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By R. S. Dean

Boron compounds have been considered for many years as possible additions to iron and steel. A very recent use of boron-steel rods was for the control of neutron intensity in the graphite-uranium pile at the Clinton plutonium plant(130).4/ Norris(129) reports that slags containing boric oxide reduce the ferrous oxide content of steels and thereby the aluminum required for deoxidation. Boron is not considered an alloying element, but minute amounts produce what is often called a "needled" steel. The study of a series of iron-boron alloys by convenient steps, starting with iron containing no boron, indicated that boron was a hardening agent and made the iron very difficult if not impossible to forge. Then came the discovery that very minute traces of boron are quite different from the smallest amount previously thought worthy of study.

Jan 1, 1946

By G. R. Fitterer, C. H. Herty

"INTRODUCTION Manufacturers and consumers of steel have come to realize during the past few years that cleanliness is of great importance in steels which must meet rigid specifications for various physical properties. Of equal importance is the consistent production of steel which is uniform in these properties. For maximum utility steels should be uniform not only from heat to heat, but also from ingot to ingot and within each ingot. In the manufacture of killed steels such as the higher carbon forging grades, uniformity as indicated by the usual chemical analysis in easy to obtain, provided that a normal top discard is taken, as is always the case in steels poured with hot—top practice. No such uniformity, however, holds true for the nonmetallic matter, which consists for the most part of the products of deoxidation of the steel.For a large tonnage of steels which go into articles manufactured by deep—drawing processes, killed steel has never been successfully applied because with the present deoxidation practice, low—carbon killed steel is almost invariably extremely dirty. To obtain the desired qualities for deep drawing, the steel is rimmed, — that is to say, deoxidized with manganese and perhaps a small amount of aluminum, — the resultant product being of high purity in the skin of the ingot, but very badly segregated at the center of the ingot, particularly in the upper—central section. This segregation necessitates a very heavy top discard, and one of the major segregates is carbon which renders the steel too hard to draw properly. If clean, low—carbon killed steel could be made successfully, much better ingot yields would be obtained than by the present rimming steel practice. Furthermore, banded structures and outside and inside seams, which are undoubtedly due in a large measure to blowholes in the ingot, are defects which are very difficult to control in rimmed steel. These defects would be minimized by clean killed steel."

Feb 1, 1931

By L. G. Marshall

This report presents a cross section of the sand and gravel operations in the Minneapolis-St. Paul area. The study covers individual operations, economic problems peculiar to the industry, glacial geology of the area and its effect upon the grades and types of products, and past, present, and future trends of the expanding population and its effect upon the industry.

Jan 1, 1963

By L. G. Marshall

This report presents a cross section of the sand and gravel operations in the Minneapolis-St. Paul area. The study covers individual operations, economic problems peculiar to the industry, glacial geology of the area and its effect upon the grades and types of products, and past, present, and future trends of the expanding population and its effect upon the industry.

Jan 1, 1963

By J. E. Murphy

A method is being developed by the Federal Bureau of Mines for recovering lead metal from galena without the generation of SO2. Lead chloride is obtained by leaching lead concentrate at a temperature of approximately 100° C with FeCl3 solution: PbS + 2FeCl. " PbC1 2 + 2FeC1 2 + S. Electrolysis of the PbCI 2 product in a fused-salt bath results in deposition of molten lead metal at the cathode and evolution of chlorine at the anode. The chlorine can then be absorbed in the spent leach solution to regenerate FeCl3 for recycling. Optimum electrolyte composition was a PbC12-LiCl eutectic containing 7.6 wt-pct LiCl. The PbCl2-NaCl eutectic also proved satisfactory. Electrolysis in the PbCl2-LiCl bath at 450° C yielded 99 pct current efficiency at a current density of 5 amp/in2 with an energy requirement of only 0.24 kW-hr/lb metal produced. This compares with 98 pct current effi¬ciency and 0.26 kW-hr/lb metal produced for the PbCI2-NaCI bath. A typical lead deposit contained less than 100 ppm total detectable metallic impurities. At the low temperature employed for electrolysis, there was essentially no vaporization of Pb or FbC12.

