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By J. P. Jylhä, A. Jokilaakso

The Outotec Flash Smelting process is widely used in primary copper production. A layer of slag on top of matte (copper–iron sulphide melt) creates a barrier through which matte droplets descend. Droplets of different sizes settle through the layer at different rates, which increases possibility of copper losses as smaller matte droplets may be removed with the slag. In this work CFD-DEM (computational fluid dynamics – discrete element method) coupling was used to simulate matte droplets settling through the slag during slag tapping. Discrete droplets and slag flow were simulated with DEM and CFD, respectively. This new approach enables tracking and solving movement and interactions of individual droplets. User-defined models were created to take coalescence and reaction kinetics into account. Coalescence created larger droplets, while the reactions decreased droplet size and increased its density. Drag caused funnelling effect, which pulled droplets towards the centre line of the descending cluster. This research is the only study known by the present authors in modelling liquid-liquid systems with the CFD-DEM coupling. Simulating coalescence and chemical reactions for discrete droplets enables more realistic simulations. However, CFD- DEM simulations are computationally resource intensive already without additional models, so a full scale industrial settler modelling still waits for further increase in computer performance. INTRODUCTION Flash smelting is a method used in copper and nickel production. In the flash smelting process, oxidation of sulphides in a concentrate is used to release energy needed to smelt the feed. In the process, copper matte is formed. Matte has copper content in the range of 55 – 70% (Sridhar, Toguri, & Simeonov, 1997), the rest is mainly sulphur and iron but has still many other impurities (Taskinen, Seppälä, Laulumaa, & Poijärvi, 2001). Oxidized iron forms iron-silicate slag while SO2 is collected for acid production (Davenport & Partelpoeg, 2015). The Outotec flash smelting furnace (FSF) can be divided in four major component: concentrate burner, reaction shaft, settler and uptake. Concentrate, flux and oxygen enriched air are injected into the reactor through the concentrate burner. The mixture then reacts in the reaction shaft forming matte and slag, which are collected in the settler, while off-gases flow out of the reactor through uptake for heat and dust recovery, and SO2 collection for H2SO4 production. The matte and slag form separate layers due to immiscibility and density difference. Raw material feed is continuous, but the matte and the slag are tapped periodically. A flash smelting furnace is depicted in Figure 1.

Jan 1, 2019

By Stephen Hardcastle

Supplying ventilation in underground metal mines can be one of the most energy demanding services required to support production activities. Consequently, as energy, in the form of electricity or combustible fuels can be expensive and their unit cost is expected to increase, there is significant interest in reducing the overall demands of a mine?s ventilation system through such initiatives as controlling ventilation based upon demand and exploring other power alternatives to the current usage of the diesel engine in mobile mine vehicles. However, determining the benefit of any energy saving technology is complex and not universal applicable across the industry, consequently they have not been widely adopted. For these technologies to succeed they must be strategically applied based upon sound business cases. The intent of this paper is to provide information on some of the prospective control strategies and their potential impact on the power consumption related to supplying ventilation.

May 1, 2007

By Harry Siewert, Tom Milner, Jack Stickney

"LocationThe Gibraltar mine is located in central British Columbia (NTS 93B/9W), 362 km north of Vancouver. Access is provided by 20 km of paved road from McLeese Lake, which lies 45 km north of Williams Lake on Highway 97. Latitude and longitude of the mine are 52° 30' and 122° 16', respectively.The total area of the McLeese Lake site is approximately 1700 ha (4200 acres). This includes the orebodies, dumps, surface drainage collection system, plant site, roads and tailings ponds.Brief Description of OperationOre is mined by open pit methods and is concentrated using conventional crushing, grinding and flotation processes. Copper and molybdenum flotation occurs at an average rate of 40 000 tons per day. Tailing is discharged to an impoundment area and the water recycled as process water. Additional copper is extracted from the waste dumps using sulphuric acid as a leach solution followed by solvent extraction and electrowinning.HistoryExploration by Gibraltar began in 1964, continuing until late 1970, at which time it was announced that the property would go into production. Construction started in early 1971, with initial production in March 1972. Target capacity of 30 000 tons per day was achieved by the end of March and is currently at 40 000 tons per day.Ore reserves as of January 1, 1998 were 184 384 000 tons grading 0.31% Cu and 0.010% MoS2."

