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By Linli Wu

During the measurement of contact angle, a misty band was observed near the substrate. Hsien-Nan Ho and Shinn-Tyan Wu thought this was because the oxygen atoms on the interface migrate to the droplet surface to form an oxide band near the substrate. But from our experiments misty band appeared before the drop reach to the substrate. Theoretically speaking, the oxygen partial was the same everywhere in the vacuum furnace. So there was no condition to provide enough oxygen forming oxide. This appearance would be explained more reasonably with the optics principle. Most reflected light would be absorbed by the substrate and the light cannot reach the observation area, so the misty band formed.

Jan 1, 2006

By H. Antrekowitsch

The decreasing quality of the input materials in copper recycling leads to a higher content of impurities in the anode copper. An improvement of the pyrometallurgical refining process is therefore necessary to produce high quality anodes for the copper refining electrolysis. The behaviour of the most important accompanying elements (e.g. nickel, tin, lead, zinc etc.) at different reaction conditions has to be investigated in order to improve the metal/slag reactions as well as the vaporisation by selective oxidation in the anode furnace. Therefore the thermodynamic conditions like reaction order and the activity coefficients at the copper refining process have to be known for the optimisation of this technique. Additionally the interaction between different elements has been investigated as a function of the temperature, the content of the elements and the slag composition especially for nickel. These investigations were done at the Christian Doppler Laboratory for Secondary Metallurgy of Nonferrous Metals.

Jan 1, 2005

By Bowen Li

Silicon Carbide is an excellent refractory material. Its physical properties make it extremely useful, particularly in applications where corrosion resistance and wear are important considerations. Commercial silicon carbide refractory is frequently manufactured by bonding silicon carbide particles with clay; however, clay may cause problems in the sintered products. This study investigates the potential of replacing a portion of the clay with andalusite powder. The results show that micron size andalusite powder can improve not only the strength of the refractory but also the sinterability. The mechanisms for these improvements are discussed.

Jan 1, 2006

By A. Gibson

Most methods for the treatment of scrap printed circuit boards do not reclaim the components in working order as the boards are either fed to a copper smelter, to recover the valuable elements, or, simply landfilled. This work reports the dissolution of the solder in fluoroboric acid containing Ti4+ ions which was particularly selective for solder, allowing the components to be recovered. The solder was subsequently electrowon from the leachant. The boards were then shredded and the copper dissolved in ammonium sulfate and, then treated via solvent extraction to give an electrolyte suitable for electrowinning. The remainder of the metals were dissolved aqua regia, silver remained unattacked by the aqua regia, palladium precipitated as Pd(NH4)Cl6 in the presence of zinc and nickel, the gold was removed by solvent extraction and precipitated as nanoparticles. The aqua regia was then diluted and the zinc and nickel separated by solvent extraction.

Jan 1, 2009

By Zhang Chuanfu

Keywords: solid solution, Ni-Co alloy powders, thermal decomposition, fibres. Synthesis of fibrous Ni-Co alloy powders was achieved by thermal decomposition of precursor of complex Ni-Co oxalates solid solutions obtained via modified coprecipitation method among intimate mixing solution of NiCl2?6H2O , CoCl2?6H2O and H2C2O4?2H2O in the presence of surfactant polyvinylpyrrolidone (PVP) and organic solvent ethanol. Scan electron microscopy (SEM), X-ray diffraction (XRD), X-Ray photoelectron spectroscopy (XPS), disperse energy X-ray analyses (EDX) were used to characterize the structure features and chemical compositions of the as-prepared fibres. The influences of decomposition conditions, including temperature, time, the flow rate of N2+H2, and the heating rate, on the morphology, average size and specific surface area of the Ni-Co alloy powders were investigated. It is found that a trend of the mutual alloying of nickel and cobalt: the formation of perfect solid solution for any compositions NixCo100-x was indicated and corresponding NixCo100-x alloys with fcc phase can be obtained under the optimal conditions.