Jan 1, 1974

By K. C. Dean

The Bureau of Mines, following passage of the Solid Waste Disposal Act of 1965, was authorized to conduct research on methods for utilizing, stabilizing, or reclaiming mineral wastes. This report summarizes laboratory research conducted by the Bureau and cooperative field studies made with the mineral industry to reduce the environmental impacts of air and water pollution deriving from mineral wastes. Utilization research showed that both dry-press and steam-cured building bricks and ceramic tile could be made from copper mill tailings and other discarded mineral wastes. Sponge iron was produced from steel mill and amination industry wastes, and valuable mineral products were extracted from such diverse sources as flue dusts and uranium tailings. Mineral wastes were combined with agricultural and/or sewage wastes to make artificial soils that have the potential of resolving several disposal problems by production of a useful commodity. Physical, chemical, and vegetative stabilization methods were evaluated, singly and in combination, for reclamation potential on copper, uranium, lead-zinc, and asbestos tailings. Suitable methods were developed in the laboratory for overcoming major adverse conditions of these wastes such as salinity, heavy metal toxicity, acidity, basicity, lack of nutrients and organics, and unstable surfaces. Field testing of these methods was performed on a variety of mineral wastes. Costs for the various stabilization and utilization-procedures developed were also determined.

Jan 1, 1986

By Norma Golumbic

The primary purpose of the Bergius (hydrogenation of coal) and Fischer-Tropsch (hydrogenation of carbon monoxide) processes is the production of synthetic liquid fuels. This objective is of importance in insuring an adequate supply of motor fuels and lubricating oils in the United States. In the urgency of the basic research and process development work on synthetic liquid fuels, the possibilities for the production of synthetic chemicals inherent in these processes have hitherto received little attention in this country. However, the by-products, as well as the primary products, from the Bergius and Fischer-Tropsch processes are rich source materials for organic chemicals. The overhead oil from liquid-phase hydrogenation of coal, for example, contains benzene, toluene, xylene, cyclohexane, methylcyclohexane, aromatic solvents, about 20 percent tar acids (largely phenol, cresols, and xylenols), and 3 percent nitrogen bases. Wax, alcohols, and acids are by--products of the Fischer-Tropsch synthesis. In addition, techniques have been developed which make possible the production of aliphatic hydrocarbons, alcohols, acids, aldehydes, and other oxygenated organic compounds. These chemicals are more valuable on a unit basis than gasoline. Because of continued rapid expansion of the plastic, resin, lacquer, and solvent industries, larger amounts of many of these chemicals will be needed in the near future.

Jan 1, 1949

By O. C. Blade

This report on the properties of motor fuels sold through service stations in the United States was made in accordance with a cooperative agreement between the American Petroleum Institute and the Bureau of Mines of the United States Department of the Interior. By agreement with the American Petroleum Institute, identification of the items is confidential. It presents analytical data for 4,680 samples, representing the products of 130 companies. The samples were collected during December 1953 and January and February 1954. As in previous surveys, the gasolines covered by this survey include those from both large and small suppliers. The data were obtained by laboratories of various refiners, motor manufacturers, and chemical companies and submitted to the Bureau of Mines for compilation. A list of the National Motor-Gasoline Survey reports published during the past ten years is given on page 5.

Jan 1, 1954

By J. W. Howland

To determine their effectiveness in different climate and soil conditions, a demonstration of dozer blades specifically designed for recontouring mine spoil was conducted at an East Texas surface coal mine. The specialized equipment included a 48-foot angle blade, a modified 24-foot "U" blade, a 13-foot deep "U" blade, and a 24-foot grading bar. Both the 4b-foot and the 24-foot "U" blades were mounted in a two-tractor, single-operator configuration. To meet flotation problems common in this mining region, a 22-foot lightweight blade was developed and demonstrated for use on a 400-430 hp tractor. The demonstration involved 1,185 acres and showed a 50% reduction in reclamation costs and a 47% reduction in fuel requirements for this mine site over conventional equipment. Improved equipment, trained operators, good supervision, and improved monitoring techniques contributed to the savings. Procedures and results of the demonstration are presented and analyzed here along with guidelines for application of findings.