Jan 1, 2000

By N. Dufresne

"The evolution of mining methods at Brunswick Mining and Smelting shows that, in the case of a large deposit, technology must adapt itself to changing conditions. As problems are encountered, management must modify their approach if they hope to meet production quotas. This search for new and better ways started with the opening of the No. 12 orebody and is still going on today.From large-scale open stoping, the Brunswick Mining and Smelting operation went to transversal cut-and-fill, then to longitudinal cut-and-fill, which is the main mining method now employed. However, to solve certain problems experimenting with Avoca methods was initiated. Rebar grouting and prepinning have also made significant contributions toward securing relatively poor ground in the hanging wall and holding badly fractured backs in wide stoping areas. Introduction In 1952, M.J. Boylen had incorporated Brunswick Mining and Smelting Corporation Limited to develop his recently found No.6 and No. 12 orebodies near Bathurst, New Brunswick. Between 1953 and 1957, St. Joseph Lead Company was brought in to try and initiate mining . During those years, St. Joseph Lead sunk two shafts at No. 12-No. 1 to 425 feet below surface and No.2 to 982 feet. They also developed the 200 and 350 levels to sample the ore at depth and operated a 100-tpd pilot plant at the No.6 mine. However, due to low recoveries and depressed metal prices. the project was shut down in 1957.A group including M.J. Boylen. K.C. Irving. Maritime Mining Corporation and Patino Corporation reacquired the property from St. Joseph Lead Company in 1961. New financing was arranged involving La Societe Generale des Minerais, S.A . of Belgium and Engineering Consultants Limited of Saint John. New Brunswick. During the years 1962 and 1963, construction of surface and underground facilities progressed rapidly."

Jan 1, 1981

By G. Tairova, M. Murchie, B. Esford, E. Lam

"The objective of this project is to investigate methods to lower the sulphate concentrations in the mill effluent. Currently, the concentration of sulphate in mill effluent is approximately 2 g/L. The high concentration of sulphate ion in the effluent has the potential to become a regulatory issue. The target sulphate concentration in mill effluent for this work was less than 500 mg/L. The pilot studies, using sulphate precipitation, were carried out at the mill. The results of the sulphate precipitation pilot study, using calcium hydroxide and sodium aluminate, indicated that:• The sulphate concentrations in effluent could be reduced to less than 500 mg/L.• The concentrations of most other elements of concern, such as selenium, arsenic, cobalt, nickel and vanadium, were also reduced.INTRODUCTIONHistorically, the concentration of sulphate, SO4 2-, in water has not generally been subject to regulation. However, with the increasing global consumption of water, stricter regulations on sulphate quantity may be imposed. Sulphate is a concern in process waters as it forms scale on process equipment and leads to operational problems. High sulphate concentrations may result in adverse health effects. The taste theshhold for the most sulphate salts in drinking water ranges from 250 to 500 mg/L.A literature search and review to identify methods to reduce sulphate concentration in the mill effluent was carried out. A number of methods were selected and tested in the lab. The experimental results indicated that the precipitation methods, using calcium hydroxide and aluminum compounds, barium compounds, as well as the ion exchange and the membrane methods, were effective for the removal of sulphate to below the required limits. Some other elements, such as vanadium, nickel, cobalt, selenium and molybdenum, were also removed.The process, using calcium hydroxide and aluminum compound for sulphate precipitation, similar to the Cost Effective Sulphate Removal (CESR), also known as “Walhalla” process, described in the Montana Tech report (“Demonstration Of Sulfate Removal” 1999), was selected for further consideration [1]. In the CESR process, the water is treated with lime for precipitation of gypsum, followed by the reaction with a proprietary aluminum compound for removal of a residual sulphate. The final pH adjustment is carried out using carbon dioxide. Results of a preliminary cost estimate indicated that the removal of sulphate using calcium hydroxide and aluminum compound was the preferred method of treatment, considering its low cost, availability of chemicals and minimal changes to the existing plant circuit."