Jan 1, 2005

By Kunihiko Takahashi, Gjergj Dodbiba, Hisayoshi Umeda, Toyohisa Fujita

"An increasing number of mobile phones is increasing the number of the discarded mobile phones. Many efforts are thus being made to collect and recycle these devices. This paper is a short introduction of the recycling system of precious metals from the discarded mobile phone, currently available in Japan. Moreover, an attempt has been made to compare the energy recovery and the mechanical recycling of plastic wastes from the discarded mobile phone. The assessment has been carried out in the context of the life cycle assessment methodology (LCA). The environmental impact of each option was assessed by calculating the following impact indicators: depletion of abiotic resources (ADP), and global warming potential (GWP). 1. Introduction In 2003, the demand for mobile phones was increased since the camera was included in a mobile phone and the 3rd generation of mobile phones was introduced. In turn, the number of discarded mobile phone is rising sharply. Generally speaking, all the metallic parts of mobile phones can be recovered and recycled by using smelting and purification techniques. The recycled materials are then used to fabricate other new products."

Jan 1, 2008

By Rashmi Ramesh

Zinc oxide nanoparticles and nanostructures form an active area of research in the recent years. It can be doped to modify electronic, optical and other properties. Synthesis and characterization of zinc oxide is of extreme importance in order to understand the structure property relationship in this material which is now being considered of importance next to carbon nanotubes. Microstructure of zinc oxide nanomaterial is extremely sensitive to the preparation conditions. Nanocrystalline pure and Mn and Mg doped zinc oxide samples were prepared by wet-chemical method under different growth conditions. The samples were investigated for crystalline phase, microstructure, morphology and luminescence characteristics. The effect of Mn and Mg doping on the characteristics of ZnO have been discussed.

Jan 1, 2010

By Varadajan Seshadri

Keywords: torpedo car, kinetics, physical modeling A 1:6 torpedo car physical model was built to assess the optimum refining conditions for pig iron desulfurization in the torpedo car considering the industrial parameters used in the steel plant CSBM (Companhia Siderurgica Belgo-Mineira, João Monlevade, MG, Brazil). The refining practice in this plant is through injection of a CaO-CaF2-Mg powder in the pig iron melt. Similarity between the model and prototype were established through Froude and turbulent Reynolds criteria. Mixing times were evaluated by pulse tracer addition and the kinetics of metal/slag interactions were assessed from experiments investigating iodine transfer from kerosene to water. The influence of parameters such as level of metal, gas flow rate, lance penetration, lance orientation were also evaluated.

Jan 1, 2005

The effect of rare earth element Y (0-2.0at.%) on the microstructure of TiAl alloys at the as cast and rapidly solidified conditions has been investigated. The results show that the addition of Y greatly refined the microstructure of TiAl alloys at both conditions. The refinement is more significantly with higher Y content. The refinement of Y in the cast alloys is attributed to that the strip-shaped Y-rich phase locating on the grain boundaries impedes the grain growth during solidification. In the rapidly solidified alloys, Y-rich phase dispersing uniformly as spherical particles in the matrix acts as heterogeneous nucleation sites which increases the nucleation rate of ??phase during the ????phase transformation, and produces a refined initial microstructure during solidification. Higher cooling rate restricts the grain growth during subsequent cooling.

Jan 1, 2010

By Fumito Tanaka

The Mitsubishi Process is the sole pyrometallurgical process for the continuous production of blister copper from copper concentrates. Continuous converting originates from the application of the proven technology of a lime-ferrite slag (CaO-FeOX-Cu2O) on the Converting Furnace (C-furnace). Recent improvements on the C-furnace operation have included increasing the processing of recycled materials and the investigation of alternative fluxing agents. However, some minor oxides adversely affect C-furnace operation, with respect to magnetite behavior of the slag, with the most significant impact having been observed with the silica content of the slag. This paper will quantify the impact of silica on the lime-based slag, and discusses the controls that have been identified to sustain continuous converting operation.

