Search Documents

By W. D. Riley

The U.S. Department of the Interior, Bureau of Mines, has been conducting minerals recovery research in support of the nation's geothermal program since 1974. The Bureau's program of laboratory and field studies has focused on determining the materials of construction for geothermal resource recovery plants and an the recovery of mineral values from the geobrines. An analytical program has been conducted at the Avondale Research Center to determine the chemical constituents of some high- and low-salinity geobrines found in the Imperial, Valley of California. Data are reported for the early stages of brine production of femur geothermal wells--the low-salinity, medium-enthalpy brines from the East Mesa Known Geothermal Resource Area (KGRA), Mesa 6-1 and 6-2, and the high-salinity, high-enthalpy brine from the Salton Sea KGRA, Magmamax 1 and Woolsey 1. The reported results indicate the importance of the operating and engineering history, the operating parameters during sampling, and the method of sampling in order to evaluate the chemical analyses.

Jan 1, 1980

By R. R. Nothdurft

The internal friction of eight single crystals of magnesium with orienta-tion ranging from 10° to 84° was measured at 33.5 kc and 272° C, and the results were interpreted in terms of the pinned-dislocation model proposed by Granato and Lucke. Results show that the strain-amplitude-dependent decrement varies with orientation in a manner predictable by the G-L model. Different values of strain-amplitude-independent decrement were observed at different orientation angles, but correlation with the theory was not conclusive. Problems and steps for further study are discussed.

Jan 1, 1965

By James H. Jolly

Although zinc in the environment is generally considered to be beneficial or benign, excessive amounts can cause deterioration of environmental quality and toxicity problems for some plants and animals. High amounts of zinc in the environment are often associated with anthropogenic activities, mainly those involving zinc production and consumption and those related to the use and disposal of zinc-containing products. To obtain some upper limit parameters on the historical quantities of zinc chat may have entered the U.S. environment from anthropogenic sources, the Bureau of Mines conducted a materials flow study of zinc from the earliest beginning of the domestic industry through 1990 and for the year 1989. For comparative purposes a generalized historical materials flow of zinc for the world was also prepared. The United States was the world's leading producer and consumer of zinc in the 1850-1990 period. In that period, U.S. mines and smelters produced 15% and 20%, respectively, of world output, and U.S. zinc consumption accounted for about one-fourth of the world total. Maximum zinc losses into the environment related to the above production, consumption, and disposal of end use products total about 63 million tons. Dissipative uses and landfill disposal have accounted for about 73% of the potential zinc losses to the environment, followed by mining and smelting 22%, and manufacturing, 5%. At the end of 1990, contained zinc in useful end-products in the United States was estimated to be about 23 million tons. In 1989 slightly more than 1 million metric tons of zinc in new zinc-containing products were added to the domestic pool of zinc in use but in the same year, an estimated 0.9 million tons was dissipated and discarded, indicating only small net gains to the zinc pool of use annually.

Jan 1, 1992

By Roy L. Wilfong, LeRoy R. Furlong, Louis P. Domingues

The bulk and apparent densities , particle size , and surface area of ceria powders derived from the ammonium sulfate , carbonate , nitrate , oxalate , and sulfate salts and heated at 950 ° to 1,500 ° C for 1 to 24 hours were studied . The bulk and apparent densities and particle size generally increased , and surface area decreased with increase in temperature and time of heating ; surface area was more sensitive to changes in temperature and time than the other properties studied . These properties of the ceria powders had a marked dependence on temperature and a lesser dependence on duration of heating at a given temperature ; and the source of oxide and thermal treatment cannot be considered optional in the preparation of refractory powders by thermal decomposition . The ammonium sulfate and sulfate salts heated at 950 ° and 1,200 ° C produced oxide powders with the lowest bulk density , the smallest particle size , and the highest surface area . The highest apparent densities were achieved for oxides resulting from the carbonate and the sulfate but the carbonate - derived material was considerably coarser . The surface areas of ceria powders derived from cerium salts decrease in the order of sulfate , ammonium sulfate , nitrate , oxalate , and carbonate . The observation of these physical properties are useful in predicting the sintering behavior of various oxide powders .

