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By F. Rashchi, A. Ghahreman, J. Moghaddam, S. Karimi

"In this work, the kinetics of ferric-ferrous redox reaction on a passivated sphalerite electrode is studied by the application of chronoamperometry method in 0.5 mol L-1 H2SO4 solution. The electrochemical behaviour of ferric and ferrous couple was investigated on two sphalerite minerals acquired from two different geological regions (Iran and Canada). The carbon paste electrode (CPE) of sphalerite was initially prepared and passivated in 0.5 mol L-1 H2SO4 solution and after reaching the steady-state condition, ferric and ferrous sulfate solution was added. The registered current density differences between the current density of the passivated electrode and that of the electrode in the iron salts added solution were interpreted for kinetics of ferric-ferrous reduction-oxidation reaction. The equilibrium potential for ferric-ferrous couple on sphalerites surface was about 500 mV vs. Ag/AgCl. The exchange current density (i0) for ferric-ferrous redox reactions on the sphalerite samples had the same magnitude of 10–6 A cm–2. The electrochemical impedance spectroscopy (EIS) measurements at 550 mV vs. Ag/AgCl illustrated that sphalerite oxidation was controlled by two charge transfer process in both of Fe-free and Fe-containing solutions. The charge transfer resistance remarkably decreased when Fe salts added to the 0.5 mol L-1 H2SO4 solution, owing to the ferric-ferrous redox reactions being the predominant reactions on sphalerite surface.INTRODUCTION Direct atmospheric leaching processes for sphalerite concentrates are performed by reduction of an oxidant (e.g. ferric ion and oxygen) and oxidation of sphalerite to zinc ions. Oxygen could be an oxidizing agent as well, but the concentration of oxygen is very low in the solution. The role of ferric ions is predominate in this oxidation (Babu, Sahu, & Pandey, 2002). The oxidation reaction for sphalerite in the presence of ferric in can be presented as follows (Lampinen, Laari, & Turunen, 2015):"

Jan 1, 2017

By W. G. Dallas

The social and environmental problems presented by the location of a large zinc/ lead ore body within one mile of a thriving town are described. The development problems are social, involving the education of the in habitants , and environmental, requiring the development of a planning strategy and the evolution of a baseline and post -operational monitoring system. The necessity for an environmental-impact assessment and a thorough baseline study is emphasized. The continuing psycho-social consideration of community reaction is advocated.

Jan 1, 1977

By E. R. Lea

The B. M. & S. orebodies, consisting of the No. 6 (Brunswick) and the No. 12 (Anacn Leadridgz, have the distinction of being the first major 1base metal ore deposits to be found in the Province of New Brunswick. They are massive sulphide de-posits consisting of pyrite (pre-dominantly) and base metal sulphides, and they carry values in lead, zinc, copper, and silver. These orebodies are localized within favourable drag fold structures believed to be related in their origin to external forces set up in the area subsequent to the primary regional folding. Both orebodies are characterized by the presence of magnetite 'iron formation' which, in certain 'Portions of each orebody, may be found as relics within the massive sulphides. Studies show the magnetite to be the first metallic mineral within the ore ?zones, followed by pyrite, Sphalerite, galena, and finally chakopyrite. The shape of these massive pyritk orebod:es as well as the distribution of values within them is controlled to a large degree by the ore-ore drag fold structures. A possible relationship is discussed between the basic intrusives in the area ?and the magnetite deposits. It is suggested that a large portion of ?the iron content of the massive suplhedes has been derived from the earlier magnetite. Intermittent movements in the area during the sulphide mineralization are believed to belong to the last stages of deformation in the area. These late movements may have been caused by the intrusion of the granite into the area. The granite may have a genetic relationship to the B. M. & S. orebodies.

Jan 1, 1958

By Norman A. Parlee

Introduction The principal primary iron and steel producing capacity of the Dominion Steel and Coal Corporation is at the Dominion Iron and Steel, Limited, plant at Sydney, Cape Breton Island, Nova Scotia. The main raw materials are Cape Breton coal, Wabana (Newfoundland) iron ore, and Port-au-Port (Newfoundland) limestone. This plant, which was established at the turn of the century has gradually expanded its production facilities so that today its ingot producing capacity is over 720,000 tons annually. Principal operating units of the plant at present are three batteries of 173 Koppers by-product coke ovens with conventional by-product recovery equipment, three blast furnaces .of 15 ft. 6 in., 18 ft. 3 in., and 19 ft. 3 in. hearth diameter (inside the brick), one 700-ton hot metal mixer, ten open hearth furnaces (two of 175-ton capacity, three 12 5-ton, five 60-ton), one 10-ton electric furnace, a 40-inch blooming mill, a billet mill, a rail mill, a tie plate mill, rod and bar mills, and a wire and nail mill. Extensive machine shops and an iron and brass foundry are also available for plant maintenance and repairs. This paper will describe developments during the past five years and those now in process. It will also briefly discuss research being done and indicate the direction of future development.

