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By R. L. Machunda, A. M. Rugaika, D. D. Mdachi

Sedimentary and igneous rocks are the two primary sources of phosphate that are mined and beneficiated to fertilizer. During the beneficiation process, phosphate is lost into the tailings. We investigated phosphate concentrations in tailings dumps at Minjingu mine, Tanzania using energy-dispersive X-ray fluorescence spectrometry to quantify the chemical compositions. The phosphate content in the tailings varied from 12.91% phosphorus pentoxide (P2O5) in Tailings 2 to 19.61% in Tailings Dump 1. The naturally occurring phosphate concentration in rocks ranges from 3% to 35%, and phosphate tailings from various locations with P2O5 concentrations as low as 6.46-12.65% have been beneficiated to commercial fertilizer. Our investigation revealed that phosphate concentrations in Minjingu tailings may be sufficient to be recovered for commercial applications. Suitable recovery methods are discussed, and we recommend that beneficiation should be performed to minimize the loss of phosphate into tailings. Further research is needed to identify the optimal beneficiation methodology.

Aug 8, 2024

By P. J. H. de Graaf, S. D. N. Wessels

"Rio Tinto’s Western Australian expansion, combined with mining within structurally complex geology and increasingly below the water table, presents challenges in effective slope management to ensure safe and economic mining.The Geotechnical Management System (GMS) was developed by Rio Tinto Iron Ore (RTIO) to manage geotechnical risks identified during the design process and implementation, and to ensure feedback based on the ‘as-found’ conditions. The GMS utilizes a risk-based approach to geotechnical risk management and is centred on the geotechnical risk and hazard assessment management system (GRAHAMS). GRAHAMS is used to assess pre- and post-control risk for future potential risks (planned slopes), current risks (as-built slopes), and actual geotechnical hazards (realized risks) identified in the pit. This serves as a core operational risk management tool in identifying and prioritizing key risk sectors and management of critical controls. The system’s database reporting functionality supports effective communication of operational risks to operational personnel, as well as reporting the risk profile across operations to management.A rigorous engagement process between design engineers and sitebased engineers is implemented to ensure that key design assumptions, limitations, risks, and opportunities are understood by the site teams. This information, together with mine plan schedule details, is used to assess the design risk and develop appropriate controls. These controls typically include slope performance monitoring and slope reconciliation. The design feedback loop is closed through sharing of key slope performance and reconciliation data with the design teams.The GMS has been successfully implemented in RTIO pits and is fundamental to successful geotechnical slope management. Improved characterization of design assumptions has allowed for re-assessment of the pit design and improved hazard management in high-risk pits. The GMS, GRAHAMS, and other processes reduce the incidence of unexpected slope instability. Improved understanding of rock mass conditions has allowed for economic optimization through redesign of slopes, allowing for an improved understanding of risk and fewer unexpected conditions (surprises), hence an increased realized value."

Jan 1, 2016

By P. M. Mashaba, S. O. Bada

An advanced high internal phase water-in-oil (HIP W/O) emulsion binder and flotation with an internal dispersed water phase of 95 vol% was used to beneficiate South African weathered coal from discard dumps. Five coal samples with calorific values ranged from 8.48 MJ/kg to 20.94 MJ/kg were utilized. The performance of the HIP W/O emulsion was compared to that of kerosene in terms of the physicochemical properties of the clean coal products. A 5 kg/t emulsion binder addition produced a high-quality coal concentrate with 11.76% ash and a heating value of 28.61 MJ/kg from a sample containing 29.34% ash. Using the same dose and coal sample, kerosene resulted in a clean coal concentrate with 17.47% ash and a calorific value of 26.42 MJ/kg. Further samples were also beneficiated using 5 kg/t of W/O emulsion. The highest increase in calorific value was achieved from the beneficiation of a sample containing 48.71% ash, from 8.48 MJ/kg to 18.16 MJ/kg. It has been established that emulsion binders can upgrade coal samples dumped many decades ago.

