Search Documents

By L Lorenzen

The selection of samples for metallurgical test work is generally focused on providing geologically representative samples. One of the major problems experienced with metallurgical test work using drill hole data, is the small sample sets selected for metallurgical testing. Major process and financial decisions are being made from results obtained using snapshot samples. Snapshot samples means that samples are basically selected only by grade and spatial location with the assumption that the rest of the orebody or portion of orebody is similar and will respond metallurgically the same way – ie the assumption is that the mineralogy and lithology are basically the same as the test sample. From the test work, algorithms were usually developed and used to describe throughput and recovery using some explanatory variables including grade (mineral chemistry) and ore hardness. These algorithms were then used in the recovery models to determine tonnes produced and plant throughput. However, the metallurgical parameters are a function of many geological factors including grade, lithology, alteration, mineralogy, spatial relationships and SG. In previous years, the limited mineralogical information available was deemed enough for the metallurgist to make decisions as to how many samples are needed to evaluate the metallurgical performance of the ore during processing, and subsequently the basis for the plant design. If the orebody is consistent and not complex or refractory (thus, relative simple lithology), then only spatial and grade samples will be needed to evaluate the throughput and recovery, so limited mineralogical information may be acceptable. There is now, however, an increasing realisation that the mineralogy and geology change, as do the metallurgical characteristics of the orebody, so limited samples may not be sufficient for effective metallurgical test work.It is the purpose of this paper to discuss the effect correct mineralogical information has on the subsequent metallurgical test work program and process selection using a case study. Factors such as type of rock, rainfall and topography are thought to influence the minerals that ultimately form in various orebodies, with the result that different orebodies often react differently during metallurgical test work programs. It is therefore important to obtain accurate mineralogical and elemental deportment data, which will also indicate where the valuable metal containing minerals are located within the orebody. The better you plan and execute your metallurgical test work program during the early phases, the more accurate the decision-making process will be during the selection phase. Improved integration between geology and metallurgy data gathering (geometallurgy) during early phases will result in more accurate predictions with regard to throughput and recovery during modelling and process. Equipment selection will be considerably simpler in later phases with early planning, with improved mine and process scheduling and subsequent net present value (NPV).

Sep 5, 2011

By OÆNeil G. R

The gold adsorption capacity of ash-char and ion exchange resin Zerolit F.F. (I.P.) was evaluated by obtaining Freundlich isotherms in the presence of selected variables. It was found that the presence of Na , 2+, Ca 2+ cations and SO4 , CN , S Z, 0 2- Zn anions prompted adsorption of gold onto the char and reduced gold adsorption capacity of the resin. Temperature, particle size of adsorbent and pH of solution were found to influence the gold adsorption capacity of char and the resin. The most efficient desorbent for gold adsorbed on the ash char was S2 ions. Optimum sulphide concentrations were found in the region of 1% Na2S. Investigation into the concentration of gold from actual carbon contaminated gold residue dumps in Kalgoorlie area onto ion ex- change resin showed limited success in one case and not so in another. Maximum gold adsorption by the resin appeared when cyanidation and sulphidization treatments were carried out simultaneously in the presence of the resin.