Jan 1, 1951

By T. D. Chatwin

Acid rock drainage (ARD) is one of the most serious and potentially enduring environmental problems of the mining industry. High liability costs carried by many mining companies to cover potential obligations of ARD are a clear indication of the gravity of the problem. Unchecked, ARD can result in water quality impacts that could well be the industry's most significant financial and credibility risk. Effectively preventing acid drainage is a formidable challenge that requires the total commitment of the mining industry throughout the entire life-cycle of a mine. To achieve this commitment a strong business case for ARD prevention must be developed. This paper will address the elements of acid prevention and discuss their importance not only to the company but the entire industry as well. The International Network for Acid Prevention (INAP) is an industry-led group created to help meet this challenge. In 2009, INAP published the GARD Guide (www.gardguide.com), a web-base best practices guide for the prevention of ARD [1]. In this paper, the GARD Guide will be used to identify preventative actions for all mining industry stakeholders. It will, in turn, be used to estimate ARD management and mitigation value accrued to the company from ARD prevention, which will be used in developing a business case for acid prevention.

Jan 1, 2011

By Serena Biella

Gold has received a growing interest as a catalyst for the selective oxidation of organic molecules using oxygen under mild conditions1. In the liquid phase application small gold particles (2.5-7 nm) deposited over different solid supports can be used but, like many other noble metals, their catalytic activity depends upon the nature of the support and the preparation metod2-5. In particular, gold on carbon is the preferred catalyst for the oxidation of the alcoholic 2-7 and the aldehydic7-9 groups and one of the best preparation method is the immobilisation of colloidal particles2-5,8,9. Suggested application of gold catalysis in fine chemicals production, tested on laboratory scale preparations, is reported in table 110. In order to produce more efficient catalysts for the liquid phase oxidation and to derive new insights into the reaction mechanism, we have made a comparison among catalytic systems based on different metals. The first effort was to test the activity, if present, of naked metal particles and then to study the influence of various materials commonly used as a support.

Oct 1, 2003

By A. H. Harvey, M. Delangen, A. D. Fernie

"A large-scale expansion to Pacific Coast Bulk Terminals Ltd. has now been completed and placed in operation. The original plant, built approximately eight years ago, consists of the direct rail-car to ship transfer of bulk commodities. The extension includes additional rail-car unloading, a transfer house system for directing commodities to storage or ship, major storage and reclaim facilities, a second shiploader and a second deep-sea berth. In addition to the facilities for overseas shipments, a wood-chip loader and a barge berth have been installed for domestic shipments of wood chips and, occasionally, for other local commodities. The design considerations imposed by the nature of the products to be handled are covered in this paper."

Jan 1, 1969

By G. B. Harris

A new process for the recovery of copper and associated base metals from a polymetallic massive sulphide ore is described. The massive sulphide contains copper and especially nickel sulphide in a mineralogical form which negates both good recovery and high grades in concentrates using conventional flotation methods. Flotation concentrate processing and smelting from this ore is therefore probably not an economically viable option. Utilising the properties of high concentration chloride brines, a flow sheet has been developed and tested whereby the recovery of all of the metals and some of the power requirements for the plant itself can be derived from the ore. The new process overcomes the less-amenable-to-flotation ore characteristics, and provides the opportunity of economic processing in remote locations where the dependency on fossil fuels is both a logistical and an economic concern. The Ferguson Lake deposit of Starfield Resources in Nunavut, Canada, is the subject of this paper, which focuses on the leaching and copper recovery unit operations of the proposed flow sheet.