Aug 2, 2022

By M. Pawlik, N. Ghaffari Touran

The interactions between apatite and hematite were studied through zeta potential and stability experiments, for this paper. The zeta potential measurements were conducted in both background electrolyte and mineral supernatants. The difference in electrokinetic properties of minerals in the presence and absence of supernatant was explained in terms of the dissolution of minerals and the subsequent readsorption of dissolved species at the mineral-water interface. The stability measurements in individual and mixed mineral systems were also performed to identify the extent of interaction between apatite and hematite upon their direct contact. The results from stability measurements in individual and mixed mineral systems indicate that there is an interaction between apatite and hematite. Based on the results, the implications for the apatite-hematite separation process were discussed. Keywords: Apatite, hematite, dissolved ions, stability, zeta potential

Jan 1, 2020

COUNCIL The following served on Council during the year under review Office Bearers Dr J. P. Hugo (President), P. W. J. van Rensburg and Professor R. P. Plewman (Vice-Presidents), Professor D. D. Howat (Immediate Past-President), and D. G. Maxwell (Honorary Treasurer). Ordinary Members of Council H. P. Carlisle (until February), R. C. Espley-Jones, G. H. Grange, Dr D. I. Legge, W. W. Malan, J. B. Mudd, Dr R. E. Robinson, Dr M. D. G. Salamon, L. W. P. van den Bosch, D. A. Viljoen (co-opted May 1973), and P. A. von Wielligh. Branch Chairmen A. Bain (Witbank-Middelburg Branch), C. J. Isaac (O.F.S. Branch). Past Presidents Serving on Council R. J. Adamson, M. Barcza, H. Britten, J. K. E. Douglas, R. C. J. Goode, P. Lambooy, Professor J. de V. Lambrechts, Dr J. T. McIntyre, J. F. Reid, and V. C. Robinson. Ten Council meetings were held during the year, with an average attendance of 18, and the standing committees held 29 meetings. MEMBERSHIP Twelve Fellows, ten Members, twenty-one Graduates, eleven Associates, thirty-one Students, and forty-two Company Affiliates were elected during the year. One Member was reinstated. Eight Fellows, two Members, and two Associates were admitted to retired membership. Four Graduates were transferred to Members, one Associate to Member, three Students to Members, one Graduate to Associate, two Students to Graduates, and one Student to Associate. Your Council records with deep regret the death during the year of the following : D. R. Campbell, J. Daniel, M. J. Dennehy, and F. S. C. Rogers (Life Fellows) ; W. T. balling and T. Pryor (Life Members); C. Boocock, W. Drake R. J. Moore, M. P. Pearse, J. M Pike, W. A. Schwezoff, A. I. Suss man, and L. G. S. Wright (Fellows) ; A. F. Chalmers (Member) ; and W. R. Gerry and G. T. Rimmer(Associates). A comparative statement of membership as at 30th June, 1973, and the end of the previous year it shown in the following tabulation: 30th - 30th June, - June, 1972 - 1973 Honorary Life Fellows 5 - 4 Honorary Fellows 13 - 9 Life Fellows 181 - 177 Fellows 541 - 536 Members 479 - 487 Graduates 115 - 128 Associates 182 - 186 Students 162 - 183 Company Affiliates 24 - 64 1 702 - 1 774 JOURNAL The papers that were published in the Journal during the year are listed below: August, 1972 The effects of chromium oxide, iron oxide, and calcium oxide on the liquidus