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By H. H. Yancey

In this information circular is presented a summary of the more important articles that nave appeared in the literature pertaining to the experimental work and to the commercial operation of the froth-flotation and Trent processes as applied to the cleaning of fine coal.

Jan 1, 1933

By James M. Stuckey

In a search for improved methods of upgrading tar obtained by low-temperature carbonization of coal, monoethanolamine (MEA) was found to be effective in extracting tar acids from coal tar distillates derived from a subbitunwous and a lignite coal. Patch extractions showed that both yield and purity of the extracted acids improved with increasing volume ratios of monoethanolamine to tar acid, varied from 1:4 to 8:1. Yield improved, but purity decreased as the concentration of monoethanolamine was changed from 30 to 70 volume-percent, and as the concentration of tar acid in distillate was increased ad from 14 to 45 percent. In a continuous countercurrent extraction employing a double solvent (monoethanolamine and hexane) approximately 80 percent of the tar acids was extracted from 170° to 350° C. tar distillate when using 1.6:1 volume ratios of amine:tar acids. Tar acids isolated from his extract, although of improved purity, contained appreciable quantities of neutral oils and some tar bases. Aqueous monoethanolamine was not effective for extracting the last 10 to 15 percent of tar acids in 170° to 350° C. distillate oil from lignite coal. The highest yield of isolated tar acids and the best recovery of monoethanolamine were obtained by diluting the extract with water and saturating with C02. Some losses of solvent were encountered when aqueous monoethanolamine solutions were heated through decomposition of the amine with the liberation of ammonia.

Jan 1, 1960

By James C. Cawley

The Bureau of Mines conducted an investigation to statistically determine the mean current or voltage for resistive, inductive, and capaci-tive circuits that would cause spark ignitions in 8.3% methane-air, 5.3% propane-air, and 7.8% ethylene-air mixtures. Each mean ignition current or voltage was determined on the basis of 100 trials. Each trial consisted of 400 revolutions, 200 in each polarity, at 80 rpm of the standard breakf1ash apparatus. In general, spark ignition curves published in UL 913 for resistive and inductive circuits represent approximately the mean current values determined in this study, while published capacitive circuit values in methane are considerably less than the mean voltage values from this study, especially for a capacitance of less than 100 ~F. For resistive and inductive circuits, spark ignitions were obtained at currents con-siderably below those in the published curves, but this study was not optimized to find minimum ignition values. This report defines "safety factor" as applied to intrinsic safety testing as the energy ratio of the mean values of ignition current or voltage for two test gases. The safety factors presented in this report are not constant with voltage or current and, therefore, are not recommended for use.

Jan 1, 1986

By William J. Campbell

The columbite-tantalite mineral series was studied by various instrumental techniques to establish the relationship of density to composition. The samples used were carefully selected to obtain a mineralogical purity of at least 98 percent. Impurities were determined by optical microscopy, X-ray diffraction, and optical and X-ray spectroscopy. Each sample was analyzed by fluorescent X-ray spectroscopy for iron, manganese, columbium (niobium), and tantalum. The existence of a unique relationship in this isomorphous series permits a simple correlation of the intensity of a spectral line with the concentration of the analytical element.

Jan 1, 1955

By Raymond B. Ladoo

"The talc and soapstone deposits of Vermont have been worked more or less continuously for nearly 100 years, but all of the early efforts seem to have been directed toward the production of slabs for foot warmer, and other similar uses. Altho soapstone of good quality occurs at several places, much of the material first utilized was really talc and was not massive enough to be cut successfully. The grinding of talc in Vermont seems to have commenced in about 1902 and has shown continuous growth since that time. Statistics compiled by the Geological Survey in Mineral Resources of the ,United States show that the production of talc in Vermont has increased, from 8,978 short tons valued at $65,525 in 1905 to 93,960 short tons valued at $625,150 in 1917. Until 1917, New York was the leading producer in both tonnage and value with Vermont second, but in 1917, Vermont took the lead in tonnage produced, although not in value, with a production of over 47% of the total tonnage produced in the United States and over 35% of the world's pro-duction. This increase in production will probably be continued, though possibly at decreased rate, for the reserves of talc In Vermont are large.Active talc mines and mills in Vermont are found in four districts: Chester, Windsor County; Rochester, Windsor County; Waterbury, Washington County; and Johnson, Lamoille County, These mines and mills are distributed as shown in the following table:While there are a great many other known deposits of talc and soapstone in Vermont, some of which have been worked, those listed above are the only ones which have survived and are producing on a commercial basis. The closing down of many mines and quarries, for example, those at Perkinsville, Stockbridge, Reading, Cavendish, and Athens, has been attributed to several causes. Of these causes the most important seem to be exhaustion of the deposit, poor grade, long haul to the railroad, poor management due to lack of knowledge of mining methods and failure to consider talc mining strictly as a business proposition. The companies which are now operating with greatest apparent success are those which have realized the present and future possibilities of their industry, and have invested sufficient capital in both equipment and personnel to establish their companies on a firm business basis."

