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By L. C. Kitchener, K. Vollenwyoer

"This paper describes the development of an automated, 70-ton capacity, underground electric trolley truck at Inco Ltd. The purpose of the project is to provide a high capacity and high productivity haulage system to suit continuous loader applications in existing mining horizons where conveyor belt application is not immediately practical. IntroductionWith the start o f a program by Inco in mid-1983 to develop a continuous loader for bulk mining of our hardrock orebodies, the need for a rapid ore transportation system was recognized to match the increased extraction rates planned. Two methods were investigated, truck haulage and conveyor belt. As a result, a conveyor belt system has since been designed and installed with a continuous loader at Stobie Mine and an electric truck has been designed, fabricated and assembled, with shop testing underway. This paper deal s with the latter project. BackgroundMany existing mining horizons which could utilize continuous loaders do not have the straight runs required for conveyor belts. In these situations, truck haulage would be the only alternative of the other transportation methods that would be practical. In order to match the high productivity potential of the continuous loader, however, a more efficient trucking system is required than would be available with conventional diesel powered trucks or with electric truck designs commercially available, or under development. A higher capacity truck and an automated operation is necessary so that the application of additional units to suit increasing haulage distances matches loader output without reducing over-all productivity because of the need for additional operators.A first effort to work with a major electrical manufacturer was unsuccessful and resulted in a project delay of almost one year. In November 1984, an investigation into the concept was reinstigated with UTDC, and an agreement to start design was reached in April 1985."

Jan 1, 1988

By B. D. H. Knights, N. B. du Preez

The recovery of the economy of the Democratic Republic of Congo has allowed for the rapid increase in production of copper from this region, while the increased price of cobalt continues to support the recovery of that country’s economy. This has enabled the modernization of the process technology used, particularly the change from direct electrowinning of copper to solvent extraction-electrowinning. With this change has come a variety of technical challenges in optimizing the recovery of cobalt from these sources. In this paper, we discuss aspects of the flowsheets for the production of cobalt from the ores of the DRC and Zambia, highlighting the technological improvements that have been made. Following this description of the practice, we assess the challenges of further improving the recovery and purity of cobalt from these sources. INTRODUCTION The African Copperbelt (Figure 1) is by far the biggest producer and holds the greatest reserves of cobalt (Sheed, 2015). However, the ores of this great mining region are extracted primarily for their copper content, and cobalt is a by-product. The ratio of copper-to-cobalt is between 6 and 20 to 1, with the ores from the DRC richer in cobalt than those from Zambia. The overall supply of cobalt, shown in Figure 2, is increasing due to an increase in demand for its use as a battery material. Cobalt is used in superalloys, hard metals, pigments, catalysts magnets, tyre adhesives, lithium-ion rechargeable batteries, and wear-resistant coatings, amongst others. Although these generic categories persist, Figure 3 shows how the relative usage of cobalt is changing due to the uptake of electric vehicles in China and Europe. Cobalt is a key element in lithium-ion batteries, and because it is widely anticipated that electric vehicles will be legislatively encouraged, it is anticipated that the demand for cobalt will rise. This anticipated increase in demand resulted in an increase in the price for cobalt, to which suppliers responded over-eagerly, and the price has dropped dramatically in the first few months of 2019, as shown in Figure 4. However, there is a clear cycle of price peaks in cobalt’s history.

Jan 1, 2019

By E. Dernedde

Cell rooms of aluminium smelters have large openings in the sidewalls and in the roof. These openings provide a high ventilation rate, which removes heat and contaminants emitted by the reduction cells and thereby ensures acceptable working conditions inside the cell room. However the large openings make the airflows through the smelter building sensitive to the wind. In this study equations for the airflow through the openings of a smelter building exposed to crosswinds were developed and verified against plant measurements. The equations were then used to estimate the airflows through a two-storeyed smelter building containing VS Soderberg cells. Wind protection by wind-covers over the sidewall openings and by upwind buildings made the airflows through the building less sensitive to the wind. Physical and mathematical modelling showed that working conditions inside the wind-protected cell room would be acceptable for crosswinds at speeds up to 16 km/h. These predictions were confirmed by measurements taken in a VS Soderberg smelter.

