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By H. William Zeller

The Bureau of Mines performed laboratory research to determine the effects of a barium-based fuel additive on diesel particulate emissions. The test engine was typical of types used to power underground coal min-ing equipment. Test parameters consisted of baseline measurements without additive, three fuel additive concentrations, and five steady-state engine loads, all at 1,200 r/min. Additive effects on soot mass concen-tration, opacity, particle size distribution, volatile fraction, and NOx emissions were determined. Important findings are as follows: Using the manufacturer's recom-mended additive concentration increased the gravimetrically measured mass of particulate by 30 to 80 pct at four of the five steady-state load conditions. Soot measurements by optical methods did not agree with those by gravimetric techniques, for additive-treated fuels. The additive reduced volatile hydrocarbons adsorbed on filter deposits by up to 50 pet. At most engine loads, carbon particulate was also reduced. About 40 pet of the barium added to the fuel was accounted for in the exhaust. The health implications for miners were considered, but no firm conclusions were drawn or recommendations made because the results are for steady-state conditions, which may not be representative of real-world operation of diesel-powered equipment underground.

Jan 1, 1987

This Information Circular from the National Institute for Occupational Safety and Health (NIOSH) documents and supplements the information presented in a series of workshops held during 2002 and 2003. The primary intended audience consists of all who are involved in developing and conducting miners' training. According to the Mine Safety and Health Administration (MSHA), mine operators reported 240,000 full-time equivalent workers and independent contractors reported 42,000 full-time equivalent workers working on mine property during the year 2000. Unfortunately, these workers have a relatively high risk of suffering serious work-related injuries and illnesses. The mining industry has the highest rate of occupational fatalities among all U.S. industries. The fatality rate is 30 deaths per 100,000 workers compared to 4.6 for all private industry (Morbidity and Mortality Week Report, 2001; NIOSH, 2002). Compared to workers in other industries, miners also have a relatively high rate of nonfatal lost-time injuries, and their injuries tend to be more severe (Bureau of Labor Statistics, 1999). Many miners are also exposed to significant health hazards, including coal and silica dust, diesel exhaust, and noise. More than 1000 U.S. miners die of lung disease each year (NIOSH, 1999). Mine safety and health professionals have long recognized training as a critical element of an effective safety and health program. Federal regulations (30 CFR, Parts 46 and 48) require mine operators to provide initial safety and health training to all new miners, as well as a minimum of 8 hours of refresher training each year. The time and money being spent to train U.S. miners is substantial, and so there is a strong and steady demand for new and better mine training materials and methods. A growing concern among mine safety professionals regards the training of new workers. A major change in the mining workforce is anticipated within the next decade. In major segments of mining, especially coal, relatively few workers have been hired since the 1970's. Thus, as an entire cohort of miners in the current workforce nears retirement, the replacement of these employees will require an influx of new workers. New miners may be young people who lack the ability to recognize and respond to mining hazards in an appropriate manner. They may also have had different educational experiences than their older counterparts. Many safety professionals believe that these two cohorts require different approaches to training. The papers in this report should help prepare mine trainers for the changes about to occur in the workforce and acquaint them with strategies they can use to enhance the effectiveness of their training. The first three papers present basic principles for teaching adults. The five remaining papers are intended to illustrate how these principles can be applied to the development and imple¬mentation of effective training for miners. Below is an overview of these papers. 1. Kowalski and Vaught review the process and principles of adult learning. The learning model they present includes a discussion of goals, content, delivery, assessment, and remediation. Adults are viewed as active learners, experienced-based, expert in their own right in specific areas, independent, real-life centered, task-centered, problem-centered, solution-driven, skill-seeking, self-directing, and internally and externally motivated. Basic aspects of curriculum development are briefly reviewed. For further information about adult learning, see Camm and Cullen's paper. 2. Mallett and Reinke's first paper discusses issues related to training new miners who have recently or will soon be entering the mining workforce. These new generations of miners have different learning style preferences and training needs than Baby Boomers and other older miners. Even trainers who have been highly effective in the past should reassess their training styles and their classroom materials to determine if they are prepared to meet the needs of these young new workers. This paper provides information that will help mine trainers communicate across the generation gap. 3. Mallett and Reinke's second paper provide an overview of training evaluation. Trainers and decision-makers are given a framework for planning and assessing training evaluation strategies. The authors present Kirkpatrick's (2001) model of evaluation categories and discuss how to start an evaluation plan and various ways to collect data. They do not provide detailed instruction in evaluation methodologies, but give trainers a review of the things they need to consider when developing an evaluation plan. A good evaluation plan can inform revisions to a training course, assess trainee learning, and/or answer managers' questions about program effectiveness. 4. Brnich, Derick, Mallett, and Vaught discuss a technique for incorporating worker participation into fire prevention and safe equipment operation training. This technique involves development of short (5 to 7 minutes) videotapes coupled with toolbox talks that ground the content of the videos within the context of a miner's workplace. An example of one of these training modules is presented, along with the results of an evaluation performed on its effectiveness at improving miners' understanding of what types of information they should be sure to communicate during a mine emergency. 5. Wiehagen, Conrad, Friend, and Rethi discuss on-the-job training (OJT) as a method for teaching miners safety and production skills. Much of the training is done by experienced workers. This paper describes how small investments can help improve the effectiveness of on-the-job training. Effective on-the-job training involves some structure and planning in the transfer of responsibility for task performance from the trainer to the novice. Assisting the trainer could involve helping develop up-to-date job analyses and offering strategies for teaching and evaluating job skills. This paper addresses organizational considerations supporting structured on-the-job