Jan 1, 2007

By J. Koponen, K. S. Stadler, A. Fuerst, S. Gaulocher, Th. von Hoff, R. Veldsman

"Gearless mill drives (GMDs) are the workhorse in the mineral processing industries, more specifically when it comes to grinding crushed ore and cement (in various production stages) in semiautogenous (SAG) mills and large ball mills. They are renowned for their excellent reliability and robustness, long lifespan, and little need for maintenance, and thus yield a low total cost of ownership (TCO).A GMD represents a major investment for a mineral processing plant, and its availability is pivotal for the grinding process. As a basic rule, shut-down periods are to be minimized, but even much more important is that unscheduled shut-downs be avoided. In this contribution, we will present a portfolio of innovative remote diagnostic that consist of the following three key components:1. Trouble shooting is a form of corrective maintenance and is based on state-of-the art remote access technology, thus enabling highly skilled engineers to access the current sensor readings anytime and from anywhere in order to resolve urgent problems together with the GMD user.2. Periodic maintenance reports are a form of preventive and predictive maintenance and aim at continuous improvement based on long-term historical records and analyses of multiple measured signals. These detailed reports highlight the health and operational status of the GMD and are periodically (e.g. 3 months) submitted to the customer.3. Remote condition monitoring spans across preventive and predictive maintenance and is based on continuous recording and automatic analyses of relevant signals using advanced algorithms. The main issue is how to handle the enormous flood of data in an intelligent manner. The results of these analyses are made available to both the GMD user and supplier in real time in order to increase the availability and reliability of the GMD.In this paper, we consider various parts of the GMD, e.g. the cycloconverter, the ring motor, the auxiliary devices (e.g. cooling and lubrication systems), and also phenomena related to the mill itself (e.g. state and quantity of charge). The signal analysis techniques range from simple threshold-based analyses to complex time and frequency domain analyses. We will illustrate the benefits of the proposed approaches with some selected examples."

Jan 1, 2012

By A. -M. Lafront

The corrosion resistance of die-cast and freely-solidified and electromagnetically-stirred thixocast AZ91D alloy has been studied using electrochemical noise technique in a 0.05M NaCI solution at pH 6.1 and 25°C. Specimens polished at different depths were immersed for a period of 75 min in order to assess the influence of the microstructure on corrosion kinetics and morphology. At depths between 10 and 50 µm (skin), all specimens showed general non-uniform corrosion with the lowest corrosion resistance. Between 100 and 200 µmn (interior skin), the observed corrosion was accompanied by superficial undefined pits due to metastable pitting. The corrosion form for 100-200 µm gave the best corrosion resistance. Stable pitting corrosion was observed beyond 400 µm deep on the bulk specimens. The skin of all thixocast specimens prepared billets showed a more corroded surface than that of die-cast. The interior skin as well as the bulk specimens showed better performance than that of the die-cast specimens.

Jan 1, 2007

By V. Prasad, A. Afacan, K. Popli, S. Dubljevic

Froth flotation is one of the most common and widely used separation processes in the mineral processing industry; however, its complexity means that complete understanding of the process has not yet been achieved. A dynamic fundamental model is needed to enhance the understanding of the process and to improve process control. It is challenging to capture all the phenomena involved; hence, we propose a multiscale modeling approach with a framework ranging from macroscopic (equipment scale) to microscopic (attachment, detachment) models along with distribution models for ore particle sizes. Real-time froth properties are obtained using a vision-based sensing system. These measurements can be used for developing a soft sensor for grade using statistical methods such as PCR (principal component regression) and PLS (partial least squares) regression. The fundamental model is updated in real-time using extended Kalman filtering. Attachment dynamics are studied for different particle size distributions. The modeling and soft sensing is tested on batch flotation cell for the pure mineral galena with different particle size distributions using Xanthate and MIBC as collector and frother, respectively. The model, online measurements and soft sensor are useful in developing monitoring methods for froth flotation.

Jan 1, 2015

By A. M. L. Cushing, S. Kelebek

Presently, adsorption is one of the effective methods of removing toxic contaminants from waste waters. The contaminants from metal mining industrial operations include an effluent water containing various types of heavy metal species at concentrations beyond the maximum allowable limits, which are 0.5 ppm and 0.3 ppm for nickel and copper species, respectively. Adsorption behavior of copper ions pre-chelated with diethylenetriamine (DETA) and triethylenetetramine (TETA) onto natural bentonite and peat has been investigated. Both natural bentonite and peat was found to be capable of removing these copper-polyamine complexes from aqueous solutions relevant to process water effluents. However, the adsorption capacity of bentonite was significantly higher than that of peat. Two models were used to study the adsorption kinetics: a pseudo-first-order rate expression and a pseudo-second-order rate expression. For both adsorbents, the data conformed best to the pseudo-second-order rate expression. Representation of the experimental data through adsorption models was also investigated. Out of the four cases considered, namely, Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherms, it was found that for both bentonite and peat, the copper polyamine adsorption data conformed best to the Dubinin-Radushkevich adsorption model. The Langmuir model also represents the bentonite-copper polyamine adsorption system reasonably well as the second best case, suggesting that the amount adsorbed on bentonite might be a monolayer with strong affinity.