Jan 1, 2012

By P. K. Kaiser, C. D. Martin, F. Amann

"This article focuses on the uniaxial compressive strength (UCS) of homogeneous and heterogeneous rocks. Critical factors impacting the UCS of rocks are reviewed and then separate assessments of UCS data from homogeneous and heterogeneous rocks are presented. The variability (coefficient of variation) of UCS test results for homogeneous rocks is found to be generally <25% while for heterogeneous rocks the variability is >35%. Failure mode variation is found to be the cause of the variability of UCS test results in heterogeneous rocks. Empirical engineering design methods that use UCS as an input parameter are discussed and suggestions are provided for selecting appropriate UCS values.INTRODUCTIONThe UCS is one of the most commonly used rock engineering parameters whether for rock mass classification or for strength determination. The mean UCS and its variability are often assumed to represent a reliable rock material property. For the reasons discussed in this article, UCS is rarely representative of the intact rock UCS. The UCS test simply records the collapse load during uniaxial loading of a cylindrical specimen. As suggested by many, the UCS is an index rather than a unique engineering parameter. The UCS is thus a proxy for rock strength which depends on the loading rate (e.g., Bieniawski 1967), specimen geometry (e.g., Hudson et al., 1971), specimen size (e.g., Bieniawski 1968), and many other factors. Furthermore, the UCS is not the same as the Hoek-Brown strength criterion parameter sci.There are differences in opinion on what is commonly considered to be ‘intact rock’. When sampling ‘intact’ pieces of core from drillholes crossing blocks of rock bound by block forming discontinuities, samples will be ‘intact’ but some samples will be veined, others will be damaged, and others will be neither. According to Hoek (1983), intact rock pieces are “the unfractured blocks occurring between structural discontinuities in a typical rock mass” and the sci parameter for intact rock is determined using the fitting procedure proposed by Hoek and Brown (1997) based on the data requirements outlined by Hoek (1983). Studies (e.g., Bewick and Kaiser 2014; Kaiser and Kim 2014) have shown that independently determined UCS and sci values for the same rock type are not equivalent. Thus, UCS data cannot be used as a replacement for sci."

Jan 1, 2015

By G. G. Eichholz

SUMMARY RADIOACTIVE dynamite has been prepared by introducing a small amount of antimony-124 into the explosive. Test work is described on the effectiveness of this tracer, on radiation levels in its neighbourhood, and on different methods of .application. Factors determining the choice of isotope, amount of activity, and overall cost of this process are discussed. INTRODUCTION Instances are known in which dynamite remains unexploded in drill holes in mining operations. Usually such &apos;bootlegs&apos; are easily located by inspection of the face and the powder is removed before subsequent drilling is started. Occasionally, however, serious accidents occur because workmen drill into an undetected piece of dynamite. In order to avoid such accidents it was suggested that a different method of location might be tied, such as that afforded by the use of radioactive tracers. This paper describes some experiments that were carried out under the auspices of the Department of Mines and Technical Surveys, with the active co-operation of Canadian Industries Ltd. and Canadian Refractories Ltd., to test the feasibility of such a scheme.

Jan 1, 1957

By Louise Corriveau, Bronwyn Azar, Valerie A. Jackson, Luke Ootes, Jeff Harris

We use the results of new bedrock mapping, combined with geochemical point data and airborne radiometric data (in particular equivalent uranium concentrations) to help determine which geological units in the Paleoproterozoic Great Bear magmatic zone (GBmz) contain elevated uranium. The data collectively indicate that the highest primary uranium concentrations are in equigranular granites and subvolcanic/volcanic porphyries. Notably, these rocks host the majority of known uranium-bearing deposits and/or prospects in the GBmz. We speculate that the uranium in these deposits/prospects was derived from nearby, uranium-enriched rocks and was mobilized by much younger, circulating hydrothermal fluids. Sedimentary rocks of the Thelon and Dismal Lakes groups unconformably overlie the GBmz and are known to host unconformity-type and sandstone-hosted uranium prospects. Most likely, the uraniumenriched rocks of the GBmz acted as a uranium donor to these overlying sedimentary basins. The method of investigation employed in this study may be applicable to other ‘granitic’ terrains in order to identify regions with favourable rocks for uranium exploration.