Jan 1, 2002

By Bill M. Stewart, Philip W. Patton, Curtis C. Clark

Handling materials in underground mines continues to be a major safety problem. To help reduce materials-handling injuries, researchers at the Spokane Research Laboratory of the National Institute for Occupational Safety and Health are investigating those materials-handling tasks in underground mines that appear to generate a high number of injuries. Data from the Mine Safety and Health Administration for the years 1989-1999 were studied to find out if there were any trends in materials-handling accidents and if so, to determine what tasks were involved and the sources of injuries. Several underground coal and metal mines we revisited to document innovative materials-handling technologies. Considerations for safety training and mechanization needs for continued reduction in materials-handling injuries are described.

By Robert K. Koch

Laboratory-scale studies on defluorination of natural and synthetic fluorspars by pyrohydrolysis at 1,500° C. were made to determine the feasibility of developing a process for producing hydrogen fluoride from siliceous fluorspars. It was found that the reaction (at 1,500° C.) is not promising for process development, even though a silica-free offgas can be generated. The primary difficulty is the low hydrogen fluoride content of the offgases; an HF content of 6 percent was the best achieved. Previous research by the Bureau of Mines has demonstrated that offgases averaging 27 percent hydrogen fluoride can be produced under carefully controlled conditions at 1,280° C. The lower temperature process is a better method for production of HF. However, charges in which the CaF to Si02 mole ratio varied from 0.4 to 2 could be processed with similar results. Also, combined alumina and ferric oxide contents up to 25 mole-percent did not noticeably alter the rate of defluorination. Therefore, virtually any natural siliceous fluorspar would respond in essentially the same manner when exposed to water vapor at 1,500° C.

Jan 1, 1962

By M. P. Ristenbatt, E. K. Holland-Moritz, K. Metzger

A new post-disaster signalling system for the Bureau o Mines, using through-the-earth EM propagation, was successfully field-tested in the Lake Lynn test mine. Successful detection at an estimated input SNR of -30dB was accomplished using a coherent integration time of 4.46 minutes. The transmitted waveform consisted of a repeating pseudonoise maximal length sequence phase modulating a 1950Hz carrier. The receiver used a sliding-window matched filter, optimal for signal known exactly except for phase and starting time, implemented via a special purpose processor. Parallel processing permits adaptive signalling, where the detection (integration) time is determined by the actual input SNR encountered. This field test demonstrates a trapped miner detection system that is about 36dB more sensitive than a current pulsed system. This increased sensitivity permits some desired combination of increased range, shorter detection time, and reduced transmitter power or antenna-size. The combination of pulse-compression-type-signal, coherent integration, parallel-processing, and output peak-detection algorithms permit implemention of an ultra-reliable detection system. The same combination is compatible with digital Pulse Position Modulation and Emitter position location strategies.

