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By Fabiano Soares

Strand guide rolls in continuous casters are crucial components for guaranteeing an optimum process for the production of high-quality steel grades. The properties of these rolls greatly influence the quality of the slab produced. The most commonly used designs so far have been the axle roll and the solid roll. A quite new roll concept is the STEC-Roll®. It combines the advantages of the axle roll with those of the solid roll. This paper explains the development of this roll type and shows the current design. The characteristics of the STEC-Roll® are presented in greater detail and are underlined by a number of simulation results. Beside the design itself, the benefits for casting and maintenance are explained, including for example the easy assembly and dismantling or the use of the roll for dry casting. A brief examination is made of the TCO for the STEC-Roll® and an estimation is provided of the exchangeability of this roll. To conclude, an overview on the current applications is presented.

Aug 17, 2017

By J. Kempken

Driven by customers, especially from the automotive sector, the supply of 100% prime quality has become essential. Furthermore the implication of quality costs and the yield of first class products define the steel companies' profitability and overall success significantly. The SMS group together with its subsidiary MET/Con has developed a comprehensive solution to assess the product quality over the production and processing chain. Process and production parameters originating from various data sources of the process automation are examined on their impact of quality related characteristics.Expert know how and comprehensive operational experience is translated into a quality guideline and a regulation framework as the sensitive core of the PQA solution.Once implemented, the system identifies immediately steel grade specific, deviations from ideal standard and proposes corrective actions including a final evaluation for each product at each processing step.The X-Pact® PQA (Product Quality Assessment) system is a substantial tool for root cause quality analysis and provides the required support to the production team. It will become an integral part of the corporate quality management system.

Aug 17, 2017

By Breno T. Maia, Débora C. O. Silveira, Mariana A. Ribeiro, Daniel A. G. de Carvalho, Roberto P. Tavares, Raissa S. Salgado

Mixing time is an important parameter when considering chemical and thermal homogenization in steelmaking reactors. It can also be relevant in the kinetics of chemical reactions. Different methods have been used to estimate mixing times in physical models of steelmaking reactors. In the present work a new method to estimate mixing times in physical models has been proposed. This method can be used when transparent fluids are used to simulate the liquid steel and the slag. Results of mixing times in a physical model of a BOF obtained with different techniques were compared. It was shown that the new method is more reliable and consistent than the common methods based on electrical conductivity measurements and colorimetric analysis.

Oct 1, 2019

By Milan Terčelj, Matej Drobne, Urška Klančnik, Peter Fajfar

The study of oxidation behavior of High Chromium Steel material used for surface layer of work rolls was carried out. Specimens taken directly from the roll were subjected to thermal fatigue in the temperature range between room temperature and 500 °C up to 700 °C by using thermo-mechanical simulator Gleeble 1500D. Our observation was focused on the impact of oxidation as a principal mechanism of degradation of the roll’s surface layer - mainly on the characteristics of oxidation propagation in relation to the test temperature and microstructure constituents characteristics of the material. Oxidation is considerably accelerated by certain characteristics of eutectic and primary carbides, i.e. their size (area), composition, morphology, orientation regarding to the water-cooled surface, etc. In the presented paper selected cases where emphasized oxidation takes place are investigated, analyzed and explained. Obtained results thus represent a contribution to explanation of conditions which lead to acceleration of oxidation behavior that in turn can lead to chipping or even early spalling of material from the roll surface layer.