temperatures, viscosities, and electrical conductivities of slags in the system MgO-Al2O3-SiO2, by M. S. Rennie, D. D. Howat, and P. R. Jochens A study of the dust exposure of South African white gold miners, by R. J. Page-Shipp and Elizabeth Harris A forecast of the coal and uranium requirements for electric power generation in South Africa, by E. J. Maunders September, 1972 Mine management by objectives, by A. A. Hazell Some aspects of the deformation behaviour and temperature rise during instantaneous compression loading of high purity aluminium, by H. J. E. Hamel Computer control of flotation at the Ecstall concentrator, by M. P. Amsden, C. Chapman, and M. G. Reading Optimizing the public gains from the exploitation of mineral resources, by A. Azis and J. Zwartendyk October, 1972 Presidential Address: Nuclear energy: its interactions with mining and metallurgy, by J. P. Hugo Presidentsrede: Kernenergie: sy wissel-werkinge met mynbou en metallurgic, deur J. P. Hugo Raise-boring experiences in the gold mines of the Anglo American Corporation Group, by J. W. Wilson and P. C. Graham November, 1972 Materials for winding plant components, by G. T. van Rooyen An analytical solution to the batch-comminution equation, by R. P. King A new approach to the study of human factors in stope productivity, by A. C. Lawrence Fundamental studies of the flotation process: the work of the National Institute for Metallurgy, by N. P. Finkelstein and V. M. Lovell Growing use of deionised water in surface coating techniques, by W. F. Lorch December, 1972 The development and application of a computer system to aid in the planning of production in mines, by F. H. Deist, L. F. Duvel, J. D. Austin, and H. D. Small PERT, and how PERT techniques can be used in modern mine management, by E. J. Boome and A. C. Schmidt A critical comparison of specific cooling power and the wet kata thermometer in hot mining environments, by J. de V. Lambrechts January, 1973 Liquidus temperatures in the Cr-Fe-Si system in the composition range representative of ferrochromium-silicide produced in South Africa, by J. C. M. Wethmar, D. D. Howat, P. R. Jochens, and O. A. W. Strydom Platinoids in the Witwatersrand System, by C. A. Cousins The development of a continuous recording scintillation counter mounted on a cyclometer, by P. D. Teens and D. Visser February, 1973 Computer analysis, modelling, and optimisation of gold recovery plants of the Anglo American Group, by M. I. Brittan and E. J. J. van Vuuren The significance of the mineralogical and surface characteristics of gold grains in the recovery process, by C. E. Feather and G. M. Keen Statistical valuation of diamondiferous deposits, by H. S. Sichel March, 1973 The effect of the reactivity of lime on desulphurisation efficiency in the basic oxygen furnace, by A. A. Hejja, D. D. Howat, and P. R. Jochens A review of real-time particle size analysers, by A. L. Hinde In situ measurements of the surface heat transfer coefficient in underground airways, by K. R. Vest April, 1973 An investigation into the kinetics and mechanisms of the oxidation of iron (II) by oxygen in aqueous chloride solutions, by R. P. Colborn and M. J. Nicol Electric smelting at Rustenburg Platinum Mines Limited of nickel-copper concentrates containing platinum-group metals, by J. C. Mostert and P. N. Roberts Metallurgical considerations in the

