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By Ofori-Ansah K

The zeta potential on the surface of activated orit carbon were estimated in lhe presence of selected cations and anions that are normally associated with gold bearing ores in Kalgoorlie area of Western Australia. Additions of such ions to solution of varying pH shifted the isoelectric point of carbon from pH 4.45 to pH 7-8.3, while the anions moved Lhc isoelectric point 10 less than pH 3.2. In the presence of gold cyanide SoluLion additions of spectator ions indicated the isoelecLric poilll to be aL pH less than 3.2; the only exception was for Fe" ion where the isoelecLric point was at pH 5.9. The decrease in zeta potential appeared to be related to the counter-ions present. The decrease may also be related to the adsorption of hydroxyl ion complexes that are likely to be formed when cations are present in the solutions.Gold adsorpLion by activated orit carbon from gold cyanide solution seem to be indicated by the magnitude of zeta potential on the carbon surface. An attempt is made to relate gold adsorption and zeta potential on carbon surface with the pH of the medium.

Jan 1, 1984

By Lawson F

A rotating disc geometry has been used to provide a uniformly accessible surface for a kinetic study of the cementation of the metals cadmium, lead and silver from dilute aqueous solutions. This work is an extension of studies carried out on the Cu/Zn and Cu/Fe systems for which the rection rate was found to be completely solution-phase mass-transfer controlled. When the amount of material deposited was greater than 0.2 to 0.4 mg/cm2 there was an apparent enhancement in e which is attributed to the formation of a roughened deposit. This same phenomeon was obseived in the Cu/Zn Cu/Fe systems. Again, the rate of reaction of each system investigated was found to be solution-phase mass ,..~sfer controlled.

Jan 1, 1970

Mt. Whaleback is in the Pilbara region of Western Australia approximately 1200 kilometers north of Perth, the State capital. In this deposit the Mt. Newman Joint Venturers are mining ore reserves totalling 1500 million tonnes of high grade hematite averaging 64.0% Fe. In addition to Mt. Whaleback, 38 ore bodies have so far been identified outside Mt. Whaleback on the Company's remaining 75,000 hectares of lease area. These ore bodies contain major tonnages of iron ore. Extraction at present is planned at a rate of 37 million tonnes per annum at an ore-to-waste ratio of approximately 1 to 1.4. The ore is railed north to Port Hedland on the Indian Ocean where the different products are screened, crushed and blended prior to shipping. The purpose of this paper is to acquaint the reader with the facilities installed in the Mt. Newman operation to form a background to the sampling techniques employed, describe the precisions which were achieved in experiments conducted February through June, 1976 and also to assess the degree of blending which takes place during the various processes and to put a quantitative measure to the degree of blending. There have been many excellent papers written on the more theoretical aspects

Jan 1, 1976

By Kubo H, Ninomiya R, Ojiro T, Sato T

New high-strength Zn alloys for moulds are demanded from the automobile and electric industries in Japan, because the s rength of Zn moulds is still not high enough for the mass production. There are two approaches to improve the strength of Zn alloys. One is to increase the Al content. ZA alloys (ZA-8, ZA-12, ZA-27) were developed through this approach. The other is to increase the Cu content. But it is known that an increase in Cu generally depresses the castability of Zn alloys, so that the alloys with increased Cu have been rarely studied until now. In this study a reconciliation between the strengthening and the castability of Zn alloys by enriching both with Al and Cu has been attempted. Accordingly we have studied on the Zn alloys containing 4 to 25 mass per cent Al and to 24 mass per cent Cu have been studied. Their fluidity, which primarily corresponds to the castability of the alloy, were measured first and 19 alloys were selected based upon their fluidities and casting temperatures. Mainly the mechanical properties of all 19 alloys were tested and some were found to be excellent in both strength and castability. Z1009 (Zn-IOAI-9Cu-0.02Mg alloy) cast in a sand mould has the tensile strength of 360 MPa while ZAS (Zn-4AI-3Cu-0.04Mg alloy), which is the most popular alloy for moulds, is 215 MPa. Z2520 (Zn-25AI-20Cu-0.02Mg alloy) cast in a sand mould has a Vickers hardness of 178, compared to 107 for ZAS and 104 for ZA-27 (Zn-27AI-2Cu-0.02Mg). Furthermore the castability of Z1009 is as good as that of ZAS. The underside shrinkage occuring in casting ZA-27 is restrained in Z2520.