Jan 1, 2013

By Juliana Parreira

The past decade shows record increases in global demand for minerals and metals with an accompanying significant decline in skilled personnel. Mining companies today are examining new technologies to maximize production, reduce costs, and create safer work conditions to deal with this shortfall. Automation of an open-pit mine haulage system is receiving attention as a beneficial option since it provides more consistent and efficient operation of mining equipment, it removes workers from potential danger, it reduces fuel consumption significantly reducing greenhouse gas (GHG) emissions, and it can help optimize vehicle repairs and equipment replacement because of more-predictable and better-controlled maintenance. This paper describes a simulation model under development using the EXTENDSIM software package to examine scale-up issues and constraints of autonomous vehicles in comparison to a manual system. The software can predict and manage Key Performance Indicators (KPIs), such as productivity, safety, cost, equipment failures, fuel consumption, and tire wear under different road and load conditions. By breaking-down the various systems of an autonomous haulage truck and simulating the overall haulage system using a Monte Carlo approach, the model becomes a flexible and powerful tool to use within a mining organization. Direct comparison to a manuallyrun system can be done to show the cost and operational benefits of automation. Project managers can use this tool to guide decision-making about possible application of autonomous haulage trucks at a specific mine site.

May 1, 2010

By N. Romani, R. Provost

"Commissioning of a circulating dry scrubber plant was recently completed at an existing facility, in order to treat the sulphur dioxide off-gas emitted from rotary kilns. Proper planning of the different commissioning stages and staffing an integrated team are the most important factors required for a successful plant start-up. A strong operational readiness plan must be in place as early as the start of construction in order to ensure a smooth transition from commissioning to operations. Plant performance can meet or exceed performance criteria within the required timeframe if the proper group dynamic and good communication is established between construction, commissioning and operations teams.INTRODUCTIONCommissioning of a circulating dry scrubber (CDS) plant was recently completed at an existing facility in Quebec, Canada. The CDS plant treats the sulphur dioxide off-gas emitted from rotary kilns in order to meet increasingly stringent environmental requirements. This installation enables the existing facility to reduce their sulphur emissions by over 90%.The CDS ProcessA general overview of the CDS process is presented in Figure 1 below. The combined, de-dusted off-gas from multiple kilns is sent to the CDS, which acts as an entrained fluid bed, where the gas is contacted with a water mist, re-circulated solids and hydrated lime. The SO2 from the gas stream and the available calcium hydroxide (Ca(OH)2) from the hydrated lime dissolve in the water and react to ultimately form calcium sulphites and gypsum. The solid residue (referred to as CDS residue), is the primary byproductof the process.Fresh hydrated lime and CDS residue is captured by the dust collection system and is re-circulated to the CDS via a fluidised transport system. Clean off-gas passes through the dust-collection system and is then sent to the atmosphere by a single exhaust fan.The CDS residue purged from the system is combined with the dust collected from the kiln offgas system and this mixture is wetted in the already exiting agglomeration system, to minimize dust generation during handling, and then sent to disposal."

Jan 1, 2016

By V. S. Papezik

Pyrophyllite, an AI silicate used in the production of ceramic materials, is formed mainly by alteration of felsic to intermediate volcanic rocks, either directly (at temperatures of 250-300°C and pressures of 1-2 kbar) or by subsequent low-grade metamorphism of aluminous protoliths produced by thermal fluids or even by prolonged weathering. Most pyrophyllite deposits in North America are concentrated in a belt of Late Precambrian volcanic and sedimentary rocks, the "Avalon Zone ", which extends along the eastern flank of the Appalachian mountain system from Newfoundland to the southeastern U.S.A. The only producing pyrophyllite mine in Canada is an open pit located near the settlement of Foxtrap on the Avalon Peninsula of Newfoundland. It lies in a belt of rhyolitic flows and pyroclastics intruded by a granitoid pluton. The rocks have been leached along a shear- or fracture zone, depleted in silica, alkalies, Ca, Mg and Fe by the action of hydrothermal fluids, and recrystallized to a very fine-grained massive assemblage of pyrophyllite, muscovite ("sericite") and quartz. High-grade pyrophyllite lenses contain small nodules of diaspore with minor barite; rutile is present in trace amounts. The close proximity of all pyrophyllitized zones on the peninsula to the granite contact suggests that the alteration was produced by thermal fluids genetically connected with the granitoid pluton. The fine-grained pyrophyllite-bearing rocks, with their simple mineralogy, are suitable for quantitative modal analysis by X-ray diffraction. Chemically analyzed samples from the alteration zone were used for the construction of working curves by plotting calculated mineral content against the intensity of selected diffraction peaks. The accuracy of the resulting curves is ±4.5% for quartz, ±3.6% for pyrophyllite and ±2.7% for muscovite. Pelletized samples give best results. The XRD method is suitable for a rapid analysis of a large number of grab or core samples to outline higher-grade areas for more detailed sampling.