Oct 1, 2019

By Ryoma Fujiyoshi

In this article, the technologies of highly durable MgO-C bricks for the scrap impact zone and bottom blowing tuyere of converters are demonstrated. On the bases of our recent investigations, wear of scrap impact zone and bottom tuyere are explainable in terms of crack initiation and propagation. Theoretically, crack propagation in brittle material is regarded as generation of new crack surface area. It occurs when the elastic strain energy stored in the material exceeds the energy required to generate a new crack surface area. Since the overall energy consumed for crack propagation until fracture is evaluated by fracture energy, materials exhibiting high fracture energy can be regarded as materials with high fracture resistance. Therefore, two fracture energy-improving technologies for MgO-C bricks were developed. One is matrix reinforcement and the other is carbon bond enhancement. These technologies were applied to bricks for the scrap impact zone and bottom tuyere. As a result of commercial applications, notable decreases in wear rates were recognized for high fracture energy materials for the scrap impact zone and bottom blowing tuyere of converters.

Oct 30, 2017

By Jorge Madias

O trabalho está centrado na análise comparativa de normas de vinte paises/regiões sobre vergalhão, escolhidos levando em conta os principais paises productores, exportadores, e consumidores deste produto para a construção civil. São comparadas as propriedades mecânicas: limite de escoamento, resistência à tração, elongamento à rotura, elongamento uniforme, relação escoamento/tração), a análise química, testes especiais como fadiga e adherência e outros ítens. Tambén é tida em conta a evolução dos quesitos das normas ao longo do tempo. O foco é o comportamento anti seismo do vergalhão.

Oct 30, 2017

By Steven George Jansto

The hot ductility behavior of different microalloyed steel chemical compositions was examined simulating the thermal and strain conditions through the straightening or unbending section of the continuous casting machine. All samples were obtained from industrial slab casters ranging from 200 to 300 mm in slab thickness from steel mills throughout the world including China, Brazil, North America and Europe. The slabs were crack-free and hot rolled into prime quality products. No laboratory heats were tested. Although these microalloyed steels exhibit inherently lower hot ductility behavior, as measured by percent reduction in area at elevated temperature, these steels still exhibit sufficient ductility to satisfactorily meet the unbending stress and strain gradients existing in the straightening section of most casters. The majority of the published hot ductility data, as measured by % reduction in area (%RA), were based on laboratory heats and hence, are inaccurate in accessing the propensity for slab cracking on an industrial caster. This situation then results in invalid conclusions for different chemistries. This research has determined the minimum required %RA for crack-free casting is significantly lower than results based upon previously published laboratory generated data. For example, the literature quotes 40% RA minimum for Nb-bearing steels when in fact as low as 10% minimum RA is more than sufficient to assure crack-free casting based upon the extensive testing and analysis performed in this study. Instead of %RA, the measurement of strain energy has been introduced to evaluate hot ductility behavior. It is concluded that strain energy is a better measure of hot ductility behaviour than %RA. There is considerable value in the evaluation of the hot stress and strain curves, process metallurgy parameters and their relationship to slab quality instead of just basing hot ductility decisions on simple %RA measurements.

Aug 16, 2017

By Rodrigo Perito Cardoso

Low-temperature nitriding of stainless steels is applied to obtain wear resistant surfaces without losing its corrosion resistance. The treatment consists in introducing nitrogen into the steel surface avoiding chromium nitride precipitation. The corrosion resistance of martensitic stainless steels is expected to be improved if the treatment parameters are correctly selected. It can be related to ?Fe2-3N and a'N phase formation on the treated surface. In the present work the influence of the pretreatment and treatment temperature on corrosion resistance of plasma nitrided AISI 420 steel samples is studied. Annealed, as-quenched and 400ºC-tempered samples were nitrided at 300, 350, 400, 450 and 500°C, for 6 h at 600 V. The pressure was 3 Torr and the gas mixture was composed of 70%N2, 20%H2 and 10%Ar, at a gas flow rate of 3.34×106 Nm3s-1. Plasma was generated using a square-wave pulsed DC power supply and the sample temperature was controlled by the duty cycle. The modified layers were characterized by optical microscopy, X-ray diffraction and microhardness measurement. The corrosion resistance was studied by electrochemical characterization, by means of Open circuit potential and Anodic polarization curves. The maximum surface hardness was achieved at 400°C. This temperature seems to be near the limit temperature for low-temperature treatment aiming to improve or at least to keep unaltered the corrosion resistance in relation to that verified for non-treated steel samples. Results confirm that the pretreatment and treatment temperature significantly affects the corrosion resistance of the treated surface.

