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By R. D. Hagni

Introduction The ore deposits of the Viburnum Trend in the Southeast Missouri Lead District constitute the world's largest lead producing district. Six or seven mines currently are in production in the Viburnum Trend. The principal minerals are few in number, simple in composition, and form simple superposition and replacement textures. The economically valuable minerals in the typical lead-zinc ores of the Viburnum Trend are the sulfides, galena, sphalerite, chalcopyrite, and siegenite. The most abundant gangue minerals are dolomite, marcasite, pyrite, calcite, quartz, and dickite. Four concentrates, lead, zinc, copper, and cobalt are produced from the ores, and they contain an interesting suite of trace elements, of which silver and cadmium are recovered at the smelter and refinery.1 Emphasis is given here to the variations in directions of ore fluid flow based upon interpretations of the positions of orebodies due to the ore fluids being impeded by Precambrian basement relief and upon patterns of ore mineral/metal zoning. The Precambrian basement relief and Lamotte Formation pinchout has exerted an important control upon the specific locations of orebodies in the Southeast Missouri Lead District. The locations of some orebodies along one side of Precambrian knobs or ridges strongly suggests that they are positioned on the side from which the ore fluids flowed. Other orebodies are located in positions that suggest that they formed where the ore fluids passed around or between Precambrian knobs. Patterns of mineral and/or metal zoning have been used in many mineral districts to interpret the directions of ore fluid flow. The mineral/metal zoning pattern correlates closely with that of the mineral paragenesis. The earliest deposited minerals tend to be deposited nearest to the source, the later deposited minerals next closest to the source, and the latest deposited minerals furthest from the source. In the Southeast Missouri Lead District, it is interpreted here that the early-deposited copper-rich ores are closest to the source of the ore fluids, the subsequently-deposited zinc-rich ores are next closest to the source, and iron-rich ores are furthest from the source.

Jan 1, 2006

By S. J. Page

The personal dust monitor (PDM) is a combined tapered element oscillating microbalance (TEOM) respirable dust monitor and cap lamp, configured to have dimensions and weight similar to those of a lead-acid miner’s cap lamp battery. The Higgins-Dewell (HD) cyclone design operated at 2.2 L min-1 airflow has previously been reported to have low bias relative to the International Organization for Standardization (ISO) convention. Previous reports have described the PDM as meeting the NIOSH Accuracy Criterion. In order to avoid certain analysis anomalies encountered during these evaluations, a different method of establishing the PDM relative standard deviation was employed. Re-analysis of laboratory data for both the early prototype and precommercial PDMs indicates that the PDM still meets the NIOSH accuracy criterion, and that the precommercial PDMs are more accurate than previously reported.

Jan 1, 2011

By T. J. Driscoll

The effect of coatings on the incendive properties of aluminum alloy 6061-T651 in air-6.4%CH4 was studied for collisions between rusted steel and both uncoated and coated projectiles with incident energies as high as 300 J (220 ft-lb) and velocities as high as 200 m/s (660 fps). These conditions were intended to simulate the rough handling of equipment in coal mines. The ignition probability using uncoated alloy projectiles increased with increasing relative humidity and appeared to be influenced by atmospheric ozone content. The incendive properties of both the uncoated and coated alloy depended on the type of rust used, but the dependence of the coated alloy was very different from that of the uncoated alloy. A number of coatings developed in the last 25 years were found to offer protection from ignition and to remain largely intact for occasional collisions or collisions randomly distributed over the coating surface, but probably not for repetitive collisions at any given point on the coating. These protective coatings utilize a hard anodized aluminum alloy surface coated with one or more layers followed by heat treatment of the coating. Coatings containing Teflon and MoS2 and thicker than 50 µm (2 mils) appear to be most effective.

Jan 1, 1987

By H Vigil, G. Peach

Long tunnels with only one access shaft pose many program problems for logistics, combine these with the requirement to drive directly out under the seabed for 10.2 km, and the program issues become even more challenging. The Musaimeer outfall tunnel was one such tunnel and to meet and eventually improve on the planned completion date required a complex and extensive management of all tunnel logistics required to support consistent tunneling for a two-year period. This technical paper will discuss the management issues and solutions implemented to meet the challenges of the Outfall tunnel construction.