Jan 12, 1983

By J. Mutmansky, C. Lee

"The size distribution of coal mine dust is one of its most important characteristics because the particle size is known to govern the region of deposition of dust within the human respiratory tract. In addition, dust characteristics, particle settling rate, transportability of the dust and the efficiency of dust control measures are all affected by the particle size. As a result, particle size distribution of the airborne dust in a coal mine is a fundamental property that impacts on the health of underground workers.This paper deals with some basic findings on the size distribution of cool mine dust based upon the results of data collection in six underground coal mines using continuous miners. All airborne dust sampling was performed on development sections using eight stage cascade impactors and permissible 2. O l / min pumps. Samplers locations were fixed in the sections with respect to the continuous miner and roofbolter or with respect to the intake and return airways • Sampling times varied from 45 minutes to 6 hours , depending upon the dust concentration. The first topic of analysis was the test to determine whether the commonly used lognonnal distribution is valid when applied to airborne coal mine dust. Secondly, the conventional method of representing the· distribution using two parameters, the geometric mean and the geometric standard deviation, is questioned. Since almost all size data were found to show some degree of bimodality, the two parameter lognonnal distribution may not represent the total airborne coal mine dust size , quite adequately. Bimodal lognonnal distribution was tested to be a good approximation in the case with two modes in the size distribution.The final topic discussed in this paper is the 'locational variation of the airborne dust size distributions within the continuous mining section. The size distributions varied considerably at the different sampling locations with the continuous miner and roofbolter producing the coarser distributions. Fine size modes in the range of 2 to 4µ m including mostly respirable dust particles were present in almost all samples • Second dust generating sources such as the shuttle car movement were found to be major causes of high respirable dust concentrations in some cases ."

Jan 1, 1988

By McHenry Mosier

Mercury is one of the strategic metals the supply of which has been raised from critical uncertainty to more than enough for essential demands. Work by the Bureau of Mines has contributes substantially to increased production of mercury in the United States and to consequent accumulation of Governments stock. Other contributing factors were higher prices for mercury and Government loans to operators. The Bureau has undertaken 15 exploration projects, 13 of which have been completed. This work comprised 40,307 feet of drilling arid 35,082 linear feet of sure ace trenching and has indicated commercial ore containing 37,400 flasks of mercury and marginal ore contain¬ing 29,200 flasks - a total of 66,600 flask , equivalent, respectively, to domestic production at 50,000 flasks per year for 9 months , 7 months, and 16 months. Early in 1944, as Government stocks had become adequate, domestic production was gradually curtailed cancellation of Government contracts for the purchase of mercury and Government control of labor and operating supplies.

Jan 1, 1944

By E. L. Rawlins

A previous report4 has explained that pipe lines for the transmission of natural gas should be buried to minimize temperature fluctuations because when excessive the latter decrease accuracy in measuring gas volume and increase leakage of gas due to expansion and contraction in the pipe joints. These effects are governed by the rapidity of the temperature fluctuations and by the total variation over a period of time. The temperature of gas flowing through a pipe line depends to a large extent, upon the temperature of the ground adjacent to the pipe; hence, fluctuation of the ground temperatures at various depths determines the economic depth at which pipe lines should be buried. Scope and Purpose of Report This report covers a record of the daily atmospheric temperature fluctuations at Bartlesville, Okla., for 12 months and a-similar concurrent record of the temperature variation 1, 2, 3, and 4 feet below the surface of the ground.

