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By G. Mucsi, J. Faitli, K. Bohács

"The authors developed an online tube rheometer to supplement a Netzsch MiniCer (Netzsch GmbH, Germany) stirred media mill in order to monitor online the rheological characteristics of the suspension and therefore the result of grinding during the process. Previously it was demonstrated that the above measuring system was working appropriately based on the preliminary tests. The product related stress model was applied for the evaluation of the grinding results. It was found that the suspension concentration and the change of the material properties during grinding, consequently the rheology strongly affects the grinding result, i.e. specific surface area, median particle size as well as specific grinding energy. The tested model limestone – water suspensions behaved Newtonian initially, then after a given grinding time their properties had changed and they become Bingham plastic. INTRODUCTIONStirred media milling now is a common practice to produce fine and ultrafine granular materials for different purposes. With an increasing demand of ultrafine powders for industries (Kwade, 1999), wet and dry ultrafine grinding has been increasingly used in various fields, such as minerals (Mucsi, Rácz, & Mádai, 2013)(Rácz, 2014), ceramic materials (Becker & Schwedes, 1999), pigments (Ohenoja, Illikainen, & Niinimäki, 2013), chemical products (Baláž et al., 2013), microorganisms (Kwade & Schwedes, 2002) and pharmaceutics (Afolabi, Akinlabi, & Bilgili, 2014). It is well known that suspension rheology affects the wet comminution of materials (He, Wang, & Forssberg, 2006a). The rheological behaviour of the suspension containing the ground particles might indicate the level of interparticle interaction or aggregation and therefore it is an important variable factor of the process control (Muster & Prestidge, 1995). The influence of the rheological behaviour of mineral suspensions on their grindability has attracted more and more interests and attention, especially on ultrafine grinding performance (He, Wang, & Forssberg, 2006b) (Bernhardt et al., 1999). However, there are still many issues concerning the machine and the process for the different applications. When grinding is effective and the particle size range decreases significantly, the circulating suspension is becoming typically non-Newtonian. The changed rheological behaviour and the increasing rheological material parameters can negatively affect the grinding efficiency; therefore it is an important issue. Ultrafine stirred media milling as well as solid-liquid two phase flow have been studied for a long time at the Institute of Raw Materials Preparation and Environmental Processing of the University of Miskolc. Regarding ultrafine grinding the research is focusing on the description of materials’ grindability (energetic aspects) both in wet and dry circumstances (Mucsi et al., 2013; Rácz, 2014). Concerning rheology, the three measuring pipes tube rheometer was developed decades ago (Faitli & Gombköto, 2015). So far many different solid materials from all over the world had been tested in this rheometer (Faitli & Gombköto, 2015). Main aim of these tests was to gain basic data for large scale hydraulic transport applications. Among the many stirred media mills there is a Netzsch MiniCer mill at the Institute. It was reasonable to combine the two fields together, and the goal of the research presented in this paper is to develop an online tube rheometer for the Netzsch mill and to carry out grinding and rheological testing simultaneously."

Jan 1, 2016

By Y. A. Topkaya

In this research work, a process was described for the recovery of copper and zinc in copper converter flue dust from the Black Sea Copper Works' Samsun Smelter Plant. After characterization of a representative flue dust sample, the process included roasting of the flue dust and then leaching in dilute sulfuric acid solution. Roasting time and temperature were studied to determine the optimum roasting conditions. Sulphuric acid concentration, duration, temperature of leaching and solid to liquid ratio were the parameters studied in the bench scale laboratory leaching experiments.