Sep 1, 1919

By Debra A. Griffith

The U.S. Bureau of Mines currently is researching the relationship between the level of back strength and the probability of low-back injury. This report is a review of the literature and statistics on over-exertion injuries. Overexertion continues to be a significant source of injury in metal and nonmetal mining, accounting for approximately 24 pct of all injuries yearly. These injuries, particularly to the lower back, can be very expensive in human and monetary terms. An examination of the accident data on overexertion injuries is necessary to provide a background for research into prevention and/or amelioration of those in-juries. The job categories outlined in the Accident Data Analysis data base most affected are "Mechanic/Electrician" and "Mill/Plant Worker." The age group most affected is "30-39" years, and the experience group most affected is "0-.99" years. The most prevalent type of overexertion injury is "Strain/Sprain," and the trunk is the body part most often involved in an overexertion injury.

Jan 1, 1994

By B. L. Razzaboni, P. Bolsaitis

"The formation of reactive oxygen species resulting from the interaction of silica dust particles with red blood cell membranes was investigated; particularly, the effect of surface hydroxyl (silanol) group concentration on the rate of formation of such reactive oxygen species was investigated. The rate of formation was measured indirectly through the effect of catalase, a hemoprotein peroxidase, on silica-induced hemolysis. It was found that the addition of exogenous catalase to erythrocytes markedly reduces the hemolysis caused by silica particles. Furthermore, the amount of catalase required for deactivation of silica per unit area of particle surface is lower for fumed silica particles and calcined crystalline particles than for uncalcined, crystalline silica, suggesting a correlation between the concentration of OH groups at the silica particle surface and its potential for generation of H2O 2• The addition of albumin, a copper chelator, also decreases hemolysis. These results suggest that the hemolysis caused by silica particles is at least partly related to the formation of H2O2 at the particle surface and its subsequent reaction with Cu+ ions. The relationship between the concentration of surface silanol groups on the silica surface and the amount of catalase required to decrease hemolysis may also provide a method for testing potential fibrogenicity of respirable dusts. IntroductionReactive hydroxyl groups on silica surfaces are known to be cytotoxic and are believed to play a major role in silicosis (1-9). It has been proposed that this cytotoxicity results from hydrogen bonding to cell membranes and a resulting increase in membrane fluidity and permeability (4). Surface hydroxyl groups on silica surfaces have also been shown to interact with carbonyl oxygens in cell membranes (1,5). An extensive study by Nolan et al. (6) of the relationship between the negative surface charge resulting from ionized silanol groups and the hemolytic activity of crystalline a-quartz (Min-U-Sil) has shown a positive correlation between hemolytic activity and the surface concentration of silanol groups. These authors demonstrated that the hydrogen bonding of polyvinyl-N-oxide (PVPNO) with silanol groups, as well as the bonding of metal cations to the ionized sm- groups, results in significant decreases in hemolytic activity. Furthermore, it has been found that the complete removal of surface hydroxyl groups from the surface of respirable silica particles nearly eliminates the hemolytic potential of silica (7), suggesting that hydroxyl groups might be involved in other cytotoxic processes associated with silica-induced lung injury. Reactive oxygen species have been .implicated in cellular damage caused by respirable silica particles. Evidence for the presence .of oxygen radical species (02, OH°, H2O2) generated by silica, especially on freshly formed surfaces, has been produced by various investigators. Kalbanev et al. (8) detected H2O 2 in aqueous suspensions of quartz. Electron spin resonance and spin trapping by Shi et al. (9) confirmed the presence of OH"" radicals in aqueous suspensions of quartz, and Gulumian and van Wyk (10) suggested that both glass and quartz produce hydroxyl radicals in the presence of H2O 2 • Gabor et al. (11) detected the presence of malondialdehydereactive lipid peroxides (i.e., lipid-0°) in cultures of macrophages and respirable silica particles using the thiobarbituric acid (TBA) reaction test. Will (12), however, reported that iron enhances the TBA value of peroxidized lipids, and Scheulen and Kappus (19) found that catalase augmented malondialdehyde formation, thereby increasing the TBA values."