Jan 1, 1979

By P N. Duan, Z G. Liu, M S. Chu, X X. Xue, B Liu, G J. Cheng, T Jiang, J X. Liu

High-chromium vanadium-titanium magnetite has not been exploited and made full use of on a large scale so far due to the immature utilisation technology and the reality that the utilisation efficiency of valuable metals still urgently needs to be improved. In the present paper, the isothermal reduction kinetics and mechanism of high-chromium vanadium-titanium pellets were studied at 800–1100°C. The mineral composition transformation of pellets before and after reduction was analysed by means of X-ray diffraction (XRD), and the microstructures were examined by scanning electron microscope (SEM) equipped with energy dispersive X-ray (EDX) to reveal the elemental distributions. The effect of reduction temperature on the volumetric swelling degree and cold crushing strength was also studied. It was found that reduction temperature has a large effect on the reduction rate of pellets, and the increase in reduction rate is more obvious in the range 1000–1100°C than 800–1000°C. The volumetric swelling degree of pellets increased with increasing reduction temperature, while the cold crushing strength decreased. The transformation of mineral species can be expressed as Fe2O3 ? Fe3O4 ? FeO ? Fe, Fe2O3·3TiO2 ? Fe3O4· (2FeO·TiO2 ) ? 2FeO· TiO2 ? FeO·TiO2, (Fe0.6Cr0.4)2O3 ? FeO· Cr2O3 ? Cr2O3 , and Fe2O3· VO/V2O3 ? VO. The apparent activation energy of the reduction reaction was calculated to be 44.3 kJ/mol, and the reduction rate is controlled by the combined effect of interfacial chemical reaction and gas diffusion through the porous product layer. The rate controlling steps were further studied by calculating the resistance percentages. The interfacial chemical reaction was found to be predominant in the initial reduction stage, with the percentage effect of gas diffusion through the porous product layer gradually increasing during reduction.CITATION:Cheng, G J, Xue, X X, Liu, J X, Liu, Z G, Chu, M S, Jiang, T, Liu, B and Duan, P N, 2015. Reduction kinetics and mechanism of pellets prepared from high-chromium vanadium-titanium magnetite concentrate, in Proceedings Iron Ore 2015, pp 349–358 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

The Barmac autogenous crushing mill is one of the most successful new comminution technologies to become available to the mining and industrial minerals industries in this decade.The Barmac autogenous crushing mill is an innovative Vertical Shaft Impactor which operates in essence like a high intensity dry ore centrifugal pump with the reduction occurring primarily as a result of high velocity rock to rock impact in a fully rock lined crushing chamber. With applications in a wide range of mining and industrial minerals operations the Barmac autogenous crushing mill presents an opportunity to enhance reduction and liberation whilst providing many cost savings and production increases in new and existing plants.This paper briefly describes the operation of the Barmac autogenous crushing mill and reviews its benefits.

Jan 1, 1990

By K Lee, L Mann, J Bygrave, G Sheldon

Ausmelt is supplying commercial quantities of an alkyl hydroxamate flotation collector AM28 for flotation of oxide and supergene base metal ores and tailings. AM28 is a non-hazardous product used as a ten per cent to 50 per cent solution in dilute potassium hydroxide. It is a selective flotation collector for oxide or oxidised base metal minerals and replaces conventional sulfidisation for oxide mineral flotation. At Radio Hill, the AM28 is used in conjunction with traditional sulfide collectors, which allows simultaneous flotation of oxide and sulfide copper minerals. The Fox Resources Radio Hill copper concentrator near Karratha, Western Australia, is currently configured to treat supergene copper ore sourced from the West Whundo open pit. This Archean VMS type copper deposit has been deformed and remobilised with uplift, erosion and weathering to form a significant supergene zone. The sulfide copper minerals present in the upper zone are digenite and chalcocite with lesser chalcopyrite and covellite. Oxide copper minerals present include cuprite, with lesser malachite and azurite. Gangue minerals include quartz, talc and chlorite. Plant trials at Radio Hill are reported for supergene West Whundo ore, where the AM28 was stage added into the circuit at nominally 80 g/t. Plant data over three months shows the copper recovery increased consistently from around 50 - 60 per cent to above 70 per cent when AM28 was added. This has been proven statistically. The grade of the concentrate was consistent with and without AM28, at nominally 22 - 24 per cent copper.