Jan 1, 1981

By Joseph A. Cavallaro

This report describes the timed release analysis technique that was developed to serve as a tool for assessing the froth flotation cleaning potentials of fine-size coals. Using this developed technique, 16 coals from 10 different coalbeds were tested. All of the coals included in this study were quite amenable to froth flotation with float coal yields ranging from 80.7 to 99.5 percentage points. Float-and-sink analyses of the coals tested are shown to be of limited value in predicting froth flotation cleaning potential. Generally the float-and-sink analyses indicated a better product could be obtained than froth flotation could provide; although, in four of the coals tested froth flotation results were superior to those expected from the gravimetric analysis. The fixed carbon content of the samples collected was found to correlate with the floatability of the coals. The higher rank coals were the most readily floatable coals while the lower rank coals did not respond quite as well to flotation.

Jan 1, 1965

By Rolland L. Blake

The Bureau of Mines investigated the mineralogy, tonnage, and beneficiating characteristics of oxidized (nonmagnetic) taconite iron resources of the Western Mesabi Range as part of its program to insure adequate future domestic mineral supplies. Magnetic taconite currently provides about 95 pct of Mesabi production, but the large tonnages of oxidized taconite between the magnetic deposits will be needed to help meet future domestic demand for iron ore. Three bulk samples that represent large tonnages from the Western Mesabi Range were selected to determine their mineral composition and liberation by light optical microscopy and to test their beneficiating response. This report describes the mineralogy and liberation characteristics of the three samples of the Biwabik Iron-Formation for 26.5 mi (42.7 kID) from Keewatin to Grand Rapids, MN. (Details of response to beneficia-tion were reported previously.) The samples represent mostly material from the Lower Cherty Member of the Biwabik-Iron Formation, although one sample included some Upper Cherty Member. Minerals of all three samples were quartz (chert), hematite, goethite, and minor to trace amounts of magnetite, iron carbonate, and iron silicates. It was concluded that the oxidized taconites of the Western Mesabi Range represent a subeconomic indicated resource that can be selectively mined and beneficiated as a future large source of iron feed for steelmaking.

Jan 1, 1983

By A. L. Service, C. C. Popoff

Phosphate deposits in Montana , Idaho , Wyoming , and Utah are important factors in the mineral , agricultural , and industrial economy in the western part of the Nation . This report presents background information , including geology , mining , beneficiation , processing , resources , and economics , assembled to provide a comprehensive introduction to a series of four area reports . About 20 percent of the Nation's phosphate is produced from the Western field where there were 6 surface and 9 underground mines in operation in 1963 . This region also has an estimated 58 percent of the Nation's phosphate reserves , and continuing development is assured by these abundant resources and an increasing demand for phosphate products . Long range forecasts indicate that the United States will continue to use increasing amounts of both agricultural and industrial phosphate products . Beneficiation has become an important part of the phosphate processing industry , and two flotation plants and several washing plants were in operation in 1963. Recent studies by the Bureau of Mines Metallurgy Research Center , Albany , Oreg . , have been directed toward developing flotation processes applicable to treatment of marginal phosphate rock . Other Bureau of Mines research is being directed toward improved methods of ore recovery , ground control , and mining .