Dec 1, 2022

By Felicia F. Peng

The plant data were collected from three streams around a dense medium drum for coarse coal cleaning operated at various volumetric ratio of medium-to-feed. The effect of the volumetric ratio of medium-to-feed (MF) and particle sizes on the performance criteria, g50 and Ep, of the dense medium drum. These measured data were adjusted and calculated for the yields and balanced relative density distributions by mass balanced method based on the statistic principle. These balanced data were then used to formulate the mathematical models of the separation distribution curves for the various feed size intervals. The correlation equations for the g50 and Ep as the function of inverse of the feed size, and MF and total throughput were established. A numerical algorithm utilizing the Secant method, based on the root searching principle, was developed for yield optimization and simulation of dense medium drum separation to improve the separation efficiency and hence the product yield. The relationships between the direct ash content and relative density of the particles in feed and the products were established and incorporated into the numerical algorithm for predicting the product quality.

Jan 1, 1996

By D. Marino

Over the last 20 years, the manufacturing sector of our country has been called upon to comply with ever core stringent environmental standards. The primary metals sector was particularly hard hit early on, to develop the technology, acquire the equipment, and implement the programs to eliminate or reduce the by-products of metal making. To this end, through a combination of technological innovation and extensive capital expenditures, the metals industry has met, and in many cases, exceeded the minimum standards. It is to this escalating cost - liability exposure issue - that Dereco has addressed itself. As we move into the decade of the 90's, the challenge facing the metals industry concerning the environment will be even more difficult than the previous decade. To focus in on one major aspect of legislated environmental regulations, the issue we will address today is; now that the by-products of metal production have been identified, accounted for and collected, how are they to be disposed of? During the course of this presentation, actual data will be presented from our 4 1/4 year on-site experience at J & L Specialty Products

Jan 1, 1992

By J. Diao

In order to understand the flotation kinetic behavior of coal and associated mineral matter, a detailed investigation was conducted in a 2-liter Denver flotation cell using three high sulfur coals at three feed sizes, minus 28. 100 and 200 mesh. Subsequently. the flotation products were sieved into different size fractions and analyzed for their ash and pyritic sulfur content in order to delineate the effect of particle size on the rate at which each constituent floats. The results were tested with several different flotation kinetic models and the best model for coal was then chosen. The flotation rate constant and the ultimate recovery calculated from a kinetic model were used to delineate the effect of particle size, collector (dodecane) and frother (MIBC) dosages on the flotation kinetics of coal, ash and pyrite.

Jan 1, 1992

By Bruce K. Cantrell

As part of a continuing study of diesel exhaust aerosol characteristics, the Bureau of Mines has applied Chemical Mass Balance (CMB) model source apportionment analysis to evaluate a size selective sampling method for determining the separate diesel exhaust and coal dust aerosol concentrations in a diesel equipped coal mine. Size selective sampling was used under the premise that diesel exhaust aerosol dominates the submicrometer aerosol size range, while most of the mineral dust aerosol is greater than 1 m. A micro-orifice, uniform deposit impactor (MOUDI) was used as the size selective sampling method. Concurrent samples of mine aerosol were collected using a dichotomous, respirable aerosol sampler. This sampler separated the fine and coarse size portions of its sample at 0.7 m. Trace element concentrations for in-mine aerosol sources and the dichotomous samples used by the CMB model were measured using Instrumental Neutron Activation Analysis. The CMB analysis, applied to both the fine and coarse fractions of the respirable mine aerosol, yielded the mass concentration contributed to each by diesel exhaust and mineral dust aerosol sources. The MOUDI size distribution data were analyzed using nonlinear regression to parameterize the fine and coarse fractions of the sampled aerosol and to estimate the contributions to each fraction from both coal dust and diesel aero- sol sources. For the diesel mine visited, analysis of the MOUDI samples yielded a value for the fraction of the fine aerosol attributable to coal dust of 15[]7% fine fraction coal from analysis of the MOUDI samples versus 25[]4% from the CMB analysis. The remainder of the fine aerosol in the mine was diesel exhaust aerosol. CMB analysis confirms the original premise for such sampling. After correcting for the presence of coal dust in the fine aerosol fraction, analysis of the MOUDI size distributions yielded estimates of respirable mineral and diesel exhaust aerosol concentrations that were accurate to with-in 10% of values determined by the CMB apportionment.