Jan 1, 2007

By H Rossiter, C Simpson, J Market, P Jeanneau

Downhole Assay tools are a geophysical method to collect an instigated response from the material surrounding a drill hole and deliver a multielement proxy-assay. They were first tested in the Pilbara at the turn of this century, however since 2011 they have seen a more focused testing and implementation regime with multiple companies across multiple Pilbara mine sites. The increase in the volume of data has led to advances in the measurements and significant improvements to the efficiency of the calibration process. Pulsed Fast and Thermal Neutron Activation Analysis (PFTNA) downhole assay tools collect gamma photon spectra which are characteristic of elemental signatures. One of the key components of the technique is calibrating the spectral signatures to lab assays. Each tool is slightly different due to the organic nature of the crystal detector and therefore responds slightly differently. Environment and hole conditions as well as ore characteristics are among other external influencing factors. Thus, a unique calibration is required for each tool. In addition, not all elements are measured directly, but some are actually characterised by proxy, meaning that if the signal-to-noise ratio for an element is small, it may be easier to identify the mineral or geology in which that element is found and thus infer the concentration of the element. These proxies may differ for each site or geology type within a site. There is a large advantage to build a unique calibration per tool at each site rather than a universal one to be used across the whole province. This then delivers the accuracy and precision of measurements that mining companies require for modern operations. Early work with the tool required several thousand metres of calibration data and several weeks of analysis to build each calibration. This process has now been streamlined to significantly reduce the amount of data required and the analysis time to make it much easier to introduce new tools to a site with an existing model or to create new models. This paper details the calibration process, illustrating the increasing accuracy of the models as training data are acquired as well as the methods for transferring a calibration from one tool to another.

Nov 8, 2021

Designing for early access to deep orebodies is an essential driver for improved project payback. Vertical shaft sinking techniques have been developed to allow concurrent mine level excavation while continuing to sink. Project cash flows can also be improved when simultaneously deepening existing shafts beneath operating hoisting systems. Further economic advantage has been realised through creative sinking sequencing in twin ventilation/service shaft projects. A fourth technique to reduce project schedules involves partial shaft barrel equipping allowing unrestricted access to construct stations and continue with level installations. This approach reduces interference with barrel sinking activities to insignificant proportions. This paper reviews how these approaches have added significant value to actual shaft sinking projects, as assessed from a contractorÆs perspective, and discusses some of the practical issues to be addressed when planning future projects. Designers need to take cognisance throughout all project engineering phases of the adage that you are only sinking when cleaning the face. Cleaning can only be sustained when there is sufficient hoisting capacity.

Jan 1, 2005

By Browner R, Kyle J

The adsorption of gold cyanide by the weak base ion exchange resins, PAZ-4¦ and Duolite A-7C, the neutral polymeric adsorbent, Amberlite XAD7¦, and the strong base resins, PAZ-8~a and IRA-400 have been studied in both low and high salinity waters, and their performance compared with activated carbon. A systematic study has also been made of the effect of different ions (Na+, Cat+, Mgt+, Cl', SO4) ) on the gold adsorption capacity and kinetics of these resins. The results indicate that, contrary to popular belief, the ion exchange resin, can perform effectively in highly saline environments. The performance of the neutral polymeric adsorbent im- proves with increasing salinity but cannot match the performance of the ion-exchange resins.