Jan 1, 1990

By M. S. Oudenhoven

The Bureau of Mines conducted an investigation to determine the theoretical stress distribution in the vicinity of explosively expanded rock bolt anchors independent of their bolts. Plane-strain solutions applicable to this problem were obtained by combining the field pressure with the uniform pressure that would be produced by vertically placed anchors having 2-, 3-, and 4-foot spacings. High rock stress which would be produced by an anchor was localized, as would be expected from St. Venant's effect, and increased as the field pressure decreased.

Jan 1, 1967

By Gary W. Krantz

Fibered, portland-cement-based gunite products were applied in the Bureau of Mines Lake Lynn Laboratory Experimental Mine using a variety of pneumatic guns and gunning crews, The demonstrated wet-mix (with silica fume), dry-mix, and surface bonding products were sampled by the Bureau and subjected to a suite of engineering analyses. Gunite flexural and compressive strength, rebound, permeability, porosity, dust loading, shooting rate, crew requirements, and cost factors were evaluated. Steel, fiberglass, or polypropylene fibers were contained in all but two of the gunires tested. Both Bureau and private testing laboratory analyses are provided for some products. Electron probe micro-analysis and X-ray diffraction analysis were performed on the silica fume fraction of the wet-mix gunite to characterize the dust. Aggregate size fraction distribution analyses were performed to provide strength relationships. Results indicate that all of the commercially available fibered-gunite materials tested can provide beneficial sealant, spall prevention, or roof stability control attributes for underground mining environments when applied by an experienced crew using a well-maintained gun, in accordance with product manufacturers' recommendations and when used for the designated purpose.

Jan 1, 1984

By Walter W. Fowkes

Leonardite is a coallike substance, similar in structure and composition to lignitic coal and believed to be derived from lignitic coal by the process of natural oxidation. Leonardite is little known outside lignite-producing areas and has been developed commercially only to a minor extent. The higher oxygen content and less compact structure of leonardite, compared with lignite, make it undesirable as a fuel but indicate that it has potential as a source of chemicals and for other nonfuel uses. It is a convenient source of humic acids. The United States has a large natural reserve of leonardite; furthermore, it can be produced in the laboratory under controlled conditions. The significant elemental difference between leonardite and lignite is the oxygen content (leonardite, 28-29 percent; lignite, 19-20 percent). The higher oxygen content of leonardite is due entirely to a Larger number of carboxylic acid groups. This fact explains the 17-Cold increase in alkali solubility of leonardite. Spectral studies indicate that the material is mixed salts of humic acids.

Jan 1, 1960

By Suresh K. Bhatt, Gary L. Mowrey, Timothy R. Rehak, David K. Ingram

Coal and nonmetal mining used about 4.3 billion pounds of explosives and blasting agents during 2001 in the United States. A major part of this consumption was related to surface mining. Mine Safety and Health Administration accident data indicate that flyrock and lack of blast area security were the primary causes of blasting-related injuries in surface mining. Fatal injuries due to lack of blast area security were primarily caused by failure to clear blast area or inadequate access control to the blast area. At a coal mine, a neighbor walked into the blast area and was fatally injured. The blaster could not see the victim entering the blast area from the firing station. In another case, a passenger in a vehicle was fatally injured by flyrock because highway traffic was not monitored during the blast. In another example, a dozer operator entered a blast area due to lack of access control. Several fatalities resulted from using inadequate or no blasting shelter. A crane operator was fatally injured while standing in the open about 120 ft from the blast site. In another instance, a helper, standing about 150 ft away from the edge of a blast, was fatally injured by flyrock. In a limestone mine an equipment operator was fatally injured while guarding access roads in a pickup truck. This paper briefly describes six representative fatalities due to flyrock and lack of blast area security in coal and nonmetal mines. Several mines were visited to collect information relative to working practices aimed at mitigating blasting hazards. Salient information obtained through these visits is presented.