Jan 1, 2007

By Isabel F. Barton, J. Brent Hiskey

Chalcopyrite (CuFeS2) is the earth’s most abundant copper ore mineral, but is refractory to leaching with sulfates, chlorides, and other common lixiviants and oxidants. This has led to increasing research into alternative lixiviants for recovering Cu from chalcopyrite. Here, we review the leach kinetics of chalcopyrite in glycine, ionic liquids, and methanesulfonic acid, compared to baseline ferric sulfate and ferric chloride. Glycine (CH2NH2COOH) has long been used in applications such as biocatalysis and electroplating, and has recently been examined as a lixiviant for whole ores and concentrates of both copper and gold. It is nontoxic, biodegradable, and capable of strongly complexing Cu2+. Compatible oxidants are peroxide, dissolved oxygen, and ferric sulfate. Chalcopyrite leaching rate in glycine is chemical reaction-controlled, but the effects of grain size and the reaction orders with respect to lixiviant and oxidant concentrations and mass transfer vary. The use of ionic liquids as a leaching agent for chalcopyrite has been extensively investigated in recent years. This system is based primarily on the use of the imidazolium molecule (C3H5N2), which is a planar 5-member ring structure. This lixiviant has been applied to the leaching of chalcopyrite in the form of pure mineral, concentrates, and ores. Kinetics of ionic liquid leaching of chalcopyrite vary substantially depending on the type and concentration of ionic liquid. Methanesulfonic acid (HCH3SO3) is one of the newest lixiviants available in leaching, having only been examined in the last decade. It has been examined as a substitute for sulfuric acid, since it is less corrosive, is biodegradable, and breaks down to carbon dioxide and sulfate over time. The rate of copper leaching from chalcopyrite by methanesulfonic acid is controlled by diffusion and exhibits a strong dependence on oxidant type and concentration. Despite promising reaction rates and total extraction by some of these novel lixiviants, comparison with baseline ferric sulfate and ferric chloride systems makes it doubtful that any will be commercially viable in the near term. Only at very high reagent concentrations and temperatures, and/or very fine grain size, did any of the systems perform comparably to the much cheaper ferric chloride at extracting Cu from chalcopyrite. Most had similar overall reaction rates and total extraction to ferric sulfate, which is relatively common and cheap. However, the leaching kinetics of these novel lixiviants offer valuable insight into the dissolution behavior of chalcopyrite in various systems.

Jan 1, 2019

By G. R. Sadowski

"Large subhorizontal joints have been found in the foundation excavations in basalt and granite of Brazilian Dams. Some spread for hundreds of square meters showed slickensides—polished surfaces plus striations—and laminations interpreted as related to shear displacement, what substantially reduced their shear strength and imposed special reinforcement measures against the potential sliding of overlying concrete structures. The geological characteristics of these discontinuities have raised speculations related to their origin, be it related to mechanisms of bulging, cambering or to some tectonic or primary geological event.Several geologists and engineers from the northern hemisphere including Terzaghi already showed to be concerned with their role in granite foundations while in the southern regions Brazilian authors have found similar occurrences but also affecting individual lava flows of continental flood basalts in the foundations of major dams of the Parana Basin, which they designated under the particular name of “fault-joints”. This double-standard designation is self-explanatory of the difficulties involving their origin and related geomechanical properties: faults or just shear joints?Recently, similar features were encountered in the foundations of large dam constructions in anorogenic granites inserted in the realm of the Brazilian Amazon, where some of these discontinuities exhibit features common to tectonic thrusting combined with deep tropical weathering.The evidence of preshearing along the surfaces of such fractures, also associated to products of deep weathering, reduces their geomechanical strength substantially, suggesting values of ultimate phi spanning 12 to 28°. The detection of these descontinuities during initial investigation phases continues to be a major complex task in geological risk evaluations surveys. Trenching associated to some geophysical exploration techniques, although considered to be very basic exploration techniques are still the suggested methods for their forecast and previous determination."

Jan 1, 2015

By Mark B. Thorpe

Golden Star Resources started gold mining operations in Africa in 1999 after 15 years of exploration in South America. At the time, the approach to local assistance was through "alternative livelihood" programs and the donation of infrastructure to local communities. This was initially successful with local community support. However, with time and on reviewing the implemented projects, it became evident that the success was limited and many if the projects were either poorly used or in disrepair. Through a review of the options, we decided to develop a community assistance model driven by the communities themselves, while keeping control of the finances and the actual construction of the projects. Through the formation of the Golden Star Development Foundation, we began to support community driven projects for local economic development. The evolution of economic development projects continued over the next several years with the addition of project requirements for partnerships with government, and finally an evolution to a partnered turn-key piece of infrastructure that we hand over to an agency for operation and ongoing maintenance. We are currently working with outside partners to further our economic development activities in Ghana to the benefit of our stakeholders.