Jan 1, 1987

By Jung-Joo Kim, Jong-Uk Kim, Turab H. Jafri, Han-Kyu Yoo

"INTRODUCTION Steel sets such as H-type and lattice girders are often installed in the tunnels before the hardening of shotcrete to ensure the stability of conventional tunnels in soft ground conditions. In practice, while designing the tunnels with the help of numerical analysis, steel sets are generally considered only as temporary support elements. Only a few studies propose the direct application of composite support in the tunnel design, based on large-scale experiments and numerical analysis. In order to assess the structural performance of the composite support consisting of shotcrete and steel sets, large-scale experiments were performed on two types of arch-shaped specimens by applying the combined effects of axial forces and bending moments. Based on the experimental results, numerical analysis was performed to assess the application of composite support in tunnel design. The crown settlement, axial forces, bending moments, and load distribution in the composite support were analyzed in the light of different structural patterns. LARGE-SCALE EXPERIMENTS USING COMPOSITE SUPPORT Preparation and Procedure of the Experiments The preparation setup as well as the organized procedure of the large-scale experiments using composite support is shown in Figure 1. An appropriate geometry of the specimens was selected by considering the standard cross-section of a two-lane highway tunnel in South Korea. Under the loading conditions meant to develop the axial forces and bending moments simultaneously, arch-shaped specimens were assembled with the ends of the specimens subtending a 60° arc angle at the center of the arc circle as shown in Figure 2. The fabrication of six specimens was completed in two groups based on the dimensions of steel sets, with the first group of three specimens being reinforced by H100 (No.1, No.2, No.3) and the other three by H125 (No.4, No.5, No.6). In order to reduce the voids on the boundary of the shotcrete and steel sets, concrete was casted over the steel sets instead of using shotcrete. The specimens were designed to incorporate the uniaxial compressive strength of 21 MPa. Shear keys and steel plates were installed at the ends of the specimens, so that shear failure could be avoided at the ends and the specimens could also be protected from detachment at the fixation. Translational and rotational movements at the ends of specimens were fixed."

Jan 1, 2016

By Levent Ozdemir

An extensive study involving laboratory testing and computer modeling has been performed to assess the technical and economic feasibility of utilizing the recently developed minidisc cutters on roadheaders for hard rock mining. The results show that heavy duty roadheaders fitted with minidiscs can excavate hard rock formations at acceptable production rates and cutter costs. This paper presents and discusses the results of this study together with the ongoing developmental efforts of this technology, which include laboratory testing of a roadheader cutting drum with minidiscs and full scale field testing of a machine in hard rock

Jan 1, 1995

By M. S. Safarzadeh

Cu-As feedstocks are among the most problematic copper sources that have been avoided over the past years. The high arsenic content of such ores/concentrates combined with their refractory nature have directed the metallurgical industry towards developing efficient technologies for the treatment of high-arsenic copper ores/concentrates. As the most important member of Cu-As-S mineral system, enargite (Cu3AsS4) is frequently encountered in some of the important copper deposits. Several hydrometallurgical and pyrometallurgical processes have been examined for the treatment of enargite concentrates, but currently, no commercial operation exists. In an effort to develop an original processing option, an acid bake-leach process has been identified and applied to an enargite concentrate containing ~67% enargite, ~27% pyrite (FeS2), ~3% chalcopyrite (CuFeS2), ~6% sphalerite (ZnS) and <1% galena (PbS). Sulfuric acid baking of this concentrate resulted in the transformation of the concentrate to S8, As2O3, HFe(SO4)2?4H2O, PbSO4 and Cu0.47Fe0.53SO4?H2O, all of which (except elemental sulfur and PbSO4) dissolved during the water leaching step. More than 87% Cu and 64% As were leached when the concentrate was baked at 200°C over 7 h with a sulfuric acid to concentrate weight ratio of 1.6. Less than 1% As was lost to the gas phase. Upon water leaching, copper and arsenic were released to the solution at a concentration ratio of about 3:1. While enargite is very reactive during the sulfuric acid baking reaction, other minerals present in the concentrate such as pyrite, galena, and sphalerite may compete to consume sulfuric acid and be converted into their corresponding sulfates at different levels. The purpose of this paper is to evaluate phase transformations during the acid bake-leach process for the treatment of an enargite concentrate, and to study the effect of sulfuric acid dosage on the extraction of Cu, Fe, and As. In this regard, the concentrate, baked concentrate, and the leach residues are characterized and a conceptual process flowsheet is described for the acid bake-leach process for the treatment of enargite concentrates.