Jan 1, 2015

By B. Lewis

Paper did not make deadline for printing

Jan 1, 1982

By P. J. Urso

"The coal reserves of the Crow's Nest Basin in British Columbia have been known since the late 1860's. The 51.0-million-long-ton (over 15 years) sale of low-volatile coking coal to Japanese steel mills, as finalized in 1968, establishes the importance of these coal reserves in the world markets.In the early stages of the exploration program, which began in January, 1967, emphasis was placed on deter-mining the reserve of underground low-pitch coal within the No. 10 or Balmer seam of the Kootenay coal forma-tion. The finding of low-cover reserves in excess of 100,000,000 tons altered the initially planned underground program. Extensive tests were performed, establishing the excellent coking characteristics of the open-cast Balmer coal. Due recognition was given to the ultimate reclamation costs of mined lands and associated spoil areas.t was determined that, to achieve the costs desired, a high productivity was necessary, requiring large mining equipment. Operating criteria were set out, based on producing 4.2 million tons of clean coal per year. To optimize recovery, the preparation plant feed size was fixed at Yi in. x 0. The initial basic design capacity of the plant was 1,000 tph. The washing plant is composed essentially of four separate cleaning sections: a dedusting section; a multi-stage heavy media cyclone section; water cyclones; and flotation cells. Subsequent to the basic program, additional sales were made of 6.0 million long tons over the initial three-year period and the plant capacity was raised to 1,400 tph through the addition of a 400-tph coarse-coal treatment section. All wet coal products from the fine coal plant will be dried in a 70-tph (water) heat dryer. A unit-train concept of coal transportation between the mine site and the Westward Terminals at Roberts Bank has been negotiated with the Canadian Pacific Railroad. Facilities at the port will include a 4,000-tph rotary car bumper, 400,000-ton clean-coal stockpiles, and a bucket reclaiming system having a total ship-loading capacity of 6,000 tph."

Jan 1, 1969

By H. J. Burchell

"IntroductionTHE PURPOSE of this paper is to introduce the reader to rock bolting and its present application in mining.Rock bolting consists of bolting insecure rock to secure rock in order to form a safe structure. The insecure rock may be a weak beam or loose from arching or from sloughing. The material is strengthened and held in place before damage can result.Little is known of the limitations of rock bolting; to date, work has been carried on by trial-and-error, with large safety factors being used. Rock bolts have been principally used for roof support. Bolting offers a new field of support to the mining industry: it now has a permanent position as a ground control method.HistoryRock bolting is a relatively new means of support, its exact origin being unknown.Bolting has been in use at the St. Joseph Lead Company's property in Southeastern Missouri for the past twenty-six years, the first attempts having been hit-or-miss trials before a systematic attack was made. Many instances of occasional use of rock bolts have come to light .in widely separated mining camps, .some dating back forty years.The first installations were made as supplements to wooden timbering where space was restricted. The excessive costs compared to wooden timbering hindered their advancement for a number of years"

Jan 1, 1955

By Jonathan Matthews

Efficient and effective management of mine tailings is essential for continued successful development of Alberta?s vast oil sands resources. Syncrude Canada Ltd. continues to research novel tailings management techniques in an effort to improve production efficiency and environmental sustainability. During the summer months of 2001, Syncrude Canada Ltd., in collaboration with members of the Canadian Oil Sands Network for Research and Development (CONRAD), conducted field-scale trials of thickened tailings technology at Syncrude?s Aurora mine, north of Fort McMurray, Alberta. This paper provides an overview of the test program including discussion of objectives, test configuration, and program observations. 0Data collected during the field trial indicate that substantial swings in feed slurry composition challenge effective thickener operation. When coarse mineral solids dominated slurry composition, thickener rake torque rose to unmanageable levels. It was determined that the end-of-pipe depositional characteristics of thickened oil sands slurry were generally consistent with present understanding of oil sands tailings slurries. After shear, thickener underflow product exhibited very shallow beach angles and a limited capacity to keep coarser particles in suspension indicating that stacking of ?paste-like? thickener underflow product from a conventional thickener is not practical in an oil sands setting unless process adjustments can be made to increase the underflow density and/or preserve the initial high yield stress of the underflow during transport and deposition. These technical challenges notwithstanding, Thickened Tailings technology offers considerable promise for recovery of warm water from oil sands process tailings.