Jan 10, 1973

By G. E. Rencken, J. H. Potgieter, A. Narain, J. Smith

To conserve fresh water resources and comply with environmental regulations, DRDGOLD, a South African gold producer re-treating surface tailings, has transitioned to a fully closed water circulation system. Consequently, the accumulation of contaminants, as well as addition of reagents, has led to changes in water composition that have compromised leach performance and overall gold recovery. A two-sample t-test confirmed a significant difference in gold recoveries between the use of Rand Water, which was used as a benchmark, and untreated process water. Atomic absorption analysis of ERGO’s process water, confirmed the presence of iron, nickel, zinc, and manganese. A study of the effect of the identified contaminants on gold recovery showed that iron, nickel, and zinc have the largest negative effect on gold recovery, with iron and nickel being more detrimental than zinc. Sulphates were shown to have a possible passivation effect, which also influenced gold recoveries, although to a lesser extent than the heavy metals. Calcium, when present in excess, had a positive influence on gold recovery indicating the possible formation of a calcium aurocyanide complex. Lime softening successfully reduced the heavy metal and sulphate concentrations, and the gold recoveries obtained with the treated process water were similar to those as achieved with Rand Water.

Jul 1, 2021

By J. D. Zhou, F. Yang, X. G. Bi

"In this investigation, the phosphorus distribution ratios in the CaF2 system and B2O3 system dephosphorization slags for high-phosphorus hot metal pretreatment were measured by an indirect method under laboratory conditions. Firstly, the phosphorus distribution ratio between liquid slag and solid iron was measured, and then the phosphorus distribution ratio between liquid slag and hot metal was calculated. Phosphorus capacity was calculated in terms of the composition and optical basicity of the slag. Dephosphorization slag was also studied by scanning electron microscopy, energy dispersive analysis, and X-ray diffraction analysis. The experimental results show that the phosphorus capacity of the B2O3 slag system is much greater than that of the CaF2 system. It is demonstrated thatB2O3 can completely replace CaF2 as fluxing agent for high-phosphorus hot metal pretreatment. With CaF2 as fluxing agent, the phosphorus capacity increases with increasing CaO content in the slag, but the phosphorus distribution ratio decreases. B2O3, when used as fluxing agent, can react with high melting point phases such as 2CaO·SiO2 and 3CaO·P2O5 in the slag to form new phases with low melting points such as 11CaO·B2O3.4SiO2, 2CaO·B2O3.SiO2, and Ca9.93(P5.84B0.16O24) (B0.67O1.79), thereby acting as a fluxing agent. When the ratio of w(B2O3)/w(CaO) is 0.16, the phosphorus distribution ratio reaches its maximum value, that is, the dephosphorization ability of the slag is at its maximum. IntroductionAs international iron ore prices continue to rise, the development of China's steel industry is facing a lot of pressure. Against this background, development and utilization of domestic high-phosphorus iron ore resources is particularly important. When highphosphorus iron ore is used in ironmaking, the phosphorus content in the hot metal can reach 0.35% or more, and the hot metal must be pretreated. For hot metal with 0.08–0.10% dissolved phosphorus, the traditional hot metal dephosphorization pretreatment technologies are relatively mature. However, when using these methods to dephosphorize hot metal containing 0.35% P or more, the amount of dephosphorization slag can reach 100–150 kg per ton of hot metal. Furthermore, the traditional dephosphorization methods require the addition of large amounts of CaF2 as fluxing agent, and this results in high fluoride levels in the dephosphorization slag. The fluorine in the slag can partially dissolve in water and thereby causes high fluoride concentration in the water and soil. Once the fluoride is absorbed by humans or animals, it can result in toxic effects on the central nervous system and myocardium. In addition, fluoride can accumulate in the environment, and thereby pose a health risk to animals and humans through the food chain (Li, 2007; Liu, Wang, and Dong, 2011, Diao, 2013). The objective of this research is to replace CaF2 with B2O3 as fluxing agent while achieving the expected goals of hot metal pretreatment."

Jan 1, 2016

The AMIRA Code of Practice and Guidelines for Metal Accounting was developed in response to demand from a number of sponsor companies, including one major platinum producer. Since its publication in 2007, the Code has become widely accepted in the mining industry world-wide as a guide for best practice in metal accounting. With the changes in the structure of the platinum mining industry in South Africa over the last 10 ? 15 years, in particular, the starting up of a number of small platinum producers who must have their concentrate smelted and the contained valuable metals refined by third parties, the need for metal accounting systems that are accurate and have an acceptable level of precision has become even more critical to the success of a platinum-producing operation. The current state of metal accounting in the industry is discussed and possible areas for improved accounting and associated metallurgical efficiencies are identified.

Jan 1, 2012

By S. Stone

Because of problems encountered with conventional timber supports, a system of concrete sausageshaped support pillars was tested. The pillars are 3 m long, 0,6 m wide, and between 70 and 80 cm high (the height of the stoping width). They consist of bags filled with a grout of cement (slagment and sand in the ratio of I :2, and are installed in a staggered pattern 6 m apart on dip and 2 m apart on strike. These support packs have proved successful, and, although they cost more than the timber supports formerly used (R4,63 per cent are supported as against R2,26 for the conventional timber pack), their use is felt to be justified when account is taken of the costs of lost production and low productivity due to the bad hangingwall conditions that occurred with the conventional system.

Jan 1, 1978

By K. A. du Preez, P. J. van Staden, M. van Rooyen

Mine-impacted water, including acid mine drainage (AMD), is a global problem. While precipitation of dissolved metals and neutralization of acidity from mine-impacted water is accomplished relatively easily with lime addition, removal of sulphate to permissible discharge limits is challenging. This paper presents a high-level comparison of four sulphate removal technologies, namely reverse osmosis, ettringite precipitation, barium carbonate addition, and biological sulphate reduction. Primarily operating costs, based on reagent and utility consumptions, are compared. Each process is shown to be subject to a unique set of constraints which might favour one over another for a specific combination of location and AMD composition. Access to and cost of reagents would be a key cost component to any of the processes studied. The total cost calculated for each process also depends on the type of effluents that are allowed to be discharged.