Jan 1, 1964

By A. T. Coumbe

The first survey 3/ covering sales of liquefied petroleum gases was made in 1930 by the Bureau of Mines, which at the time was under the United States Department of Commerce. This original canvass covered national totals for 1922 through 1929, and most of the supply came from natural gasoline plants. The 1930 report showed approximate totals for butane and propane and for butane-propane mixtures and pentane grouped together. No attempt was made to breakdown the national sales by various uses until 1931, when the quantities for domestic or household consumption, gas manufacturing, and industrial requirements, including miscellaneous uses were indicated. As the market for these liquid petroleum gases expanded and as new uses came into importance, their respective quantities were shown separately in the annual survey. Sales for internal-combustion engine fuel and for raw material for chemical plants were first taken out of the industrial total in 1936. During World War II liquefied petroleum gases became important as feed stock diverted to synthetic rubber plants, and consequently the survey was broadened to cover this particular demand, beginning in 1944. Pentane was dropped from the survey after 1943, as, being liquid at atmospheric pressure, it is not considered as one of the liquefied petroleum gases and furthermore, the quantity reported made up less than 1 percent of the total sales. Thirteen producing companies reported to the Bureau in the first survey made in 1930, and in the 1952 canvass about 130 producers--petroleum refiners and natural gasoline companies--and about 1,300 dealers cooperated by filing schedules showing a breakdown of their sales. Their 1952 deliveries of approximately 4.5 billion gallons of liquefied petroleum gases were equivalent to about 3.4 billion gallons of gasoline or 3.1 billion gallons of distillate fuel oil.

Jan 1, 1954

By Theodore L. Turner, Joseph H. Swift

A study on a small laboratory scale was made of the use of ammoniacalammonium carbonate for batch leaching Mn from low- grade manganiferous materials ( 6 to 16 pct Mn) obtained from deposits in the southern district of Aroostook County , Maine . These materials were partially reduced at 500 ° to 700 ° C with H₂ or CO and then leached with solutions of NH and CO₂ dissolved in water . Extraction of 80 to 90 pct of the Mn was obtained from some sample materials , but 10 to 34 pct of the iron was also extracted . Material from the Littleton Ridge deposit contained manganese intimately associated with Fe , a condition which contributed to difficulties in obtaining a commercially acceptable product . Extensive investigations of the leach and reduction processes with various mixtures of H₂ and water vapor , and CO and CO₂ , failed to disclose a set of conditions for selectively leaching the manganese . Finely divided metallic Fe was probably produced during the reduction steps so that Fe was leached with the Mn in the subsequent extractions .

Jan 1, 1964

By M. J. Gavin

Within the past three years numerous inquiries for information on oil shale have been received by the Bureau of Manes. These inquiries have been increasing to such an extent that it has seemed advisable to issue a short paper prior to the publication of a bulletin on the subject, giving a, general discussion of the subject and a comprehensive list of references, so that those interested in the details of obtaining oil from shale can find additional information without much difficulty. Some of those who desire information are interested only in a general discussion of the subject, or are not in a position to refer to books and' articles describing the industry. The material for this paper is largely derived from published information on oil shale. Much of the information is obtained-from the books and articles mentioned in the list of references, and has been compiled with the intent of furnishing information to those not interested in all the details.

Jan 1, 1921

By R. F. Zaffarano

Data presented on the physical characteristics of the reservoir oil, Aneth field, represent the initial phase of a study of Paradox basin reservoir oils being made by petroleum engineers of the Federal Bureau of Mines, Petroleum Research Center, Laramie, Wyo. The purpose of the study is to determine the original reservoir-oil characteristics in several important new discoveries in the Paradox Basin and to investigate correlations between the properties of these reservoir oils and structural or areal position within the basin, If migration is limited and oil accumulates near its source, then it seems probable that few differences should be found in the composition and characteristics of reservoir oils occurring in given age rocks and within the confines of a geological basin. Within these limits, conditions that effected the formation of oil and its transfer from parent to storage rocks probably were rather uniform in an area the size of most of our geological basins. However, if oils should migrate considerable distances, it seems logical to expect that the relative quantities of gas and liquid components may differ in traps occurring along the direction of migration, corresponding with the theory of differential entrapment (5).4/

Jan 1, 1959

By Robert E. Barieau

General expressions for evaluating practically all the thermodynamic properties of a fluid from a single equation of state are derived. Most of the formulas are expressed in terms of the compressibility factor, with this factor being an explicit function of the temperature and the molal density. Similar expressions are given using reduced variables.