Jan 1, 2005

By S. Y. Tan

The thermal stability of fully silicided NiSi with arsenic doping on silicon was investigated. The aims of the work were to investigate the Ni silicide phase-related issues associated with arsenic dopant and thermal annealing on Ni-FUSI/HfO2/Si and Ni-FUSI/HfSiO/Si gate stacks. It was found that arsenic-incorporation demonstrated some improvement in both morphology and phase stability of nickel silicided films at high processing temperatures regardless underlying gate dielectrics. The correlations of Ni-Si phase transformation and arsenic doapnt with their electrical and physical changes were established by sheet resistance measurements, X-ray diffraction (XRD), atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS) analysis. Furthermore, the modulation of the work function (WF) of Ni fully silicided gates by arsenic impurity is presented, comparing the effects of dopant (As) on the WF and silicide phases (NiSi and NiSi2). It confirmed that the work function of NiSi can be tuned by implanting arsenic dopant, but it ineffective for NiSi2 phase.

Jan 1, 2010

By Jilai Xue

Fe-Ni alloys can be used as raw material in making stainless steel. Laterite nickel ore is one of mineral resources for producing nickel alloys. In this work, the laterite ore after dehydration at 800 °C and the anthracite as reducing agent were mixed for pre-reduction at 900 °C, and then reduced to form Fe-Ni alloys at 1550-1620 °C through carbon-thermal reduction process. A high Ni-content alloy component in the metallurgical mixture can be formed through pre-reduction. Better separation of the resulting metals from the slag is found with lower Ni-content alloys produced or higher temperatures during reduction. An effective processing of Fe-Ni alloys needs further understanding of the process fundamentals and optimizing of the process parameters.

Jan 1, 2010

By Pengfu Tan

Lead blast-furnace bullion cools to near its freezing point in an operation known as copper drossing or hot drossing usually contains 0.02-0.06% copper. The removal of this copper is usually carried out in a batch operation known as sulfur drossing. Sulfur is stirred into the bullion at temperatures near its freezing point, and the dross of copper and lead sulfides that floats to the surface is skimmed off manually. A thermodynamic model has been developed to simulate the copper drossing. The phase diagram of Pb-Cu-S system has been calculated, and the effects of the process parameters, such as temperature, copper content, and sulfur content, on the drossing process have been simulated and discussed.

Jan 1, 2006

02, NaCI03, H202, Na0CI and Ce+4 have been examined as oxidants in an alkaline carbonate system for uranium in in situ leaching. The South Texas and New Mexico ores contained up to 2.6 meqJg of reducing compounds which consume oxidants in the leading operation. Leaching rates did not increase linearly with the oxidation potential of the oxidants. A mild oxidant can be used to maximize uranium oxidation selectively and oxidant efficiency. 02 can oxidize most of the uranium mineral with an adequate rate and high oxidant efficiency.

Jan 1, 1990

By Hector Carreon

Due to elevated temperatures, excessive stresses and severed corrosion conditions, turbine engine components are subject to creep processes that limit the components life such as a turbine bucket. The failure mechanism of a turbine bucket is related primarily to creep and corrosion and secondarily to thermal fatigue. As a result, it is desirable to assess the current condition of such turbine component. By using eddy current images, it was shown that the eddy current technique could be used to monitor creep damage in a nickel base super-alloy. The eddy current results also show a significative variation in the electrical conductivity on the creep damage zone with respect to the background zone in nickel-base super-alloy samples. In addition, the absolute thermoelectric power coefficient show also a strong dependence associated with creep damage in nickel base super-alloy samples using a copper hot tip reference. The eddy current and thermoelectric power techniques seems to show promise as nondestructive evaluation tools for monitoring the level of creep damage in metallic alloys.

