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By L. J. E. Hofer

This Bureau of Mines study, part of a broad program of research in air pollution related to minerals, was conducted to determine the nature and extent of the poisoning of catalysts when used to remove certain air pollutants from exhaust gases. The poisoning examined in this investigation occurs when leaded gasoline is used as a fuel for automotive engines. This research was conducted in cooperation with the Public Health Service. The smog in the Los Angeles area is attributed to the effect of radiant energy on the mixture of hydrocarbons and nitrogen oxides found in the atmosphere there. A large portion of the hydrocarbons is believed to originate in the exhaust gases of automobiles. To prevent the escape of these hydrocarbons into the atmosphere catalytic mufflers have been proposed. In principle, these are simple and nonmechanical, consisting of a vessel charged with a catalyst capable of destroying the exhaust hydrocarbons by catalyzing their oxidation. However, these catalysts are severely affected by the particulate matter, mainly in the form of lead sulfate (PbS04), lead oxysulfate (PbS04.Pb0), and Lead chlorobromide (Pb(Cl,Br)2), contained in the exhaust gas. Deposition of lead on the catalyst as PbS04, PbS04, PbS0, and Pb(Cl,Br)2 restricts catalytic activity. As a result,after 20,000 miles of operation the temperature necessary to achieve 50-percent conversion of isopentane in a mixture of 0.2 percent isopentane, 2 percent carbon monoxide and 4 percent oxygen, and the balance nitrogen at 10,000 hourly space velocity has risen from 400° C. to 500° C. even with a catalyst taken from the exit portion of the catalyst bed. The rest of the catalyst was more severely affected. Therefore, it would appear that operation for 20,000 miles is near the limit for a catalyst.

Jan 1, 1963

By John Nagy

To facilitate increase in the rate of coal production the Bureau of Mines conducted a study several years ago, on the basis of which the allowable charge limit for permissible explosives in single-hole blasting was raised from 1.5 to 3.0 pounds. Further demands for accelerated production led to consideration of multiple blasting in coal, a practice that is deemed hazardous and is not permitted by most States in this country. In multiple blasting, 10 to 20 pounds of explosive or more may be detonated in a coal face within a fraction of a second, which might result in blown-out or blown-through shots with possible ignition of gas or coal dust. As experimental evidence was lacking, in January 1949 an investigation was undertaken in the Experimental coal mine at Bruceton, Pa., principally to study and compare with single blasting the condi-tions under which simultaneous multiple blasting and particularly multiple short-delay blasting may be practiced without danger of igniting gas or coal dust in mines. The first report on this subject was presented at the last international conference of mine safety research. Since that time numerous additional experiments have been made; because of other pressing problems the work has been brought temporarily at least to a conclusion. This paper is the second report on the problem. It does not contain a detailed description of all test conditions and test arrangements, many of which were described 2 years ago in part 1 (now available as Report of Investigations 4868), but the conclusions are based on the entire study. A more complete review, which will incorporate data from the entire investigation, is being prepared as a Bureau of Mines bulletin. Up to the present time, short-delay blasting of coal in commercial mines has been introduced only experimentally in Washington and in a few mines elsewhere. If the system is adopted more generally, new problems may arise, and the study may have to be reopened.

Jan 1, 1952

By W. S. Landers

In contrast to the large fund of information available on the carbonizing properties of Eastern U.S. coals, the experimental data available for most Western U.S. and foreign coals are meager. To supply some self-consistent data, the Bureau of Mines conducted 220 low-temperature carbonization assay tests at 500° C. in a laboratory-scale carbonization apparatus. The results are included in this report. The U.S. coals tested are from Alaska, Arizona, Colorado, Illinois, Montana, New Mexico, North Dakota, Pennsylvania, Ohio, Texas, Utah, and Wyoming. Assays were also made on coals from Canada, Ecuador, France, Greece, India, Mexico, the Philippine Islands, Thailand, and Yugoslavia. In addition, one assay of pine sawdust and one assay of a peat from Ireland are reported. Prediction equations were developed relating the yield of products of carbonization obtained at 500° C. in the assay unit to the proximate and ultimate analyses of the coals. The equations for predicting the yields of tar plus light oil, char, and gas, and the heating value of the gas, are considered good, each equation having a multiple correlation coefficient of 0.90 or higher. The equation predicting volume of gas obtained upon carbonization is considered as fair, with a multiple correlation coefficient of 0.84. A reproducibility study of the assay made on 10 replicate samples of a subbituminous coal indicated that the standard deviation of the individual products was 0.31 percent or less.