Jan 1, 1991

By S Morgan, L C Pagdalian, S Serdzeff, C Malaloy-on

It is widely accepted that mineral deposits are decreasing in metal grades. To remain profitable and meet market demand, mining companies are expanding their operations by increasing the tonnage treated. These expansions may include new concentrators with higher nameplate tonnages or upgrading the capacity of existing ‘brownfield’ operations. In many cases, the brownfield upgrade route is preferred as it is less capital intensive; however, brownfield upgrades are never straightforward and present many metallurgical and engineering challenges.For example, to increase feed throughput at a brownfield site, there will be a requirement to modify the mine development plan. This may result in the ore mineralogy varying beyond the current feed fluctuation range. To accommodate these ore variations, a combination of mineralogical analysis and small scale testwork can be used to develop a new process flow sheet to achieve the product recovery/concentrate grade requirements. In general, however, flow sheet development does not usually consider site specific layout constraints and equipment requirements. At sites where future expansions were never considered, taking this silo approach could lead to project delays and compromise the circuit design.Engaging an experienced technology partner ensures the nominated project team is involved throughout all stages and aspects of a given brownfield upgrade – from conceptual flow sheet development, through to detailed engineering, construction and commissioning. The recent Carmen Copper Corporation (Carmen Copper) circuit upgrade has been completed in technology partnership with Outotec. The circuit upgrade was extensive and included new equipment additions to the comminution, flotation and dewatering circuits. Carmen Copper’s intimate knowledge of the ore characteristics, in conjunction with a trusted, knowledgeable technology partner, facilitated a robust circuit design, and fast-tracked the project execution. This paper deals specifically with the flotation circuit upgrade and highlights the benefits to Carmen Copper of this holistic approach.CITATION:Morgan, S, Serdzeff, S, Malaloy-on, C and Pagdalian, L C, 2014. The benefits of technology partnerships during brownfield upgrades, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 471–476 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

By N Pirouznia, F Rashidi Nejad, S Naraghi

Sungun Copper Mine, which is the second largest copper mining operation in Iran has a large tailings storage facility with a seepage control dam located downstream of the main dam. Surface and groundwater in surrounding area of the tailings storage facility has been monitored for ten years. This paper will discuss the results of the surface and groundwater monitoring and seepage control at the Sungun Copper Mine. The results of the study show that if the tailings storage facility influence the water quality of the rivers, this effect is not significant, so that the prevailing parameters of the measured parameters were within the permissible standard of drinking water in Iran.CITATION:Rashidi Nejad, F, Naraghi, S and Pirouznia, N, 2018. Surface and groundwater monitoring and seepage control at the Sungun Copper Mine, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 439–453 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By Morley I. W

In the year 1926, Edie Creek, in the Morobe District of the Mandated Territory of New Guinea, saw the greatest gold rush of recent years. Situated 35 miles inland from the coast, and at an altitude of over 6000 feet, Edie Creek presented to the original prospectors a wet, jungle-clad uninhabited, and inhospitable region. There were no roads; and the only means of approach from the equally inhospitable coast was by an eight to ten days' tramp through coastal swamps and gorge-scarred mountains. All food supplies and equipment had to be carried on the backs of "kanakas," and in many cases through country occupied by hostile natives.Since the first discovery of payable gold at Edie Creek, mining on the Morobe Goldfield has shown remarkable progress, and in spite of the tremendous natural difficulties, the field today ranks as one of the most important in Australasia.Aeroplanes, more than any other factor, have been responsible for this rapid development. They provide the only means of transport from the coast, and at present serve the needs of over 600 Europeans and 3000 indentured native labourers engaged in the industry.

Jan 1, 1933

By MacLean L

In 1975 the Commonwealth Government established import parity pricing for all liquid hydrocarbons discovered after the 16th September, 1975. These discoveries were termed "new oil" to differentiate them from existing discoveries and production. Overnight the price of the product being sought trebled, resulting in greatly enhanced economics by increasing the potential returns on existing prospects and by making smaller plays economically viable. After 18 years of drilling, the offshore Gippsland Basin has attained a moderate level of exploration for a basin of its size. Fifty seven prospects have been drilled within the basin but only a few of these were drilled along the southern and northern margins, while the deep water areas along the eastern margin have remained virtually undrilled following the Hapuku-1 oil discovery. The major hydrocarbon accumulations within the basin are trapped beneath the Latrobe Unconformity surface and exploration has largely concentrated on this single play in areas immediately adjacent to the major producing fields.