Aug 8, 2018

By Johanna Alegría-Ortega

Cr/CrN bilayer coating was deposited on AISI 440C by Cathodic Arc. The composition and structure of the Cr/CrN coating were investigated by scanning Electron Microscope, X-Ray Diffraction and X-ray Photoelectron Spectroscopy. The results show that crystal structure obtained was CrN phase with preferred [220] orientation. The hardness and adhesion of coating also were studied. The evaluation of erosion-corrosion (EC) on 440C bare and coated with Cr/CrN was performed by carrying out wear tests using a slurry jet with impingement angle 90° at 4 and 8 m/s. Corrosion, erosion and synergism wear rate were evaluated following the procedure described in ASTM G-119-09. This study presents that the synergism wear rate exceeds 40% of the total mass loss for coating and 60% of mass loss for the 440C, being the most aggressive wear component. The increase in impact velocity generated a rise in mass loss for both 440C bare and coated. The Cr/CrN coating offers better corrosion and erosion–corrosion resistance under all the tested conditions.

Aug 8, 2018

By Constantino Capurro

For certain applications, coarse titanium nitride (TiN) precipitates can be deleterious for the final properties of the material. Hence, in order to better understand the mechanisms involved in the generation of these precipitates, a thorough characterization of the particles observed in steels with different titanium and nitrogen content was carried out. Samples from liquid steel (tundish), continuous casting billets and final product were evaluated using an Automatic Particle Analyzer (APA) coupled to a Scanning Electronic Microscope (SEM). The location, frequency, size distribution and composition of the different particles observed were assessed. While only few TiN precipitates were observed in liquid steel samples, the density of this type of particle significantly increased in the continuous casting billets samples. Particles ranging from 1 to 10 µm were mainly found in the interdendritic zones of the as-cast structure. The density of TiN particles observed in these samples did not change after re-heating and rolling operations. A model to predict TiN precipitation during solidification was developed. A reasonable agreement was found between model results and measured data. Results of this analysis confirmed that the precipitated fraction of TiN increases as the product of steel Ti and N contents rises.

Oct 30, 2017

By Aline Lima da Silva

The present work is focused on the thermodynamic study of the methane or biogas mixtures conversion on Cu-ceria catalysts. Several experimental studies reported in literature have demonstrated the ability of these materials to operate as SOFC anodes for direct methane oxidation, with the evidence of enhanced tolerance towards sulfur poisoning and carbon deposition. More recently, experimental investigations have shown the feasibility of Cu-ceria anodes to directly operate with simulated biogas feeds at intermediate temperature (1023K). In this way, the effect of the ceria redox properties on the equilibrium composition is investigated, considering methane or biogas mixtures as the fuel. Conditions under which carbon deposition and sulfur poisoning can be prevented are determined. Our study combines results from the classical thermodynamics, obtained with the help of FactSage software, with the new Cu-S and Ni-S diagrams proposed in literature, which were calculated based on the Density Functional Theory (DFT). These diagrams are able to predict a region where sulfur interacts with the metal surface through chemisorption. A comparison between the performances of Ni-YSZ and Cu-CeO2 catalysts is established from a thermodynamic viewpoint. Theoretical results are in agreement with the experimental trends from literature.

Aug 8, 2018

By Jochen Wans

BCT® - Belt Casting Technology is the new horizontal near-net-shape casting process to produce flat steel products. BCT is the revolutionary leap in casting technology, designed for the production of special and conventional steel grades. Within a partnership between Salzgitter Flachstahl GmbH and SMS Siemag AG, the worldwide first caster is now in operation. SMS Siemag AG (in cooperation with Salzgitter Flachstahl GmbH) has erected the first industrial-scale casting machine located at Peine steelworks. The lecture will start with an overview about the highlights of the BCT® process with regard to the mechanical engineering aspects, while the second part will present current commissioning results and operation experiences. Since December 2012, the BCT plant is running. Up to March 2015 more than 90 casts have been carried out, 26 with FeMn-alloys. Never before flat steel was casted in dimensions of 1000 mm * 15 mm and with casting speeds more than 14 m/min.