Jan 1, 1928

By D. E. Hirsch

The Bureau of Mines has developed a systematic procedure for separation, characterization, and semiquantitative analysis of high-boiling (350° to 550° C) distillates of crude oils. Isothermal and molecular distillation were used to prepare the 370° to 530° C distillate of Recluse, Wyo., crude oil. The distillate was separated into fractions by chemical treatment, silica-alumina gel adsorption, and gel permeation chromatography (GPC). The fractions were analyzed by use of GPC correlations and mass and nuclear magnetic resonance (NMR) spectrometry. The increased knowledge of petroleum composition obtained from the data will contribute to improved petroleum processing and utilization and energy conservation.

Jan 1, 1974

By H. H. Schrenk

Much has been written and said concerning tables of permissible or maximum allowable concentrations of various toxic substances in air, but not enough attention has been given to their limitations and how to use them intelligently . There is a tendency to place too much reliance on figures , with little or no consideration of their real meaning . The repeated publication of a figure often adds significance to it far beyond that intended by the original author or publisher . How are these figures referred to as "maximum allowable concentrations " established? What is their real meaning? To answer these questions it is necessary first to define maximum allowable concentration . The usual definition is somewhat as follows : "The average concentration to which an industrial worker can be exposed for 8- hours daily for an indefinite period without injury or occupational disease . This definition is made up of the following items : ( 1 ) Average concentration, ( 2 ) 8 - hour day , ( 3 ) indefinite exposure period , and ( 4 ) lack of injury or occupational disease . There is some controversy regarding item ( 1 ) , items ( 2 ) and ( 3 ) are usually though not invariably accepted , and there is definite disagreement regarding the interpretation of item ( 4 ) . . To reach a more satisfactory interpretation of maximum allowable concentration , attention is directed to ( 1 ) the development of tables of maximum allowable concentrations , ( 2 ) criteria on which limits are based , and (3 ) methods used to obtain data on which limits are based .

May 1, 1948

By Wallace W. Roepke, Jon I. Voltz

"The Bureau of Mines determined coal-cutting forces and primary dust generation of four styles of radial gage bits as used on end rings of continuous mining machines. Direct comparisons for reference were made with two widely used conical plumb-bob types having 60° and 90° (nominal) included tip angles. The cutting forces for all of the gage bits were similar to those of the 60°-tip plumb-bob bit. All bits except the RAD-3 gage bit generated similar amounts of primary total dust at shallow cutting, but during deeper cutting, the amounts varied and the gage bits produced as much as 2-1/2 times the dust produced by the 60° bit. This seems atypical since past experience has always shown differences in dust generation at shallow cutting. The specific energy was more like that found previously with other bits, since the values were spread at shallow cutting but became nearly similar at deeper cuts. The 90° bit and the RAD-3 gage bit are not recommended for use except in extremely difficult cutting conditions where dust and forces are of secondary importance. The choice among the remaining four bits can be made on the basis of dust, energy, forces, or cost, as circumstances dictate. INTRODUCTIONThe Federal Coal Mine Health and Safety Act of 1969, with revisions in 1977, was enacted to ensure more healthful and safer working conditions for miners. The Bureau of Mines coal-cutting research facility at Twin Cities (MN) is examining fundamental aspects of the cutting system, including generation of primary dust causing pneumoconiosis in miners and ignition of methane by the frictional impact of cutting bits used on continuous mining machines (CMM's). The cutting system is defined as the cutter-mineral interface area with all its variables, e.g., forces, speed, cutter geometry, bit-mounting geometry, and wear. It has become obvious over the past several years that the cutting system directly affects the economics and design of the ""total system,"" which is defined as all areas of the operation, from the mine face to the preparation plant, which support the mineral recovery by cutting tools to obtain a salable product."