May 1, 2011

By Teresa Sikora

For over 40 years the Institute of Innovative Technology EMAG has specialized in the development of systems and equipment for laboratory and on-line monitoring of coal quality parameters, as well as the implementation of these systems and devices in mines and power stations. Some of these systems, based on advanced radiation detection techniques such as ?-ray backscattering (ALFA-06 and ALFA -06/T systems) or dual energy ?-ray transmission measurement (ALFA-06/2E ash meter), and also the ALFA-06/3E system applying microwave technology for the measurement of moisture, have had numerous applications in Poland. At present, over 100 systems and devices are used in Polish hard and brown coal mines. For over 10 years, EMAG has been specializing in the development of systems and devices, based on natural gamma measurement technology. An on-line ash meter, RODOS and RODOS Ex, based on measurement of natural gamma radioactivity of coal, has been developed and put into operation. This technique has been also used in developing the portable ash meter WALKER and laboratory analyzer GAMMA NATURA. The paper briefly presents features of the above-mentioned devices, their limits and their obtained accuracy, but in particular refers to the laboratory analyzer, GAMMA NATURA, as the first such device in the world, and presents the results of ash and moisture content measurement in hard, brown coals and potassium salts. The possible applications and advantages of the device in coal mines are discussed. The paper also presents the implementation results of the portable ash meter, WALKER, and the on-line ash meter, RODOS, that is used underground in coal mines.

Aug 1, 2013

By D. Tao

The adverse effects of clay particles on coal and mineral processing processes such as gravity separation, flotation, filtration, and thickening are well known in the mining industry. In particular, the presence of ultra-fine clay particles deteriorates froth flotation performance, which has been attributed largely to slime coatings that inhibit bubble attachment and to adsorption of the frother and/or collector by the clay particles. The present study was conducted to evaluate the performance of clay binding agents developed by Georgia-Pacific Resins, Inc. in enhancing coal and mineral flotation performance. Mechanical and column flotation tests were carried out using coal and potash samples. Process parameters investigated include slurry solids percentage, impeller rotation speed, binder dosage, collector dosage, etc. Flotation results show that use of GP reagents significantly enhanced flotation efficiency under different conditions. The required binder dosage and conditioning time was about 1 lb/t and 0.5-1 min, respectively. More significant improvements in process performance were observed at higher solids percentage and higher impeller rotation speed.

Jan 1, 2006

By J. F. J. Thomas

"AbstractBoth the quantity and quality of waters available as raw materials are important to Canadian industry and to the national economy. The huge demands of many Canadian industries is illustrated by tabulated figures, based on the 1950 Canadian production of certain products, and on United States figures for the gallons of water required to produce a unit quantity of each product. It is suggested from comparison with American survey results and figures that Canadian industrial water consumption is 1 to 11/2 billion Imperial gallons per day. Since present information on Canadian usage is meagre and it is not certain that American survey results can be directly applied to Canadian industry, this estimate must await confirmation in future studies.The hydrologic cycle and the principal factors affecting the quantity and quality of water, namely, climate and season, topography, geology, vegetation, and human activities, are discussed and the principal salts dissolved in water which affect industrial use are enumerated.The present survey studies by the Mines Branch on water quality are outlined. Besides chemical analyses of municipal water supplies within a watershed, periodic sampling and analyses of major surface waters for a one-year period is being carried out. The importance of studies on seasonal variation in quality is stressed by comparing the dissolved salts in various river waters with river flow. Figures showing such relationships in the Rideau river and Ottawa river at Ottawa, the Columbia river at Trail, B.C., and the Battle river at Unwin, Sask., are presented. Different rivers show different quality changes with changing flow, and possibly only after long-term studies can the relationships be predicted.Quality studies on water may be as important as studies on many other raw materials. The quantity of the raw material, water, is not inexhaustible nor is the quality indestructible, and more realization of its importance, followed by conservation and intelligent use, is desirable."

Jan 1, 1952

By P. R. Cook

Thunder Bay Terminals' plant, now in operation, cost about 70 million dollars and was completed on time and under budget. The paper is the project manager's account of this accomplishment. From site selection through feasibility, engineering and construction to realization, he emphasizes the necessary philosophies for the control of time and money. The computer as a tool is discussed, as well as techniques for procurement.