Aug 16, 2017

By Lionel Loïc Limol

Polymeric materials, such as polyurethanes and rubbers, are widely used in the mining industry because of their moderate cost and excellent mechanical properties. Such polymers have been used mainly in transportation (conveyor belt systems and pipes coatings) and screening, for their appreciable abrasion wear resistance. Studies revealed the complex influence of test parameters, such as grit size and applied normal load, on the abrasion wear process for polymers. In this study, the abrasive wear behavior of several polyurethanes and rubbers were investigated at room temperature according to a rotary drum abrasion method (DIN 53516). Wear tests were carried out at 26 cm/s test speed and load value of 5 N and 10 N. Corundum paper grit varying from 60 to 400 mesh were used as an abrasive surface. After each test the mass loss of the pin was recorded and the wear rates were calculated from wear volume. The wear surfaces were investigated by scanning electron microscopy.

Jul 31, 2018

By Daniel Antonio Kapper Fabricio

A avaliação das propriedades de mecânica da fratura dos materiais é uma necessidade crescente, sobretudo no setor de óleo e gás. Esse cenário exige a garantia da qualidade na execução de ensaios de tenacidade à fratura. Esse trabalho tem como objetivo realizar uma comparação intralaboratorial para o ensaio de tenacidade à fratura KIC variando o executante do ensaio, visando atender ao requisito de garantia da qualidade da norma NBR ISO/IEC 17025. Os resultados foram comparados através de análise de variância. As diferenças entre os operadores não foram significativas frente ao erro residual a um nível de confiança de 95%, sendo tal resultado considerado satisfatório.

Aug 16, 2017

By Maciej Korecki

Pyrowear®Alloy 53 steel is an excellent material for the construction of drive transmission components (gears, shafts, etc.) which have to operate in difficult conditions primarily in the aviation industry (Fig. 1.). Among the properties of such items is a high case hardness and abrasion-resistance, while the core remains flexible and is capable of carrying large impact loads. They can work at elevated temperatures with limited lubrication. The thermal treatment of such materials is based on case hardening by means of carburizing. This paper presents the technology of vacuum carburizing of Pyrowear® Alloy 53 steel. It discusses the methods of establishing different profiles of carbon concentration in a layer and their influence on the hardness profile. The effects of sub-zero treatment and tempering on the properties of the hardened case are also considered. It also presents a SimVaC® simulator of vacuum carburizing, designed especially for Pyrowear® Alloy 53 steel, which provides highly accurate predictions of the outcome of the process as the profile of carbon concentration in the layer, or vice versa: establishes the process parameters which will guarantee the required profile.

Aug 16, 2017

By Breno Totti Maia

In the present paper, a new energy balance equation was developed, considering the slag phase, in order to define the effects of jet penetration and determine a new value for the factor K. The factor K measure the resistance to momentum transference between exit nozzle and metallic bath. The experiments were performed based on the same conditions of the article used as a comparison. The results showed the same behavior between the experiments and it was possible to determine a new value for the factor K, which changed from the unit order for the metal phase system to hundredths order for the metal and slag phase systems. These results are considered unprecedented.