May 1, 2003

By B. R. Conard

Copper refining at Vale Canada (previously known as Inco) has been associated with Ni production. Because Cu and Ni carry risks for adverse health endpoints through inhalation exposure, it is critical that their aerosol levels, and the metallurgical processes through which they enter the air, are understood. Because certain Ni substances have been linked to respiratory cancers, it is also important to characterize the amounts and types of Ni compounds in occupational settings. This paper describes electrorefining and electrowinning operations near Sudbury, Ontario (1930–present), and gives aerosol measurements (1978–present).

Jan 1, 2014

By J. F. Henderson

"IntroductionTHE National Advisory Committee on Research in the Geological Sciences was set up by the Privy Council of Canada in 1949. It was set up because you, the Geology Division of the Canadian Institute of Mining and Metallurgy, asked that it be set up. The Committee is, therefore, to a consider-able degree, your offspring. In the role of good parents you, of the Geological Division of the C.I.M., should be interested in the progress of your progeny. How is the Committee organized? What has it recommended? What has it accomplished? On behalf of the National Advisory Committee, that is what I want to tell you about this afternoon.HistoryYou will remember that, in 1946, the Geology Division of the C.I.M. set up a Committee on Geological Research. This Committee, under the Chairmanship of Dr. J. E. HAWLEY, found ""that there is no national organization interested in surveying, co-ordinating, and implementing with financial help, fundamental and much needed geological research. Accordingly, the first and most necessary step to put the geological sciences in Canada on a proper footing .is the recommendation that a National Advisory Committee on Research in the Geological Sciences be formed"" (l).This recommendation was endorsed •by the President and Council of the C.I.M. in 1947 and submitted to the Minister of Mines and Resources."

Jan 1, 1952

By Ahmad Ghahremaninezhad, Denver H. Cowan

Much of today’s gold is locked within sulphide minerals. These sulphide minerals, including pyrite, need to be subjected to oxidative pre-treatment in order to leach the refractory-gold using traditional methods. Typically autoclaves employing high temperatures between 180?225 ºC, and extremely high pressures between 1,500?3,200 kPa, are used for the oxidative pre-treatment. However, the autoclaves themselves are very expensive, costly to operate and maintain, and produce excess sulphuric acid. This paper studies the atmospheric oxidation of pyrite in ferric sulphate solutions. In general, pyrite oxidation under atmospheric pressure can result in high elemental sulphur production, i.e. less acid generation. Activated carbon has displayed an ability to catalyze the process, achieving reasonable kinetics. The reaction kinetics were investigated by altering acidity of the leaching solution, temperature, catalyst ratio, sparged oxygen and agitation. A combination of X-ray diffraction, scanning electron microscopy, optical microscopy, X-ray fluorescence, inductively coupled plasma mass spectrometry (ICP-MS), and atomic absorption spectroscopy (AAS) were used to monitor the kinetics of the process and elemental sulphur yield. The purpose of this investigation was to determine optimal operating conditions that maximized kinetics of the atmospheric oxidation while maximizing elemental sulphur yield.

Jan 1, 2015

By W. S. Urbanski, A. L. Devernoe, R. W. Stuart, M. S. Walker

"Although many investigators have successfully achieved separations using variations of a concept wherein particles are buoyed upwards against gravity in a magnetically attracted fluid, none have succeeded in separating fine particles in a manner that is practical tor mineral beneficiation. This paper describes laboratory tests and preliminary economic analyses for a new mineral separation process which provides enhanced magnetic buoyancy and separation capabilities. The process provides a means of gravity separation in a regime where conventional gravity separation is inadequate; that is for small differences in mineral densities and for very fine particles. Although early interest centers on gravity separation, the process has also been successfully used for precise magnetic separation.Tests were conducted on a variety of mineral mixtures, ore samples and concentrates including; a sphalerite ore, pyrochlore ores and concentrates, cassiterite pre-concentrates, a chromite pre-concentrate, and heavy mineral placer samples. Separations requiring high discrimination between fine particles narrowly different in density or weak magnetic properties were obtained. Of particular interest is the ability of the process to concentrate or remove oxide minerals or gangues, especially silicates. Potential applications are discussed."

Jan 1, 1985