Jan 1, 1979

By Mehmet Guney

This article is based on a detailed heat investigation conducted at the Rokana Division of Nchanga Consolidated Copper Mines Limited while both authors were employed in Zambia. Mindola Mine is one of the three underground mines comprising the Rokana Division on the Copperbelt of Zambia, producing about 270,000 tons of ore per month at 1.9% Cu and 0.14% Co. The total volume of air being circulated by means of five primary fan installations slightly exceeds 1,000 m3/sec at standard density. Sectional bulk cooling is practised where air cooling coils are installed at primary splits some considerable distance from the stoping operations. Total capacity of the refrigeration complex is 10,500 kw (3,500 R. tons), of which about 7,000 kw is available as effective cooling power after losses, but the heat removed from the coifs is about 3,500 kw with 61% over-all plant performance. An extension program is planned for a further five production levels with the re-deepening of a sub-vertical shaft. Thermal heat will become a major problem at increased depth associated with higher rock temperature, higher thermal conductivity of the rock groups encountered and fissure water flowing into working areas through the strata with increased rock temperature. This paper describes the ventilation and refrigeration practices in Mindola Mine, with special reference to future thermal heat problems. These are discussed with a view to mining at depth.

Jan 1, 1979

By E. Ghali, J. F. Dorion

This paper presents the results of on-going investigations on the influence of corrosion on the performance of support systems in selected underground gold mines. Rock support is exposed to various conditions that can be aggressive. Samples of corroded support were analysed using SEM and photomicrography to determine the main corrosion forms. Tests are on-going in controlled corrosion chambers to qualify and quantify the impact of rock and minerals particles on steel corrosion. As more data become available these relationships can lead to useful information on the choice of support systems and reliable estimates of their longevity.

Jan 1, 2011

By M. Celikin, M. Isac, R. I. L. Guthrie, S. Ge

Horizontal Single Belt Casting (HSBC) is a near-net-shape casting process in which molten metal is directly cast into thin strips, at high cooling rates (order of several 100°C/s), with the potential for high volume, friction-free, continuous production of metal strips. This casting process was used in the present work to produce strips of Al-Mg alloys in the AA5000 series, with additions of Sc and Zr. Such aluminum alloys show exceptional potential as a structural material for transportation/aerospace applications. To demonstrate the suitability of the HSBC process to manufacture competitive strip products of Al-Mg-Sc-Zr, the mechanical properties and microstructures of the strips produced using the HSBC process were compared with conventionally cast products. The effects of annealing on the mechanical properties of the strip-cast Al-Mg-Sc-Zr alloys were also investigated.

Jan 1, 2014

By D. Neely, D. Milne, L. R. Feldman

"Resin-anchored rebar is commonly used for rock support in mining. The rock properties and environment determine the average bond strength, allowing mine engineers to select the appropriate length and installation pattern for the support. In weak material such as potash, the average bond strength tends to be lower than for a typical hard-rock installation. Determining the failure mechanism by which the support fails in soft-rock applications could lead to improved bond strength and better calculated installed support capacity. This paper reports on research conducted at a potash mine in Saskatchewan and analyzes the failure mechanism of the support.RÉSUMÉ Dans les mines, les barres d’armature enduites de résine sont fréquemment utilisées pour soutenir le roc. L’environnement et les propriétés du roc déterminent la résistance moyenne d’adhésion, permettant ainsi aux ingénieurs miniers de choisir la longueur de barre appropriée et le diagramme d’installation du soutien. Dans des matériaux faibles, tels que la potasse, la résistance moyenne d’adhésion tend à être plus faible que pour une installation typique dans de la roche dure. La détermination du mécanisme de rupture selon lequel le soutien fait défaillance dans des roches tendres pourrait conduire à une meilleure force d’adhésion et à un meilleur calcul du soutien installé. Le présent article fait état de la recherche effectuée dans une mine de potasse en Saskatchewan et analyse le mécanisme de défaillance du soutien. ,"