Jan 1, 1978

Diverse and considerable energies are associated with mobile equipment operated and maintained on mine sites. Loss of control of these energies is a common cause of injury on mine sites and this is well recognised by the mining industry. In 2006, 4 multi-national mining companies formed the Earth Moving Equipment Safety Round Table (EMERST), with the aim of engaging collectively with the manufacturers of equipment to accelerate improvements in mining equipment design. Originally focused on surface mining equipment, and particularly haul trucks, the focus of EMESRT widened to include underground and exploration equipment. Since 2006, EMESRT has maintained a program of regular visits and other engagements with a steadily increasing number of manufacturers. The membership of EMESRT has also increased, with 15 companies being members in 2012. An initial step undertaken by the EMESRT members was the development of ?Design Philosophies? which drew of the collective experience of mining companies to identify potential unwanted events which cause equipment related injuries and illness. A technique for analysing risks associated with operation and maintenance tasks, the Operability and Maintainability Analysis Technique (OMAT), was subsequently developed and trialled. In 2011, the EMERST members resolved to propose a common form of safe design information to be requested by all members companies during procurement, and the resulting EMERST Design Evaluation for Equipment Procurement (EDEEP) process was launched at MINExpo in Las Vegas in September 2012. The outcomes of OMAT risk assessment and control activities are integrated during this process into a common ?Safe Design Information? template for communication to prospective purchasers. The aims of requesting manufacturers to follow this process are to provide equipment purchasers with a common way of assessing how well the issues in the EMESRT Design Philosophies are addressed in the equipment design; and to provide manufacturers with additional information for use during equipment design. The process involves identifying priority tasks based on frequency and the severity of the consequences of potential unwanted events identified in the EMESRT Design Philosophies; undertaking a task-based risk assessment of priority tasks in conjunction with site-based personnel; evaluating the effectiveness of control measures; and providing information about safe design features in a standardised format.

Aug 1, 2013

By P. G. Rueffel

"Natural deposits of sodium sulphate are the result of normal geological processes. They are world-wide in occurrence and are found in depressions in arid and semi-arid regions. Primarily, the sodium sulphate deposits of the prairies are post-glacial and differ from rock salt deposits, which originated from connate water (fossil sea-water). Sodium sulphate on the Canadian prairies occurs as brine or in beds of intermittent and/or permanent crystals. Most beds are contaminated with various amounts of silt, sand and decayed organic matter. Soluble impurities such as chlorides, carbonates and bicarbonates of sodium and sulphates of magnesium and calcium are leached out from the soil of the surrounding run-off area of the deposits.In this paper, the origin of sodium sulphate, and the physical and chemical aspects related to the development of the Ingebrigt Lake deposit are dealt with. The problems of garnering raw material, and of refining and de-hydration are discussed, with emphasis on the Ingebrigt Lake plant. The utilization of the ""Total Power Concept"" in a sodium sulphate plant is described. The principal uses of sodium sulphate are also discussed."

Jan 1, 1968

By Roy O. Ifill, W. Charle Cooper, Alan H. Clark

"A detailed study of the compositional relationships of the Uand Th-bearing minerals in Elliot Lake uranium ores has been conducted, particularly with regard to uranothorite, which clearly plays a critical role in hydrometallurgical processing. Application of the rotating disc progressive-leaching technique to individual mineral grains and intergrowths of known compositions has defined for the first time the solubilization behaviour ofthe minerals in question.In descending order of leachability, regardless of leaching conditions, the phases are: uranothorite, uraninite, and monazite. Inclusions of secondary uranothorite enhance the dissolution kinetics of uraninite, which exhibits a complex dissolution mode. U-rich uranothorite dissolves more readily than Th-rich. Monazite is soluble in HJ)04 and HCI solutions only at temperatures exceeding 85°C. Consequently, it is deduced that the 15% to 20% of thorium not leached from the ore is lost both as monazite and as uranothorite inclusions locked in monazite which persists to the tailings. INTRODUCTIONThe importance of precise information on the mineralogy of ore and gangue constituents for the optimization of metal recovery in hydrometa Uurgical processing has been recognized for some years (e.g. Burkin, 1969), and numerous investigations integrating mineralogical studies and experimental leaching have been reported for ores of gold, nickel, copper and uranium (see summary by Henley, 1983). The complex mineralogy of uranium ores hosted by Precambrian pyritiferous, quartz-pebble, conglomerates has prompted particular attention in this regard (e.g. Liebenberg, 1956; Liebenberg and Taverner, 1958; Feather and Snegg, 1978). In the great majority of documented studies, however, petrographic examination has been followed by bulk leaching, an approach which, although providing valuable information, does not permit precise definition of the evolution of mineral dissolution processes. The authors contend that experimentation involving the step-by-step leaching and mineralogical study of ores is more likely to reveal the actual dissolution events which control the release of metals and, hence, may better define the optimal conditions for hydrometallurgical processing. Such studies (e.g. Hausen, 1983; Horlick et al., 1981) in addition lend themselves to the prediction of changes in the leaching behaviour of ores in which one or more mineralogical feature is subject to modification, a common characteristic of mineral deposits."