By D. S. Burgess

An investigation of the hazard of spillage of liquefied natural gas (LNG) onto water is described. About 2,000 gallons of LNG were consumed in various tests. The initial vaporization rate of LNG following spillage was found to be 0.037 lb/ft2 sec; when the spill was confined, this vaporization rate was moderated after about 20 seconds by the growth of an ice layer on the water surface; when the spill was unconfined, a coherent ice floe was not observed and the vaporization rate was essentially time independent. The maximum diameter (in feet) of the spreading LNG pool was found to be given by 6.25 Wo 1/3, where Wo is the weight of LNG in pounds, Downwind of a natural gas source, time-averaged methane concentrations were given in good approximation by standard air pollution equations. However, peak concentrations were as much as twentyfold higher than average, adding an additional factor to the assessment of hazard. The effect of layering by the cold vaporized natural gas was similar to the effect of a temperature inversion on normal gases in the atmosphere. Small-scale explosions were observed on pouring LNG onto a water surface; no single explanation seems pertinent to all of the incidents observed.

Jan 1, 1970

By Steven R. Munts

In 1985, at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied 8,445 acres of the 20,650-acre Tunnison Mountain Wilderness Study Area in order to evaluate its identified mi nerd 1 resources. The study area is located in Lassen County, CA, about 8 miles northeast from Susanville. No mineral resources were identified in the study area based on literature, field observations, and sample results. No mines were operating in or near the study area in 1985, and no mines, prospects, or claims have been located in or within 1 mi le of the study area. The study area is underlain by Pliocene and Pleistocene volcanic units composed of basalt, andesite, rhyolite, and some pyroclastics. No metallic and only nonmetallic commodities are present in the study area. These included stone and sand and gravel. Although substantial volumes of basalt and andesite (stone) occur within the study area, no identified resources of these commodities were delineated. Sand and gravel is not economic because of small occurrence size and lack of local markets.

Jan 1, 1987

By Lung Cheng

Based on earlier tests that showed steel to be much more likely to cause frictional ignition than tungsten carbide, the Bureau of Mines redesigned coal-cutting bits to reduce the hazard of face ignitions. Two bit designs--a mushroom-shaped bit with a conical shank and a dove-tail bit with a rectangular shank--are described, as well as bit wear tests conducted in the laboratory and in an operating coal mine. In laboratory tests, for 1/8-, 1/4-, and 1/2-in-deep cuts and cutting speeds of 280, 500, and 660 ft/min, the mushroom bit had significantly longer tip wear life than the conventional bit; the dovetail bit was also superior to the conventional bit. Results of in-mine tests on the mushroom bit agree well with laboratory results. In-mine tests of the dovetail bit are underway.

Jan 1, 1983

By Robert C. Ellman

Stockpiles containing 2.3 million tons of lignite constructed in the period 1948-56 in conjunction with the construction of Garrison Dam on the Missouri River demonstrate successful stable long-term storage of lignite. Uniform and thorough compaction of each of the I-foot-thick layers by which the piles were constructed produced a bulk density of 70 Ib/cu ft. Air penetration into the stockpiles was restricted to a degree that prevents spontaneous heating or deterioration of the stored lignite, A continuing record of observations beginning with stockpiling operations in 1948 has been accumulated, This includes periodic fuel analysis, analysis of pile gases, and measurement of pile temperatures on the first large stock-pile, pile 5. This report describes the stockpiling method, the changes in heating value, pile gas composition, and pile temperature and summarizes observations from 1953 to 1964, Data accumulated attest to the stability of the stored lignite. The variation of the average heating value of periodic pile-depth samples is only 160 Btu/lb (11,990 to 11,830) on the moisture" and ash-free (maf) basis during almost 10 years of storage. Temperature levels of the pile interior are progressively decreasing. At pile surface, cyclic variations occur with the season. The only problem encountered with the large stockpiles is wind and water erosion of the pile surface. The partially successful control measures used are described.