Jan 1, 2016

By F. Chiesa, Jeremy Carignan, B. Duchesne, D. Levasseur

"Aluminium A206 (AlCu4) is one of the strongest aluminium casting alloys with tensile properties approaching those of ferritic ductile iron. If the specification on the silicon content (< 0.05%) is easy to achieve during alloy ingot production, it is not the case in a foundry, where returns are used which are not perfectly cleaned from the silicate containing molding sand (Olivine). In alloy A206, the Si content is controlled in order to avoid the formation of a low melting point intermetallic phase (such as phase Q Al5Cu2Si6Mg2); these phases will melt during the solutionizing heat treatment to which alloy A206 must be subjected to develop its outstanding mechanical properties. This incipient melting may deteriorate the mechanical properties of Alloy A206 if the solutionizing treatment is applied at the standard temperature of 530°C.In the present study, a lower temperature solutionizing (520°C) was applied to a high Si content 206 alloy in order to reduce or eliminate the possible incipient melting. This was carried out on a complex shape industrial casting weighing 14 kg (31 lb) and 560x410x250 mm (22x16x10”) in size poured in aluminum 206 with a high silicon content (0.22% vs 0.05% max for alloy A206). Twenty ASTM E8 subsize tensile specimens were excised from two locations in the casting in order to compare the tensile properties for the two solutionizing temperature used (530 and 520°C). Optical and SEM microscopy allowed to investigate the causes of the differences in the properties observed between the 2 zones of the casting studied for 3 different heat treatments. INTRODUCTIONIn spite of their “textbook” outstanding mechanical properties (Up to twice the strength and elongation of the widely used A356 alloy), aluminum-copper alloys of the 2xx series are seldom used because of their propensity for hot tearing [Li, 2011], the segregation of copper [Cho, 2003], and their sensitivity to stress corrosion cracking [Jean, 2009, p. 113)]. Also, because of their wide freezing range and high thermal conductivity, a wide mushy zone makes feeding difficult, unless strong temperature gradients are created by liberal use of chills and risers in the critical zones of the part. Because they are prone to hot tearing, grain refining of Al-Cu alloys is particularly important, titanium playing a major role in the process [Sigworth, 2003]; grain refining has also been shown to be beneficial to fatigue strength [Jean, 2009, p. 103]. The practical basis of foundry practices pertaining to these alloys is outlined in an AFS webinar [Weiss, 2014]."

Jan 1, 2016

By Peter J. Franklin

"Short-term mine planning of open pits is an activity that has historically been carried out by hand. Typically, the use of computers has played little part in this type of mine planning. This paper describes the objectives and the procedures involved in short-term mine planning, comments on the type of computer systems available, and describes in detail a computer-aided short-term planning and scheduling system known as STEPS.IntroductionThe mine planning department of any o pen-pit mining operation performs a wide variety of different tasks. However, their primary concern is the preparation of detailed long-and short-term mine plans. These mine plan s will define the long-term operating strategies and definitive everyday working plan s for the ongoing development of the open pit.In this day and age, when operating costs have spiralled upwards due to inflation , and product revenues have decreased due to depressed economies and poor markets, it is vitally important for all aspects of the mining operation, including mine planning, to be efficient and cost effective.There are numerous options available for planning engineers when generating a mine plan. A cost effective mine plan must investigate all these options and select the optimum. When using manual planning techniques, it is often impossible to evaluate all the available options. To do this, and to produce an optimum mine plan, a computer is required.This paper discusses mine planning, with emphasis toward the short-term plan and comments on how the processes may be computerized. It also describes in detail, a computer software system called STEPS, which has been designed as an interactive graphics, computer-aided short -term mine planning and scheduling tool."

Jan 1, 1985

By Niraj Bala

Boiler tubes of coal-fired boilers suffer severe erosion-corrosion (E-C). One method to counteract this problem is by the use of therma, spray protective coatings. Cold spray coating process was used to deposit Ni-20Cr powder on SA 516 (Grade 70) boiler steel. The bare as wel, as the coated steels were subjected to cyclic experimenta, studies, in the superheater zone of a coa, fired boiler. The weight change technique was used to establish kinetics of the erosion-corrosion. XRD, FE-SEM/EDS and X-ray mapping techniques were used to analyse the as-sprayed and corroded specimens.

Jan 1, 2010

By J. Ramirez-Castro, J. A. Finch

"Galena is the finest component of the product of a closed-circuit grind treating a lead-zinc ore, largely due to preferential recycling of this high-density mineral by the cyclone. For example, at the Pine Point Mines concentrator, for ~ 55% -200 mesh over-all, the galena will be close to 95% -200 mesh. This sliming of the lead can limit recovery, selectivity and dewatering. A proposed circuit modification to reduce the sliming is to incorporate a unit cell. A simulator was constructed to study the No. 3 grinding circuit at Pine Point modified by a unit cell on ball mill discharge (BMD).The simulator used a cumulative size basis rate-of-breakage with plug flow ball mill model, the parameters being obtained by laboratory grinding tests. Flotation and the cyclone models used a cumulative recovery/size matrix. The behaviour of each mineral, galena, sphalerite, pyrite and calcite/dolomite, was simulated. Simulation was adapted to a programmable calculator. A close fit to the existing circuit performance at two tonnages and mineral mixes was established.The simulator showed that the modified circuit could significantly coarsen the Pb grind, from 95% to —50% -200 mesh, depending on recovery, without substantially altering the size of the other minerals. The other principal findings were: compared to laboratory flotation tests on existing circuit BMD, the unit cell concentrate (CONC) will be coarser and markedly lower in grade; relatively low unit cell stage recoveries are desirable, because the cyclone scavenges the tail to give a circuit recovery which is higher than the unit cell stage recovery; unit cell stage recovery should not exceed the cyclone stage recovery, as the latter is the maximum circuit recovery; low unit cell stage recovery helps offset the disadvantage of the high flow at BMD; other high-density minerals will also be scavenged into the CONC, as illustrated by pyrite, making CONC quality difficult to maintain; density control of BMD flotation does not greatly alter feed density to the cyclone or ball mill.Possible plant metallurgy is forecast for a CONC diverted to final lead concentrate."

