carbon formation than the pure Ni catalysts. Blocking of highly reactive Ni edge and kink sites by Au atoms is assumed to be the reason for the increased robustness of the Ni-Au catalyst. Nevertheless, the own catalytic properties of pure gold have been almost ignored up to the pioneering work of Haruta et al [3] which demonstrates the high activity of gold for CO oxidation at low temperatures. Other reactions such as WGS reaction, propylene epoxidation or benzene total oxidation have then been shown to be catalyzed by gold [4]. This discovery induced the publication of papers devoted to analyze the different factors controlling the activity of gold catalysts. Among them the most relevant appears to be the gold particle size, the nature of the support [5] and the preparation methods [6]. Clearly distinguish between support and size effect is not straightforward. Indeed, the calcination step often needed to synthesize supported catalysts on different supports, leads to different particle sizes showing that particle size and support are interdependent. To circumvent this difficulty, Au-based supported catalysts have been synthesized by using laser vaporization and low energy cluster beam deposition. The as prepared catalysts have then been characterized and tested in CO oxidation reaction.

Oct 1, 2003