Jan 1, 1961

By Aner W. Erickson

"Magnetite iron deposits on Tolstoi Mountain were examined as part of the investigations by the Bureau of Mines of iron and copper ores on Prince of Wales Island. The Tolstoi Mountain project was a part of a program for investigating mineral deposits in Alaska, under the general supervision of R. S. Sanford, acting branch chief.A preliminary examination was made by S. P. Holt, mining engineer of the Bureau of Mines, in company with John Reed, L. A. Warner, and W. S. Twenhofel of the Federal Geological Survey, on July 14, l943. Three samples were taken, rough estimates were made, and it was proposed that the area be mapped, topographically and geologically,. Dip-needle work was added to the program, and it was decided that, should results warrant, the deposits would be diamond-drilled.From March 26 to May 28, 1944, the deposits were examined thoroughly by Bureau of Mines personnel under the direction of the author. Thirty-two acres were mapped with contour intervals of 10 feet, grids were established covering the principal outcrops, over 1,500 dip-needle readings were secured, and the magnetite bodies were outlined. Additional information was gathered by trench inch and channel-sampling, 600 linear feet of trench being dug and 32 channel samples being cut. Finally, the mapped area was checked for nonoutcropping deposits by taking dip-needle readings at 10-foot intervals along the traverse lines, creeks, trails, and all outstanding topographical features. This re-connaissance work gave sufficient coverage of the 32 acres to eliminate the possibility of further magnetite bodies of any consequence remaining undiscovered.Acknowledgment is made to Nile Johannsen, assayer, Territorial Department of Mines, Ketchfkan, Alaska, for determination of samples.The deposits are on Prince of Wales Island in Southeastern Alaska near Tolstoi Pay, a deep-water indentation at the northwest and of Kasdan Peninsula. The physical features are shown on figures 1 and 2 and the location of the deposition figure 3. Old workings were found on the west side of Tolstoi Mountain; between elevations of 650 and 1,150 feet, at distances of 3/4 to 1-1/4 miles from the east shore of Tolstoi Bay.Access to the area is over a brushed foot trail built by the Bureau of Mines. Topography would permit construction of either surface or aerial tramways at moderate cost but would make road building expensive. Deep-water navigation, permitting inexpensive water transportation, is possible the year around.Kasaan Peninsula is an area of moderate relief, being considerably less rugged than the mainland to the east. Most of the mountains and ridges are less than 2,500 feet in height and show evidence of having been covered by the ice cap of the Pleistocene age. Rock exposures below elevations of 2,000 feet are limited, as extensive overburden 2 to 20 feet deep covers the greater part of the peninsula."

Dec 1, 1948

By S. J. Broderick

"INTRODUCTION Dark soils are commonly believed to be better for agricultural purposes than light-color soils. Much of this feeling may be purely psychological, as many persons have unconsciously acquired the habit of associating richness of soil with color light soils, however, may be just as rich in humus and plant foods as the best of the dark soils. A dis-cussion of the manifold attributes that play an important role in soil technology is beyond the scope of this paper, but the color factor will be considered, as it has a particular bearing on some field experiments using coal-mine waste as a darkening medium.It has been established that dark soils absorb more of the sun's radiation, consequently are maintained at a higher temperature than light soils. This physical principle is applied in our daily lives in the choice of clothing. White clotnes in summer are cooler than dark ones. Conversely, dark clothes in winter are warmer than light-color clothing. A decided advantage of dark soils over light soils is the higher average temperature of the former, resulting in an earlier maturing crop. This advance of the maturing season may range from a few days to a month, depending on such factors as climate, crop, and degree of color of the soil. It has been reported that in parts of Russia where the growing season is short, perhaps comparable to that in Pennsylvania and. New York, cotton has been grown successfully on soils originally of light color, but darkened with coal, dusts. The growth of cotton is, accordingly, speeded up a full month. 3/"