Feb 23, 2014

By James W. Derrick

General widespread interest in fine coal cleaning circuits did not occur in the United States until the mid 1960&apos;s. Up until this period the relatively low price for which bituminous coal was sold did not justify for many operators the capital and maintenance costs associated with the beneficiation and drying of fine coal. However, with current growing interest in this area, the introduction of new types of process equipment along with modifications to existing components is occuring to maximize the recovery of coal fines. In 1973 Derrick Manufacturing Corporation introduced high frequency screening machinery into the coal industry. The first design consisted of a 4 ft. wide 18 ft. long single deck screen frame with three 100 mesh woven wire screen surfaces divided by repulping troughs for the addition of wash water. In addition, a special slotted rubber dewatering deck was installed on the discharge end of the unit to assure adequate dewatering of the screen oversize. This panel had nominal 25 mesh X 3.0" slotted openings. The machine was also equipped with a special high speed-low amplitude (3600 RPM .032" % AMP.) integral vibrator.

Jan 1, 1983

By Y. J. Zhang

This paper presents the results of a recent study on the development of an in-situ testing method for determining the coal strength in mine pillars. The strength testing is performed in the horizontal holes drilled into the coal rib using the penetrometer. It is a hydraulically powered device that uses an indenter to press the surface of the borehole until the load reaches the failure point of coal. The pressure and the penetration of the loading pin are recorded by the data acquisition unit. The results collected from several coal mines indicate that this testing method is ideally suited for the realistic coal strength measurements. The new testing system not only improves the accuracy of pillar strength determination, but it is more cost efficient than the conventional method.

Jan 1, 1995

By Jon A. Hummer, MICHAEL R. SHAHAN, Aleksandar D. Bugarski, Shawn Vanderslice

A study was conducted in an undergroundminewith the objective to identify, characterize, and source apportion airborne aerosols at the setup face and recovery room during longwall move operations. The focus was on contributions of diesel- and battery-powered heavy-duty vehicles used to transfer equipment between the depleted and new longwall panels and diesel-powered light-duty vehicles used to transport personnel and materials to various locations within the mine. Aerosols at the setup face were found to be distributed among diesel combustion-generated submicrometer and mechanically generated coarse aerosols. According to the data, the submicrometer aerosols downstream of the setup face were sourced to diesel exhaust emitted by vehicles operated inside and outside of the panel. Depending on the intensity of the activities on the panel, the outby sources contributed between 12.5 and 99.6% to the average elemental carbon mass flow at the setup face and recovery room. Extensively used light-duty vehicles contributedmeasurably to the elemental carbon concentrations at the setup face. The number concentrations of aerosols downstream of the setup face were associated with aerosols generated by combustion in diesel engines operated in the shield haulage loop and/or outside of the longwall panels. Entrainment of road dust by diesel or battery-powered load-haul-dump vehicles operated near the measurement site appears to be the primary source of mass concentrations of aerosols. The findings of this study should help the underground mining industry in its efforts to reduce exposures of miners to diesel and coarse aerosols.

Apr 14, 2020

By J. A. González-Anaya

This laboratory work presents a study of the effect of ultrafine grinding on the gold recovery of a highly refractory gold concentrate. The particle size of the concentrate was P80 = 46 µm and the main species present were quartz (28.58%), dolomite (25.63%), pyrite (20.93%), arsenopyrite (15.39%) and 112 g/t gold. After optimizing hydrated lime and lead nitrate additions, standard cyanidation with 1% NaCN, pH = 12.3, 25% S/L permits to recover only 9.4% of the gold. Different particle sizes were submitted to cyanidation. When the concentrate was ground to ultrafine sizes (P80= 4.6 µm), the gold recovery for the same cyanidation conditions increased to 67%, with cyanide consumption of 66.7 kg NaCN/t. Additional tests were performed in order to reduce the cyanide consumption. The reduction of the cyanide concentration in the leaching solution from 1 to 0.5% and the addition of 100 g Pb(NO3)2/t allowed the reduction of the cyanide consumption to 27.6 kg NaCN/t (58% reduction), while maintaining the same gold recovery of 67%. The remaining gold could be present as very fine inclusions or in solid solution in the matrix.