Jan 1, 1982

By S Maritsa, E K. Chiwandika, S M. Masuka

The iron and steel industry is experiencing an increase in the use of iron and steel commodities within societies, decarbonisation pressures, depletion of high iron ore grades and high energy consumption. This necessitates scrap metal recycling, low-grade ore utilisation using the induction or electric arc furnace to achieve the global target of net zero CO2 emission. The available highquality scrap metal cannot sustain the steel industry but the world has unused hematite-goethite ores. It is the aim of this research that this resource be utilised using the induction furnace to sustain the steel industry in an environmentally friendly manner. Indurated pellets prepared from the hematite-goethite ore, 5 wt per cent limestone and 5 wt per cent coal addition were smelted in the induction furnace at 1350 ± 50°C with 25 mins holding time. The effects of basicity and carbon content were also investigated to optimise the smelting parameters. The results showed that the careful control of the basicity, and iron-to-carbon ratio maximised total metal recovery. The optimal basicity ratio was determined to be 1.3 and a carbon to iron ratio of 1.4 achieved a total metal recovery of 73 per cent. The metal recovery was closely related to the estimated slag melting temperature. The basicity ratio of 1.3 achieved the lowest slag melting temperature estimated to be around 1380°C based on the CaO-SiO2-Al2O3 phase diagram. The recovered metal had a comparable chemical composition and microstructure to that products from an ITmk3 furnace.

Jun 19, 2024

By Y Peng, B Guo

In gold processing plants, the water from the cyanidation stages is treated to detoxify cyanide species and this recycle water becomes the main part of the process water. Despite the low concentration of free and weak acid dissociable (WAD) cyanides in process water, the recoveries of gold and silver is still affected during flotation, especially when gold and silver are associated with iron sulfide minerals. This is a case at the Hidden Valley (HV) Mine. In this study, the effect of free and WAD cyanides on gold and silver recoveries by flotation from the HV Mine was considered.WAD cyanide (WAD CN) was prepared by mixing sodium cyanide and copper sulfate at a cyanide to copper ratio of 3:1 dosed at different cyanide concentrations. It was found that both free and WAD CN depressed gold and silver and particularly iron sulfides in flotation. The depressed gold and silver recoveries were closely associated with the depressed recovery of iron sulfide minerals, suggesting that free and WAD CN may not depress the flotation of liberated gold and silver minerals significantly. It was also found that 10 ppm free cyanide completely depressed the flotation of iron sulfide minerals and WAD CN depression is probably through the WAD dissociation to free cyanide species (mainly aqueous HCN) during the grinding process, resulting from a decrease in pH. Thermodynamic calculation showed that 5.5 ppm free cyanide was released in the end of grinding at an initial WAD CN concentration of 50 ppm. This research provides a guideline to counteract the negative effect of WAD CN in the flotation of gold and silver minerals.CITATION:Guo, B, Peng, Y and Espinosa-Gomez, R, 2013. The effect of weak acid dissociable cyanide on gold and silver flotation in Hidden Valley Mine, in Proceedings World Gold 2013 , pp 341-346 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By Scoble M, Peck J

This paper reviews the instrumentation and monitoring of blasthole drills and electric mining shovels at a surface coal mine in western Canada. The drill monitoring component involved the development and implementation of microprocessor-based hardware on Bucyrus-Erie 45R and 60R drills. Over a two year period 3800 metres of blasthole drilling were monitored The drill data was subsequently correlated with core and geophysical logs towards identifying unique and reproducible ranges of performance parameter data for the different rock types penetrated. Using this technique, the geology of the study area benches was characterized in detail. Once these same benches had been blasted, the performance of a P&H 2800XP shovel was monitored as it worked through the blasted ground. In this regard, the influence of different digging conditions on shovel performance were identified in a range of blast and geological environments within the study area. The precise nature of these environments was confirmed by a correlation with the interpreted drill monitored data and muckpile size distributions obtained from a digital photo-analysis study. The excavation of 500 000 bcm of waste was thus monitored and a digging index derived which reflected variations in muckpile diggability. The paper concludes by proposing an integrated monitoring approach which, as a first step, uses interpreted drill data for explosive loading. This capability would permit greater accuracy in explosives loading ie. charge placement within higher strength lithologies, while avoiding weaker units. The performance of an instrumented shovel would then be monitored as it works through the resulting muckpile. Interpretation of the shovel performance data would determine the overall quality of the blast in terms of a digging index (DI), providing an indication of the relative digging effort and the effectiveness of the blast design.