May 1, 1940

By L. J. Kane

Applications are described of various methods for determining the weight concentration and physical properties of solid and liquid impurities of gases in connection with problems encountered in synthesis-gas production. Of special interest among these methods may be listed: 1. A method developed for determining, the weight concentration of solid and liquid impurities in. hot, crude synthesis gas containing a high concentration of moisture. 2. A method developed for the same purpose but for highly purified synthesis gas or atmospheric air. 3. A method for obtaining a uniform dispersion of dry duet or, a microscope slide for particle-size determination or other purposes.

Jan 1, 1954

By Alexander May

The U.S. Bureau of Mines investigated the application of oxidation-reduction potential (ORP) and pH measurements to environmental studies of mining and mineral processing wastes, and developed a computer program to estimate the concentrations of species of lead present in samples from a lead processing waste site. The methods and techniques for the ORP-pH measurements were investigated using known standard solutions made in the laboratory, samples from a ferric oxide waste disposal pond at a rutile production plant, and samples of well water and stream water from the lead processing waste site. ORP values were measured from 5 to 80 °C, from pH 1 to pH 12, and at various ratios of oxidant to reductant. The ORP-pH values can help identify valence values and species of ions present, including those of major, minor, and trace concentrations, and also indicate possible reactions at various pH values. The ORP measurements versus temperature yield data from which thermodynamic values can be calculated. The application and limitations of these measurements are discussed, and a brief discussion of the computational program to identify species of lead is presented.

Jan 1, 2010

By A. R. Mumford

During the course of an investigation conducted by the fuel section of the Bureau of Mines , on a hand- fired return- tubular boiler plant , it was found that the average cost of fuel to produce 1,000 lb. of steam was $ 0.5287 . Tests conducted after some simple changes had been made in the furnaces , and in the control of the boilers , showed the previous high cost of fuel per 1,000 lb. of steam could be reduced to the reasonable figure of $0.3540 , or the equivalent of over 30 per cent saving in fuel cost .

Mar 1, 1923

By R. J. Fantel

To determine the availability of phosphate rock from domestic re- sources, the Bureau of Mines evaluated the potential production of phosphate rock from the demonstrated resources of 130 mines and deposits. The evaluation included an estimation of resources, engineering methods, and capital and operating costs, and an economic analysis to determine each operation's average total cost of production over the life of the mine, including a 15-pct discounted-cash-flow rate of return on all investments. Quantified but not evaluated in this report are substantial phosphate resources at the inferred and hypothetical resource levels. The 130 mines and deposits contain 6.4 billion tons of recoverable phosphate rock product, about 20 pct from producing mines. At total production costs of under $30 per ton in January 1981 dollars, about 1.3 billion tons of phosphate rock product is potentially available, over 90 pct from producing mines. This study suggests that production from low- cost, high-grade phosphate mines now in operation will decline during the next decade, and new higher cost, Lower grade mines will have to be developed to satisfy demand into the next century, In addition to the demonstrated resources evaluated in this study, 7 billion tons of inferred-level and 24 billion tans of hypothetical- level phosphate rock are potentially recoverable, which, in part, includes material containing high amounts of magnesium, Much of this material could likely become available in the near future.