Jan 1, 2007

By B. Hewitt

Murrin Murrin Operations has not had a successful beginning. Numerous reliability and operability issues many of which are the result of design decisions have been addressed through mechanical and operational changes and the CCD circuit is no exception. The decision to install, the installation and the results of the CCD1 rake-lift mechanism and feedw ell dilution system are discussed in this paper. The installation was justified on improved operational robustness and an increase in the in the underflow density of 1% (per cent w/w). At approximately the same time process modifications in the solution neutralisation circuit were implemented and these changes altered the rheology of the slurry reporting to CCD1. Since the modifications to CCD1 and the solution neutralisation circuit, the CCD circuit has averaged a 2% improvement in the circuit underflow density. The CCD1 modification was completed on time and mechanically has performed well. From a risk point of view, the central rake-lift and Turbodil® dilution system add a degree of freedom and robustness to CCD1 operation that has extended the range of operational confidence. In this respect, the modification has been a success and is complementary to solution neutralisation improvements.

Jan 1, 2004

By J. R. Smith

"The Lake Dufault orebodies were discovered by deep surface diamond drilling. When a reasonable amount of outline drilling had been completed, the decision to go into production was made. The fact that shaft sinking, lateral development, the detailing of the orebodies and stope preparation were to be carried out as rapidly as possible necessitated very close scheduling.After a study of varions possible mining methods, an open-stoping system using long-hole blasting was chosen. Diesel-powered Transloaders were selected for the mucking and transportation of ore from the drawpoints to the orepass.At the time of writing, the choice of mining method appears to have been fully justified, although more time will be required to arrive at true operating costs and efficiencies."

Jan 1, 1966

By James Tuer, John R. Goode, Jim Cambon

"Hudson Resources Inc. (Hudson) has defined a major resource of high purity anorthosite (calcium feldspar) assaying about 30% Al2O3 at the White Mountain (Naajat) deposit in Western Greenland. Extensive beneficiation and evaluation testwork has shown that the material can be simply beneficiated to produce a feed material ideal for the production of low-alkali E-glass used for making glass fibre. An offtake agreement is in place with a major US fibreglass manufacturer and, subject to the mine construction schedule, shipments are scheduled for late 2016 or early 2017. In parallel with the E-glass program, Hudson has completed an initial program of metallurgical testwork which shows that the White Mountain anorthosite can be processed by hydro- and pyro-metallurgical processes to yield either smelter-grade alumina (SGA), suitable for conversion to aluminium metal, or a high purity, chemical/specialty-grade alpha-alumina (CGA) commanding a premium price. The process includes dissolution of the anorthosite in hydrochloric acid, HCl sparging to precipitate aluminium chloride hexahydrate (ACH), recycle of the ACH filtrate to leaching with a bleed stream processed for HCl regeneration from CaCl2, and two-stage calcination of the ACH to regenerate HCl and produce SGA and/or CGA. Calcium silicate and amorphous silica are marketable by-products. This paper discusses the White Mountain anorthosite deposit; the process testwork completed to develop production processes for SGA and CGA; production plans, and indicative economics.INTRODUCTIONHudson Resources Inc. (Hudson) holds a 100% interest in the Naajat Exploitation Licence in Western Greenland that cover the White Mountain high-calcic anorthosite deposit. Anorthosite is a calcium aluminosilicate of slightly variable composition but generally containing about 30% Al2O3. The alumina content is similar to that in bauxite and anorthosite has long been studied as a feedstock for the production of alumina. Other potential uses include feedstock for the high-end fiberglass (E-glass) industry and as a filler for use in paint and plastics."