Jan 1, 1989

By Jeanne B. Percival, Paul Ramaekers, Charles W. Jefferson, Pat A. Hunt, Eric G. Potter, Katherine E. Venance, William Davis, Sean A. Bosman

"A 10-cm thick clay-rich layer near the top of the Manitou Falls Formation of the Athabasca Group is unusual in its breccia texture, alteration, and detrital mineral composition relative to the adjacent overlying and underlying sedimentary beds. This layer is composed of angular quartz grains set in an illite >> kaolinite + dickite matrix. Deformed clay-rich fragments within the layer have very similar mineral assemblages. The presence of euhedral accessory minerals including Ti-oxides and aluminophosphatesulphate minerals points to a diagenetic/hydrothermal origin. The presence of individual grains of Kfeldspar and amphibole is unusual relative to the typical Athabasca quartz arenite; originally, these minerals were probably included in detrital quartz and subsequently liberated during fracturing. The textures and alteration characteristics suggest that this layer is a hydraulically-fractured unit, which has experienced hydrothermal fluid alteration - a possible pathway distally related to uranium mineralization Une couche argileuse de 10 cm d’epaisseur pres du sommet de la Formation de Manitou Falls du Groupe d&apos;Athabasca est remarquable par sa texture brechique, son alteration et la composition de ses mineraux detritiques qui different de ceux des couches sedimentaires sus- et sous-jacente. Cette couche est composee de grains de quartz angulaires dans une matrice composee d’illite >> kaolinite + dickite. Des fragments deformes riches en argile dans cette couche presentent des assemblages mineraux tres similaires. La presence de mineraux accessoires idiomorphes dont des oxydes de titane et des aluminophosphates-sulphates suggere que ces derniers ont une origine diagenetique / hydrothermale. La presence de grains de feldspath-K et d&apos;amphibole est inhabituelle comparativement aux arenites quartziques typiques de l’Athabasca; initialement, ces mineraux constituaient probablement des inclusions dans le quartz detritique qui ont ete subsequemment liberees pendant la fracturation. Les textures et les caracteristiques de l&apos;alteration suggerent que cette unite a subi une fracturation hydraulique et a ete alteree par un fluide hydrothermal - possiblement en lien avec les effets distaux de mise en place de la mineralisation en l&apos;uranium."

Jan 1, 2013

By F. T. Rabbitts

Introduction When the investigation of radioactive ores began at the Mines Branch about five years ago it was at once evident that improved chemical methods for the determination of uranium were essential. The published methods available were time-consuming and insensitive and were lacking in accuracy and precision. It was desirable to obtain methods which would be rapid, sensitive, and accurate. They should also allow for the possible presence of any interfering elements and should be adaptable to routine analysis by technicians. Chemical methods are necessary to provide standard analysed samples for counting and to check analyses by counter methods. Moreover, counter methods cannot be used, and only chemical methods are suitable, when the sample is not in equilibrium, as with weathered minerals and leach residues. As leaching processes are improved, more sensitive chemical methods are required for the increasingly lower content of uranium in the leached residues. When the leaching process reaches the plant stage, speed of analysis becomes more important, without sacrificing accuracy. The purpose of this paper is to describe briefly .the methods used at the Mines Branch for the chemical analysis of uranium in ores. These methods represent the results of investigations by a number of groups in the United Kingdom, the United States, and Canada.