Jan 1, 1993

By Brimblecombe P

Morwell Open Cut is a continuous mining operation employing 5 buck- etwheel excavators, I bucket chain excavator and 54 conveyors. The combined bunkering capacity at both client Power Stations represents less than 12 hours maximum coal demand. This creates an extremely dynamic operating environment, which is further complicated with significant variations in both excavating and transportation plant capabilities. To achieve set objectives, including- I adequate reserves, 2 coal supply reliability, 3 cyclic plant maintenance, 4 minimal cost of coal, scheduling of the operation requires constant monitoring and reappraisal. Investigations are in progress to develop a computer based scheduling tool capable of simulating the complex operating environment. A review of computer scheduling packages currently available within the State Electricity Commission of Victoria has found limitations making most unsuitable for the task. The type of package found to be most suited is a knowledge based system ('Expert System')capable of operating within a set of rules defined by the user. Work is proceeding on the development of a knowledge base to test the effectiveness of Personal Computer based `Expert Systems'.

Jan 1, 1989

The Que River Mine is a small under-ground base and precious metals mine located in north-western Tasmania. Current production rate is 220,000 tonne/yr from reserves grading 0.37% copper, 7.1% lead, 12.2% zinc, 195 g/tonne silver and 3.4 g/tonne gold.Ore is mined using longhole open stoping techniques. Cemented fill is placed in primary stopes to permit safe and efficient recovery of pillars. The operation is trackless with both shaft and decline access from surface.Ore produced is trucked 40 km by road to be sold to the Electrolytic Zinc Company of Australia Ltd., for treatment at their Rosebery concentrator.

Jan 1, 1985

By Lloyd F, Bayley F. J

The new South Mine in the Western Deep Levels complex is destined to become an ultra deep project extending to depths of 4 200 m below surface and where rock temperatures are likely to exceed 65 ¦C. Initial estimates put refrigeration requirements at 133 000 kWR. A surface refrigeration plant with an initial capacity of 42 000 kWR has been commissioned and will be used for mining the upper levels.

Jan 1, 1988

In a country richly endowed in mineral wealth, Climax Arintco Mining Corporation's ICAMC) Dinkidi porphyry Au-Cu deposit in Nueva Vizcaya, Philippines, represents the most significant mineral discovery in this country in recent times. The deposit is located within a belt of young intrusive and volcanic rocks in the Sierra Madre mountain chain of north Luzon, a region previously unassociated with porphyry -style mineralisation.Since 1989, drilling of the Dinkidi deposit has outlined a resource of 124 million tonnes of 1.0 g/t gold and 0.4 per cent copper. Regional exploration throughout CAMC's 37 000 hectare FTAA has identified a further 16 potential porphyry-related deposits.

Jan 1, 1997

By Walton M. C

A combination of flotation and smelting technologies is proposed as a cost-effective means to maximise the revenue of base metal operations. The proposed treatment route breaks the grade - recovery nexus associated with the treatment of ores exhibiting difficult mineralogy in conventional plants. Aspects of the two technologies are reviewed and typical capital and operating costs presented. A significant improvement in revenue is demonstrated in a worked example, where a copper-lead-zinc operation is examined in terms of the conventional and proposed treatment options. For the selected ore, the net smelter return per tonne of mill feed improved 57 per cent, from US$89.70 to US$141.10 with the proposed treatment option. This represents an additional US$51.4 million in annual revenue. Metallurgical operating costs increased by US$20.12 per tonne of mill feed for an incremental capital requirement of US$30.3 million for an existing operation.