Jan 1, 1983

By J. E. Pahlman

As part of its effort to reduce the need for strategic minerals through conservation and to reduce the capital and energy requirements of mineral processing, the Bureau of Mines has investigated a method for preparing ferrochromium alloys containing less than 2 percent carbon. This method will conserve chromium and should reduce the capital and energy requirements for chromite reduction. Reduced products containing less than 2 wt-pct C and as low as 0.01 wt-pct C were obtained by reacting pellets of chromite and carbonaceous reductant mixtures at pressures of 0.1 to 1 torr and temperatures of 1,230° to 1,320° C. The extent of reduction increased with increased temperature and decreased pressure; however, operating conditions were limited due to the onset of significant chromium vaporization at higher temperatures and lower pressures. Foundry coke, anthracite, and carbon black were found to be supe¬rior to graphite as reductants. The reduction of chromite to metallics was found to proceed via the carbide intermediates (Fe,Cr)7C3 and (Fe,Cr)23C6, No evidence of carbide intermediates Fe3C or Cr3C2 was found. Buttons of ferrochrome alloys were made by melting a mixture of reduced products with CaO and Si02 at 1,700° C for 20 minutes in an induction furnace,

Jan 1, 1980

By C. J. Chindgren

Upgrading of commercial red cake and recovery of vanadium oxide from uranium-vanadium mill solutions were investigated by the Bureau of Mines. Alternative procedures potentially useful for manufacture of high-quality vanadium oxide at the mill site were explored and developed. The simplest and best procedure for converting commercial red cake containing about 10 percent combined sodium and potassium oxides (Na20) (K20) into a 98- to 99-percent vanadium pentoxide (V205 product appeared to be a metathesis in an ammoniacal solution of ammonium sulfate. Molybdenum, as well as the alkali metal oxides, was removed from the red cake by this procedure at a modest expenditure of labor and reagents. When preparing vanadium oxide of higher grade, it was necessary to dissolve the red cake and reprecipitate the vanadium as ammonium metavanadate. Calcination at 450° C, decomposed the metavanadate and yielded oxide of about 99.5 percent V205. By recyrstallizing the metavanadate before decomposition, an oxide product approaching 99.9-percent purity was obtained.

Jan 1, 1962

By S. J. Broderick

[The discovery in 1934 that carbonaceous materials, such as coal, peat, and lignite, when treated with concentrated sulfuric acid, were given cation or bate-exchange properties opened up a field of new materials with many interesting possibilities. These hydrogen exchangers, as they were called, were so superior to the impractical hydrogen exchangers made from natural and synthetic zeolites tat they were accepted immediately by the water-conditioning industry. A noteworthy advantage of the carbonaceous exchangers is that they are nonsiliceous, hence they do not give up silica to the water as do the natural and synthetic Zeolites, especially if the hard water is corrosive. For this reason the new exchangers found immediate favor in boiler-feed-water conditioning.]

Jan 1, 1941

By W. A. Selvig

"The purpose of the investigation described herein was to determine how closely different laboratories can check one another in making determinations of fusibility of coal ash with the De Graaf electric coal-ash fusion furnace: how well duplicate determinations by the same laboratory will check, and how the results with the De Graaf furnace compare with those of the standard gas-furnace method of the American Society for Testing Materials.4Thanks are due the following laboratories who cooperated in this study by making fusibility tests with the Do Graaf electric coal-ash fusion apparatus: J. J. Brennan, testing engineer, Northern States Power Co.; R. E. Gilmore, superintendent, Fuel Research Laboratories, Canadian Department of Mines A. T. Leavitt, president, and W. Mueller, chief chemist, Hamilton By-product Coke Ovens. Ltd.; Edgar Stansfield, chief chemical engineer, Scientific and Industrial Research Council of Alberta. Canada; and H. S. Vassar, laboratory engineer, Public Service Electric and Gas Co.The ash-fusibility determinations by the standard gas-furnace method were made in the Coal Analysis Laboratory of the Bureau of Mines at Pittsburgh under the direction of H. M. Cooper, associate chemist. The investigation was made at the suggestion of A. C. Fieldner, chief engineer, Experiment Stations Division of the Bureau of Mines.Routine determinations of the fusibility of coal ash are made in the laboratories of the United States Bureau of Mines by the gas-furnace method. This method was standardized after considerable experimentation5 on the nature of the fusion of coal ash and the various factors which affect its determination. The method was subsequently adopted by the American Society for Testing Materials as one of its standard tests."