Jan 1, 2016

By Nigel Saunders, Zhanli Guo

"Quench sensitivity of heat-treatable aluminium alloys is closely related to the precipitation process taking place during quenching. Faster cooling results in less precipitation of coarse phases during cooling, leaving more solutes in the solution before ageing. An alloy in such state would be of greater hardening potential as larger amounts of hardening phases may precipitate out during ageing. Hence, to understand the quench sensitivity of an alloy, it is essential to understand its precipitation process. Precipitation is a diffusion-controlled process and the diffusion is made complicated by the so-called quenched-in vacancies. These vacancies form during solution treatment, become “excess” when temperature goes down, and annihilate during the following cooling and ageing treatments, making diffusion now a function of both temperature and time. This paper first investigates the formation and annihilation of quenched-in vacancies and their effect on diffusion. The diffusion affected by quenched-in vacancies is considered in the kinetic models to realise the calculation of TTT/CCT diagrams for aluminium alloys. The calculated CCT diagrams have been used to explain the observed quench sensitivity and age hardening behaviour of various commercial alloys. The transformation from GP zones to other hardening phases during ageing is also discussed.INTRODUCTION The heat treatment of aluminium alloys mainly consists of three stages: a solution treatment at an elevated temperature, quenching from this solution treatment temperature to room temperature, followed by an ageing treatment to allow the precipitation of strengthening phases(Davis, 1993).The following statements generally describes how quench sensitivity is observed in heat-treatable Al-alloys: faster cooling results in,(i) less precipitation of coarse phases formed at high temperature during cooling, (ii) more solutes kept in solution before ageing, and (iii) larger amounts of hardening phases being formed, i.e. a greater hardening potential. Thus, the quench sensitivity of an alloy is closely related to its precipitation kinetics."

Jan 1, 2018

By Tong Gao, Jingyu Qin, Xiangfa Liu, Zengqiang Li, Yaoxian Zhang

"The recycling of aluminum materials is a green industry while Al–Si–Fe is a typical scrap aluminum alloy. The key point of recycling Al–Si–Fe alloys is to separate Al and Fe. A method by introducing Al–Si–Fe alloy into Mg melt has been investigated in this work. A separation layer with gathered Fe–rich and Al–poor Fe3Al0.7Si0.3particleswereobtained at the bottom of the cooled ingot, indicating that ß–Al5FeSi phase evolves to Fe3Al0.7Si0.3,and quantities of Al are released to the upper Mg matrix simultaneously. However, the evolution of Al3Fe by adding binary Al–Fe alloy into Mg melt is different. It is supposed that element Si plays an important role in the phase evolution procedure, thus affects the performance of this method.INTRODUCTIONThe rapid development of aeronautic, automotive and aerospace technologies strongly depends on the consumption of materials while sustainable development is the future direction. Aluminum is a recyclable material and Fe is one of the most common impurities. Fe can be introduced into Al alloys by adding low–purity alloying materials and by using unprotected ferrous crucible, tools, or equipment (Belov, Eskin, & Avxentieva, 2005; Lu& Dahle, 2005).For instance, wear–resistant rings are usually inserted into piston head when producing Al–Si pistons and an infiltration procedure by putting the cast iron rings into Al melt before casting is always essential. As a result, both the re–melting of pistons and the reuse of Al melt for infiltrating rings lead to the enrichment of Fe element, which can be even high to5 wt.%(Viala, Peronnet, Barbeau, Bosselet, & Bouix, 2002).It is widely known that coarse ß–Al5FeSi particles will form in high Fe–contained Al–Si–Fe alloys which is harmful for the mechanical properties. In the past decades, several methods to eliminate the harmful effect of ß–Al5FeSi have been investigated which can be widely referred (Munson, 1967; Lee, Kawamura, Inoue, Cho, & Masumoto, 1997; Suárez–Peña& Asensio–Lozano, 2006; Eidhed, 2008).These methods can be divided into two kinds. One is to aggregate and remove the Fe–rich phase through the methods of centrifugation, gravity filtration or magnetic separation. The other way is modifing the morphology of flake–like ß–Al5FeSi by overheating the melt or adding neutralized elements. However, these traditional methods are rarely used due to respective disadvantages, while the commonly used method in industries is using primary aluminum for dilution. However, only less than 30wt.% of scrap Al can be added into primary Al melt for each melting work while it also results in the decrease of product quality simultaneously(Zhang, Liu, & Liu, 2016)."