Jan 1, 1992

By Colwell JB, Cronan DS

Manganese nodules cover great areas of deep ocean floor far from land, and have long been considered a major potential resource of nickel, copper, cobalt and perhaps manganese. A decade ago there was a period of intense evaluation of nodule fields, especially those lying between the Clarion and Clipperton Fracture Zones in international waters southeast of Hawaii. There, nodules are abundant and of high grade (average of 2.4% Ni+Cu+Co). The evaluation activity has since declined, but a recent agreement on lease boundaries among all interested parties may lead to a resurgence of work. Indeed, French and Japanese groups have pushed ahead with field and economic assessments.The Southwest Pacific, where there are large nodule fields in the waters of the Cook Islands and Kiribati, has seen considerable assessment of resources in the last ten years, especially through a major field programme of the Japanese Metal Mining Agency. The best prospect appears to be in the South Penrhyn Basin, in Cook Islands waters, where nodules are very abundant but of only moderate grade (1% Ni+Cu+Co). Using a cut-off of 5 kg of wet nodules per m2, Cronan (1989) and Cronan et al. (1989) have estimated the total resource to be a huge 110 million tonnes of Ni+Cu+Co.

Jan 1, 1990

By Moxon N. T, Berndt J. R

BHP-Utah Coal Limited's Peak Downs Mine is located in Cen- tral Queensland, approximately 200 km south west of Mackay. The annual raw coal production of the mine is over 8 million tpa, requiring the removal of about 40 million cubic metres of prime overburden. This is achieved through the use of five large draglines. The large depths of overburden (up to 55 metres) encountered over half the strike length of the mine enables cast blasting to be carried out in conjunction with draglines employ- ing the chopping method of digging. The objective of cast blast- ing is to use explosive energy to move as much material directly into spoil as possible. The additional costs of drilling and blast- ing are offset by reducing dragline rehandle. Two factors which are of primary importance to the design of cast blasts are initiation control and material velocity. High speed motion picture photography is a powerful diagnostic tool to quantify these aspects of blasting (Winzer, Montenyohl and Ritter, 1979; Chiappetta et al., 1983; Anon., 1983). The objec- tives of such analysis are to: 1. Determine the burden velocity, 2. Determine the time to initial movement (that is, the inter- val between a face hole firing and the initial movement of the burden), 3. Check the accuracy of the initiation sequence. BHP Central Research Laboratories (CRL) and Peak Downs Mine monitored a cast blast in the mine's Winchester Pit on 18 August, 1988. The objectives of this exercise were to: 1. Quantify current cast blast performance, providing a base case for comparison with modified blast design. 2. Compare two orientations of angled holes within the blast. 3. Assess the effectiveness of cast blasting utilising an air-deck. 4. Check blast timing with respect to burden movement times.

Jan 1, 1989

By Johnson N. W, Quast K. B

Over the years there have been occasional references in the literature to the activating effect of cyanide in galena flotation with xanthates. These have usually been associated with the processing of lead-zinc or copper-lead-zinc ores. Bubble contact curves for the pure galena-xanthate system show a flotation edge at pH 10.4 independent of sodium cyanide concentration which was thought due to hydroxyl ion, not cyanide ion.Flotation tests were conducted on samples of Mount Isa lead-zinc ore using varying concentrations of sodium ethyl xanthate and sodium cyanide. At low collector concentrations, galena recovery kinetics improved with sodium cyanide addition, and the higher the cyanide concentration, the higher the galena recovery rate. At higher collector concentrations, galena recovery rate was independent of sodium cyanide addition.For a given collector addition, the lead grade-recovery curve shifted to an improved position with increasing sodium cyanide level. For the same recovery there was an increase in the lead grade with increased sodium cyanide addition, and this increase was most dramatic at high sodium cyanide concentrations.The presence of sodium cyanide during the grinding of Mount Isa ore caused surface passivation of the iron sulphides and possibly the sphalerite.These sulphides, therefore, reacted with less of the oxygen present in the pulp, hence more oxygen was directed to the surface of the galena. This resulted in an enhancement in the total amount of xanthate adsorbed on the galena that is reflected in the improved flotation response of that mineral.

Jan 1, 1990

By Orr D. B

This is a case history of prospec- ting carried out by Comstaff Pty. Ltd. over the Pinnacles Area, part 4 of Exploration Licence 5/63, 9 km north of Rosebery in Western Tasmania. Evidence is presented to show that A 0 soil samp ling is a viable prospecting method for outlining polymetallic sulphide occur- rences in areas where leached organic/ glacial soils are common. Diamond drilling of low threshold anomalies has intersected base metal mineralisation.