Jun 1, 1930

By R. V. Ramani, R. Bhaskar

"The control of respirable dust in mines has been given paramount importance due to the health and safety implications associated with fine dust. The understanding of the temporal and spatial behavior of dust has been recognized as essential for increasing the efficiencies of the existing control techniques and for developing new control strategies. Mining-related studies in this area are, in general, limited. They are also mostly experimental. Some mathematical and computer analyses have been attempted. In this paper, first a review of the mathematical studies performed in the last three decades in this area is presented. Second, a mathematical model for analyzing dust flow in mines is proposed. The model takes into account a number of factors affecting dust transport. It incorporates varying dust generation source strengths and dispersion, deposition, and coagulation of dust in mine airways. Finally, application areas for the model are discussed. A computer program based on the mathematical model has been developed. The program will output the dust concentration in the mine atmosphere as a function of time and distance from the source. The amount of dust deposited on the sides, roof, and floor of the airway is also determined.IntroductionAn airborne dust cloud is a complex system containing particles of varied size, density, shape and state of aggregation. The behavior of the particles is dependent on a number of complex physical mechanisms, often opposing in nature. The net interaction results in the ambient concentration. This size dependent behavior of particles contrasts with that of gases, an area quite widely studied.The term aerosol is used to describe clouds of microscopic and submicroscopic particles in air such as chemical smoke or particulate matter released from smoke stacks. An aerosol system can be regarded as an arbitrary element of volume filled with gas and suspended particles of possible highly variable physiochemical nature. The parameters that are used to describe an aerosol system include concentration, mass average velocity and particle mass and radius. In characterizing such systems, several assumptions are made. Among these is the assumption that particles are smooth, inert and rigid spheres. Again, for example, when the particles are in transport, the possibility of collision exists. As a result of the collision, the particles may coalesce to form larger particles. The probability of sticking is considered a known quantity (lady, 1970). In this paper, the application of the principles used in aerosol systems is explored for the study of the transport and deposition of fine coal dust in underground mines."

Jun 1, 1988

By Xavier B. Starnes

The Dike and Eaton veins in Crittenden County, Ky. (fig. 1), are along northwesterly trending relief fractures that lie between two northeastward striking major faults - the Moore Hill and- the Levias, in Crittenden County, Ky. The veins contain small, narrow, irregular ore bodies of fluorspar with subordinate quantities of sphalerite and galena. Gravel fluorspar was found on the surface in the Eaton vein, and open-cut mining was in progress on the W. M. Conyer property about 1900. Discovery of fluorspar in the Dike vein came much later, about 1933, on the W. H. LaRue tract, but the principal production on the Dike vein started after the discovery of gravel spar in 1938 on the land of the P. J. Gilless estate. Production from the Eaton vein was estimated at 9,400 tons and that from the Dike vein at 15,700 tons, a total of 25,100 tons. A large part of this production was gravel fluorspar from within 50 foot of the surface. Beneath the gravel spar the veins are very narrow, averaging 2 to 2.5 feet in width, and the ore shoots are small. The deepest mine level was 140 feet below the surface, and the deepest shaft 150 foot. Orb was concentrated by log washer or sent unwashed to custom mills at Marion, Ky. about 6 miles distant.

Jan 1, 1950

By E. S. Leaver

The gold that is not recovered by a particular process is refractory to that process. A study to determine how the refractory gold is associated in the ore constituents usually indicates the needed improvement in the process or additional methods for bettering recovery. In preliminary work, segregation of the various minerals, gangue or impurities, and data showing the reactions of each in the recovery method readily confines the refractory gold to a certain part on which extensive research can be directed. In this dissecting plan, the microscope is an important aid in locating the refractory gold but should be supplemented by chemical tests. Each ore is an individual problem until the association of the gold has been determined. Knowing the problem through the interfering minerals or elements, the solution often is only the application of part of a former known practice as an auxiliary or additional feature. In the treatment plan for most gold ores, it has been the custom to try each of the usual recovery methods or combinations thereof, accepting the best results on a basis of the lowest cost. A better plan includes knowledge of the association of the gold and the various minerals from which it is to be recovered. This presents reasonable foresight into the problems that should be expected and permits some provision for avoiding probable difficulties. The preliminary work should include: Determination of the percentage of free gold with classification showing size of gold particles to be expected; determination of the percentage of gold associated with each mineral and whether it be freed from the mineral by crushing; and an analysis of representative samples of the ore to include other valuable minerals and the form in which they occur.