Oct 1, 2021

By C. Chingwaru, W. Chingwaru, J. Vidmar

"Zimbabwe is endowed with rich deposits of minerals such as diamonds, platinum, coal, uranium, lithium, gold, antimony, iron, and chrome. Bioleaching has been implemented as an efficient and low-cost method to extract metals such as copper, cobalt, and gold from sulphide and/or ironcontaining ores and mineral concentrates in a number of countries around the globe. Zimbabwe, despite being a world leader in mineral wealth, has gone through years of economic stagnation which have brought with them energy shortages. Bioleaching is an innovative way to recover minerals from ores using relatively low-capital-cost and non-polluting technology. Principally, iron- and sulphur-oxidizing bacteria can be used to oxidize iron and sulphide to ferric iron and sulphuric acid, respectively, and the ferric iron oxidizes the insoluble metal sulphides to soluble metal sulphates that can be readily recovered from solution. Although some minerals such as gold are inert to biological reactions, they can be liberated using bacteria that act on certain types of ores and other minerals that co-occur with these minerals. The geology of the mineralized areas in Zimbabwe, rich in chalcopyrite / pyrite, allows a number of microorganisms to be used for the extraction of minerals by bio-oxidation. This paper reviews the potential of bioleaching in the country. IntroductionZimbabwe has rich deposits of minerals including diamonds, platinum, coal, uranium, lithium, gold, antimony, iron, and chrome. Bioleaching is defined as the use of microorganisms to facilitate the extraction of metals from sulphide or iron-containing ores or concentrates (Rawlings, 2004, 1997). Bioleaching has been shown to be an efficient (Blowes, Ptacek, and Jurjovec, 2003; Nordstrom and Southam, 1997; Schippers, 2004) and low-cost (Schippers et al., 2010) method to extract minerals in many countries around the globe. For example, aerobic Fe(II)- and sulphur-oxidizing bacteria have been shown to be up to two orders of magnitude more efficient in the oxidation of pyrite than the chemical processes (Blowes, Ptacek, and Jurjovec, 2003; Nordstrom and Southam, 1997; Schippers, 2004). Additionally, bioleaching can be used to extract minerals from low-grade ores, sulphidic waste rock dumps, and tailings efficiently (Schippers et al., 2010)."

Jan 1, 2017

By K. Sasaki, S. Kuroiwa, H. Miki, Y. Aoki, T. Hirajima, Y. Orii, G. P. W. Suyantara

Selective flotation to separate copper minerals from, for example, Mo- and/or As-bearing minerals is a continuing problem because the selectivity of current systems is imperfect. Selective Cu-As flotation is currently difficult, and the most common Cu-Mo selective flotation method uses NaHS; this must be done in an enclosed system because, under acidic conditions, this method produces hydrogen sulfide. In this paper, some novel alternative flotation processes that use redox reactions are discussed; these methods have a much lower environmental impact. Oxidation and reduction reactions can be used to make copper minerals more hydrophilic and Mo-bearing minerals more hydrophobic. X-ray photoelectron spectroscopy (XPS) analyses indicated that the copper minerals became hydrophilic because hydrophilic iron precipitated and several hydroxides covered the copper minerals’ surfaces, whereas the molybdenum minerals remained hydrophobic because their sulfide surfaces were not covered. Flotation experiments on these minerals after redox treatments indicated that excellent separation of Cu-minerals from Mo-minerals can be achieved. Possible mechanisms for this separation were investigated using detailed surface analyses and thermodynamic calculations. The additives used to initiate the redox reactions are easy to handle and make these new flotation procedures better than current processes because the new methods do not emit effluent gas and because they are commercially viable. Keywords: Flotation; chalcopyrite; molybdenite; oxidation; reduction

Jan 1, 2020

By O. T. Konina, V. A. Masloboev, A. V. Svetlov, E. A. Krasavtseva, D. V. Makarov, A. A. Goryachev

Dusting phenomena have been examined at the tailings storage facility of Apatit JSC Kirovsk, a mining operation located in the far north of the Russian Federation. The material composition of the tailings was identified. Existing dust suppression methods were examined. Field observations were undertaken and official data was obtained from the Murmansk Administration for Hydrometeorology and Environmental Monitoring, and analysed. A database was built for forecasting dusting according to critical scenarios in order to estimate the peak MPCs of suspended solids in the atmospheric air. Mitigation measures were formulated and recommended to the mining operation. Keywords: Mineral dust particles, apatite-nepheline ore concentration tailings, suspended solids MPC, climate change