Jan 1, 2018

By A. Zarei-Hanzaki, O. Golmahalleh, S. M. H. Hosseini, H. Azizi-Alizamini

The main importance of acicular ferrite microstructures arises from their desired combination of mechanical properties in comparison with the bainite and ferrite-pearlite microstructures. Several factors affect the microstructural transition from bainite microstructure into the acicular ferrite one. As is well established any factor corrupting the prior austenitc grain boundaries nucleation potential, such as the thin layer of allotriomorph ferrite and the austenitc deformation inhomogenities may promote the acicular ferrite formation instead of bainite. Accordingly, this study deals with the effects of the aforementioned features on the acicular ferrite formation in low carbon microalloyed steel. The results indicate that the formation of strain-induced ferrite at the prior austenite grain boundaries accompanied by deformation inhomogenities in the austenite grains change the effectiveness of allotriomorph ferrite on acicular ferrite formation from active to inert one.

Jan 1, 2004

By A. Kozlowski

We present research on cable fault location methods for mines where coal dust and methane explosions are a frequent potential hazard. The methodology and devices for low- and medium voltage cables fault location are well known and applied in classical power distribution networks. They are based on solutions for underground mines with a high risk of explosion. The lack of a safe solution for the location of a fault has contributed to the initiation of a research project by a group of Polish companies. The consortium consists of research institutes (Institute of Innovative Technologies EMAG, Tele and Radio Research Institute, Central Mining Institute GIG-KD ?Barbara?), Silesian University of Technology and a private entrepreneur MARTECH PLUS. Fast and exact determination of fault location is one of the important factors for minimizing power outage time. The lack of technical solutions to obtain measurements in a secure way leads to the use of the methods connected with a high risk of explosion. For example, the application of high energy can lead to arc discharge where there is a fault in insulation, creating the risk of an explosion. Measurements of methane concentration along the analyzed section of the cable reduce the risk; however the shock wave generated by the electric arc may raise coal dust and make an explosive mixture, which is an object of ignition. Low energy methods, like those based on reflection waves, have low sensitivity for high- and medium-resistance faults. This technique has difficulties in joints, which create false echoes. The fundamental problem is to determine the topology of the network using a reflectogram and find anomalies of a different nature ? not only open and short circuit. Included in the scope of the project is an analysis of Polish legal regulations related to fault location and operational work for low- and medium-voltage networks. Two of the methods used on the surface were selected as feasible to implement under explosion hazard conditions. In the process of development of the fault location methodology, installation features characteristic of underground mines were used, namely access to the whole length of a cable. This is the attribute that provides an opportunity to do measurements that are usually not possible for typical surface power nets. To carry out laboratory tests, a dedicated measuring stand with various types of cables was built. The authors describe the principle of operation of the fault locator and the results of the laboratory tests carried out on the cables with built-in damage (prepared for tests). Results of the work will be the basis for the next stage of the project associated with operational analyses of the prototype.

Aug 1, 2013

By W. Gan

The interactions between bitumen and quartz sands in aqueous solutions were studied with the objective of recovering residual bitumen from Athabasca oil sands froth treatment tailings. It was observed that the presence of various multivalent metal cation (Fe3-, Fe2+, Mg2+,Ca2+, etc.) increased the mutual coagulation between quartz particles and oil or bitumen droplets within certain pH ranges. While the increased coagulation was detrimental to the recovery of the bitumen since it lowered the degree of bitumen liberation from sands, this effect could be reduced or eliminated by the addition of organic chemicals such as citric acid, oxalic acid and EDTA. Among these organic chemicals, citric acid was found particularly effective even at very low concentration.