Jan 1, 1934

By Robert H. Ridgway

This circular outlines salient facts regarding the sulphur industry of the United States and the world. It is founded chiefly upon published information available in the literature of the subject. The Bureau of Mines has in its files additional, more detailed data upon many of the topics presented very briefly here, and will endeavor to assist the mineral industries and the public by giving further information in response to individual inquiries. It will welcome comments, criticisms, and contributions of data that may assist in making later editions of this circular more accurate, or in developing more fully the bureau's mineral files pertaining to sulphur. Throughout this paper sulphur is used to designate crude sulphur or brimstone, not sulphur produced from pyrites or' smelter gases.

Jan 1, 1930

By R. J. Leary

The natural gas-air burner described in this report was designed and constructed to meet the thermal requirements of a convective process for heating steel scrap. This process involved downward combustion of natural gas with air, blending the combustion products with diluent air, and then passing this tempered stream of gases downward through a porous bed of steel scrap contained in the furnace chamber. The scrap would be heated to a temperature limited by the adiabatic flame temperature of the gas stream in a period that depended on the rate at which heat was supplied per unit of bed cross section. The temperature of the gas stream would be limited to that beyond which an objectionable degree of oxidation would occur; for carbon steel this limit had been found to vary from 1,900° to 2,100° F. with the superficial velocity of the gas stream. The productivity of the process was dependent on the rate of heat input per unit of furnace cross section; for the 3-foot-diameter experimental furnace an input of 680,000 B.t.u. per hour was desired. The burner described was designed to meet these conditions of temperature and heat input. It provided for three streams of entering gases: (1) A primary air-fuel mixture too rich to be combustible, that is, above the upper flammable limit; (2) secondary air for combustion of the primary mixture; and (3) tertiary air, principally for cooling the combustion products to the temperatures desired for process operation. Downward combustion of the primary and secondary streams occurred in a flame stabilized on an annular port, while tertiary air flowed in an annular path surrounding the port and also through an axial channel whose wall formed the inner ring of the annular port. This burner performed beyond the designed heat-input rates while producing stable flames, which were adjusted readily to the temperatures desired. Gas-stream temperatures were easily controlled to within 15° F. of the desired value by simple manual adjustment of the flow valves.

Jan 1, 1959

By W. O. Vanderburg

The leasing or tribute system has been an important factor in the development of our metal-mining industry, particularly in the gold and silver mines of the Western States. It has received its widest application in. the early history of many camps and in the last stages of many mines. The system is especially adapted to mining where the ore's occur in narrow veins or are erratically distributed in small bunches or pockets so that selective mining, hand sorting, screening, or hand cobbing is required to produce shipping or milling-grade ore. The leasing system is also applicable to the development of prospects where the owners are unable or unwilling to assume the risks of searching for ore. The virtue of the system lies in the opportunity it affords miners with little capital to get started; at the same time, it rives owners an opportunity to have their property developed at small cost.

Jan 1, 1934

By Melvin E. Poad

This Bureau of Mines report presents two phases of a research program to evaluate a single-entry system for longwall development. Organizations participating in the program; which began in July 1971, include the Bureau of Mines, the Mining Enforcement and Safety Administration, and the University of Utah, working under a cooperative agreement with Kaiser Steel Corp. at its Sunnyside mine in Utah. Part 1 of this report describes the present longwall mining practice, including a brief history, and discusses the advantages and disadvantages of a single-entry development system and its introduction in the United States. Part 2 of the report presents the research program; test design, instrumentation for ground and support evaluation, and the test results from the No. 2 mine. Subsequent reports will describe the research conducted in the No. 1 mine.

Jan 1, 1977