Jan 1, 2020

COUNCIL The following served on Council during the year under review: Office bearers: Prof D. D. Howat (President), Dr J. P. Hugo and P. W. J. van Rensburg (Vice-Presidents), V. C. Robinson (Immediate Past President) and D. G. Maxwell (Honorary Treasurer). Ordinary Members of Council: H. P. Carlisle, R. C. Espley-Jones, G. H. Grange, Dr D. I. Legge, W. W. Malan, Prof R. P. Plewman, Dr R. E. Robinson, Dr M. D. G. Salamon, L. W. P. van den Bosch and P. A. von Wielligh. Branch Chairmen: A. Bain (Witbank-Middelburg Branch), J. M. Meyer (O.F.S. Branch). Past Presidents serving on Council: R. J. Adamson, M. Barcza, H. Britten, H. E. Cross, J. K. E. Douglas, R. C. J. Goode, P. Lambooy, Prof J. de V. Lambrechts, Dr J. T. McIntyre, J. F. Reid and H. Simon (until March 1972). Ten Council meetings were held during the year with an average attendance of nineteen, and the standing committees held 27 meetings. FINANCE The annual accounts which are attached to this report show an excess of income over expenditure of R21 519. It is very gratifying to be able to report that Council's efforts to stop the depletion of our accumulated funds are meeting with success. The most important contributors to our surplus this year are symposia and colloquia, sales of publications, Company Affiliate subscriptions and the profit on the journal. While we do not expect continued profits from all these sources in the future we do feel that we are now in the process of accumulating a substantial financial foundation. This will give the Council the necessary confidence to initiate the new developments in the activities of the Institute which are now under consideration. The decision to create a new grade of membership, Company Affiliate, is dealt with elsewhere in this report. There has been a generous initial response from companies and this is the cornerstone of our improved financial expectations. The MacArthur Forrest Memorial Fund shows an excess of income over expenditure of R91 and the total fund was, therefore, increased by this amount to R4 502. The balance sheet shows that the market value of quoted shares and debentures increased during the year from R9 160 to RH 331, which is R2 134 in excess of the book value. Accumulated funds now amount to RH 529 compared with R23 010 a year ago. MEMBERSHIP Sixteen Fellows, twenty Members, six Graduates, nine Associates, twelve Students and twenty-four Company Affiliates were elected during the year. One Member and two Associates were reinstated. Twelve members were admitted to retired membership. Transfers: Member to Fellow, three. Graduate to Member, seven Associate to Fellow, one. Student to Member, one. Student to Graduate, four. Student to Fellow, one. Your Council records with deep regret the death during the year of the following: Dr A. J. Orenstein (Honorary Life Fellow), R. A. Cooper, R. J. Spargo, H. Simon and F. Meyer (Life Fellows), S. D. Loxton, W. P. Arnold, G. C. Needham, W. G. Pyne-Mercier, J. Innes and O. T. Wright (Fellows), E. P. Mennell and O. B. Prentis (Members), J. Brits (Associate). After careful consideration of all the implications it was decided during the year to create a new grade of membership to be known as Company Affiliate, in order that there might be a formal and permanent channel for companies to contribute to the important work of the Institute. As recorded above, 24 companies had joined by the end of the year and many further applications have been received since. We extend a hearty welcome to all our new members. A comparative statement of membership as at 30th June, 1972, and the end of the previous year is shown in the following tabulation:-

By V. I. Ryaboy, V. P. Kretov, I. V. Ryaboy

Attachment of collectors containing thioamide groups to sulfide minerals is interpreted as interaction between NH-acids and sulfides acting as solid bases with the formation of a donor–acceptor reagent–mineral bond. As the acid function of the reagents increases, their sorption optimum is observed to shift to a less alkaline region. The developed concept has enabled us to propose a method for calculating optimal pH values for the sorption of reagents on mineral surfaces depending on the acidity of the reagents and the pH value of the medium. Our estimates correlate well with the experimental data. We studied the spectra of the reagents containing thioamide groups and the spectra of copper salts and their surface compounds on an oxidised copper film, chalcopyrite, and pyrite using the infrared (IR) spectroscopy. Some effective applications are described of reagents containing thioamide groups in the flotation of copper, copper-molybdenum, and gold ores, both separately and in combination with other collectors. It is shown that the flotation performance is maximised by adding two- and three-component collector combinations, including collectors containing thioamide groups. In this case, the increase in the recovery of copper, molybdenum, and gold is up to 2-5% compared to conventional process conditions. A new, high-performing reagent containing a thioamide group is proposed. A commercial pilot batch of the reagent was produced and sent for flotation tests in gold ore applications. Keywords: Thioamide reagents, dialkyldithiophosphate, collectors, flotation, arsenopyrite, chalcopyrite