Jan 1, 1977

The Ok Tedi Project has been planned as a selective mining operation since the Feasibility Study. The nature of the orebody, and the need to 'stage' the infrastructure buildup meant that initially the mill would process gol ore using a leach-CIP process, followed by parallel leaching of gold ore and flotation of copper ore, and finally all flotation of copper ore. Cutoff grades were applied to gold and copper ore of 1.0-1.3 g/t Au and 0.4-0.3% Tot. Cu. Since startup, unpredicted occurrences of sulphide copper and, to a Lesser extent, carbonaceous material, has necessitated significant additional short term drilling (other than at grade boundaries), and shift grade control in the pit to control contaminant levels. Remodelling of the orebody based on the most up to date variography and geological interpretation has had a significant impact on the reserves, and thus the whole project development strategy; necessitating the earlier processing of copper ores, and preflotation of the gold ore.This paper discusses some of these points in detail, and in particular highlights how unforseen geological occurrences coupled with processing restrictions can have significant impacts on ore reserves and the mine development schedule.

Jan 1, 1986

A four monthly period was analysed for each retreating longwall face which indicated that output increased from 1140 tonnes/day for Longwall 1, to 1620 tonnes/day for Longwall 2 and to 2090 tonnes/day for Longwall 3. An output of 2500 tonnes/day should be achieved from the new Longwall 4, largely due to the improved tailgate corner design and despite a continuing lump coal problem. The evolutionary trend is a feature of longwall mining; the evolution occurring both with mining and mechanical design at the colliery itself and with the longwall equipment offered by manufacturers. The trend is towards simplicity, increased strength and capacity, simplified maintenance and increase relia- bility.

Jan 1, 1976

Five types of mineral resource were known in the sedimentary cover of the oceans and seas floors prior to the 1980's :1) hydrocarbon fields including some very large zones of oil and gas accumulation; 2) "Red Sea" type thermal oozes with increased concentrations of noble metals; 3) ferromanganese nodules; 4) concentrations of metallic sulphides ("Black Smokers"); and 5) cobalt-bearing ferromanganese crusts on the summits and slopes of seamounts. Since then, the so called "White Smokers", containing sulphides of copper and zinc, have been discovered. The ore horizons (manganese, copper, nickel and other metals) of the sedimentary cover of deep-sea basins comprise a sixth type of mineral resource in the oceans. These horizons have not only a theoretical, but also a principal economic significance

Jan 1, 1995

In the first half of 1987 two four metre diameter raise bore holes were drilled at the Olympic Dam Project for ventilation purposes. The first hole, 476 m x 4.0 m diameter was completed in 96 days, 35 days longer than scheduled. The second hole, 407 m x 4.0 m diameter was completed in 39 days, 2 days ahead of schedule. Both holes were drilled with a Robbins 121R rig using a Wirth head that consisted of 23 face cutters and 5 side cutters, supplied by a contractor. After the sites were located a grouting program was carried out to help seal off an aquifer between 160 and 180 m below the surface. Cavities discovered in the Andamooka Limestone were filled with concrete. Because of the overlying dune sands and clay both sites were pre-sunk to the competent Andamooka Limestone.