Jan 1, 2010

By Jeremy Gregory

The disposal of end-of-life electronics is an issue receiving increasing scrutiny. This paper evaluates several alternatives for recycling cathode ray tubes (CRTs) within monitors and televisions. The primary recycling options for the glass, reuse in new CRTs or as a smelter flux, are examined from economic and environmental standpoints. The economics are modeled using a cost model that includes dependencies on processing costs, transportation logistics, and incoming material composition. The environmental consequences are modeled using life cycle assessment methodologies to determine the energy embodied in each processing alternative. Results map out preferred processing alternatives across a range of technological and operational conditions. The results indicate that economic costs and environmental consequences are heavily impacted by transportation. The preferred destination of CRT glass for a recycler is highly dependent on the proximity of the consumer to the recycler, although it is generally economically advantageous for the recycler to extensively dismantle the CRTs.

Jan 1, 2006

By Harumasa Kurokawa

Since the initial start-up, the Toyo Smelter & Refinery has been operating in harmony with the ambient environment, and improvements have been implemented with technologies specifically developed for further protecting the environment. Toyo Smelter & Refinery is now planning to increase the copper production capacity from 280,000 tpy to 450,000 tpy, over a period of several years. In 2003, the first step of this smelter expansion and modernization plan was implemented. The production capacity of the P-S converter was increased dramatically, as it became possible to operate under a ?2 hot-2 blowing? schedule. In 2005, an additional converter will be installed, in order to allow operation under a ?3 hot-2 blowing? schedule. This report will describe the technical improvements on the P-S converters, as well as describe the Toyo expansion program and discuss the technologies applied to the fugitive gas collecting system.

Jan 1, 2005

By Xiaowen Liu

The DSC/TG, IR and XRD analysis were used to characterize the heating phase transformation of illite, which came from Ouhai deposit, China. It was discovered that the dehydration and de-hydroxylation of illite carried out stage by stage during heating. The adsorptive water and layer-inter water were dehydrated from room temperature to 500°C; and dehydroxylated in the range 500°C~800°C. In these stages of process, illite?s layer structure kept almost unchanged. After 800°Cillite began to change into disorder structure. At about 1100°C, the layer structure of illite had been destroyed, and amorphous SiO2 and mullite crystallite appeared. At about 1200°C the structure of illite completely destroyed and mullite crystal phase had become perfect..

Jan 1, 2006

By B. P. Sereda

The properties, characteristics and phase structure of chamotte refractories produced with the usage of mullitecorund chamotte and caoline have been given. The comparison of new refractory C-45 obtained by us and refractory C-43 produced by traditional method has done. The physical-chemical properties of refractories is reviewed. The visual porosity, density and pore characteristics of given refractories was calculated. It is established that C-45 has the less gas permeability then C-45 that gives melting units more stability. The petrographical microstructures of refractories have been done. The main phase structures and their influence on refractories properties have been observed. It is established that refractories with mullitecorund chamotte adition has more advantages then refractories gained by traditional method and can be applied to melting units.

Jan 1, 2010

By Anne Kvithyld

Silicon solar cells, that convert the energy of sunlight into electric energy, are attractive sources of energy. In the production line wafers of solar cells are sliced from a multicrystaline ingot solidified unidirectionally. Recycling scrap from top and sides of such ingots is addressed. SiC and Si3N4 inclusions are a major problem. Scrap from Scan Wafer ASA is melted in a high vacuum furnace at around 1500ºC. The filters, from commercial producers, are C and SiC with 10, 20 and 30 ppi. Characterisation of inclusions before and after filtration, and in the filter itself, is performed by microscopy. Dissolution of silicon in acid and counting of the un-dissolved inclusions is also carried out. In the filter Si3N4 needles and SiC inclusions were identified. The amount of these inclusions in the filtered silicon is much less than in the input. In conclusion, filtration using SiC and C filters in vacuum system in argon atmosphere removes SiC and Si3N4 inclusions from solar cell scrap. Flow of metal through the filters is not a problem. These results are promising with scale-up to industrial application in mind.

Jan 1, 2006