Jan 1, 2006

By J. A. Maritz

"The Hedley and Grant formulation for pillar strength has been widely adopted by the South Africa hard rock mining industry. Today, some forty year later, this formula still provides the foundation for pillar strength calculations when designing for stability and utilising pillars in mine layouts. Various mine specific back analyses were conducted to adjust the equation parameters based on underground observations of failed pillars and comparing to the pillar stresses calculated using numerical models. In all these instances, the influence of shear stresses was ignored. The key to more representative pillar strength estimation is a better understanding of the pillar loading environment.In this paper, special mining cases are evaluated and the existence of shear stresses on the pillar loading environment is illustrated. By revisiting some back analysis data for optimisation of the equation parameters, recommendations were made in respect of the influence of the shear stress component and on how this should be considered in determining the pillar strength.INTRODUCTIONCommon practice on flat dipping, shallow and intermediate depth ore deposits in the South African hard rock and coal mining industry is to exploit the mineral resource using a room-and-pillar layout. The design methodology is mainly based on a Factor of Safety (FoS) approach, where the strength of the pillar is compared to the effective load on the pillar. In these environments, FoS values of 1.6 are applied as it was found to correspond to a probability of failure in coal mines of 0.001. As discussed by Ryder and Jager (2002) page 279: “For lack of anything else more substantial, the figure of 1.6 is generally used in hard rock pillar design in South Africa”. Dependant on the designed purpose of the pillar, the FoS might be selected as high as 2.0 where long term stability is required. The factors directly influencing the FoS include the pillar height (which is linked to the mining height), effective pillar width, a rock-strength factor and extraction ratio."

Jan 1, 2015

By Ning Yu

There are about 1.341 trillion tons (t) of proven coal reserves in China, of which 279.58 billion t are available for mine well construction basis. Thick coal seams are 44% of the reserves. The production of thick coal seams exploitation is over 45% of the total coal production. Full-seam mining and fully-mechanized mining for large mining height is the technology development direction of thick and extra thick seam mining. It is also the important way to achieve efficient and intensive mining with the characteristics of high production, high mechanization, high efficiency and low energy consumption, etc. Complete set of technology and equipment of fully-mechanized top caving for large mining height of full-seam (7m) mining and extra thick seam ( 14-20m) has been gradually mature and for demonstration application by the joint research of government, enterprises, universities, scientific research organizations and users. It has solved some technical problems of coal face for large mining height (over 7m) such as the coal wall spalling control, stability of support, wall rock coupling, cooperation work of mining and caving, full roadway support for super large section, end support, equipment matching of coal shearers, hydraulic support and scraper conveyor. It has developed key equipments including powerful hydraulic support of fully-mechanized mining and fully-mechanized top caving for large mining height, electrically-driven coal shearer with high speed and reliability, scraper and belt conveyer with big capacity, soft-start and high reliability, automatic control system of coal face with the core of electric-hydraulic control, bolting drill boom large section coal roadway shearer, heavy auxiliary transport equipment. The operation rates of fully-mechanized top caving equipment for full-seam and large mining height are 94% and 92.1%, and recovery ratios are 93.6% and 88.9% respectively. The annual raw coal production of single work face is over 10 Mt. The automation and intelligentization level have been clearly improved. The exploitation of thick and extra thick coal seam that is safe and efficient has been achieved in China.

Aug 1, 2013

By J. C. Kurnia

Presence of fine dust in air causes serious health hazard for mine operators resulting in such serious problems as coal workers? pneumoconiosis and silicosis. Major sources of dust appear of course along the mining face where the minerals are extracted. Proper control and management are required to ensure safe working environment in the mine. Presented here is the use of a computational fluid dynamic (CFD) approach to investigate the flow and dust behaviour in mining tunnels. The objective of this study is to propose and examine various strategies to mitigate dust dispersion from the mining face and reduce dust concentration to a safe level for the operator. In a companion study, the authors investigated various methods for mitigating dust dispersion from the mining face to ensure safe dust concentration levels in the mine tunnel. Among the examined methods, implementation of brattice to direct the flow from the main airway to the mining face is the most effective method to disperse dust particles away from the mining face. The installation of brattice, however, will limit the movement of mine operators and vehicles in the tunnel. Hence, application of a hybrid brattice which is a combination of a physical brattice along with suitable directed and located air curtains is proposed and examined. Based on the CFD simulation results, over a range of parameters of interest, it was found that the physical brattice blocks the ventilation air and directs it to the mine face while an air curtain located along the brattice outlet offers flexibility in keeping the dust away from the operator allowing more freedom for the operator and the equipment. Results of the modelling over a range of parameters of interest are presented and discussed with the goal of managing dust concentrations within safe limits for the operator.