Jan 1, 1983

By S. H. Ash

As part of the work done at the Washington coal mines during the year 1929 , a study was made of the safety practices in and about the mines . Inasmuch as electrical blasting has made considerable headway it is interesting to note the manner in which it is done and the reasons why it was discarded at some of the mines . Blasting is done at the mines in the State by means of capped fuse , electric blasting " caps , " and in some instances by electric delay detonators . Black blasting powder with fuse is used at most of the open- light mines . The use of squibs was discontinued several years ago because the coal operators , without exception , recognized the dangers incidental to their use . Permissible explosive and dynamite are also used at some of the open- light mines . With the exception of some rock work and the driving of level work in gangways and air courses the explosive is detonated by means of capped fuse .

Apr 1, 1930

By Lars Osen

The Bureau of Mines investigated (1) the effect of torsion on yield and ultimate strengths of bolts when the torsion is applied first and tensile load is applied independently of torsion and (2) various methods of increasing the tension-torque ratio and/or narrowing the data spread of the tension-torque relationship. A special torsional attachment was fabricated to attach to a universal testing machine to independently subject rock bolts to combined tensile and torsional loads. It was found that initially installed torsion is nullified during tensile loading and the tensile yield and ultimate strengths are not significantly reduced. Lubricating various components of a bolt assembly or using hardened washers will improve the tension-torque relationship during conventional installation; however, the torsional load is not nullified during this type of loading. Hence, a bolt is subjected to a combined stress throughout the loading cycle; the yield point will thus be lowered compared with the pure tensile yield if care is not taken during installation to stay below the torsional yield.

Jan 1, 1966

By W. E. Miller, W. P. Yant, G. W. Jones, R. E. Kennedy

"The determinations of the limits of inflamability of diethyl ether and ethylene in air described in this report were made primarily for comparison with similar determination of other compounds in the same apparatus and by the same laboratory technic. The experimental procedure and the results obtained differ somewhat from those of other investigations. The work also included determinations of the limits of inflamability of these combustibles in oxygen The investigation,was conducted at the Pittsburgh Experiment Station of the United States Bureau of Mines in cooperation with Merck & Co., Inc. LIMITS OF IMFLAMIABILITY OF DIETHYL ETHER-AIR MIXTURESThe limits of inflamability if diethyl ether in air were determined for upward propagation of flame in an upright, closed 8-liter, cylindrical iron bomb 10.2 cm in inside diameter and 96.5 cm in length. This bomb been described in a previous publication. 6Two brands of diethyl ether were used, one a C. P. sulphuric ether manufactured by Baker & Adamson, and,the other Merck & Co. product manufactured for anaesthesia and containing about 3.5 percent of ether alcohol."

Jul 1, 1935

By W. H. Rinkenbach, C. A. Taylor

"Among the recently patented detonating compounds that have been suggested as substitutes for the commonly used fulminate of mercury is the normal lead salt of trinitroresorcin, or styphnic acid. As no data concerning its use or practi¬cability were available, a study of its properties was made in the explosives laboratory at the Bureau of Mines experiment station at Pittsburgh, Pa. This paper embodies the results obtained.Normal lead trinitroresorcinate was first prepared and patented*** by Herz; it probably found some use during the World War, but no record of its performance is available,Preparation of Lead Trinitrpresorcinate.In his patent specifications, Herz states that the normal salt may be obtained in a quantitative way by precipitating a multiple of the equivalent weight of the lead salt of a strong inorganic acid - such as lead nitrate - in the presence of a weak organic acid - such as acetic acid - by heating with a Teak solution of the alkali-metal salts or alkaline-earth salts of trinitroresorcin. Herz gives the following example: 245 grams of dry trinitroresorcinand 290 grams of crystalline sodium carbonate are dissolved in in 18.8 liters of boiling water, to which 77 c.c. of glacial acetic acid is added. The toiling solution is mixed with a boiling solution of 650 grams of lead nitrate in 1.4 liters of water, stirring rapidly; and the mixture is boiled for two minutes, after which it is cooled quickly with constant stirring. The precipitated crystals are then filtered off, washed several times with cold water, and dried."