Aug 17, 2017

By Martim Hideki Nakayama Kurauchi

One of the main issues regarding the use of charcoal in metallurgical processes is its mechanical strength, which is much lower than coke. There is no defined standard to determine charcoal compression strength, and the methods described in the literature consist in using a prepared specimen and applying compressing load in the same direction of the charcoal fibres. As charcoal is highly anisotropic, it is proposed a procedure that does not use a specimen and with load applied on a specific direction. Instead, it intends to simulate industrial conditions by randomly dumping charcoal inside a tube, without preferential directional arrangement. This is an attempt to determine charcoal mechanical strength and predict the behaviour of bulk charcoal under a static load, as in a blast furnace. Experiments with controlled loads have been carried out on randomly distributed bulk charcoal with controlled initial size and their effect on the size distribution has been analysed. After compression, charcoal is screened and each size is weighed, determining the particle size distribution of the experiment. This method can therefore be used to evaluate charcoal mechanical strength.

Aug 1, 2018

By Afshin Sadri

One of the main reasons for blast furnace reline is the loss of refractory lining, particularly in the hearth and taphole regions. Intense operation of the blast furnace can result in extensive refractory wear and deterioration. This can then affect the continuity of the operation and the furnace campaign life. Novo-Lipetsk (NLMK) and Hatch developed a systematic approach to monitor the condition of blast furnace hearth linings using Acousto Ultrasonic-Echo (AU-E), a non-destructive testing system developed by Hatch. Continuous and periodic inspections of blast furnaces revealed areas with accelerated refractory deterioration, formation of elephant foot, extent and speed of refractory wear, as well as cracks and other anomalies. Improvement in coke quality, stave washing, the addition of titania, and other changes were recommended and implemented to prolong furnace life while maintaining the intensity of furnace operation. This paper demonstrates how the coordinated efforts between NLMK and Hatch resulted in prolonging the blast furnace campaign life.

Aug 17, 2017

By Patrizio Damiano

Competitiveness in Electric Arc Furnace production is pushing steelmakers to increase the throughput at the lowest expenditure. The technological challenge is therefore to operate the existing facilities at their top capabilities and to exploit materials and energy sources at the upmost yield and efficiency. Moreover, seizing the opportunity offered from the price variability of metallic feedstock calls for flexible practices, versatile equipment and tools to rapidly tune the melting profiles without hindering steel quality and equipment lifetime. The innovative Danieli Q-MELT Automatic EAF system addresses these aspects implementing a centralized control system which interacts with multiple technological packages. Each of these cutting-edge technologies focuses on one aspect of the EAF cycle, increasing machine availability and resource efficiency, by means of electrode regulation and foamy slag control, charging optimization, off-gas analysis and closed loop injectors control. Moreover, these modules provide the process supervisor application (Melt Model) with important information regarding the process status, thus allowing the adoption of a unified control strategy. The supervisor implements a robust statistical approach to identify process deviations in real time. The first results and technology perspectives inferred from the field immediately after the start-up are described in this paper.

Oct 30, 2017

By José Fagundes Jr., Juliano Braz Possatti, Bruno Câmara Vieira, Gabriel Godinho Alves, Bruno Bastos da Silva Murad, Cristina Maria de Oliveira Roque

Driven by market trends, increasing environmental accountability, government regulations and fostered by the Company’s strategic plan, ArcelorMittal Tubarão has developed new steel products to deliver better solutions to fit each customer’s needs. This often translates in higher strength, more complex and dimensionally challenging (thinner and wider) steels to attend a broad array of goals, such as reduction of vehicles fuel consumption and carbon emissions, increase in fatigue performance of heat treated parts, higher load capacity per net weight in vessels or wagons and lower supplying lead time as ArcelorMittal Tubarão establishes itself as a domestic option for so far imported grades. Based on the annual Product Development Plan, a structured workflow involves technical discussions from an operational point of view about safety issues, metallurgical project, steel grade family definitions, offline simulations prior to field trials, deformation resistance and process parameters adjustments and scheduling strategy. As a result of the increasing synergy between the areas, the share of new materials developed in recent years has been sustainably increased up to 15% in 2018, adding value to the final product without impact on hot rolled coil output and with a low cobble index.

Oct 1, 2019