Jan 1, 2020

By R. B. Khumalo, T. Chauke, T. Mtshali, F. K. Mulenga, B. Makgate, N. M. Chiloane, T. Moyane, V. C. Madanda

While high production rates are important for the profitability of a mine, the influence of geotechnical engineering cannot be ignored. In block caving, a high-stress level is required for cave propagation; this is one of the core elements for ore recovery. Therefore, stress distribution and geological structures play a major role in the planning and layout design of the mine. This paper explores the influence of stress and geological features on the design of the mine from the feasibility study phase. The geology and stress measurement of the mine were determined through logging and overcoring, respectively. This study found that while production rate is the primary operational consideration, the long-term layout design of the undercut face advance, face angle, drawpoint spacing, and undercutting sequence is mainly governed by the stress orientation and major geological structures. Moreover, widely spaced drawpoints result in isolated draw zones, consequently, resulting in ore loss and early dilution whereas closely spaced drawpoints affect the stability of the major apex pillar. This paper also provides insight into how operations can leverage stress distribution to optimise mine layout and safety in massive mining methods.

Nov 24, 2025

By M. J. Voigt, R. A. Govender, A. Mainza, L. Bbosa

"Mineral texture is a critical factor which controls ore variability and is an important attribute in geometallurgy. In relation to downstream processes, it affects the fracture pattern during breakage, where rock strength is inherently a function of mineral texture. Because of the subjective nature of mineral texture, it has not been easy to quantify, especially in the context of a measurement suitable for use in geometallurgical programmes. The aim of this paper is to present the first steps in developing a 3D mineral texture quantification method for drill core and to assess its sensitivity to differences in rock strength using a case study. The methodology includes classifying the textural information using the 3D grey level co-occurrence matrices (GLCM) and X-ray computed tomography (XCT) coupled method. Rock strength tests were performed using the split Hopkinson pressure bar (SHPB). The case study investigates a heterogeneous polymetallic sulphide deposit and a homogeneous shale subdivided into three ’mineral textural types’. The variability is largely captured by the GLCM matrices, and preliminary trends can be observed where the shale is finer grained and has a higher yield strength in comparison with the coarser grained polymetallic sulphide ore. IntroductionModern mining requires the exploitation of lower grade and more complex, heterogeneous orebodies to address the growing industry demands. Historically, processing plants were designed and built based on average ore characteristics and therefore are relatively inflexible when facing the full spectrum of ore variability in heterogeneous orebodies (Lamberg, 2011; Lotter, 2011; Schouwstra et al., 2013). The practice of geometallurgy represents an opportunity to manage ore variability in the mining industry (Powell 2013; Baum, 2014; Yildirim et al., 2014; Nguyen, 2013). It focuses on quantifying the relationships between ore characteristics and their downstream mining and processing responses, often starting with small-scale laboratory testing. The purpose of geometallurgy is linked to maximizing the net present value (NPV) of an orebody by minimizing technical and operational risk – where ‘ore variability’ is considered one of the most significant technical risks."

Apr 1, 2019

By A. Doroudgar, H. Noferesti

Unstable rock failure or rock bursting is one of the most dangerous problems in deep hard rock mines. This type of failure, that occurs uncontrollably, is associated with a significant release of strain energy from the surrounding rock. In this study, the numerical simulation of unstable rock failure was carried out using the three-dimensional explicit Lagranian finite-volume finite difference method to identify the onset and location of unstable failure events in the model. On this basis, a numerical simulation of mine pillars with width-to-height ratios of 0.5, 2 and 3 was performed. A criterion was developed, based on the calculation of the elastic strain energy, to determine the prone areas for the initiation of rockburst in the models. The results of this study showed that, in softer loading systems, due to large amounts of stored elastic strain energy, an unstable equilibrium is established, which leads to the rapid transfer of strain energy to the rock in the form of violent failure. It was also found that the unstable failure starts at the corners and free surface of the model. The new criterion developed in this study may help predict the occurrence of rockbursts in slender pillars and the design of pillars to control human and financial losses caused by this phenomenon.