Oct 1, 1923

By Kyei-Sing Kwong

The U.S. Bureau of Mines investigated the synthesis of advanced ceramics (SiC+AlN, SiAlON, SiC+A1203, and Si3N4+AlN) from natural clays (kaolin, halloysite, or montmorillonite) by an intercalation and heat treatment method. This process includes the steps of refining a clay, intercalating organic chemicals into its layered structure, drying the intercalated mixture, firing the treated structure at certain temperature ranges in controlled atmospheres to form desired compounds, and grinding the loosely agglomerated structure. Focus of this research is to economically process advanced ceramic structures from abundant natural resources. The advanced ceramic phases produced in this simple treatment are homogeneously distributed at the nanostructure level, and may potentially lead to cost effective manufacturing processes. The intercalation of clay was confirmed by X-ray and BET analyses. The evolution of chemical compositions during carbonization reactions and carbothermal reduction was investigated. The characteristics of refined clays and synthesized powders were studied. Advanced ceramic composites/solid solution have been produced from intercalated clays, without the presence of other compounds.

Jan 1, 2010

By R. V. Subramanian

This project financed by the Bureau of Mines investigated the use of polymers to achieve rock bonding and reinforce coal mine structures for better or permanent ground support. Support was achieved by pumping the polymers into the rock interstices to bond the mass together for increased structural competence. Holes were drilled in the mine roof, after which the polymers were injected at about 100 psi to permeate the cracks. Initial laboratory work indicated that of all the resin systems tested, the epoxy resins could most likely be modified to be suitable for rock injection. This was confirmed when several potentially suitable resin systems underwent intensive evaluation. In a series of three field tests, two conducted in a copper mine with coal mine-type shale and the third in a coal mine, it was shown that the polymers penetrated cracks less than 0.005 inch wide. The fast-setting epoxy systems, cured out in thin films under mine conditions, produced a bond exceeding the strength of the uncracked virgin rock.

Jan 1, 1974

By Ann G. Kim

The Bureau of Mines estimated the methane content of a coal, which depends primarily upon rank and pressure, from the adsorption equation V =kpn, where k and n are constants related to rank. By incorporating corrections for moisture, ash, and temperature, and estimating pressure and temperature as a function of depth, the methane content of coal in place can be estimated from the following equation: [ ] Values calculated with this equation generally are in reasonable agreement with direct determinations. By assuming a standard moisture and ash content, and using the hydrostatic head to estimate pressure, a graph of rank and depth versus gas content was constructed. Although estimated values were consistently high for several high-volatile bituminous coals from an area where the pressure is known to be less than hydrostatic, the estimated methane content for most coals shows reasonable agreement with values determined by the direct method.

Jan 1, 1977

By Robert W. Freedman

In the Bureau of Mines study, a filter with a 20-by 20-inch-square cross section was inserted into the exhaust ducting of a 4-stroke-cycle, 90-hp diesel engine, and the efficiency of removal of total particulate was measured gravimetrically as a function of time. Removal efficiencies were close to 90 pct during the main portion of several extended runs employing several combinations of filter beds. Variations in engine load had little effect on collection efficiency. Particle size as measured by a Bureau-developed online instrument centered on 0.07 m based on number count. Removal efficiency increased rather sharply for both larger and smaller particles.

Jan 1, 1979

By William J. Campbell

The Federal Bureau of Mines provided five test materials--amosite, short-and long-fiber chrysotile, crocidolite, and nonfibrous tremo1ite--to the National Institute of Environmental Health Sciences (NIEHS) for studies on the biological effects of orally ingested asbestos-related materials. An inter-agency agreement between the Bureau and NIEHS made possible this program to characterize these test materials. The Bureau in turn received support through contracts with the Ontario Research Foundation for the milling of amosite and crocidolite, and with the University of Maryland for microscopic measurements. The five test materials, which were supplied in quantities of 960 to 1,200 pounds each, were characterized by chemical-instrumental analysis for elemental composition, surface area, density, X-ray diffraction, infrared spectroscopy, thermogravimetric analysis, mineralogy, and particle size analyses. Particle size distributions were emphasized because of the current theories relating adverse biological effects to length-width characteristics of durable elongated particles.

Jan 1, 1980