Aug 1, 2013

By J. Shibata, N. Murayama

"Rare earth elements are present in more than 100 minerals, of which monazite, bastnaesite and xenotime are typical. Rare earth elements have excellent chemical and physical properties for industrial use in functional materials such as phosphors, magnets, electronic components, abrasives and catalysts. China produces more than 90 % of the world’s rare earths, and Chinese trends significantly influence the demand and price of rare earths. From the viewpoint of resource securement, it is desirable to separate and recover rare earth elements from low-grade resources and wastes. Phosphate gypsum, which is a by-product of wet phosphoric acid manufacturing, contains low concentrations of rare earth elements. In this research, the separation and recovery of rare earth elements from phosphate gypsum were investigated. A series of recovery methods including washing of phosphate gypsum, leaching of the rare earth elements with sulfuric acid, adsorption and desorption of rare earth elements by using ion-exchange resin, and precipitation of rare earth oxalates were carried out. The separation of rare earth elements from Ca2+ simultaneously leached from phosphate gypsum was also investigated."

Jan 1, 2014

By C. Cortés

Flotation is a highly interactive process where a change or disturbance in any part of the circuit results in different final grades and recoveries. This high variability of the circuit metallurgical performance complicates the diagnosis of the scavenger stage at the end of the line, as copper losses in the final tailings are erratic and not totally a consequence of problems in the scavenger section. The assessment of the scavenger performance requires a more elaborated procedure than that used for others stages of the circuit. This communication describes the application of an approach that combines results of laboratory flotation tests with those of surveys performed at the plant. The approach is based on running surveys in one of the circuit lines to collect samples for determining grade vs. recovery curves for total mass and size-by-size fractions. Full mineralogical and liberation analyses are also considered on some samples of the feed and tailings streams selected to have a range of feed grades. A separate sample of the feed is used to run laboratory flotation tests to determine optimum flotation time. Two additional pieces of information are the effect of operating variables on recovery, determined through a test program based on design of experiment techniques, and operational data on every cell in the line gathered by visual observation. The application of this approach to one of the scavenger lines at Los Colorados concentrator (Minera Escondida, BHP Billiton) is demonstrated.

Jan 1, 2007

By Youngsoo Song, Hyunjung Kim, Junhyun Choi, Siyoung Q. Choi, Gahee Kim

In this study, for the first time, to confirm the effect of bacterial growth phase on the malachite flotation were investigated in a well-controlled Hallimond tube system. The test results showed that the bacteria in the stationary phase exhibit two-fold greater floatability than those in mid-exponential phase. To understand the observed flotation behavior, complementary cell characterization tests and cell attachment tests were conducted. Interestingly, the bacteria at both phases exhibited similar surface properties as well as almost identical amount of cells attached onto the malachite, suggesting that the growth phasedependent flotation behavior cannot be attributed to the variation of cell surface properties and the extent of cell adsorption. On the other hand, cell detachment tests revealed that the amount of cells detached from the malachite surface is greater for the mid-exponential phase than the stationary phase due to the higher fluid drag applied to the cells at the mid-exponential phase, which was explained by the differences in the size and shape of attached bacteria onto the malachite surface. These morphological characteristics were found to cause the bacteria of mid-exponential phase to be separated highly sensitive and easy from malachite surface due to the fluid flow. Second, scale-up selective bioflotation tests were carried out in a 1 L Denver cell in malachite–silica binary mixture systems. Through the tests, we optimized the cell concentration and the malachite fraction in the feed. Overall, high malachite selectively was observed under optimized conditions (both recovery and grade showed more than 90%). The trend was in agreement with classical DLVO interaction energy profiles, which show the relative magnitudes of the adhesive forces between the mineral and the attached cell under equal hydrodynamic conditions.