Jan 1, 1964

By R. L. Hopkins, H. T. Rall

A continuous method has been developed for preparing thiolacetic acid . Acetic anhydride and hydrogen sulfide are passed concurrently over an amine ion- exchange resin , under 20 - psi pressure . The thiolacetic acid , a product of the reaction , is flashed continuously from the crude reaction mixture and is purified by fractional distillation . The yield of thiolacetic acid is in excess of 80 percent based on the acetic anhydride charged . INTRODUCTION In the synthesis of reference compounds needed in the identification of sulfur compounds in petroleum , thiolacetic acid has become an important reagent because of its use in the synthesis of thiols by addition to appropriate olefins : R - CH = CH₂ + CH3 - COSH R- CH2 - CH2 - S - COCH R - CH2 - CH₂ - SH + CH3COONa NaOH (1 ) The commonly used procedures for its preparation , as described by Clark and Hartman (1 )4 and by Ellingboe (2 ) , are based on the batchwise reaction of acetic anhydride with hydrogen sulfide :

Jan 1, 1964

By R. W. Lewis

The Federal Bureau of Mines Boulder City Metallurgy Research Laboratory conducted experiments in order to develop a spectrochemical method for determining the concentrations of impurities In high-purity tungsten. This report presents a procedure, developed by these experiments, for determining 19 impurities in high-purity tungsten. Metal samples were thermally converted to the oxide, mixed with graphite, which was prepared and mixed with an internal-standard element, and excited in a d.c. arc. Sixteen of the impurity elements were determined with one set of conditions, using germanium as an internal standard. Lanthanum was used as an internal standard in the tests for boron and chromium. Molybdenum required the substitution of sodium chloride for the graphite and the use of copper electrodes. Data on the precision of the method are included in this report. The coefficients of variation vary considerably but average about 15 percent. Higher concentrations of impurities than those investigated may be determined with some modifications of the testing procedure, provided attention is given to the possibility of interelement interferences.

Jan 1, 1961

By J. M. Mutmansky, R. A. Jankowski, M. A. K. Mohamed

"SYNOPSISKnown health hazards associated with the breathing of respirable dusts, particularly silica dust, during mining are becoming a great concern in many parts of the world. The search for effective and low cost dust control methods for underdeveloped countries will help in improving the productivity and keeping the mine environment safe. This article addresses the problem by providing suggestions concerning the easiest and most cost effective methods to control respirable dust in mining and mineral processing operations. INTRODUCTIONMedical BackgroundLung diseases caused by dust in mining operations have been recognized by mankind since the time of the Roman Empire. The writings of Pliny the Younger on natural history reported on maladies associated with dust in mining in the first century AD. However, no significant advances in controlling the lung diseases of miners came about for many centuries. The effects of mineral dusts were further described by Georgius Agricola in his sixteenth century book on mining (Agricola, 1556). After the appearance of Agricola""s book, lung diseases were more readily recognized, but the nature and severity of the ailments associated with mineral dusts could not be readily interpreted.In 1896, the discovery of x-rays by Roentgen advanced the diagnosis of lung diseases and the knowledge of what causes these diseases. In addition, the discovery allowed medical personnel some method of judging the extent and severity of the lung diseases in human beings. During the ensuing years, the term 'pneumoconiosis' became the common term to describe any of the diseases of the lung in which dust particles deposited in the lungs caused fibrous tissue and loss of some of the respiratory function. However, little in the way of social remedies for the diseases resulted until much later. Society was still not ready to act decisively to reduce the causes of lung disease due to the dusty conditions in the work place.Social action against lung diseases did not occur in the United States (US) until the 1930s. At that time, a tunnel driven through a sandstone mountain near Gauley Bridge. West Virginia, caused the death of several hundred workers due to acute silicosis, a severe form of pneumoconiosis caused by silica (Seaton, 1975). Dust conditions in this tunnel were quite bad, causing many of the workers to be subjected to extremely high silica dust concentrations. The severity of the disease in many of the workers became known to the public and prompted the US Congress and many of the states to enact laws to reduce the dust levels."