Jan 1, 2011

By V. Anthony Cammarota

MINERALS INFORMATION PROGRAM Mineral data collection by the Federal Government actually began in 1882 with an appropriation by Congress to the U.S. Geological Survey (USGS). Although the Bureau of Mines was instituted in 1910, it was not until 1924 that the collection, interpretation, and dissemination of worldwide information on production, consumption, and availability of minerals became the responsibility of the Bureau. The objective of the Bureau&apos;s minerals information program is to maintain and provide reliable, timely, and comprehensive data for analysis of national minerals problems. This program is implemented by a staff of specialists who cover about 100 mineral commodities and the mineral industries of 168 countries. Data are also provided on the minerals industry on the State and county level. The specialists analyze information to identify trends and problems, forecast future U.S. and world supply and demand for the nonfuel minerals, and relate trends and developments to their impact on the domestic minerals industry. Data Sources and Publications The primary sources of data concerning the domestic minerals industry are the companies that produce, use, and trade in these minerals. Approximately 60,000 survey forms are sent to industry, on a monthly, quarterly, semiannual, or annual basis, to obtain the data. Domestic trade data are provided by the Bureau of the Census, U.S. Department of Commerce. Information on mineral developments abroad is developed by Bureau specialists from mineral reports supplied by U.S. embassies worldwide, from primary source documents, from a review of the technical mining literature, and from onsite mine and plant visits in foreign countries. The information is disseminated through a number of Bureau publications: "Mineral Industry Surveys" provide aggregated data on a monthly. quarterly, or semiannual basis to give timely information on the most important mineral commodities. "Mineral Commodity Summaries," published each January, provides preliminary annual data on supply and demand and discusses significant events of the previous year. The final data are published later in the "Minerals Yearbook," which is the definitive historical record for mineral statistics. "Mineral Facts and Problems," an encyclopedic work issued every 5 years, covers industry structure, technology, supply-demand analysis. economic factors, reserves, and forecasts of U.S. and world demand for individual commodities. "Mineral Perspectives" and "Mineral Issues" cover important international mineral developments and significant issues of current U.S. policy as they relate to minerals. Discussions and analyses of mineral trends and developments also appear in other Bureau publications, such as "Minerals and Materials" and "Information Circulars." These publications provide the basis for analysis and policy determinations by the Bureau and by virtually every Federal agency concerned with minerals, defense issues, the national economy, and foreign relations. The data are also used by industry in planning capital investments in mines and processing plants, by financial analysts, by U.S. delegations in their work with international commodity groups, and by a host of other minerals related organizations. Data Bases The data bases used by the specialists for preparing publications or in response to a continuous stream of inquiries include both those that contain individual commodity data from respondents, and those that are summary data bases on production, trade, capacity, employment and a number of other minerals-related items, not all of which are derived from data reported to the Bureau of Mines. The data bases maintained on the mainframes are not accessible by non- Bureau users. A 10-year data base of supply- demand data, published each year as an update of tables that appear for each commodity in Mineral Facts and Problems, is available on a floppy

Jan 1, 1987

By Mark J. Schultz, William J. Francart, Michael P. Snyder

The Pittsburgh Safety and Health Technology Center surveyed MSHA Coal Mine Safety and Health Districts to monitor the implementation of computer based atmospheric monitoring systems (AMS) in underground coal mines. This survey was first completed in 1984, and has been periodically updated with the latest update completed in 1995. The utilization of computer based monitoring systems has steadily increased over the past 12 years, with over 16 percent of all producing underground coal mines using this technology in 1995. This paper discusses the results of the MSHA 1995 AMS Survey.

Jan 1, 1997

By J. A. Organiscak

Enclosed cab filtration systems are typically used on mobile mining equipment to reduce miners? exposure to airborne dusts and diesel particulates generated during mining operations. Various filter configurations can be used within the heating, ventilation, and air conditioning (HVAC) systems of cabs to remove the airborne contaminants. The air cleaning performance of cab filtration systems is highly dependent on the efficiency of the air filters, the number of filters used, and their placement within the HVAC system. This paper shows how to mathematically model cab filtration systems and illustrates a methodology for developing other cab filtration system design models. Node diagrams of several filtration system circuits are illustrated with their mathematical models at steady state airflow and concentration conditions. Laboratory and field data are presented to demonstrate the validity and utility of modeling enclosed cab air cleaning performance. The paper concludes that incorporating multiple filters throughout the HVAC system improves the air cleaning performance and robustness of the cab filtration system design.