Jan 1, 1967

By Thomas F. Anderson

(Measurements of stable isotopic variations (sulfur, carbon, and oxygen), supplemented by chemical, mineralogical, and petrographic analyses have been used to investigate the processes responsible for : (1) the incorporation of sulfur in coal, and (2) the (development of permineralized peat zones ("coal balls"). Sulfur isotopic results indicate that there are two principal sources of sulfur in the Pennsylvanian coals from the Illinois Basin: (1) "primary" sulfur assimilated by plants (low-sulfur coals), and (2) "secondary" sulfur produced by reactions involving H2S that was produced by the anaerobic reduction of sulfate in seawater which permeated the peat during post-depositional marine transgressions (the dominant source of sulfur in high-sulfur coals). Sulfur isotopic compositions of low-sulfur coals in Several Tertiary basins of Wyoming are consistent with a plant sulfur source. However, the inverse correlation between content and isotopic composition of sulfur observed in coals from the Powder River Basin suggest some "secondary" additions to these low-sulfur coals. Seveeral Quaternary (freshwater pears which were submerged by sea-Level rises during deglaciation over the past 30 ka have sulfur contents and isotopic compositions similar to high-sulfur coals. Carbon and oxygen isotopic compositions of calcareous coal balls from North America and Europe suggest that (1) the carbonate was derived from variable proportions of oxidized plant matter (typically predominant) and inorganic carbonate, and (2) the carbonate minerals were precipitated from fresh-to-brackish waters. Local geochemical and hydrological conditions were apparently more important than regional depositional environments in controlling the source of carbonate and the development of coal balls.

Jan 1, 1983

By W. J. Kroll

This report is concerned with the many sidelines that were investigated incidental to developing a process to produce ductile Zirconium by members of the staff of the Bureau of Mines laboratory, Albany, Oreg. The results of the main investigation, concerning the production of malleable zirconium by reduction of chloride with fused magnesium under helium, have been described in previous publications. These should be taken as a background to facilitate understanding of this work. Literature on the metallurgy of zirconium has been summarized in a separate publication (2), and references are given in this report only when new publications have to be considered or old ones stressed. Most of the observations described in this report can be applied to the problems involved in making titanium with virtually no change. In general, titanium is easier to reduce than zirconium, since its affinities are lower. Also, its chloride is easier to handle and keep clean because it is a liquid at room temperature.

Jan 1, 1952

By Arthur E. Bruszak, Marcel Vanpée

In many practical combustion systems ignition may occur through contact with hot burned gases . Such a process plays a vital role in flame stabilization on bluff bodies . It is also of importance in the ignition of firedamp by the hot spent gases of explosives used in mines . Also , in the communication of flames through narrow channels , a problem of practical importance in flameproofing electrical equipment , the propagation of the flame is essentially a reignition process in which hot burned gases are the agent of ignition . In the actual ignition problem a great variety of conditions may be visualized . Ignition may occur where pockets of hot gases are surrounded by cold explosive mixtures or where pockets of cold mixture may be surrounded by hot gases . Alternately , a flowing stream of combustible mixture may be initially in contact with another stream of hot combustion products , or a jet of hot gases may flow into a cold quiescent mixture ; the jet may be laminar or turbulent , continuous or discontinuous . The hot gas may also consist of the oxidant ( air for instance ) and the cold combustible pure fuel . This study by the Bureau of Mines is concerned only with ignition produced by a continuous jet of gas ( hot ) flowing into a practically quiescent cold mix- The investigation of ignition by bursts of hot gases or by turbulent jets is outside the scope of this report , and work performed on this phase of the problem has been published elsewhere

Jan 1, 1963