Jan 1, 1998

By G. R. Palmer

Using a fluidized, countercurrent multiple-compartment ion-exchange (MCIX) column previously developed by the Bureau of Mines, Bureau researchers have successfully extracted uranium from a simulated acidic in situ leach liquor that contained 150 ppm U30s? This successful demonstration of the MCIX system is reported, and the effects of varying the operating conditions on the performance of the system are also examined. Operating the MCIX system with a flow rate of 15 gpm/ft2 and an aqueous-to-resin flow ratio of 200:1, more than 90 percent of the uranium Has extracted, and a resin containing approximately 28 grams U308 per liter was produced. The absorption column used to investigate the operating variables was approximately 18 feet long with a 2-inch ID and was divided into compartments that were 1 foot long.

Jan 1, 1980

By Oliver Bowles

From the most remote periods of civilization, stone Las been used to perpetuate the memory of individuals or to immortalize their noble achievements. Ancient memorials ranged from simple piles of stone (cairns) or single markers to great obelisks and pyramid or magnificent mausoleums. The Taj Mahal at Agra, India, built of white marble by Shah Jehan in memory of the Empress Mumtaz Mahal, is one of the most beautiful and costly memorials ever built. It was erected between 1632 and 1050 at a cost estimated at a: high as $50,000,000, and it is today an object of unusual attraction for travelers. Other magnificent memorials, both ancient and modern, are to be found in many lands. Memorials of varying design have characterized the passing centuries and have found an important place in the New World. In early days, monuments were chiefly imported into America, but gradually an extensive memorial stone-manufacturing industry developed on this side of the Atlantic. Sales value of domestic memorials, f.o.b. quarry or mill, attained a maximum of $17,488,755 in 1920, and retail sales, of course, reached a much higher figure. Modest markers and tombstones are to be found in almost every rural community in the United States, and there are many elaborate and costly monuments in and near urban centers.

Jan 1, 1938

By Charles C. Myers, Robert M. Doerr

The apparatus described was developed for determining the kinetics of gas - solid reactions at high temperatures by measuring the volume of gas consumed with respect to time . This apparatus consists essentially of a horizontal precision- bore glass tube connecting a small reaction chamber in a furnace to a large constant - temperature reservoir . A drop of mercury in the tube separates the two sides of the system and serves as an indicator that moves at a speed proportional to the rate of gas consumption . The sensitivity of the apparatus depends inversely on both the density of the gas in the system and the cross - sectional area of the tube ; with a tube having an area of 0.079 cm² , the sensitivity for oxygen at 308 ° K and 0.5 atm is 20 cm/mg . The reproducibility of data with the volumetric apparatus is good .

Jan 1, 1964

By Clarence O. Babcock

Model pillars of limestone, marble, sandstone, and granite having length to diameter ratios of 3:1, 2:1, 1:1, and 0.5:1 were broken in axial compression to determine whether lateral end constraint affected the breaking strength. Steel rings bonded to the ends of the model pillars with epoxy provided, during the loading cycle, a lateral end constraint of about 17 to 30 percent of the average axial stress. The effect of this constraint was to increase the breaking strength of the rock as compared to cylindrical pillars without constraint. The percentage increase in breaking strength varied with rock type and increased as the length to diameter ratio decreased. The maximum increase in breaking strength was 35 percent for marble pillars having a length to diameter ratio of 0.5:1. A theory was developed which relates the expected constraint to the physical properties of the ring and rock.

Jan 1, 1968

By J. G. Eisele

Solvent-extraction characteristics of dodecyl phosphoric acid (DDPA) were investigated to determine its potential as a fractional or selective extract-ant for individual elements in a rare-earth-yttrium mixture. The DDPA is an effective extractant for splitting rare-earth mixtures into light and heavy subgroups. Yttrium normally extracts with the heavy rare-earth elements but may be shifted toward an extraction sequence with the light rare-earth elements by increasing the pH. Elements in the light and heavy ends of the rare-earth series can be separated from middle-group rare-earth elements by using diethylenetriaminepentaacetic acid (DTPA) as an aqueous phase counter-extractant. Hydrogen-ion dependency of the distribution coefficients differs from that reported for similar systems at tracer-level concentration.