Jan 1, 1952

By T. A. Utigard, S. Pedler

Ilmenite from the Everett deposit in Quebec was characterized both chemically and mineralogically. The sample investigated contained the following main components: 40% Fe2O3, 21% TiO2 and 21% SiO2. The ilmenite grains contained about 20 to 25% hematite intergrown blades, with widths ranging from 2 to 30 \u03bcm. Crushing the sample to less than 0.85 mm led to significant liberation of the ilmenite from the gangue minerals. Gravity separation followed by magnetic separation of this size fraction led to a TiO2 concentrate grading of about 30% TiO2, with a recovery of 94%.

Jan 1, 2010

By W. L. Hunter

The preparation of coal for the commercial market is a study both varied and wide, and can be viewed from many angles and in different ways. This short paper can but touch upon the subject and is intended to discuss briefly preparation plants which in some cases would seem to be quite inadequate. The conditions confronting most operators are similar, inasmuch as the existing plants were not built specifically to prepare a product for the market of today, but rather of yesterday. The tremendous strides made in the field of combustion in recent years require that the product be of the highest grade procurable, and in a glutted and somewhat restricted market the buyer may be more pernickety than otherwise. These would appear to be the conditions of today. Where a mine is operated individually, better all-round results seem more readily procurable than in a consolidated effort where so many different conditions are sure to arise demanding cognizance, and in many cases requiring to be incorporated in the scheme of things. In the case of a number of mines being administered to form a central source, that source not having had anything to do with the bringing into being of the institutions over which it presides, we find some of the mines well equipped with facilities to properly screen and load the coal, while in others the facilities are not so good, but are doing their share towards delivering a product that will pass muster and in such quantities that they can be counted on.

Jan 1, 1930

By A. Quilodran, B. Jakovljevic, T. McCallum, P. Wong

"Rare earth separation by solvent extraction (SX) requires multiple separation plants each consisting of many extract, scrub, and strip stages to separate the individual metals. SX modeling advances have brought benefits to circuit design and process optimization by quickly narrowing test conditions without the need for exhaustive laboratory studies. Modeling can be used to optimize circuit configuration, O/A ratios, and acidities, which allows for CAPEX and OPEX savings. A comparison between pilot plant data and the results expected from modeling is presented for rare earth separations with CYANEX® 572.INTRODUCTIONRare earth separations can be difficult due to limited separation between the elements (Xie, Zhang, Dreisinger, & Doyle, 2014). This requires relatively complex solvent extraction circuits utilizing multiple extract, scrub, and strip stages as well as multiple SX configurations to achieve the desired metal purities. Designing rare earth circuits can be complex, and significant time and testing may be necessary to determine the required staging and optimal conditions.Circuit modeling for rare earth separations has been introduced to the industry using CYANEX® 572 extractant (Soderstrom, McCallum, Jakovljevic, & Quilodran, 2014). CYANEX® 572 is an acidic organophosphorus extractant formulation which has a weaker ligand-metal complex strength than that of the traditionally used phosphonic acid extractants. This allows efficient extraction while requiring a significantly lower acid concentration for stripping (Wang, Li, Zhao, Dong, & Sun, 2015). The reduced acid requirement in strip is expected to provide OPEX savings.The modeling can be utilized to quickly determine the required acidity and organic/aqueous (O/A) ratio for a given separation. It is also expected to reduce CAPEX requirements as optimal staging can be determined, and implemented.CYANEX® 572, combined with modeling, was utilized to produce a purified dysprosium (Dy) stream. To achieve this separation, multiple SX circuits were designed and operational conditions specified to separate Dy from the mixed rare earth chloride feed."

Jan 1, 2016

By G. W. Sparkes

The use of CR-39 plastic polymer as a solid state nuclear track detector in the textural analysis of radioactive minerals in geological samples was first described by I.R Basham in 1981. CR-39 autoradiographs provide a detailed, high-resolution image of the in situ distribution of the radioactive minerals within geological samples on both the macroscopic and microscopic scales. This technique is an inexpensive and effective means of obtaining detailed textural information that provides insight into the style of mineralization, its relationship to primary and secondary structures in the host rock, and its association with particular geological features or mineral phases. Although this technique does not provide any information on the identity of the minerals responsible for the radioactivity, the resultant autoradiographs can be used to select regions for further detailed analysis such as petrography, microprobe analysis, or SEM imaging. This paper summarizes the procedure and outlines the appropriate time and materials required for both the exposure and etching of the CR-39 with respect to the intensity of the radioactivity emitted by the geological samples.

Jan 1, 2013