Jan 1, 2016

By M. Fall

The progressive depletion of ore available at shallow depths in several underground mines around the world means that underground mining operations would increasingly be carried out at greater depths and therefore at higher temperatures. However, our understanding of the effect of hot temperatures on the response (mechanical, economical, environmental) of cemented paste backfill (CPB) is still limited. Hence, an extensive laboratory investigation was conducted to study the performance of young and aged CPB, in response to deep mine temperatures. Several CPB samples with different compositions, cured at different temperatures (20 to 50°C) and different times (7 to 160 days) were tested regarding their mechanical properties, economical performance (binder consumption) and microstructural properties. The results show that hot temperatures significantly affect the performance properties of CPB at young and advanced ages. An increase in the curing temperature leads to a considerable improvement of the rate of gain of CPB strength and also to a significant increase of the strength of CPBs studied. CBP samples cured at hot temperatures show lower binder consumption and finer pore structure. Results of this study could serve as background information for the development of optimal mine backfill design procedures.

May 1, 2007

By G. Ergin

The interactions taking place between Al-Mg alloys and the bed media during aluminum filtration are not yet well understood. These interactions were studied using the infiltration technique. The reaction interface was analyzed using different techniques such as SEM and TEM. Only spinel formation was observed at the interface regardless of the type of alumina and contact time. This paper discusses the results of the study.

Jan 1, 2004

By D. Kovachevich, M. A. Pfeifer

"A t remote locations typical of mines and associated ore processing plants, diesel electric generators are ideally suited for power plants due to their inherent operating flexibility, efficiency and reliability. In recent years rapid escalation in fuel and related transportation costs has made extensive waste heat recovery from generating sets financially attractive to a much greater extent than previously.The paper outlines key considerations during planning and design stages for utilizing the various waste heat sources available to best advantage. Based on two /980 mining projects built in the Canadian Arctic, data is presented on potential operating and capital costs savings. A review of heat balances, engineering flow diagrams and major equipment selections for process and building heating systems utilizing waste heat is included.IntroductionResource projects increasingly occur in remote areas requiring on-site self sufficiency in electrical power generation. For such projects, the low- or medium-speed turbo-charged diesel engine is very often the preferred choice as a prime mover for the generating sets . It is inherently reliable, has good response to load changes and has comparatively high fuel efficiency over a wide load range . From a project execution standpoint, It is capital cost- competitive and procurement lead-time normally ' fits ' within tight schedule constraints. In addition, its potential for waste heat recovery is excellent , particularly in northern climates where space heating requirements are usually substantial, and also where there a re requirements for heat for process and plant services.The high cost of fuel , with add-on transportation costs , provides a major incentive to fully exploit the available waste heat recovery potential o f such installations.As a result of the rapid escalation in the price of petroleum products following major crude oil price increases in 1973 and again in 1978-79, liquid petroleum fuels, having the desirable properties of comparatively high heat content and transportability, are no longer 'cheap' commodities and have become so valuable that industry has widely undertaken serious conservation efforts.Currently, it appears that petroleum cost trends of the 1970s may not continue, at least in the near term, and that we may see somewhat reduced energy costs for a time. In the longer term , and certainly within the life spa n of major projects, however, it is generally believed to be inevitable that these fuels will be increasingly expensive . Energy costs are today a major operating cost for remote minerals processing plants and will remain so for the foreseeable future.In order to meet the economic challenge posed by high energy costs, future projects should be thoughtfully planned from the outset with the goal of minimizing energy requirements and maximizing the use of waste heat recovery to meet such requirements. There is also considerable potential for significant energy savings by retrofitting of existing installations."

Jan 1, 1984

By D. Perednis

Fuel cells with thin samaria-doped ceria (SDC) electrolyte films deposited onto an anode support using spray pyrolysis were fabricated. The SDC films were deposited onto porous NiO-YSZ substrates at deposition temperatures between 400°C and 450°C. The influence of process parameters such as deposition temperature, flow rate, type of salt and salt concentration on the quality of the film was studied. A smooth dense film was successfully deposited using the precursor cerium ammonium nitrate and samarium nitrate dissolved in butyl carbitol (33.3 vol.%), 2-methoxy-l-propanol (33.3 vol.%), and ethanol (33.3 vol.%) solvent mixture. A deposition rate of 125 nm/h was achieved.

Jan 1, 2005