Jan 1, 1965

By A. W. Fahrenwald

The logic leading to the development of the experiments in this paper already has been stated in Part I,3 but is briefly as follows: The results of the batch-grind experiments in which time of "grind" and fineness of finished product were the variables, strongly indicated (1) that batch grinding involving a single grind could not be operated under any condition to give maximum mill efficiency, (2) that the, sieve analysis of the feed charge in the mill materially affected the efficiency of the mill, and (3) that the percentage of finished product in the mill is a vital factor in ball-mill efficiency. A laboratory closed-circuit grind technic designed to simulate present closed-circuit grinding suggested itself, in which: a ball mill and a classifier constitute the grinding unit. The features of the closed-circuit grinding system are: (1) Short large diameter mills, (3) rapid flow of pulp through the mill, (3) continuous automatic removal of finished product from the system, and (4) high circulating loads. The high circulating load is a result if the short length of the Mill - that is, of the time the charge remains in the mill - and the small percentage of finished material produced during each circuit of the feed through the mill.

Jan 1, 1930

By K. K. Kershner

The purpose of this investigation was to develop methods on a laboratory scale for recovering tin from metallurgical slime, Tin chlorides were volatilized using mixtures of hydrogen chloride and reducing gases, such as hydrogen, carbon monoxide, hydrogen sulfide, ethane, propane, and butane. Optimum conditions were found to be n mixture of 3:1 of hydrogen and hydrogen chloride at 475° C. Over 95 percent of the tin was volatilized as chlorides. Low temperatures and relatively rapid rates of reaction are distinct advantages of the chloride volatilization process. Research is being continued with various slimes and will be extended to tin ores, where the method offers interesting economic possibilities in comparison with current tin-smelting practice.

Jan 1, 1957

By W. E. Wallace

Volume-rate-of-flow measurements were made of the flow of mercury through porous samples under conditions of no field, magnetic field transverse to the direction of flow, and transverse magnetic field and electric current to determine if a magnetic method might be potentially useful in the study of pore-size distribution. No change was observed in the flow rate from the application of a magnetic field alone. The application of both field and current produced an electromagnetic pumping action with or against the direction of flow, depending upon the direction of the electric current. This pumping effect was observed to be greater in a rectangular porcelain sample than the calculated value for an equal-Sized open channel.

Jan 1, 1969

By K. Kar, A. Sreeoath, M. Gautam

"This paper presents results of an experimental investigation of the sampling efficiency of a blunt cylindrical sampler oriented with respect to the oncoming flow. The number of particles sampled by the cylindrical blunt sampler and an isokinetic sampler is measured using the TSI Aerodynamic Particle Sizer. A technique is described to conven the ratio of the particles sampled into the sampling efficiency. The experimental data thus obtained is then compared with the impaction model of Vincent and Mark (1982) with the empirical constant determined from our experiment.. The comparison shows excellent agreement for 0° and 90° orientation.1.0 IntroductionCylindrical dust samplers are widely used in practice to determine the concentration of the airborne particulate matter. The sampler is simply a means to collect particles from the ambient, whose concentration is subsequently measured by some size selective techniques. Gravimetric and optical techniques are the two most commonly used methods to measure the particle sizes. While impactors are used in gravimetric analysis, Aerodynamic Particle Sizer, Aerosizer. Electron microscope, Coulter Counter etc. use the optical method to measure the particle sizes. The Aerodynamic Particle Sizer (APS) and the Aerosizer are the new generation devices which employ the time of flight of particles within intersecting laser beams to determine the particle size.The introduction of the sampler in the free stream disturbs the flow pattern due to two distinct actions of the sampler on the fluid stream: one of them results due to the conformity of the flow to the geometry of the circular cylinder and the second one is caused by the flow into the suction orifice. If the sampler performance is determined by the number of particles entering into the sampler inlet relative to the number of particles present in the free stream, then the particle trajectory outside the sampler and into the inlet is the deterministic factor for the sampling efficiency. The particle trajectory inside the sampler is not important in this case."