Nov 27, 2024

By S. J. Baumgartner

The ferromanganese industry is under pressure to deal with the slag arising from the production of ferromanganese, which is discarded in landfills or slag heaps. This material poses an environmental and health risk to surrounding ecosystems and communities, and disposal costs are increasing. Ferromanganese slag contains an appreciable amount of residual manganese metal, which can be exploited. Previous work has shown that the slag can be leached fully, while rejecting the silica to a residue. The methods that were investigated to recover manganese from the leach solution included hydroxide precipitation to upgrade the leach solution followed by manganese carbonate precipitation to produce a pure manganese carbonate product or a manganese carbonate furnace feed material, which would be recycled to increase manganese recoveries in the production of ferromanganese. In addition, electrowinning of electrolytic manganese dioxide from the leach solution was studied. The methods were compared in terms of selectivity, costs, and product quality. Co-recovery of the leach residue, which is a potential cement additive, is discussed. Among the methods investigated to upgrade the pregnant leach solution, hydroxide precipitation utilizing ammonia to adjust the pH appears to be the most effective in removing major impurities such as iron, aluminium, and silica to less than 1 ppm. The manganese carbonate and impure manganese carbonate furnace feed products met quality specifications. However, although the production of these materials was technically viable, the large amounts of base reagent that were required to raise the pH, and the associated high operating costs, rendered the process uneconomic. An optimization study was therefore carried out with the primary objective to determine the ideal acid amount to be utilized in the waterstarved digestion stage, thereby decreasing acid and base consumption while optimizing the quality of the pregnant leach solution, and producing a leach residue that contained <1% Mn. The outcome was an economically viable process. Additional benefits included an increase in the manganese content of the impure manganese carbonate furnace feed material, and a substantial reduction in the dilution of the pregnant leach solution, thereby maintaining high manganese concentrations that rendered the solution viable for electrowinning of electrolytic manganese dioxide, the production of which yielded a current efficiency of 74%.

Jan 1, 2014

By R. H. Matjie, J. R. Bunt, A. C. Collins, J. C. van Dyk, C. A. Strydom

South African discard coal fines and K₂CO₃ blends were heated in a laboratory-scale rotary kiln to produce ashes for H₂SO₄ leaching tests. The optimized H₂SO₄ leaching conditions of 6.12 mol.dm³ (M) H₂SO₄, solid to liquid ratios 1:5 and 1:10, and 80°C for 8 hours were used. K₂CO₃ was added to increase the dissolution efficiency of K. The objective was to determine if the Al present in metakaolinite (Al₂O₃.2SiO₂), the Al, K, and Ti in the alumino-silicate glasses, and the Ti in rutile (TiO₂) in the ashes could be selectively dissolved in H₂SO₄. XRF results show that the ashes formed at 700°C dissolved more efficiently (87% Al, 89% K and 23% Ti) compared to the ashes formed at 1050°C. This can be attributed to the presence of Al₂O₃.2SiO₂, K₂CO₃ melt, K₂CO₃ remnants, KAl(SO₄)₂, and K-aluminosilicate glass in these ashes. XRD results indicate that the ashes prepared at 1050°C contained anorthite (CaAl₂Si₂O₈), microcline (KAlSi₃O₈), pseudomullite (Al₂O₃.SiO₂), and silicon spinel (2Al₂O₃.3SiO₂), which are either insoluble or only sparingly soluble in H₂SO₄. These minerals resulted in the lower dissolution efficiencies of Al and K. Based on the high dissolution efficiencies of Al and K for the ashes produced at 700°C, coal fines blended with K₂CO₃ could possibly be utilized as feedstocks for the production of aluminium(III), potassium(I), and titanium(IV) and a sulphate-containing leach liquor. Furthermore, the environmental issues and costs associated with the handling and disposal of large volumes of coal fines will also be resolved.

Aug 2, 2022