Feb 23, 2014

By V. T. McLemore

"Lindgren (1933) defined a belt of alkaline-igneous rocks associated with large quantities of gold and rare earth elements (REE) that extends from Alaska and British Columbia southward into New Mexico, Texas and eastern Mexico. The North American Cordilleran alkaline-igneous belt since has been exploited for numerous types of mineral deposits. In New Mexico, Mid-Tertiary alkaline to calc-alkaline rocks are found with seven types of deposits in these districts: (1) polymetallic epithermal/mesothermal veins, (2) gold-bearing breccias/quartz veins, (3) Cu-Au, Au and Mo porphyry deposits, (4) skarns and carbonate-hosted deposits, (5) iron skarns and replacement bodies (with some gold), (6) gold placers, and (7) Th-REE (with some U, Nb) epithermal veins. Some of New Mexico’s largest gold and REE deposits are found within this belt. Their origin is not well understood, but a compilation of new data (age dates, isotopic and chemical analyses) allows for a better understanding. The diversity of igneous rocks and associated mineral deposits along this belt suggests that this region is characterized by highly fractionated and differentiated; multiple pulses of magmas and involves both upper mantle and lower crustal sources. Once magmas and metal-rich fluids reached shallow levels, local structures and wall rock compositions determined distribution of and final style of intrusions and resulting mineral deposits. INTRODUCTION Lindgren (1933) was one of the first geologists who noted that a belt of alkaline-igneous rocks extends from Alaska and British Columbia southward into New Mexico, Trans-Pecos Texas, and eastern Mexico (Fig. 1) and that these rocks contain relatively large quantities of gold, fluorine, zirconium, rare earth elements (REE), and other elements. Since then, the North American Cordilleran alkaline-igneous belt has been explored and exploited for numerous types of mineral deposits, especially gold. The North American Cordilleran alkaline belt is a north-south belt of alkaline igneous rocks and crustal thickening, roughly coinciding with the Great Plains physiographic margin with the Basin and Range (Rio Grande rift) and Rocky Mountains physiographic provinces (Mutschler et al., 1985, 1991; Bonham, 1988; Thompson, 1991a; Richards, 1995; McLemore, 1996; Jensen and Barton, 2000; Kelley and Luddington, 2002). Deposits within this belt have produced significant amounts of gold in the United States and Canada and include Cripple Creek, Colorado (702 metric tons of gold production), Black Hills, South Dakota (235 metric tons gold production) and Landsky-Zortman, Montana. In New Mexico, the North American Cordilleran alkaline belt extends from the Sangre de Cristo Mountains near Raton, southward to the Cornudas Mountains, in the northern Trans-Pecos alkaline belt (Fig. 2). The alkaline-igneous related mineral deposits in New Mexico have been referred to as Great Plains Margin (GPM) deposits by North and McLemore (1986, 1988) and McLemore (1996, 2001). Alternative classifications by other workers include Au-Ag-Te veins (Cox and Bagby, 1986; Bliss et al., 1992; Kelley et al., 1998), alkalic-gold or alkaline-igneous related gold deposits (Fulp and Woodward, 1991a; Thompson, 1991a, b; Bonham, 1988; Mutschler et al., 1985, 1991; Richards, 1995), porphyry gold deposits, and the North American Cordilleran belt of alkaline igneous rocks (Woolley, 1987; Mutschler et al., 1991)."

Jan 1, 2015

Fundamental results obtained from research on the properties of the edge surfaces of kaolinite particles (~500 nm) are reported. Of particular significance was the development of the experimental protocol. Well-ordered kaolinite edge surfaces were prepared as an epoxy resin sandwich structure having layered kaolinite particles in the center of the epoxy resin sandwich. Images of the sectioned kaolinite edge surfaces were examined by atomic force microscopy (AFM), and the average thickness of kaolinite particles in this study was determined to be 38.3 nm ± 11.7 nm. Furthermore, the surface charge of the kaolinite edge surfaces was evaluated with a super sharp Si tip. The point of zero charge (PZC) of the kaolinite edge surface was determined to be below pH 4, in contrast to the traditional view that the edge surfaces of kaolinite particles may carry a positive charge at pH 4. This lower PZC of the kaolinite edge surface was attributed to the lack of isomorphous substitution in the silica tetrahedral layer when compared to the PZC for the muscovite edge surface. Our results are consistent with the particle aggregation and flotation behavior of kaolinite, and should provide the basis for improved flotation strategies leading to the efficient recovery and utilization of mineral and energy resources.

Feb 23, 2014