Nov 1, 1995

By J. K. Richmond

Early research on coal dust explosions by the Federal Bureau of Mines and in other countries is reviewed to examine the effect of a single inhibitor, rock dust, on the explosion limits of coal dust. The parameters studied in this research included coal dust fineness, volatile content, and type of initiation. This research resulted in appropriate safety regulations in the respective countries. Also reported are the results of recent research in the Experimental Mine of the Bureau of Mines to investigate in detail the limits of coal dust explosions; the research used three types of coal with rock dust added as the independent variable. New experimental techniques and new criteria for defining propagation/nonpropagation were applied to the experiments. Also, a limit explosion propagation model is proposed based on the assumption of rapid devolatilization of the coal particles, with the subsequent combustion of the evolved volatile products contributing primarily to the propagation of the explosions. The model assumes also that the resultant char acts mainly as an inert diluent similar to the rock dust. The model also suggests that the function of stronger initiation is mostly to lift more dust from the mine surfaces.

Jan 1, 1975

By L. E. Schultze

As part of the Bureau of Mines research program on recovering alumina from domestic resources, methods for extracting iron from aluminum sulfate solutions (obtained by leaching kaolinitic clay with dilute sulfuric ,acid) were investigated. In countercurrent extraction experiments at a l-gal/hr flow rate of aluminum sulfate leach liquor, the iron concentration 'was decreased from 1.4 g/l to 0.01 g/l after four stages of using a primary amine extractant. The iron-loaded amine solution was regenerated in five stages using 3[N] sulfuric acid or in four stages using 6[N] sulfuric acid. The aluminum sulfate solution obtained was suitable for the preparation of alumina meeting cell-grade standards of less than 0.01 pct iron.

Jan 1, 1979

By Robert Stefanko

Transients are results of sudden changes which take place in power systems and can be created by the opening and closing of switches and circuit breakers or the occurrence of a fault anywhere in the complex. Transients are of short duration, and the time during which they occur is an extremely small percentage of the total operating time. However, it is during these short periods that the greatest electrical stresses occur, mainly due to excessive currents or voltages. In extreme cases, system parts are damaged, and equipment failure follows. Safety can be further compromised because anomalous voltages can exist at machine frames. For several years, the electric utilities have been well aware of the serious nature of transients on their systems, but problems firmly believed to directly result from these phenomena are just now becoming apparent to the coal mining industry. The situation became discernible after the underground introduction of high voltage distribution systems (along with vacuum circuit breakers) and sensitive solid state electronic apparatus. In order to protect against such transients, knowledge about their characteristics and origin must be obtained.

Jan 1, 1974

Monitoring systems can have numerous uses in the mine. They can aid in the efficient management of the mine by providing environmental trend data, production and maintenance control, and communications. In some cases, they can provide justification to petition the Mine Safety and Health Administration (MSHA) fog a variance of one of the mandatory safety standards. They may also increase the gross revenues of the mine by increasing the amount of coal produced or increase profits by reducing the cost of producing that coal. No single system will satisfy the requirement of all mines. Some may require simple hard-wired status-reporting systems; others, multipurpose computer-based systems that collect, analyze, and store data and perhaps control some mine functions. Even though systems vary in complexity, they are all composed of three functional components. The first component is sensors that measure the environmental or production parameters and produce an electrical signal that is fed into the telemetry. The second is telemetry devices that receive the signal from the sensors and transmit it in either analog or digital format to the third com¬ponent, analysis and display equipment. This equipment receives the transmitted signal and either stores it for later analysis or displays it. The analysis-display equipment ranges from simple strip chart recorders with preset alarms to computers, cathode-ray tubes (CRT's), and line printers that can also provide production reports. 4.2 Uses of a Mine Monitoring System A list of potential uses for mine monitoring systems, including both production-related functions and those related to health and safety, was used to develop a questionnaire. It was presented to representatives of the mining community to determine their current monitoring priorities. The responses indicated that the industry's priorities fall into the following two categories: First priority- Production and haulage Maintenance Second priority- Ventilation Communication Fire monitoring Personnel The survey shows that production-oriented systems were the most appealing to the questionnaire respondents. Since even small improvements in production efficiency and maintenance can have a large financial impact, the desirability of monitoring systems that focus on these areas is understandable. The results are summarized in table 4-1. The function that scored 100 was viewed as the most beneficial monitoring function.

Jan 1, 1984