Jan 1, 1990

By N Guresin, A Cooper, L Lorenzen, H Muller, S C. Dominy

Sampling and metallurgical test work during various phases of engineering?studies?is of?paramount importance for a robust processing plant design. When developing a process flow sheet, risks in achieving desirable financial outcomes are minimised by ensuring appropriate sampling and adequate metallurgical test work supports the engineering and cost estimation at each phase of project development.The quality and type of samples used for metallurgical test work are just as important as the metallurgical test work itself. The key characteristic required of any sample is that it represents some defined portion of a mineral deposit. Representivity should take into account the spatial orientation, lithology, alteration, degree of oxidation, mineralogy and competency of the ore such as hardness and abrasiveness. Statistically representative sampling procedures and an appropriate metallurgical test work program should be designed to bring metallurgical understanding up to feasibility study standard and to give a basis for process plant design.Snowden has observed that the quality of sampling and quantity of metallurgical test work carried out during the various phases of engineering studies are often insufficient to truly support a robust plant design. Some designs are often the result of the plant design based on benchmarks of apparently similar orebodies or buoyant metal prices supporting cash flows until rectifications can be implemented.The paper will discuss important aspects of sampling and test work required for engineering studies in designing process plants based on industrial case studies.CITATION:Guresin, N, Lorenzen, L, Dominy, S C, Muller, H and Cooper, A, 2012. Importance of effective sampling and test work protocols for process plant design, in Proceedings Sampling 2012 , pp 95-108 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 21, 2012

By D Reid

Characterisation of non-plastic segregating tailings presents a number of challenges: the material cannot typically be sampled in an undisturbed state, remoulded samples exhibit different behaviour to undisturbed samples, penetration test interpretation methods suffer from uncertainty in their application to many tailings and the tailings gradation changes considerably over relatively small lateral distances and depth. In addition, the process liquor of many Western Australian tailings contains large quantities of salt and other dissolved solids, which can further complicate laboratory test programs. To provide an insight into the variability at a typical gold tailings facility, four gradations of the material were tested to obtain critical state parameters. Historic surficial tube samples were collated and organised by gradation to establish the range of densities typical after settling and air drying. These were then compared to laboratory-accessible densities. Finally, tube samples were tested in the laboratory to observe if the large-strain material behaviour was consistent with the inferred critical state parameters for similar gradations. Site pore fluid was used in the testing of the tube samples in an attempt to assess if the pore fluid modified the critical state conditions of the material.The tube samples tested all exhibited strongly dilative behaviour in undrained shear. Of the four samples tested, only one exhibited behaviour consistent with the inferred location of the critical state line relevant to the material’s gradation. The reasons for the unexpected behaviour of the other three samples include layering within the samples, the potential influence of large quantities of salt in the pore fluid and likely differences in the gradation of the fines components of samples taken from mid-beach and the decant area.CITATION:Reid, D, 2015. Observations on the behaviour of a gold tailings with hypersaline pore fluid, in Proceedings Tailings and Mine Waste Management for the 21st Century , pp 191–200 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015

Traditionally, the development of a mineral resource project goes through a fairly set pattern of decisions from what commodities to search for; where to look; how to locate; what are the reserves; how can they be exploited with optimum returns for all stakeholders; where are the markets and what will be the price received; what financing arrangments? However, due to the unique nature of most mineral resource properties, the relative significance of individual parameters on the ultimate development decision will vary from project to project. Sensitivity analysis in its formal sense is most frequently related to the economic analysis of a project particularly in conjunction with the ultimate development decision making process, and acknowledges the uncertainty of the actual values with their impact on the corporate decision making yardsticks. In many cases, this analysis merely adds more values to confuse the decision makers who may well opt for some subjective rationale to overcome the numeric confusion. However, sensitivity analysis should be used more frequently to exploit the development dollar to its maximum, THROUGHOUT the phases leading to the development decision. It is essential to identify the critical inputs to the various decision tiers in a project as early as possible and direct the funds to ensure that these parameters are determined as accurately as possible. Examples are used to illustrate the need for an even-handed quantification of the parameters which affect the outcome of decisions en route to the final one while minimising the risk in making an optimum assessment in relation to development funds Available.