Jan 1, 1967

By R. V. Ramani

This report is volume 1 of an eleven-volume final report for a Grant completed by The Pennsylvania State University for the Bureau of Mines to develop a dynamic general purpose computer simulation model for underground coal mining. The simulator developed under the Grant has a wide range of possible applications in the design and evaluation of underground coal mining systems from the standpoints of health and safety, productivity, and mine environment. The Master Design Simulator consists of nine free-standing function-oriented subsystem models linked together into an integrated, comprehensive model of an entire mining system. The subsystems comprising the Master Design Simulator include geology and reserves, methane generation, roof support, subsidence, production, rail haulage, cost, water generation, and ventilation. This volume of the final report contains a statement of the purpose and scope of work of the Grant, and provides an overview of the Master Design Simulator with a brief description of each subsystem. Also included is a discussion of several areas of application for the simulator.

Jan 1, 1975

By Robert L. Mentch

CADMIUM is one of the metals apparently destined to remain relatively scarce. The en tire supply of primary cadmium is recovered as a byproduct, concurrently with the treatment of ores of other metals. Development of the cadmium industry is attributed to metallurgical improvements in the zinc industry; output depends almost wholly upon zinc production. Cadmium is a metal of specialized uses where its superior performance has developed a strong, expanding demand. The supply, however, has been relatively unresponsive to price because of its byproduct nature. Cadmium's outstanding properties would assure it a manyfold greater market if more were available at lower prices.

Jan 1, 1958

By Henry P. Cole

A series of studies are described that identify critical health and safety skills needed by underground coal miners for coping with mine emergencies. First aid and self-rescue and escape were selected as two broad performance domains that include many subordinate skills needed for preventing, recognizing, and coping with mine emergencies. The performance domains and their objectives were used to direct the development of simulation exercises that permit miners to experience mine emergencies in the safety of a training room. The exercises are based upon research with similar simulations for the training of flight crews and medical personnel in information gathering, judgment, and decision making skills. Exercise content is drawn from actual mine accident and disaster case studies. The exercises incorporate recent principles of cognitive psychology and instructional design. Initial studies in annual refresher training classes suggest the exercises are stimulating for miners and their instructors, easy to use and read, sufficiently complex and authentic to challenge experienced miners, and useful devices for both teaching and testing critical problem solving skills required for preventing and minimizing emergencies.

Jan 1, 1988

By Kevin Malone

Chrysotile asbestos occurs in many counties in California, and a small production had been reported at times, but development of deposits had been disappointing. A reconnaissance survey by the Bureau of Mines indicated that several deposits in the serpentine belt in Shasta, Trinity, and Siskiyou Counties might contain enough asbestos of filler grade to supply the growing demand on the west coast. Accordingly from 1956 to 1958 parts of the Mount Eddy and Shasta View deposits were investigated by trenching and diamond drilling to determine their potential. The work comprised construction of roads, bulldozer trenching, excavation of areas for diamond drilling, sampling, and upping. The trenches were excavated to expose the surface extent of some of the asbestos-bearing areas, To determine the downward continuation of asbestos-bearing sections and to secure samples for test purposes, six diamond drill holes, totaling 1,738 linear feet, were drilled in two selected areas. The trenching and core-drilling indicated that the asbestos-bearing material occurs as ribs and lenses of varying thicknesses in a broad belt of serpentine, about 600 feet wide and several miles long,

Jan 1, 1962

By T. H. Jeffers

The Bureau of Mines conducted laboratory tests to devise a procedure for extracting copper from low-grade discarded mill tailings. A solid extractant consisting of an organic solvent extraction reagent adsorbed on granular activated carbon was investigated and proved to be satisfactory for extracting copper directly from leach pulps. When this material was used in a cyclic leaching, stripping, and electrowinning pro-cess, 95 pct of the acid-soluble copper was recovered from oxidized mill tailings. The weathered tailings contained 0.24 pct Cu (total) and 0.20 pct acid-soluble Cu. The copper was recovered as cathodes containing, in parts per million, 1.6 Pb, 3.6 Fe, 0.5 Sb, 1.5 AI, 1.9 Mn, and <1 Mg.

Jan 1, 1985