Jan 1, 1988

By Stewart R, Manson RA, Haig DW, Perembo RCB, Kruman B

Since the advent of plate tectonic modelling, the Ramu-Markham valley has been thought the site of a classical island-arc/conti- nent collision zone. In this interpretation the units south of the Markham Valley are held to be island are / micrcontinental mate- rial accreted to Australia and those north of the valley are thought to represent a separate Finisterre island-arc terrane. Recent remapping by the Geological Survey of Papua New Guinea shows: (1) there is no terrane boundary along the Ramu-Markham valley (2) the Finisterre Volcanics are probably part of either a fore-arc sequence or oceanic plateau obducted onto a microcontinent/ volcanic-arc composite terrane, accreted to the continental Australian plate. A new tectonic model is proposed for northern PNG and involves: (I) Eocene to Late Oligocene subduction below a microcontinent remote from Australia to produce the Sepik are and related intrusives, the Finisterre Volcanics (fore-arc or possible oce- anic plateau), together with the Alife blueschist. (2) obduction of the Sepik arc in Late Oligocene-Early Miocene times over the advancing Australian plate. This resulted in crustal melting, some of the products of which are the Mid- dle to Late Miocene Akuna and Bismarck intrusive complexes of the Maramuni arc. (3) obduction of the Finisterre Volcanics began in Early Pliocene times and continues today. (4) post-Middle Miocene mineralisation is the result of melting after obduction of the Sepik microcontinent.

Jan 1, 1997

By Trois P

A fully instrumented and bench-mounted diamond drilling machine, purpose designed and built, has been used for investigating the effect of aqueous solutions of various chemical compounds when used as drilling fluids. The rocks investigated were andesite, basalt and granite, the chemical compounds were alkylamines, with various hydrocarbon chain lengths, aluminium chloride and dioxane. Rotation speed seems to be one of the major factors affecting the emergence of mechanochemical effects as the results obtained with aluminium chloride clearly indicate. Penetration rate is either unaf- fected or enhanced by the presence of certain compounds, such as aluminium chloride. On the other hand, penetration rate diminishes when the drilling fluid contains dioxane and exhibits an apparently unpredictable behaviour with alkylamine solutions, although it appears that an increase in hydrocarbon chain length usually equates to an increase in penetration 1. Full Professor, Mining and Mineral Dressing Department University of Cagliari - Italy 2. Associate Professor, Mining and Mineral Ikea- sing Department University of Cagliari û Italy rate. Rock texture seems to have a pronounced effect on test repeatability. With hexadecy- lamine acetate solutions in concentrations ranging from 10-5 to 5 .10-4 molò dm 3 and 41.88 radòs-1 rotation speed, 46 % increments in penetration rate of andesite were observed, with respect to water, whereas penetration rate decreased in basalt by as much as 60¦%o when a dioxane solution was used as drilling fluid. An interpretation of the observed effects is proposed in the light of current knowledge of solid state physics and physical Chemistry.

Jan 1, 1992

Coal seam methane (CSM) is an æunconventionalÆ gas resource that is becoming an important energy resource for Australia, especially along the eastern seaboard. It has been conventionally believed that methane in high rank coals was exclusively derived from thermocatalytic processes during decomposition of coal at elevated temperatures. However, recent re-interpretations of gas composition and isotope data have indicated that microbial methane generation may be one of the main processes responsible for the accumulation of commercially producible methane in some coals. In low rank (æbrownÆ and sub-bituminous) coals, methane (CH4) is mainly generated by microbial activity at low temperatures. The amount of this biogenic gas generated and accumulated in low rank coals depends largely on the rate of burial and depth. Most low rank coals are æunder-saturatedÆ with respect to their maximum gas sorption capacity. In contrast, high rank coals may be highly saturated due to extensive gas generation from both thermogenic and secondary biogenic processes. However, in basins where secondary biogenic gases have not replenished the thermogenic gas lost during basin uplift, the coals will be æunder-saturatedÆ. In many basins around the world, high CSM producing zones appear to contain secondary biogenic CH4 generated by microbes transported in meteoric water recharge through permeable coal seams. Biogenic CH4 generation requires the activity of a consortium of anaerobic respiring microorganisms, fermentative bacteria and acetogenic bacteria to break down complex organic molecules to simpler molecules having one or two carbon atoms, which enables methanogenic archaea to generate CH4. The two main methanogenic pathways in the generation of secondary biogenic gas from coal are aceticlastic reaction and carbon dioxide (CO2) reduction. In eastern Australian coals CO2 reduction appears to be the main process. The types of microbes that are directly involved in these processes are unknown because they have not yet been isolated from the coal seams. The CSIRO is currently investigating the processes of biogenic gas generation in Australian coals. Potential may exist to introduce appropriate microbes into deep coal seams to enhance methane saturation levels, gas sorption capacities and permeabilities.

Jan 1, 2004