Jan 1, 1983

By M A. Rhamdhani, R Z. Mukhlis

Removing the ledge formation in the Hall-Heroult cell during the electrolysis process may significantly reduce the energy requirement of the aluminium production process. In the absence of the ledge, however, the sidewall-material types become heavily restricted since the cryolite is very corrosive at the electrolysis temperatures. This paper study the corrosion behaviour of sintered nickel ferrite, nickel aluminate, and magnesium aluminate refractories (as possible candidates for sidewall material) in molten aluminium and cryolite melts with various alumina content at 980°C. Immersion tests of refractories with various porosity were conducted to assess the suitability of the refractories in the corrosive environment of the electrolysis cells. Microstructural change of the refractory after immersion were analysed using secondary scanning electron microscopy (SEM). Sampling of the melts were taken at 0, 10 min, 30 min, and each hour up to 6 hrs, and subsequently analysed by Inductively Coupled Plasma (ICP) spectroscopy. Based on the projected concentration of the refractories constituents in the melts, it was predicted that the corrosion rate of NiFe2O4, NiAl2O4 and MgAl2O4 in cryolite with 11 wt per cent Al2O3 were 461 × 103, 1.03 × 103, and 798 × 103 cm/a, respectively. Much lower corrosion rate of 2.3 cm/a for NiFe2O4, 2.6 cm/a for NiAl2O4 and 0.3 cm/a for MgAl2O4 were predicted if the refractories in contact with aluminium melts. Erosion played an important role in the corrosion as the concentration of the refractory constituents in the melts were beyond its solubility limit. It is therefore crucial to increase the densities of the refractory and improve its wetting characteristics.

Aug 21, 2024

During operations, mining and metallurgical processes may generate effluents such as tailings water, acid mine drainage (AMD) and seepage and process acid streams. Depending on the type of ore and the metallurgical process, these effluents may contain one or more toxic compounds (eg acidity or alkalinity, cyanide, ammonia and/or nitrate, heavy metals, total suspended solids (TSS), sulfate) in elevated concentrations requiring treatment before their discharge to the environment or recycle/reuse in the process. Natural oxidation of sulfide minerals present in mining wastes (eg tailings and waste rock) at mining sites may generate AMD, which is characterised as a low pH, high acidity effluent containing heavy metals and sulfate. If generation of AMD cannot be controlled and/or prevented, AMD needs to be collected and treated for neutralisation of acidity and reduction of metals and TSS to meet regulated water quality standards. It is important to note that some of these compounds may persist in run-off from mine sites, even after the mine and processing facilities are decommissioned. Treatment of mining and metallurgical process effluents can be accomplished by means of various physical, chemical and/or biological methods. The mode of process application may vary from the use of either specifically designed, controlled and automated facilities or passive systems. Lime neutralisation and precipitation is the most common method used in the mining industry to treat AMD. To reduce the problems associated with disposal and long-term storage of the resulting sludge, the use of a high-density sludge process (HDS) has become a preferred option. The use of other chemical reagents, waste or by-products from other industries, and biological sulfate reduction methods can also be considered as viable options for site-specific situations. Recently, several passive treatment systems have been designed and successfully operated, even in the cold North American climate. This paper will discuss available options and provide insights for selecting a suitable method for a given situation using case studies from projects conducted by Golder Associates around the world over the last decade.

Jan 1, 2006