Jan 1, 1980

By D. D. Macdonald, G. Engelhardt

The accumulation of damage due to localized corrosion [pitting, stress corrosion cracking (SCC), corrosion fatigue (CF), crevice corrosion (CC), and erosion-corrosion (EC)] in complex industrial systems, such as power plants, refineries, desalination systems, etc., poses a threat to continued safe and economic operation, primarily because of the sudden, catastrophic nature of the resulting failures. Of particular interest in managing these forms of damage is the development of robust algorithms that can be used to predict the integrated damage as a function of time and as a function of the operating conditions of the system. Because complex systems of the same design rapidly become unique, due to differences in operating histories, and because failures are rare events, there is generally insufficient data on any given system to derive reliable empirical models that capture the impact of all (or even some) of the important independent variables. Accordingly, empirical models have generally failed to provide a robust basis for predicting the accumulation of corrosion damage in complex systems under realistic operating conditions. The alternative prediction philosophy is determinism, in which the development of damage is described in terms of valid, physico-electrochemical mechanisms with the output being constrained by the natural laws. The differential damage is then integrated along the corrosion evolutionary path for the system (i.e., over the future operating "history") to yield the desired integrated damage, which is the quantity that is most useful to an operator. In this paper, we review the theory of predicting corrosion damage within the framework of Damage Function Analysis (DFA), with particular emphasis on the pitting of aluminum in chloride solutions and on the accumulation of damage from SCC in Type 304 SS components in the primary coolant circuits of Boiling Water (Nuclear) Reactors (BWRs). These cases have been selected to illustrate the various phases through which localized corrosion damage occurs.

Jan 1, 2005

By Jochen Petersen, Alison Lewis, Cledwyn Mangunda

Run-off and waste water streams high in dissolved metal content are generated in all mining operations. The metals pose a threat to life due to their persistent bio-accumulative toxic (PBT) characteristics. Hence, there is a need to treat mine waste water effectively. Lime precipitation is the technology of choice through which Fe, as the major metal species, is removed as Fe (III) oxyhydroxides with other metals co-precipitated and/or adsorbed. Sulphates are removed as gypsum or incorporated into the Fe phases. The resulting sludge has poor dewatering characteristics and is deposited in landfills, with an inherent risk of returning the Fe back into the water cycle through leaching. This study seeks to understand the mechanisms behind the formation of this sludge in terms of product quality. The relationship between process conditions and product characteristics has been investigated through exploring the effect of Fe (III) concentration on the precipitate product characteristics (particle size distribution (PSD), size, morphology and structure) and quality (in terms of filterability, settling ability, etc.) in a simplified system. Neutralisation of acidic synthetic aqueous Fe (III) sulphate streams containing 50, 400 and 800 mg/L Fe(III), respectively, was effected by mixing it in a continuous stirred tank reactor (CSTR) with dissolved calcium hydroxide for pH control at a residence time of 15 minutes. Precipitate samples analysed for morphology and PSD, using nanoSEM and Zetasizer respectively, showed a general decrease in PSD and zeta potential with increases in feed Fe (III) concentration. These results were used to infer the particle size enlargement mechanisms of Fe (III) oxyhydroxide precipitates under a given set of operating conditions. Preliminary product quality results indicate that a high concentration (800 mg/L) leads to the rapid formation of metastable precursors with poor product quality, whilst a low concentration (50 mg/L) leads to formation of thermodynamically more stable precipitates with good product quality. The approach demonstrates a potential route forward in terms of linking operating conditions to the attainment of desirable characteristics rather than specific precipitate phases which are difficult to identify.

Jan 1, 2016